NMR Measurements in Carbonate Rocks: Problems and an Approach to a Solution

Carbonate rocks are well known for their complex petrophysical behavior where, in contrast to siliciclastic rocks, different parameters, including porosity and permeability, usually are not directly related. This behavior is the result of thorough reorganization of porosity during diagenesis, and it turns prediction of reservoir quality of carbonate rocks into a challenge. The study presented here deals with the problem of utilizing NMR techniques in prediction of petrophysical properties in carbonates.We employ a visual porosity classification as a priori knowledge for better interpreting NMR data for prediction purposes. This allows for choice of suitable T₂ cutoff values to differentiate movable from bound fluids adapted for the specific carbonate rock, thus resulting in better interpretation of NMR data. The approach of using a genetic pore type classification for adapting the conventional method for T₂ cutoff determination, which originally was developed for siliciclastic rocks, is promising. Similarly, for permeability determination on the basis of NMR measurements, the classification of carbonate rocks based on porosity types also shows potential. The approach implemented here has the promise to provide a basis of standardized interpretation of NMR data from carbonate rocks.Acknowledgment We are grateful to Baker Hughes INTEQ, Celle, for permission to publish the results of this work. This study was part of I.S.s Masters Thesis at Hannover University that was carried out in collaboration with Baker Hughes INTEQ, Celle, Germany. We appreciate comments of an anonymous referee and PAGEOPH editor Brian J. Mitchell.     

Environmental changes in northern New Zealand since the Middle Holocene inferred from stable isotope records (δ15N, δ13C) of Lake Pupuke

Maar lakes in the Auckland Volcanic Field are important high-resolution archives of Holocene environmental change in the Southern Hemisphere mid-latitudes. Stable carbon and nitrogen isotope analyses were applied on bulk organic matter and the green alga Botryococcus from a sediment core from Lake Pupuke (Auckland, North Island, New Zealand) spanning the period since 7,165?cal.?year BP. The origin of organic matter was established using total-organic?Ccarbon-to-nitrogen ratios (TOC/TN) as well as organic carbon (??¹³C_OM) and nitrogen (??¹⁵N) isotope composition of potential modern sources. This approach demonstrated that the contribution of allochthonous organic matter to the lake sediment was negligible for most of the record. The sedimentary TOC/TN ratios that are higher than Redfield ratio (i.e. >7) are attributed to N-limiting conditions throughout the record. Variations of nitrogen and carbon isotopes during the last 7,165?years are interpreted as changes in the dominant processes in the lake. While epilimnetic primary productivity controlled isotope composition before 6,600?cal.?year BP, microbial processes, especially denitrification and methane oxidation, caused overall shifts of the ??¹⁵N and ??¹³C values since the Mid-Holocene. Comparisons with climate reconstructions from the Northern Island suggest that changes in the wind-induced lake overturn and a shift to more pronounced seasonality were the most likely causes for lake-internal changes since 6,600?cal.?year BP.     

Meteorologically consistent bias correction of climate time series for agricultural models

Conventional bias correction of simulated climate time series for impact models is done separately for climate variables and hence leads to inconsistencies between them. However, agricultural models mostly use several variables, and meteorological consistency is essential. The present work points out meteorological inconsistency due to quantile mapping and describes a new method of consistent bias correction by an optimization approach. Time series of hourly precipitation and global radiation from the regional model REMO5.7 (Run UBA C20/A1B_1) were corrected with site observations from the German Meteorological Service. The results urge to check conventionally corrected series for consistency before using them for multidimensional models. Here, quantile mapping resulted in underestimation of diffuse radiation at hours with precipitation. This deficit was minimized by the developed procedure.     

Present rate of uplift in Fennoscandia from GRACE and absolute gravimetry

Fennoscandia is a key region for studying effects of glacial isostatic adjustment. The associated mass variations can be detected by the Gravity Recovery and Climate Experiment (GRACE) satellite mission, which observes the Earth's gravity field since April 2002, as well as by absolute gravimetry field campaigns. Since 2003, annual absolute gravity (AG) measurements have been performed in Fennoscandia by the Institut für Erdmessung (IfE, Institute of Geodesy) of the Leibniz Universität Hannover, Germany, within a multi-national cooperation. This offers a unique opportunity for validation and evaluation of the GRACE results. In this preliminary study, the GRACE results are compared to secular gravity changes based on the surveys from 2004 to 2007 with the FG5-220 gravimeter of the IfE.The results from GRACE monthly solutions provided by different analysis centres show temporal gravity variations in Fennoscandia. The included secular variations are in good agreement with former studies. The uplift centre is located west of the Bothnian Bay, the whole uplift area comprises Northern Europe. Nevertheless, the differences between the GRACE solutions are larger than expected and the different centre-specific processing techniques have a very strong effect on possible interpretations of GRACE results. The comparison of GRACE to the AG measurements reveals that the determined trends fit well with results from GRACE at selected stations, especially for the solution provided by the GFZ. Variations of land hydrology clearly influence results from GRACE and the AG measurements.     

