Surface analysis of pyrite in the No. 9 coal seam, Wuda Coalfield, Inner Mongolia, China, using high-resolution time-of-flight secondary ion mass-spectrometry

The chemical composition of pyrite in coal can be used to investigate its geological and mineralogical origin. In this paper, high-resolution time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to study the chemical composition of various pyrite forms in the No. 9 coal seam (S_t,d=3.46%) from the Wuda Coalfield, Inner Mongolia, northern China. These include bacteriogenic, framboidal, massive, cell-filling, fracture-filling, and nodular pyrites. In addition to Fe⁺ (⁵⁴Fe⁺, ⁵⁶Fe⁺, ⁵⁷Fe⁺), other fragment ions were detected in bacteriogenic pyrites, such as ²⁷Al⁺, Si⁺ (²⁸Si⁺, ²⁹Si⁺, ³⁰Si⁺), ⁴⁰Ca⁺, Cu⁺ (⁶³Cu⁺, ⁶⁵Cu⁺), Zn⁺ (⁶⁴Zn⁺, ⁶⁶Zn⁺, ⁶⁷Zn⁺, ⁶⁸Zn⁺), Ni⁺ (⁵⁸Ni⁺, ⁶⁰Ni⁺, ⁶²Ni⁺), and C₃H₇⁺. TOF-SIMS images show bacteriogenic pyrites are relatively rich in Cu, Zn, and Ni, suggesting that bacteria probably play an important role in the enrichment of Cu, Zn, and Ni during their formation. Intense positive secondary ion fragments from framboidal aggregates, such as ²⁷Al⁺, ²⁸Si⁺, ²⁹Si⁺, AlO⁺, CH₂⁺, C₃H₃⁺, C₃H₅⁺, and C₄H₇⁺, indicate that formation of the framboidal aggregates may have occurred together with clay mineral and organic matter, which probably serve as the binding substance. The intense ions of ²⁸Si⁺ and ²⁷Al⁺ from massive pyrites also suggest that their pores incorporated clay minerals during crystallization. Together with the lowest ²⁸Si⁺/²³Na⁺ value, the intense organic positive secondary ion peaks from cell-filling pyrites, such as C₃H₃⁺, C₃H₅⁺, C₃H₇⁺, and C₄H₇⁺, indicate that pyrite formation may have accompanied dissolution or disintegration of the cell. The intense P⁺ peak was observed only in the fracture-filling pyrite and the highest ²⁸Si⁺/²³Na⁺ value of fracture-filling pyrite reflects its epigenetic origin. Together with XRD and REEs data, the stronger ⁴⁰Ca⁺ in nodular pyrite than other pyrite forms shows seawater influence during its formation.     

青藏高原东北侧一次MCC环境流场特征分析

对１９９１年７月２８日青藏高原东北侧发生的一次中尺度对流复合体天气过程进行了环境和要素场分析，给出该类天气过程预报提示。     

中国和日本梅雨锋区（个例）结构的比较

通过１９８２年梅雨期的个例分析，研究和比较了中国和日本梅雨我的结构。分析表明：１．梅雨锋区系统对流层上部宽广的斜压区和对流层低层较狭窄的弱斜压区共同组成；２．在两个个例中，中国剖面上锋区均呈“椅”型结构。日本剖面上，６月呈均匀倾斜结构，７月略呈“椅型”，涡度场上中国剖面为相当正压结构，日本剖面为斜压结构；３．梅雨锋区系统可民是均匀斜压区在不均匀和加热情况下结构改变结果；４．中国大陆雨区高层大量潜热     

EFFECTS OF TROPOPAUSE AND POTENTIAL VORTICITY ANOMALY ON FRONTOGENESIS*

A two-dimensional,semi-geostrophic numerical model incorporating the tropopause and stratosphere is used to investigate the effects of a positive potential vorticity anomaly and latent heat release on the frontogenetic process and the structure of the resulting frontal zone.It is demonstrated that(1) the inclusion of tropopause and stratosphere significantly changes the frontal structure only in the upper levels;(2) a clearly defined quasi-equivalent barotropic structure and a region of upward motion of finite width appear when a positive potential vorticity anomaly exists on the warm side of the maximum baroclinity in the lower troposphere,especially when it is located on the south edge of the baroclinic zone;(3) the above mentioned structure deteriorates as the frontogenesis proceeds in a dry atmosphere but can be maintained in a moist frontogenetic process with condensational heating;(4) the combination of a positive potential vorticity anomaly and the latent heat release is able to accelerate the frontogenesis significantly with the time needed to form an intense frontal zone reduced to less than 15 h.The results have significant theoretical importance in understanding the complex nature of frontal structure and frontogenesis,especially in understanding the dynamic structure of the subtropical frontal zone observed during early summer over East Asia.     

