Late Quaternary glacial–interglacial variations in sediment supply in the southern Drake Passage

Geochemical characteristics of marine sediment from the southern Drake Passage were analyzed to reconstruct variations in sediment provenance and transport paths during the late Quaternary. The 5.95 m gravity core used in this study records paleoenvironmental changes during the last approximately 600 ka. Down-core variations in trace element, rare earth element, and Nd and Sr isotopic compositions reveal that sediment provenance varied according to glacial cycles. During glacial periods, detrital sediments in the southern Drake Passage were mostly derived from the nearby South Shetland Islands and shelf sediments. In contrast, interglacial sediments are composed of mixed sediments, derived from both West Antarctica and East Antarctica. The East Antarctic provenance of the interglacial sediments was inferred to be the Weddell Sea region. Sediment input from the Weddell Sea was reduced during glacial periods by extensive ice sheets and weakened current from the Weddell Sea. Sediment supply from the Weddell Sea increased during interglacial periods, especially those with higher warmth such as MIS 5, 9, and 11. This suggests that the influence of deep water from the Weddell Sea increases during interglacial periods and decreases during glacial periods, with the degree of influence increasing as interglacial intensity increases.     

A redetermination of the isotopic abundances of atmospheric Ar

Atmospheric argon measured on a dynamically operated mass spectrometer with an ion source magnet, indicated systematically larger ⁴⁰Ar/³⁶Ar ratios compared to the generally accepted value of Nier [Nier A.O., 1950. A redetermination of the relative abundances of the isotopes of carbon, nitrogen, oxygen, argon, and potassium. Phys. Rev. 77, 789-793], 295.5 ± 0.5, which has served as the standard for all isotopic measurements in geochemistry and cosmochemistry. Gravimetrically prepared mixtures of highly enriched ³⁶Ar and ⁴⁰Ar were utilized to redetermine the isotopic abundances of atmospheric Ar, using a dynamically operated isotope ratio mass spectrometer with minor modifications and special gas handling techniques to avoid fractionation. A new ratio ⁴⁰Ar/³⁶Ar = 298.56 ± 0.31 was obtained with a precision of 0.1%, approximately 1% higher than the previously accepted value. Combined with the ³⁸Ar/³⁶Ar (0.1885 ± 0.0003) measured with a VG5400 noble gas mass spectrometer in static operation, the percent abundances of ³⁶Ar, ³⁸Ar, and ⁴⁰Ar were determined to be 0.3336 ± 0.0004, 0.0629 ± 0.0001, and 99.6035 ± 0.0004, respectively. We calculate an atomic mass of Ar of 39.9478 ± 0.0002. Accurate Ar isotopic abundances are relevant in numerous applications, as the calibration of the mass spectrometer discrimination.     

Effects of BPA and DES on longchin goby (Chasmichthys dolichognathus) in vitro during the oocyte maturation

This study was performed in order to assess whether bisphenol (BPA) and diethylstilbestrol (DES) had agonistic or antagonistic effects on oocyte maturation using marine fish. We tested the effects of these chemicals on in vitro maturation, germinal vesicle breakdown (GVBD), assay using oocytes from the longchin goby, Chasmichthys dolichognathus. During the maturation process, low concentrations of BPA and DES triggered GVBD depending on the stage of oocyte development; BPA at 0.044 nM and DES at 0.037, 0.37, and 3.73 nM induced GVBD in 0.82-0.88 mm diameter oocytes (germinal vesicle located near the center of oocytes). In 0.76-0.80 mm diameter oocytes (fully vitellogenic oocytes), BPA induced GVBD at relatively higher concentrations (4.38, 43.8, and 438 nM). In 0.86-0.90 mm diameter oocytes, BPA and DES had no observable effect on GVBD at the concentrations tested. Oocytes with diameters between 0.82 and 0.88 mm appeared to be more sensitive to these chemicals. Moreover, our results showed that BPA and DES did not inhibit GVBD.     

A ground validation problem of remotely sensed soil moisture data

 As the use of space-based sensors to observe soil moisture is becoming more plausible, it is becoming necessary to validate the remotely sensed soil moisture retrieval algorithms. In this paper, measurements of point gauges on the ground are analyzed as a possible ground-truth source for the comparison with remotely sensed data. The design compares a sequence of measurements taken on the ground and from space. The authors review the mean square error of expected differences between the two systems by Ha and North (1994), which is applied to the Little Washita watershed using the soil moisture dynamics model developed by Entekhabi and Rodriguez-Iturbe (1994). The model parameters estimated by Yoo and Shin (1998) for the Washita `92 (relative) soil moisture data are used in this study. By considering about 20 pairs of ground- and space-based measure-ments (especially, for the same case as the Washita `92 that the space-based sensor visits the FOV once a day), the expected error was able to be reduced to approximately 10 of the standard deviation of the fluctuations of the system alone. This seems to be an acceptable level of tolerance for identifying biases in the retrieval algorithms.     

