Role of the Land Plume in the Transport of Ozone Over the Ocean During Indoex (1999)

Observations from aircraft, an island station, and tworesearch vessels are used to investigate the development of an elevated mixed layeror land plume over the Arabian sea during the Indian Ocean Experiment Intensive FieldPhase 1999 (INDOEX) through air mass modification. Much of the transport of aerosolsand gases occurs in this plume located above a well-mixed convective marine boundary layerwith a depth of 800–1000 m. The depth of the land plume isapproximately 2000 m with the peak ozone concentrations occurring near the centre of this land plume.Significant latitudinal variations in the concentration of ozone occur in the marineboundary layer and in the plume. Mean ozone concentrations in the land plume decreasedwith distance from the Indian coastline.     

Development and propagation of a pollution gradient in the marine boundary layer during INDOEX (1999)

The development and propagation of a pollution gradient in the marine boundary layer over the Arabian Sea during the Intensive Field Phase of the Indian Ocean Experiment (1999) is investigated. A hypothesis for the generation of the pollution gradient is presented. Infrared satellite images show the formation of the pollution gradient as the leading edge of a polluted air mass in the marine boundary layer and also its propagation over the Arabian Sea and the northern Indian Ocean. Aerosol data measured from two research vessels over the Arabian Sea show a variation in the concentrations caused by the passage of this pollution gradient. Depth of the pollution gradient was found to be about 800 m. A numerical model was used to simulate the development of this gradient and its propagation over the ocean. Results show that its formation and structure are significantly influenced by the diurnal cycle of coastal sea-land breeze circulations along India’s west coast. Transport of aerosols and gases over the Arabian Sea in the lower troposphere from land sources appears to be through this mechanism with the other being the elevated land plume.     

An unusual fluvial to tidal transition in the mesoarchean Moodies Group, South Africa: A response to high tidal range and active tectonics

The Moodies Group in the Dycedale Syncline, Barberton Greenstone Belt consists of a 100–130 m-thick upward-fining succession that exhibits a transition from fluvial to tide-modified sedimentation. A basal, 10–30 m-thick conglomerate–sandstone interval of alluvial origin is overlain by stacked upward-fining, decimeter- to meter-scale cycles within which three facies are recognized: 1) conglomerate lag; 2) cross-bedded sandstone; and 3) interlaminated sandstone–siltstone and mudstone. Within the cycles, the abundance of mudstone drapes increases upwards. Structureless conglomerates and cross-beds lacking mudstone drapes record braided-alluvial processes. In contrast, cross-beds with mudstone drapes and interlaminated sandstone–siltstone and mudstone are products of flows modified by various tidal beats. Sand and/or silt transport took place during the ebb and flood stages and mudstone accumulated during slack water phases. Alternating thick–thin laminations reflect dominant and subordinate, twice-daily tides. Thicker groupings of foresets and thicker intervals of vertically stacked sandstone–siltstone and mudstone laminations are interpreted as spring tide deposits whereas thinner groupings of foresets and thinner laminations record neap tides. Desiccated mudstone drapes on foresets indicate that bedforms rarely were locally exposed during some portion of the tidal cycle. Abundant exposure structures in the interlaminated sandstone–siltstone and mudstone facies indicate that the cycles are upward shoaling. The stacked upward-fining cycles are attributed to alternating subaerial exposure and fluvial influx followed by marine inundation, probably related to absolute sea level fluctuations. Lack of high-order vegetation on the Archean landscape promoted rapid lateral migration or avulsion of tidally influenced fluvial channels.

The association of facies within the 100–130 m-thick upward-fining succession is comparable to Holocene and ancient paleovalley fills characterized by basal alluvial gradational upwards into estuarine facies. However, in the absence of vegetation, the land–ocean interface in the Archean probably consisted of laterally extensive fan or braid deltas rather than point sources of sediment characteristic of most modern rivers. The abrupt up-section change from syntectonic, high-energy, alluvial–fluvial flash flood deposits to tide-influenced sedimentation implies a proximal source that provided sediment to a shoreline influenced by strong tidal action. Possible Holocene analogues are orogenic settings such as the Canterbury Plains of New Zealand, the Indo-Gangetic Plains of India and strike-slip settings such as the Gulf of Aqaba but all three examples lack a direct transition to tidally influenced sedimentation.     

Bar-top hollows: A new element in the architecture of sandy braided rivers

Discrete hollows in the bar tops of the South Saskatchewan River are described that form a newly-recognized morphological element of sandy braided rivers. These bar-top hollows, which are up to 1.7 m deep and may extend for 10–30 m down and across flow, have a circular to ovoid planform and are shown, through use of ground penetrating radar, to be filled by a series of distinct, often angle-of-repose, foresets. The hollows form by both erosion and bar-top deposition and may be generated by bar-tail accretion, cross-bar channel cutoff and subsequent fill or lateral accretion at the bar-head. Bar-top hollows occur in the upper part of the bar depositional sequence and may thus prove useful indicators for braid bar reconstruction in ancient sediments, and should not be confused with channel scour.     

