长江流域河水和悬浮物的锂同位素地球化学研究

深入理解流域侵蚀过程中的锂同位素分馏对于运用锂同位素来示踪化学循环和气候变化是十分必要的。研究集中在长江干流和主要支流的水体和悬浮物的锂及锂同位素组成。长江流域水体的锂及锂同位素组成（δ⁷Li）分别为150~4 570 nmol/L和+7.6‰~+28.1‰,两者沿上游至下游的变化趋势相反。悬浮物锂同位素组成（δ⁷Li）变化比较稳定,分别为41~92 μg/g和-4.7‰~+0.7‰,而且总是低于相应水体的锂同位素组成。悬浮物和流体之间的锂同位素分馏系数在0.977和0.992之间,与悬浮物的量及组成存在明显相关性,反映了粘土矿物的吸附和化学风化的程度。锂含量与锂同位素组成之间良好的负相关性表明流域水体的锂来自2个端元混合：其一可能是蒸发盐岩,并伴有深部热泉水;其二可能是硅酸岩。     

高放废物处置库天然类比及其有关的地球化学问题

介绍了高放废物处置库天然类比研究的主要内容,重点阐述了类比研究中涉及的地球化学问题,包括核素溶解度和化学形态研究、核素迁移速率研究、核素迁移影响因素研究,并总结相关问题研究取得的成果和认识.     

Chronology and cooling history of the Tianmenshan pluton in South Jiangxi Province and their geological significance

Geochronological studies on the crust-derived Tianmenshan pluton were undertaken by SHRIMP zircon U-Pb dating and Ar-Ar dating of biotite, muscovite and K-feldspar, giving a petrogenetic age of 167 Ma. Owing to the closure systems in different minerals, the cooling history of the pluton can be determined with an age-temperature diagram. The late hydrothermal event has been recognized, which is related probably with mineralization. In terms of the comparative geochronological and petrologic records, it is concluded that there are some constrains on tectonic evolution and that the formation of the Tianmenshan pluton proceeded in a transition period from Indosinian post-orogeny extension to strong compressive tectonics. And the timing of the hydrothermal event matches the compressive climax of the Yanshanian orogeny. The temporal gap between granite emplacement and wolframite mineralization could last 10-20 Ma owing to the low cooling rate of the pluton.     

Helium-argon isotopic tracing for the Pb-Zn-Ag polymetallic ore deposits in the central-south segment of the Da Hinggan Ling Range

In recent years big strides have been made in the exploration of ores in the central-south segment of the Da Hinggan Ling Range, though some debates still exist on the metallogenesis and sources of ore-forming materials. Pyrite and other sulfides in direct relation to the Pb-Zn-Ag ore deposits were chosen for the He and Ar isotopic analysis of ore-forming fluids, and the first He and Ar isotope data have been obtained from the study region. ^3He/^4He ratios in 14 samples collected from 7 mining districts are 2.17×10^-6-12.52×10^-6, averaging 6.86×10^-6 and their R/Ra ratios are 1.56-9.01 Ra, averaging 4.37 Ra. By projecting the data points onto the ^3He-^4He concentrations diagram, all the points fall near the mantle helium area. The calculated mantle-source helium ratios are within the range of 19.58%-76.96%, with an average of 49.52%. Argon isotopic characteristics are close to those of mantle source, indicating that the ore-forming material was transport upwards via the multi-stage evolution of mantle plume and concentrated as ores in the favorable loci of mantle branch structures.     

The distribution and geological significance of carbazole compounds in Silurian paleo-pools of the Tarim Basin,Northwest China

The results presented in this paper indicated that the carbazole-type compounds have high thermal stability and also show stability in oxidation and bio-degradation. This kind of compounds still has high concentrations and a complete distribution in the analyzed dry asphalt samples, showing that they are particularly useful in the study of hydrocarbon migration of the paleo-pools. The difference in the contents of nitrogen compounds in the Silurian dry asphalts from the Awati, Tabei and Tazhong areas is attributed to the difference in the extent of oxidation and （or） bio-degradation for the areas; the Awati and Tabei areas underwent relatively strong oxidation and bio-degradation. During the first stage of hydrocarbon pool formation in the Silurian system in the Tazhong and Tabei areas of the Tarim Basin （at the end of the Silurian period） and at the second stage in the Awati area （in Permian）, the hydrocarbons experienced a long-distance migration.     

The characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin

The Central Gas Field is a famous large-sized gas field in the Ordos Basin of China. However, identification of main gas sources of the Ordovician reservoirs in this gas field remains puzzling. On the basis of a lot of geochemical data and geological research on natural gases, the characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin were studied. The results indicated that natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin have similar chemical and isotopic compositions to highly mature and over-mature dry gases. Both coal-derived gases and oil-type gases coexist in the Central Gas Field in the Ordos Basin. The former was derived mainly from Carboniferous-Permian coal measures and the latter from Lower Paleozoic marine carbonates. It is suggested that coal-derived gases occur in the eastern part of the Central Gas Field while oil-type gases may be produced mainly in the northern, western and southern parts of the Central Gas Field in the Ordos Basin.     

Simulation experiment on hydrocarbon generating potential of various source rocks on the northern margin of the Qaidam Basin,Qinghai, China

The northern margin of the Qaidam Basin is one of the main oil-gas exploration areas in western China, where source rocks are composed mostly of Middle and Lower Jurassic dark mud shale, carbargillite and coal. A large number of subsurface and outcrop samples differing in lithology with different types of organic matter were selected for resource evaluation, research and calculation. And among them, 13 samples were used for simulation experiment on hydrocarbon generating potential of various source rocks. At first, two kinds of heating modes were compared through simulation experiment, including single temperature-step heating and continual heating. Perhaps, the process of hydrocarbon generation and expulsion occurred naturally between a close system and an open system. In addition, the first heating mode was convenient, and all its reaction products were involved in the whole thermal evolution, and the final simulation experimental results were basically in consistency with the natural evolution trend Therefore, the first heating mode was adopted and the hydrocarbon yield of every sample was worked out. According to the type and lithology of organic matter and the hydrocarbon yield of samples for simulation experiment, hydrocarbon generation and expulsion mode with three kinds of lithology and five types of source rock has been established to provide the basis for hydrocarbon generation evaluation, research and resource calculation.     

A framework of region-based spatial relations for non-overlapping features and its application in object based image analysis

Object based image analysis (OBIA) is an approach increasingly used in classifying high spatial resolution remote sensing images. Object based image classifiers first segment an image into objects (or image segments), and then classify these objects based on their attributes and spatial relations. Numerous algorithms exist for the first step of the OBIA process, i.e. image segmentation. However, less research has been conducted on the object classification part of OBIA, in particular the spatial relations between objects that are commonly used to construct rules for classifying image objects and refining classification results. In this paper, we establish a context where objects are areal (not points or lines) and non-overlapping (we call this “single-valued” space), and propose a framework of binary spatial relations between segmented objects to aid in object classification. In this framework, scale-dependent “line-like objects” and “point-like objects” are identified from areal objects based on their shapes. Generally, disjoint and meet are the only two possible topological relations between two non-overlapping areal objects. However, a number of quasi- topological relations can be defined when the shapes of the objects involved are considered. Some of these relations are fuzzy and thus quantitatively defined. In addition, we define the concepts of line-like objects (e.g. roads) and point-like objects (e.g. wells), and develop the relations between two line-like objects or two point-like objects. For completeness, cardinal direction relations and distance relations are also introduced in the proposed context. Finally, we implement the framework to extract roads and moving vehicles from an aerial photo. The promising results suggest that our methods can be a valuable tool in defining rules for object based image analysis.     

海底基岩高程测量中浅地层剖面仪数据处理方法研究

本文从浅地层剖面仪在海洋地球物理探测中的应用为出发点,介绍了浅地层剖面仪采集数据的构成后,提出了一种基于ESRI公司ArcGIS平台数据处理方法,并结合某跨海大桥工程桥墩附近基岩高程测量的实例,证明了该方法的快速、有效性,最后提出了对于浅地层剖面数据处理方法的结论与展望。