Photometric,spectral phase and temperature effects on 4 Vesta and HED meteorites: Implications for the Dawn mission

Phase angle and temperature are two important parameters that affect the photometric and spectral behavior of planetary surfaces in telescopic and spacecraft data. We have derived photometric and spectral phase functions for the Asteroid 4 Vesta, the first target of the Dawn mission, using ground-based telescopes operating at visible and near-infrared wavelengths (0.4–2.5 μm). Photometric lightcurve observations of Vesta were conducted on 15 nights at a phase angle range of 3.8–25.7° using duplicates of the seven narrowband Dawn Framing Camera filters (0.4–1.0 μm). Rotationally resolved visible (0.4–0.7 μm) and near-IR spectral observations (0.7–2.5 μm) were obtained on four nights over a similar phase angle range. Our Vesta photometric observations suggest the phase slope is between 0.019 and 0.029 mag/deg. The G parameter ranges from 0.22 to 0.37 consistent with previous results (e.g., Lagerkvist, C.-I., Magnusson, P., Williams, I.P., Buontempo, M.E., Argyle, R.W., Morrison, L.V. [1992]. Astron. Astrophys. Suppl. Ser. 94, 43–71; Piironen, J., Magnusson, P., Lagerkvist, C.-I., Williams, I.P., Buontempo, M.E., Morrison, L.V. [1997]. Astron. Astrophys. Suppl. Ser. 121, 489–497; Hasegawa, S. et al. [2009]. Lunar Planet. Sci. 40. ID 1503) within the uncertainty. We found that in the phase angle range of 0° < α ? 25° for every 10° increase in phase angle Vesta’s visible slope (0.5–0.7 μm) increases 20%, Band I and Band II depths increase 2.35% and 1.5% respectively, and the BAR value increase 0.30. Phase angle spectral measurements of the eucrite Moama in the lab show a decrease in Band I and Band II depths and BAR from the lowest phase angle 13° to 30°, followed by possible small increases up to 90°, and then a dramatic drop between 90° and 120° phase angle. Temperature-induced spectral effects shift the Band I and II centers of the pyroxene bands to longer wavelengths with increasing temperature. We have derived new correction equations using a temperature series (80–400 K) of HED meteorite spectra that will enable interpretation of telescopic and spacecraft spectral data using laboratory calibrations at room temperature (300 K).     

Comparison of Meteoroid Flux Models for Near Earth Space

Over the last decade several new models for the sporadic interplanetary meteoroid flux have been developed. These include the Divine-Staubach and the Dikarev model. They typically cover mass ranges from 10⁻¹⁸ g to 1 g and are applicable for model specific Sun distance ranges between 0.1 AU and 20 AU Near 1 AU averaged fluxes (over direction and velocities) for all these models are tuned to the well established interplanetary model by Grün et al. However, in many respects these models differ considerably. Examples are the velocity and directional distributions and the assumed meteoroid sources. In this paper flux predictions by the various models to Earth orbiting spacecraft are compared. Main differences are presented and analysed. The persisting differences even for near Earth space can be seen as surprising in view of the numerous ground based (optical and radar) and in situ (captured Inter Stellar Dust Particles, in situ detectors and analysis of retrieved hardware) measurements and simulations.     

Cyclicity in ridge patterns on the prograding coasts of Estonia

Recent LiDAR surveys have revealed that on postglacially uplifting coasts of Estonia rhythmic coastal landforms (beach ridge sequences and foredune plains) occur to a considerable extent. We studied four of them to reveal age and periodicity in these multiple ridge systems and discussed their genesis in the Subatlantic (semi‐continental) conditions of the Baltic Sea area. Using recent models of Fennoscandian uplift due to glacial isostatic adjustment (GIA), we constructed Holocene apparent sea level curves for the study sites at Õngu, Mänspe, Haldi and Keibu; converted distance–height shore profiles into time series (including corrections on shore profile non‐linearity and variations in GIA‐eustasy balance); and analysed the patterns using spectral analysis. It was suggested that due to non‐tidal conditions, relatively low‐energy hydrodynamic forcing and small aeolian contribution, the ridges mark ancient shorelines. They are relatively modest in height (mostly 0.2–1 m), form regular and extensive (up to 150 ridges) patterns, and date back to ~9000 years before present. We studied <5‐ka‐old sections. The mean ridge spacing varied, depending also on coastal slope, between 21 and 39 m. Both simple counting and spectral analysis involved some specific limitations, yet the estimates for typical spacing were alike, at 32 (±5) years. The regular nature of the low‐ridge patterns originated from relative sea level lowering and gradual sediment accretion/erosion. However, the progradation was rather uplift‐ than accretion‐driven and the stepwise process in ridge formation was probably not autocyclic. It was governed or modulated by quasi‐periodic 25–40 year cyclicity in local wave forcing, relative sea level variations and wind conditions. Being most likely connected to the North Atlantic Oscillation, the quasi‐regular, decadal‐scale, similarly phased variations may magnify each other's effect on the westerly exposed coasts of Estonia. Additionally, some other (e.g. event‐driven) mechanisms may also be present.     