唐古拉山冬克玛底冰川雪层中淋溶作用的初步研究

利用唐古拉山冬克玛底冰川雪坑和表层积雪样品的实测资料，初步探讨本区雪层中离子淋溶作用的特征，影响因素及其对冰芯记录的干扰。研究发现淋溶作用能够对数周至数月时间尺度的雪层记录产生“平滑”作用，但不会影响冰芯记录的长期变化趋势。     

褶皱分形分布的岩石力学机制研究

在褶皱形态的分形分析基础上，利用分形理论和褶皱的岩石力学成因理论推导出了褶皱的分数维（Ｄ）与岩层厚度（ｈ）和粘度（μ）的关系式，即找到了褶皱分形分布的岩石力学成因机制，在相同的构造应力场条件下，岩层的厚度和粘度越小，则越易产生较复杂的褶皱，即褶皱的分数维越大，因此，利用褶皱的分形测量，可以定量了分析褶皱形成的岩石力学性质，这是分形研究从形态研究到机制研究的一种探索。     

四川呷村黑矿型矿床硅质岩的硅、氧同位素组成及其与现代海底硅质烟囱比较研究

本文首次报道了川西呷村黑矿型矿床硅质岩的硅、氧同位素组成,其δ~(18)O为12.8‰-18.3‰纵,形成温度约99-120℃,δ~(30)Si为0.0‰-1.5‰,与Mariana和GalaPagos热液硅质烟囱的δ~(30)Si值范围基本相当,揭示两者具相似的形成机制。硅质岩和硅质烟囱δ~(30)Si最大值与相伴火山岩δ~(30)Si值一致,反映硅质来自被热液淋滤交代的火山岩系。根据SiO_2溶解度-温度关系提出,来自海底之下1-2km处的水-岩反应带、温度高于320℃的初始流体,通过绝热上升或传导冷     

The Confirmation of a New Type of Chondrites and Their Cosmochemical Significance

The data available show that some Antarctic carbonaceous chondrites are similar to Cl meteorites.Tehy contain a lot of phyllosilicate aggregates and the oxygen isotopic composition of the whole-rock samples is approximate to that of C1 chondrites,so they are named after quasi-C1(Q-C1)chondrites Unlike Cl metcorites,the Q-Cl chondites possess chondrule structrue,and the compositions of hih temperature condensates(chondrule fragments,mineral grains or aggregates)show that the oxygen fugacity varied within a wide range in the surroundings where they were formed,similar to the variation range from E.H.L,LL to C group chondrites.It is inferred that the Q-C1 chondrites could be formed at the edges far from the equator in the whole asteroid region of the solar nebular disk.where the nebula was lower in density and the condensates were lower in accretion velocity,so that the hydration of chon drules and matrix occurred during the late stage of nebular condensation.The discovery of the Q-Cl chondrites and the fact that the earth and other terrestrial planets contain water indicate that at the edges far from the equator in the terrestrial reigion of the solar nebular disk,a large amount of water was incorporated into the lattice of minerals in the condensates as a result of hydration during nebular condensation,and then found its way into the interior parts of the Earth and other terrestrial planets due to accretion.     

Properties of wave velocity for two types of granitoids at high pressure and temperature and their geological meaning

The wave velocity for two types of granitoids was measured using the analytic method of full-wave vibration at high pressure and high temperature. The laws of velocity changes for them differ with the pressure boost and temperature rise, and the velocity change of S-type is more violent than that of I-type. The “softening point” of compressional wave velocity (V μ) is also revealed during the measurement for two types of granitoids imitating the pressure and temperature at a certain depth. But the depth of “softening”, V_p after “softening” and the percentage of V_p’s drop around the “sofrening point” for two types of granitoids are obviously different. The depth of “softening” is 15 km approximately and V_p after “softening” is 5.62 km/s for S-type granitoid. But for I-type granitoid the depth of “softening” is 26 km approximately and V_p after “softening” is 6. 08 km/s. Through careful analysis of rock slices after the experiment, it was found that the “softening” of elastic-wave velocity is caused by the partial melting of granite. Combined with the results of geophysical prospecting, these results suggest that the low-velocity layers developing in the interior of Earth crust are related to thc partial melting of different types of granitoids. The formation of the low-velocity layer in the upper-middle Earth crust is closely related to the development of S-type granitoid, but that in the lower Earth crust is closely related to the development of I-type granitoid.     

Budd—Chiari综合征的CT评价

回顾性分析了５２例Ｂｕｄｄ－Ｃｈｉａｒｉ综合征的ＣＴ表现，ＣＴ显示肝尾叶增大５０例（９６％），肝脏呈低度密度或密度不均，４２例（８１％）肝静脉未明显，２２例（４２％）见有肝内侧枝血管，４９例（９４％）有肝外侧枝血管，作者认为ＣＴ检查对Ｂｕｄｄ－Ｃｈｉａｒｉ综合征有较高的诊断价值。