Heavy metals behavior in coastal sediments of southern California: a critical review and synthesis

The present paper reviews and discusses the studies on heavy metals behavior in coastal sediments of southern California which have been published since 1970.The available data allow for the estimation of pollution-free ‘base-line’ concentrations of some heavy metals in southern California sediments (Ag, 0.4 ppm; Cd, 0.4 ppm; Cr, 25 ppm; Cu, 9 ppm; Ni, 15 ppm; Pb, 10 ppm; and Zn, 44 ppm) which may be used as references for monitoring future metal pollution.The transport of most, if not all, heavy metals through the near-shore and shelf environments is controlled by their association with particles, a significant fraction of which is sewage-derived and rich in organic carbon. Changes in the relative abundances of the heavy metals are brought about mainly by settling differentiation of their host particles, and much less so by diagenetic solubilization. The bulk of the heavy metals are transported, within fine-grained particles, out from the shelf into deep ocean regions.Simple linear mixing of polluted outfall materials with clean natural sediments cannot explain the distribution of heavy metals in near-shore and basinal sediments in southern California, unless significant protective effects of organic coatings (near outfalls) and of grain-size distributions are taken into account. Heavy metal pollution from oil seepages are significant for only a very limited number of metals (Ni, Ba, etc.) and only on a local scale.The urgent need for standardization of heavy metal leaching techniques is demonstrated and emphasized.     

Stable isotope composition of dissolved sulfate and hydrogen sulfide in the Black Sea

The stable isotope ratio of sulfur (³⁴S/³²S) in dissolved sulfate and hydrogen sulfide was measured for 20 water samples from two deep hydrocasts from the south-central Black Sea. The isotope ratio of total reduced sulfur was also measured for surface sediment collected below each hydrocast. The range in the δ³⁴S measurements for sulfate was +18.20 to $\text{+20.17‰}$ and for hydrogen sulfide ?38.71 to $\text{?4.85‰}$. The distribution pattern for δ ³⁴S in both sulfate and sulfide appears to be the result of in situ sulfate reduction.     

Characterizing the severe turbulence environments associated with commercial aviation accidents. Part 2: Hydrostatic mesoscale numerical simulations of supergradient wind flow and streamwise ageostrophic frontogenesis

Summary Simulation experiments reveal key processes that organize a hydrostatic environment conducive to severe turbulence. The paradigm requires the juxtaposition of the entrance region of a curved jet streak, which is highly subgeostrophic, with the entrance region of a straight jet streak, which is highly supergeostrophic. The wind and mass fields become misphased as the entrance regions converge, resulting in significant spatial variation of inertial forcing, centripetal forcing, as well as along and cross-stream pressure gradient forcing over a meso- scale region. Maxima of these forces are misphased where the two dissimilar jet streaks converge and geostrophic balance is disrupted. Velocity divergence within the subgeostrophic region of largest upstream-directed pressure gradient force and velocity convergence near the region of largest downstream-directed centripetal/inertial-advective forcing act to produce a mesoscale front due to spatially varying confluent flow flanked by zones of increasing velocity divergence. This results in frontogenesis as well as the along-stream divergence of cyclonic and convergence of cyclonic ageostrophic vertical vorticity. The nonuniform centripetally forced mesoscale front becomes the locus of large gradients of ageostrophic vertical vorticity along an overturning isentrope. This region becomes favorable for streamwise vorticity gradient formation enhancing the environment for the organization of horizontal vortex tubes in the presence of buoyant forcing. This is because the mesoscale convergence of vertical vorticity on an overturning isentropic surface creates vertical rotation for the development of horizontal vorticity in regions where isentropic surfaces overturn. Vorticity, shear, and buoyancy are focused in one location by this front thus favoring an environment favorable for microvortex formation leading to turbulence.     

Panoptic geographies: an examination of all U.S. geographic dissertations

The study of geography as a discipline has often employed a top‐down approach that examines the output of the field's most prominent members. In this paper, we provide a bottom‐up approach by analyzing geography dissertations. We start by assembling a database that includes the title, author, date, and university for every geographic doctoral dissertation written in the United States over the last 120 years. The database allows us to track the rise and fall of regions of interest and specific topics. It gives a broad overview of the different schools in geography and their influence within separate historical periods. And it permits a more empirically based delineation of geographical “eras” based on the commonality of words in dissertation titles. This work is at the convergence of the quantitative and qualitative; we quantify and visualize textual data to provide a more robust history of geography. The result is a new, more comprehensive way to look at the changing discipline of geography.