Entropy‐based equation to assess hillslope sediment production

A new equation to assess hillslope sediment production, based on physical and probabilistic approaches, is presented. The equation, which allows the computation of the delivery ratio for every event, considers the physical variables of travel distance, stream power, settling velocity and gross erosion. The probability density function that arises from the new formulation is solved using the principle of maximum entropy. Based on data from five watersheds in both tropical and temperate zones, the new delivery parameter K_v is calibrated and associated with vegetation cover and conservation practice. The proposed equation is rationally based in relation to parameter K_v. The entropy‐based equation was applied to assess sediment yield in two other experimental watersheds, showing good predictability for the set (mean absolute error of 20·8%). No systematic error was found in the analysed data. The entropy‐based equation showed good predictability for long‐term sets of data and for high‐erosivity events, but did not perform well for the low‐erosivity ones. Copyright © 2007 John Wiley & Sons, Ltd.     

First comparisons of precipitable water vapor estimation using GPS and water vapor radiometers at the Royal Observatory of Belgium

We compare precipitable water vapor (PWV) time series measured by water vapor radiometers (WVRs) to PWV time series estimated using global positioning system (GPS) observations in a regional network of stations in western Europe. Inside this network, we focus on the baseline Brussels – Wettzell which presents the advantage to have the collocation of a GPS receiver and a WVR at both endpoints. The comparison between our GPS and WVR estimations of precipitable water vapor shows an agreement at the millimeter level. In addition, we show that the zenith total delay (ZTD) estimations computed with our GPS processing strategy agrees with the GPS estimations of ZTD done by the CODE analysis center at the millimeter level. Electronic Publication     

Spatiotemporal changes in cadmium contamination in the Seine estuary (France)

Cadmium (Cd) is among the major contaminants in the Seine estuary. In the biota, the RNO (Réseau National d’Observation, the French Mussel-Watch) has shown that Cd concentrations in mussels living at the mouth of the estuary are related to changes in inputs to this area of phosphogypsum, a calcium sulphate that is a by-product of the phosphoric acid naturally enriched with Cd. In the water column, Cd concentrations at several key estuary sites show a very marked trend toward decreased contamination in the particles as well as in the dissolved phase. The behavior of Cd in the estuary has been studied between 1991 and 1998 in the framework of the scientific program Seine-Aval. This program has highlighted punctual Cd inputs in the estuarine water column. The partition of Cd between the dissolved and the particulate phase, previously described in various estuaries, is characterized by an intense phenomenon of solubilization in the mixing zone freshwater-seawater, but the colloidal Cd fraction remains low along the whole salinity gradient, about 5% to 10% of the apparent dissolved fraction. Although the decrease of inputs induced a fall of Cd concentrations in the water column, laboratory experiments show that the estuarine particles are far from being exhausted in Cd. Despite continuous efforts to reduce the urban and industrial inputs into the estuarine and coastal waters, the Seine estuary still remains very contaminated by Cd.     

Sensitivity of the Asian summer monsoon to an anomalous Eurasian snow cover within the Météo-France GCM

Both observational and numerical studies suggest that the Eurasian winter snow cover has a strong influence on the subsequent summer monsoon in Asia. An updated version of the ARPEGE climate model of Météo-France, including a simple but physically-based snow parameterization, is used to test the impact of an increased snow mass prescribed at the beginning of March on the simulated summer monsoon circulation and rainfall. The large-scale features of the Asian monsoon are reproduced in a realistic way in the control integration, which is a necessary premise of such a sensitivity test. In the heavy snow cover experiment, the anomalous persistence of the winter snow pack delays the springtime continental heating. This weakens the thermal low over northern India and Persia as well as the southwesterly winds over the monsoon area. There is also a significant decrease in the rainfall over western India and Bengal-Burma, which usually represent the centers of maximum precipitation. Radiative, turbulence transfer and hydrological processes seem to be involved in the snow-monsoon relationship. The changes in the monsoon precipitation are strongly related to changes in the atmospheric circulation and are not reinforced by a local evaporation/convection feedback in our experiment. Received: 17 May 1995 / Accepted: 27 November 1995     

Cloud-radiation feedbacks in a general circulation model and their dependence on cloud modelling assumptions

The general circulation model (GCM) used in this study includes a prognostic cloud scheme and a rather detailed radiation scheme. In a preceding paper, we showed that this model was more sensitive to a global perturbation of the sea surface temperatures than most other models with similar physical parametrization. The experiments presented here show how this feature might depend on some of the cloud modelling assumptions. We have changed the temperature at which the water clouds are allowed to become ice clouds and analyzed separately the feedbacks associated with the variations of cloud cover and cloud radiative properties. We show that the feedback effect associated with cloud radiative properties is positive in one case and negative in the other. This can be explained by the elementary cloud radiative forcing and has implications concerning the use of the GCMs for climate sensitivity studies.     

Lateritic nickel deposits of Brazil

Many nickel deposits are known in Brazil, accounting for about 350 · 10⁶ tons of ore with an average of 1.5% Ni. All are of the lateritic type. These deposits are scattered throughout the country, being rarer in the Northeastern Region and in the South, below 25 °S latitude. They are mainly associated with mafic-ultramafic massifs of large dimensions and ultramafic alkaline complexes, and occur in climatic regions of contrasting seasons. The weathering profile developed over the fresh rock consists, from bottom to top, of the following horizons: altered rock, coarse saprolite, argillaceous saprolite, ferruginous saprolite and lateritic overburden. The thickness of each horizon varies from one deposit to another, the whole profile generally exceeding 20 m. The saprolitic horizons with inherited minerals (serpentine, chlorite) or neoformed minerals (smectites) constitute the silicated nickel ore and are thicker were climatic conditions are drier; the ferruginous upper horizons made up of iron oxide-hydroxides are more developed in more humid regions. In Brazil, the silicated ore generally prevails over the oxidized ore. The main Ni-bearing minerals are serpentine, smectite, garnierite and goethite. The lateritic nickel deposits of Brazil may be correlated with two erosion surfaces, corresponding to the Sul Americano (Lower Tertiary) and Velhas (Upper Tertiary) levelling cycles. The degree of dismantling of the higher and more ancient surface and the consequent development of the Velhas Surface control the position of the nickel accumulation in the landscape. Thus, the deposits may be found either in the lowlands or in the highlands, where they are always covered by a silcrete layer. The alteration profiles in the Brazilian lateritic nickel deposits are broadly similar to those described elsewhere in the world. However, they present two characteristic features: the silicated ore prevails over the oxidized ore, and a silicified layer covers the profies developed on the highlands.     

Das Karbon des Amazonas-Beckens

Summary This article is a brief résumé of the geology of the marine Upper Carboniferous beds (Itaituba series) of the Amazonian basin. The unfolded sediments cover a large area of the basin and are constituted of limestones, shales and sandstones. The macrofauna includes brachiopods, pelecypoda, corals, bryozoa, etc., from which the brachiopods are the better known by the present. The microfauna includes two genera of fusulinids:Millerella andFusulinella.According to the age as given by the fusulinids the sediments are Pennsylvanian (Upper Carboniferous), and not Permian as it has been supposed by some authors. So, the correlation with the Andean (Bolivia and Peru) permian groups is no more valid. Correlation with Tarma Group (Upper Carboniferous from Peru) and with the marine carboniferous of the MaranhÃo-Piauí (Brazil) is possible but not very well established.