Calculating the effective permeability of sandstone with multiscale lattice Boltzmann/finite element simulations

The lattice Boltzmann (LB) method is an efficient technique for simulating fluid flow through individual pores of complex porous media. The ease with which the LB method handles complex boundary conditions, combined with the algorithm’s inherent parallelism, makes it an elegant approach to solving flow problems at the sub-continuum scale. However, the realities of current computational resources can limit the size and resolution of these simulations. A major research focus is developing methodologies for upscaling microscale techniques for use in macroscale problems of engineering interest. In this paper, we propose a hybrid, multiscale framework for simulating diffusion through porous media. We use the finite element (FE) method to solve the continuum boundary-value problem at the macroscale. Each finite element is treated as a sub-cell and assigned permeabilities calculated from subcontinuum simulations using the LB method. This framework allows us to efficiently find a macroscale solution while still maintaining information about microscale heterogeneities. As input to these simulations, we use synchrotron-computed 3D microtomographic images of a sandstone, with sample resolution of 3.34 μm. We discuss the predictive ability of these simulations, as well as implementation issues. We also quantify the lower limit of the continuum (Darcy) scale, as well as identify the optimal representative elementary volume for the hybrid LB–FE simulations.     

A novel ELF radar for major oil deposits

This letter proposes a novel extremely low frequency (ELF) radar for major oil deposits. Using our recently developed whole-Earth electromagnetic wave propagation model based upon the finite-difference time-domain method, we have determined that detection of the radial (vertical) component of the scattered H-field provides a sensitive means to detect oil fields that are located within several kilometers of the Earth's surface. As an example, we provide numerical simulations of ELF radar returns from a hypothetical Alaskan oil field excited by a 20-Hz pulse emitted from the former U.S. Navy site in Wisconsin. The proposed method would potentially provide means to rapidly and inexpensively conduct aerial surveys of thousands of square kilometers for significant oil deposits.     

The Validity of Similarity Theory in the Roughness Sublayer Above Forests

Flux-gradient relationships based upon similarity theory have been reported to severely underestimate scalar fluxes in the roughness sublayer above forests, as compared to independent flux estimates (for example, eddy covariance or energy balance measurements). This paper presents the results of a unique three-month investigation into the validity of similarity theory in the roughness sublayer above forests. Eddy covariance and flux-gradient measurements of carbon dioxide (CO²) exchange were compared above a mixed deciduous forest at Camp Borden, Ontario, both before and after leaf senescence. The eddy covariance measurements used a Li-Cor infrared gas analyzer, and the flux-gradient (similarity theory) measurements featured a tunable diode laser Trace Gas Analysis System (TGAS). The TGAS resolved the CO² concentration difference to 300 parts per trillion by volume (ppt) based upon a half-hour sampling period. The measured enhancement factor (the ratio of independent flux estimates, in this case eddy covariance, to similarity theory fluxes) was smaller and occurred closer to the canopy than in most previous investigations of similarity theory. Very good agreement between the eddy covariance and similarity theory fluxes was found between 1.9 and 2.2 canopy heights (h^c), and the mean enhancement factors measured before and after leaf senescence were 1.10 plusmn; 0.06 and 1.24 ± 0.07, respectively. Larger discrepancies were measured closer to the canopy (1.2 to 1.4 h^c), and mean enhancement factors of 1.60 ± 0.10 and 1.82 ± 0.11 were measured before and after leaf senescence, respectively. Overall, the Borden results suggest that similarity theory can be used within the roughness sublayer with a greater confidence than previously has been believed.     

Gaseous and Particulate Oxidized and Reduced Nitrogen Species in the Atmospheric Boundary Layer in Scandinavia in Spring

Observations of the concentration of several nitrogen containing compounds at five rural Scandinavian sites during March–June 1993 are reported. Total nitrate (NO ₃ ^- + HNO₃) and total ammonium (NH ₄ ⁺ + NH₃) were measured by denuder and filter pack. In general the methods agree well. At all sites the particulate fraction dominated, with the largest fraction of NO ₃ ^- and the lowest of NH ₄ ⁺ at the sites which were closest to the emission sources. The fraction of NO ₃ ^- of total nitrate increased with increasing NO₂ concentrations, indicating that the nighttime conversion of NO₂ to NO ₃ ^- is an important route of formation for NO ₃ ^- . A positive correlation was found between HNO₃ and O₃ in June at all sites, while no correlation was found early in the spring. Model calculations were made with a lagrangian boundary layer photooxidant model for the whole period, and compared to the measured concentrations. The calculated ratio between mean observed and modelled daily maximum concentrations of ozone over the measurement period were within +/–10% at all sites. The models ability to describe the daily ozone maximum concentration was satisfactory with an average deviation of 19–22% from the observed concentrations. HNO₃ was underestimated by over 50% at all sites except the one closest to the emission sources. The correlation between modelled and observed concentrations was generally best for the sites with shortest transport distance from the sources of emission.     

Fabric development in brittle-to-ductile shear zones

Brittle-to-ductile shear zones from two separate geological settings are shown to have nucleated on zones of predominantly brittle deformation. The shear zones are not simply foliated cataclasites, since they contain abundant evidence of dynamic recrystallization of constituent minerals. A small quartz diorite lens in the Borrego Springs shear zone, southern California, contains centimeter-scale cataclasite zones that exhibit a gradual transition into foliated rock. Alteration of magnesiohornblende to actinolite, feldspar to white mica plus quartz, and biotite to chlorite, produced elongate minerals that define the foliation. During the later stages of deformation, intracrystalline slip and dynamic recrystallization of quartz and feldspar were important deformation mechanisms.The widespread occurrence of mineralized dilatant cracks predated the development of meter-to-decimeter-scale ductile shear zones in the Striped Rock granite, southern Virginia. Again, important deformation mechanisms in the final stages of deformation were intracrystalline slip and dynamic recrystallization of quartz.In both field areas the role of fluids has been important from the onset of brittle deformation. Fluids may have enhanced early fracturing in addition to causing the alteration and hydrolytic weakening of host rock minerals and the introduction of new mineral species. Each of these processes is thought to have contributed to the later localization of crystal plastic deformation in the rocks.