高亚洲及其邻区2003~2017年质量平衡的气候影响分析

利用重力恢复和气候实验(GRACE)数据获得高亚洲及其邻近地区的质量变化,可分析区域气候因素如印度季风、西风带和厄尔尼诺-南方涛动(ENSO)对结果的影响。然而,最近的研究发现,西风带的贡献小于厄尔尼诺,与传统研究结论不同。因此,利用2003-01~2017-06期间GRACE RL06的Mascon数据进行复经验正交函数（CEOF）分析。研究发现,前3个主要成分对研究区质量变化的贡献率分别为53%、27%和6%,与印度季风、西风带和ENSO指数的相关系数分别是0.92±0.16、0.70±0.15和0.42±0.15,说明在长达14 a的观测时间跨度内,印度季风、西风带和ENSO对研究区质量变化的贡献分别为53%、27%和6%,西风带是研究区质量变化的第2个影响因素,这支持了传统的研究结论;ENSO通过印度季风对某些区域（如帕米尔高原、喜马拉雅山脉和印度西北部）的质量变化产生影响;在印度西北部、喜马拉雅山脉和藏东南地区,由于印度季风的减弱及其相关的ENSO作用和西风带的加强,质量变化呈现下降趋势;在兴都库什、西昆仑和东昆仑地区,由于西风带的增强,质量变化呈上升的趋势;在帕米尔和天山地区,虽然受到较强西风带的影响,但由于同时受到印度季风和ENSO减弱以及气温上升趋势的影响,质量变化呈下降的趋势。     

The use of mycorrhiza for eco‐engineering measures in steep alpine environments: effects on soil aggregate formation and fine‐root development

Steep erosion‐prone and vegetation‐free slopes are widespread in alpine areas and are often discussed since they have a high socio‐economic damage potential. We present an eco‐engineering approach to test whether a mycorrhizal inoculum improves the establishment of hedge brush layers and in turn soil structural stability on a steep, coarse‐grained vegetation‐free slope in the eastern Swiss Alps. We established (i) mycorrhizal and (ii) non‐mycorrhizal treated eco‐engineered research plots on a field experimental scale, covering a total area of approximately 1000 m² on an east‐northeast (ENE) exposed slope, where many environmental parameters can be regarded as homogeneous. After a full vegetation period, we quantified soil aggregate stability, the formation of water stable aggregates and the fine‐root development. Our results illustrate that the establishment of brush layers without mycorrhizal inoculum increased aggregate stability significantly. Against our expectation and glasshouse experiments, the addition of mycorrhizal inoculum did not have a statistically significant effect after one vegetation period although it tended to increase aggregate stability. Analogously, root length density (RLD) tended to be higher at the non‐mycorrhizal treated site. Aggregate stability was significantly correlated with RLD. Studies on a bigger field experimental scale are inevitable, complement glasshouse studies and lead to a better understanding for a successful application of sustainable eco‐engineering measures in alpine environments. Based on our results and considering the fact that the response time in natural ecosystems may be slower than in laboratory approaches, we conclude that long‐term field studies are necessary to validate results gained through laboratory experiments. Copyright © 2014 John Wiley & Sons, Ltd.     

500 years of trophic-state history of a hypertrophic Dutch dike-breach lake

We present a palaeolimnological study encompassing five centuries of trophic-state change of the dike-breach lake De Waay located on the Rhine-Meuse delta (the Netherlands). Diatom-inferred total phosphorus (TP) concentrations indicate hypertrophic epilimnetic conditions (>300 μg l⁻¹ TP) since the formation of the lake in the fifteenth century until the end of the eighteenth century. Cladocera data support the reconstructed trophic state and indicate turbid conditions in lake De Waay during this period. High inferred TP concentrations as well as the amount of Ti in the sediment reflect numerous flooding events. From the nineteenth century onwards reconstructed TP concentrations decreased to 40–150 μg l⁻¹ due to improvements in sewage and dike systems that considerably diminished direct river flooding and seepage-derived nutrients. As a consequence, the increased stability of littoral habitats led to an increased diversity of the Cladocera assemblages. The most significant decrease in TP concentrations to ~40 μg l⁻¹ occurred between about 1900 and 1930. This mesotrophic phase was a consequence of the isolation of the lake from catchment drainage and the introduction of a highly elaborate flood control during this period. However, since the mid twentieth century a eutrophication trend is preserved in the record, likely related to increased agricultural activity in the vicinity of the lake. Our results emphasize that land-use and trophic-state history must be taken into account when evaluating the ecological status of lakes for water management and protection actions, especially for lakes in landscapes that are strongly modified by human action.