Site-specific prediction of West Nile virus mosquito abundance in Greater Toronto Area using generalized linear mixed models

Mosquito surveillance programs provide a primary means of understanding mosquito vector population dynamics for the risk assessment of human exposure to West Nile virus (WNv). The lack of spatial coverage and missing observations in mosquito surveillance data often challenge our efforts to predict this vector-borne disease and implement control measures. We developed a WNv mosquito abundance prediction model in which local meteorological and environmental data were synthesized with entomological data in a generalized linear mixed modeling framework. The discrete nature of mosquito surveillance data is accommodated by a Poisson distributional assumption, and the site-specific random effects of the generalized linear mixed model (GLMM) capture any fluctuation unexplained by a general trend. The proposed Poisson GLMMs efficiently account for the nested structure of mosquito surveillance data and incorporate the temporal correlation between observations obtained at each trap by a first-order autoregressive model. In the case study, Bayesian inference of the proposed models is illustrated using a subset of mosquito surveillance data in the Greater Toronto Area. The relevance of the proposed GLMM tailored to WNv mosquito surveillance data is highlighted by the comparison of model performance in the presence of inevitable but quantifiable uncertainties.     

Contribution of the east�Cwest thermal heating contrast to the South Asian Monsoon and consequences for its variability

The focus of this paper is to assess the relative role of the north?Csouth and east?Cwest contrasts in atmospheric heating for the maintenance of the South Asian summer monsoon climatology. The juxtaposition of the Eurasian land mass and the Indian Ocean is responsible for the north?Csouth contrast, while the greater diabatic heating above the western Pacific compared to the one over the African and the tropical South Atlantic Ocean region introduces the east?Cwest gradient. With a series of idealized atmospheric general circulation model experiments, it is found that both contrasts contribute to the maintenance of the South Asian monsoon climatology, but their impact varies at regional scales. The surface atmospheric cyclone and precipitation over northern India are mainly due to the north?Csouth contrast. On the other hand, when the Indian Ocean sea surface temperatures are close to their climatological mean values, the low-level cyclone and consequent rainfall activity in the Bay of Bengal and southern India result from the east?Cwest gradient. The physical mechanism relays on the southern part of the upper-level South Asian monsoon high being forced by the east?Cwest diabatic heating contrast via Sverdrup balance. The east?Cwest heating difference controls also the strength of the Tropical Easterly Jet. Finally, the contribution of the El Ni?o Southern Oscillation to the interannual variability of the Indian monsoon is interpreted as the result of a longitudinal shift of one of the centers of diabatic heating contributing to the east?Cwest contrast.     

Feasibility of red mud neutralization with seawater using Taguchi’s methodology

In this study, feasibility of using seawater to neutralize alkaline red mud for its safe disposal has been studied using Taguchi’s design of experimental methodology. Parameters such as weight of red mud, volume of seawater, stirring time and temperature were tested at three levels to study their effect on response characteristic, i.e., pH of the neutralized slurry. The analysis of variance showed that volume of seawater added and quantity of red mud are the two significant parameters with 53.59 and 44.92 % contribution each, respectively. Under the optimized parameters, pH value of red mud slurry reaches to about 8.0 which is within disposable limits. When seawater or other Ca- and Mg-rich brines are added to caustic red mud, the pH of the mixture is reduced causing hydroxide, carbonate or hydroxy carbonate minerals to be precipitated. This mechanism of neutralization process has been explained with emphasis on chemical analysis, mineralogy and morphology of the neutralized red mud. The process improved the physical characteristics of red mud with entrained liquor becoming non-hazardous water with reduced alkalinity. The results would be extremely useful in the process of safe disposal of red mud.     

Cloud vertical distribution from radiosonde,remote sensing,and model simulations

Knowledge of cloud vertical structure is important for meteorological and climate studies due to the impact of clouds on both the Earth’s radiation budget and atmospheric adiabatic heating. Yet it is among the most difficult quantities to observe. In this study, we develop a long-term (10 years) radiosonde-based cloud profile product over the Southern Great Plains and along with ground-based and space-borne remote sensing products, use it to evaluate cloud layer distributions simulated by the National Centers for Environmental Prediction global forecast system (GFS) model. The primary objective of this study is to identify advantages and limitations associated with different cloud layer detection methods and model simulations. Cloud occurrence frequencies are evaluated on monthly, annual, and seasonal scales. Cloud vertical distributions from all datasets are bimodal with a lower peak located in the boundary layer and an upper peak located in the high troposphere. In general, radiosonde low-level cloud retrievals bear close resemblance to the ground-based remote sensing product in terms of their variability and gross spatial patterns. The ground-based remote sensing approach tends to underestimate high clouds relative to the radiosonde-based estimation and satellite products which tend to underestimate low clouds. As such, caution must be exercised to use any single product. Overall, the GFS model simulates less low-level and more high-level clouds than observations. In terms of total cloud cover, GFS model simulations agree fairly well with the ground-based remote sensing product. A large wet bias is revealed in GFS-simulated relative humidity fields at high levels in the atmosphere.     

Tropical Cyclogenesis in the Intra-Americas Sea: Hurricane Cindy (2005)

The tropical cyclogenesis (TCG) of Atlantic Hurricane Cindy (2005) was investigated to study environmental conditions preceding mesoscale vortex development in the Intra-Americas Sea (IAS; i.e., the Gulf of Mexico and Caribbean Sea) using the ERA-Interim Reanalysis pressure level data. Major findings include that the development of a mesoscale vortex occurred downward over Central America due to 600 hPa level enhanced winds downstream of southeasterly winds from northern South America, triggering Cindy's TCG in a few days. The contribution of midlevel enhanced winds should be noted as a potential precursor of other TCGs in the IAS.