天然金红石光催化降解藏红T实验研究

以低压汞灯为光源研究了天然金红石悬浆体系中藏红T的脱色条件及其光催化反应动力学，讨论了溶液初始pH值、催化剂投入量、光强、气流量、催化剂粒径、反应气氛等实验条件对藏红T脱色速率的影响，阐述了实验过程中无机离子的生成情况。结果表明，该反应基本上符合一级反应动力学；在酸性条件下尤其是当溶液初始pH值为2．5时，藏红T的脱色速率要比在碱性和中性条件下快得多；增加光强度能较大地提高反应的降解速率；催化剂最佳投入量为1．3g／L；在氧化气氛下该反应比在非氧化气氛快得多；通入气体的流量在40L／h最合适；反应溶液中有氯离子溶出说明有机物中的含氯部分被降解。本研究为光催化作用降解有机污染物提供了新的途径。     

贵州某机场的主要工程地质问题分析及其处理措施建议

贵州某机场为山区高填方机场，最大填方高度近60m，场址沟谷发育，基底为软硬交替的、顺倾向岩层的斜坡地区，笔者就该机场的主要工程地质问题一边坡稳定问题、沉降问题、地表水和地下水的排泄问题进行了不同程度的研究并提出了相应的处理措施。     

大风垭口公路隧道施工中的地质灾害及对策

公路隧道的施工过程经常会碰到地质灾害，本文结合云南元磨高速公路在建特长隧道-大风垭口隧道中出现的洞口滑坡、涌水、塌方、突泥等问题，多角度论述了产生的因素以及应对措施，希望能为今后在类似地质条件下，公路隧道的勘查、设计以及施工提供借鉴和帮助。     

天然含钒金红石加热、淬火及电子辐射改性实验研究

天然含钒金红石样品经过1273K加热、淬火和高能电子辐照处理后性质发生不同程度的变化。XRD谱峰显示处理前后样品没有发生物相变化，显微IR图谱证明原样、加热、淬火样品的表面有少量吸附水存在，而辐射样品的显微IR图谱上没有检测到吸附水的吸收峰。用XPS分析比较了处理前后样品表面主要元素Ti、O和V的价态及含量，结果表明，原样经过处理后表面钒和氧的原子百分含量增加，其中淬火样品表面吸附水和钒的含量相对于原样增加最为明显，光催化活性相应较高；加热样品表面的吸附水和钒的含量比原样稍有增加，光催化活性与原样相当；电子辐射样品表面钒的原子百分含量相对原样增加不明显，而对水的吸附能力相对原样较低，光催化效率也略低。     

碳酸盐岩与泥质烃源岩生气规律对比研究

配制了两套成熟度相近的碳酸盐岩和泥质岩丰度系列样品。采用半封闭外加温加压式热压模拟装置对碳酸盐岩的生烃情况进行了热模拟实验，研究了碳酸盐岩生气量随成熟度和温度变化的趋势，探讨了碳酸盐岩生气的变化规律。碳酸盐岩与泥质岩的生烃潜力是有机质质量和有机质丰度的函数，与岩性无关；碳酸盐岩的产气规律与泥质岩相似，而且两者产烃的量级也相当，并不存在碳酸盐岩生排烃效率高的现象；碳酸盐岩和泥质岩总有机碳(TOC)含量在热模拟过程中基本上不发生变化；不同岩性的有机质的产烃效率主要受温度和有机质类型决定。     

东营凹陷地下水动力场的形成与演化

沉积盆地地下水动力场的理想模式可以归纳为对称型和不对称型两种,其中局部地下水动力单元可以划分为泥岩压榨水离心流,大气水下渗向心流,越流、越流蒸发泄水和滞流4种类型。地下水动力场的演化具有旋回性,每个旋回可以分为两个阶段:盆地沉降沉积时期的泥岩压榨水离心流阶段和盆地抬升剥蚀时期的大气水下渗向心流阶段。随沉积盆地的形成与演化,水动力场也有形成、发展和消亡的过程。东营凹陷地下水动力场在平面上呈对称性:总体上大气水由凹陷边缘向凹陷中心渗入,凹陷内部各洼陷为压榨水形成的离心流区,凹陷边缘南部斜坡带和北部断阶带以及凹陷内部中央断裂带为越流泄水区。纵向上,局部水动力单元强度及演化规律与地层的埋藏深度有关。随着埋藏深度的增加,水动力单元强度逐渐减弱。     

La vallée d'Ys : un paléoréseau hydrographique immergé en baie de Douarnenez (Finistère,France)

Interpretation of the recent high-resolution survey, CANADOU 2000, in the Bay of Douarnenez (Finistère, France) allowed us to restore the morphology of the substratum and the sedimentary filling of the bay. The Brioverian and Palaeozoic substratum reveals a well-defined network of incised valleys as results of successive emergence stages of the Bay during the Quaternary. Valleys join in a westward-widened mean valley, called Ys Valley. The present-day sedimentary fill of the bay of Douarnenez appears mainly controlled by the Holocene rise and the consecutive highstand. It comprises fluvial and estuarine deposits filling up incised valleys and marine sedimentation extending out of the incised valleys. To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).     

Magnetic activity inside the auroral zones and field-aligned currents

Big perturbations of the magnetic field (amplitudes larger than 250 nT) are simply detected by subtracting the values of a model from the measurements of CHAMP satellite. Taking a full year of CHAMP data and organizing them in four subsets of three months length (spring, summer, autumn, winter), it is found that: (a) the two domains where such big perturbations mainly exist are limited, in both hemispheres, by a parallel of high latitude of the corrected geomagnetic coordinates system; (b) a conspicuous seasonal (annual) variation affects the density of the perturbations and is opposite in the two hemispheres. We hold that these perturbations are linked to the midday magnetic activity within the auroral zone, long ago described by one of us (Mayaud, 1956). The source of the perturbations observed at the satellite altitude would be field-aligned currents resulting from the penetration of the solar wind into the magnetospheric cusps. To cite this article: J.-L. Le Mouël et al., C. R. Geoscience 335 (2003).     

Effect of the chemical composition of the crust on the metamorphic evolution of orogenic wedges

Petrological data provide a good record of the thermal structure of deeply eroded orogens, and, in principle, might be used to relate the metamorphic structure of an orogen to its deformational history. In this paper, we present two‐dimensional thermal modelling of various subduction models taking into account varying wedge geometry as well as variation of density and topography with metamorphic reactions. The models clearly show that rock type accreted in the wedge has important effects on the thermal regime of orogenic wedges. The thermal regime is dominated by radiogenic heat production. Material having high radioactive heat production, like the granodioritic upper crust, produces high temperature metamorphism (amphibolitic conditions). Material with low radioactive heat production results in low temperature metamorphism of greenschist or blueschist types depending on the thickness of the wedge. Application of this model to seemingly unrelated areas of the Central Alps (Lepontine Dome, Grisons) and Eastern Alps (Tauern Window) explains the coexistence and succession of distinct Barrovian and blueschist facies metamorphic conditions as the result of a single, continuous tectonic process in which the main difference is the composition of the incoming material in the orogenic wedge. Accretion of the European upper continental crust in the Lepontine and Tauern Domes produces Barrovian type metamorphism while accretion of oceanic sediments results in blueschist facies metamorphism in the Valaisan domain.     

成像光谱仪影像的几种处理方法

针对成像光谱仪影像的专题分析，介绍了沿用常规遥感影像分析方法时的原理和新的算法，提出了影像融合方法的应用，说明了这些方法在学术思想上的归属，并简要介绍了各种方法的实验效果。