Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

Progradational and backstepping shoreface deposits in the Ladinian to Early Norian Snadd Formation of the Barents Sea

Shoreface sandstone deposits within the Early Carnian part of the Snadd Formation of the Norwegian Barents Sea can be traced for hundreds of kilometres in the depositional strike direction and for tens of kilometres in the depositional‐dip direction. This study uses three‐dimensional seismic attribute mapping and two‐dimensional regional seismic profiles to visualize the seismic facies of these shoreface deposits and to map their internal stratigraphic architecture at a regional scale. The shoreface deposits are generally elongate but show variable width from north‐east to south‐west, which corresponds to a sediment source in the northern part of the basin and a southward decrease in longshore sediment transport. The Snadd Formation presents an example of how large‐scale progradational shoreface deposits develop. The linear nature of its shoreface deposits contrasts with more irregular, cuspate wave‐dominated deltaic shorelines that contain river outlets, and instead implies longshore drift as the main sediment source. In map view, discrete sets of linear features bounded by truncation surfaces scale directly to beach ridge sets in modern counterparts. The shoreface deposits studied here are characteristic in terms of scale and basin‐wide continuity, and offer insight into the contrast between shallow marine deposition under stable Triassic Greenhouse and fluctuating Holocene Icehouse climates. Findings presented herein are also important for hydrocarbon exploration in the Barents Sea, because they describe a hitherto poorly understood reservoir play in the Triassic interval, wherein the most prominent reservoir plays have so far been considered to be found in channelized deposits in net‐progradational delta‐plain strata that form the topsets to shelf‐edge clinoforms. The documented presence of widespread wave‐dominated shoreface deposits also has implications for how the relative importance of different sedimentary processes is considered within the basin during this period.     

Outdoor recreation monitoring in coastal and marine areas – an overview of Nordic experiences and knowledge

This paper involves a collection and communication of important knowledge about and experiences with outdoor recreation monitoring in Nordic coastal and marine areas. This is a topic that so far has received little attention, especially among researchers and practitioners working with outdoor recreation monitoring in Nordic coastal and marine areas, who are in need of knowledge on the topic in order to advance monitoring activities and procedures. To remedy this situation, the purpose of this paper is to provide a knowledge base by listing and describing central literature contributions with important insight into outdoor recreation monitoring in Nordic coastal and marine areas. More specifically, this includes information about: (a) where important knowledge about outdoor recreation monitoring in Nordic coastal and marine areas can be found, (b) who the main contributors are and (c) what monitoring knowledge that has been reported so far. The paper also examines what tasks lie ahead for researchers and area managers in order to improve knowledge about outdoor recreation monitoring in Nordic coastal and marine areas. The paper is a central contribution and addition to manuals on outdoor recreation monitoring that are currently available in the Nordic countries.     

Anticyclonic eddies in the Norwegian Sea; their generation,evolution and impact on primary production

Altimetry and ocean color observations are used in combination with a coupled physical-primary production ocean model to investigate anticyclonic eddies at two locations in the Norwegian Sea. Of particular interest are the formation of the anticyclonic eddies, and their influence on primary production. The formation of these anticyclonic eddies are due to baroclinic instabilities set up by shifts in the wind in north/south direction, leading to simultaneously formation of eddies throughout the area. After a density stratification develops in the upper 100 m of the water column, the anticyclones become a subsurface lens of well mixed water with the characteristics of intra-thermocline eddies. The deep mixed layer inside anticyclonic eddies delay phytoplankton bloom by approximately two weeks compared to the surrounding areas. As the mixed layer within the anticyclones become smaller than the critical depth, the combination of this and sufficiently high nutrient levels support a phytoplankton bloom. From the satellite observations, there is an evidence of phytoplankton being advected toward the center of the eddies, but also of isolated phytoplankton blooms within the intra-thermocline eddies. The combined use of a numerical model and satellite observations provides three-dimensional information on the structure and properties of both eddies and primary production. The presented model is particularly useful in cloud-covered areas where ocean color images are frequently unavailable.     

A mathematical programming approach for scheduling equipment in a surface coal mining operation

Summary A mathematical programming model for scheduling open pit mining was developed and validated using data from a surface mining operation. A two-phase solution procedure was used involving repeated evaluations of an integer scheduling model and a simple transportation model.     

Ultra-wideband radar studies of steep crested waves with scanning laser measurements of wave slope profiles

We report results of ultra wide-band radar sea spike experiments using steep and weakly breaking non-linear water surface features in a wave tank. To generate these features we used a 1 s paddle wave and wind waves for a sequence of wind speeds. A scanning laser was used to measure synchronously the surface slope profile across 12 cm along the wave propagation direction once per radar pulse. A time domain reflectometer (TDR) radar transmitted short horizontally polarized pulses at X-band, several hundred picoseconds long, to give a range resolution of 10 cm. A radar range of 36 cm was digitally sampled so that surface feature echoes could be tracked through the area continuously with 5 ms temporal resolution with each instrument. We report results considering the wave slope component in the propagation direction and the corresponding curvature component. For the conditions studied, two types of features which produce sea spike radar echoes were generated–a non-linear feature near the crest front of the wind wave, caused by extreme steepening as a result of the passage of the paddle wave, and a steepened blocked wind wave in the trough of the paddle wave, caused by the local orbital current of the 1 s wave being nearly equal to and opposite the phase velocity of the wind wave.     

Olivine phenocrysts of Hawaiian olivine tholeiite and oceanite

Olivine phenocrysts of Hawaiian tholeiites display a variety of textures and a variation in composition which is due to supercooled crystallization. The highest forsterite content measured is 91%, and the highest magnesia content estimated for a tholeiitic liquid is 17%, using the olivine geothermometer. The liquid of this composition may be either a primary magma or a primitive magma. It is not yet possible to specify any particular composition range for the primary Hawaiian tholeiites.     

Distinct modes of bidecadal and multidecadal variability in a climate reconstruction of the last centuries from a South Pacific coral

The Rarotonga coral Sr/Ca time series (Linsley et al. in Science 290:1145–1148, 2000) provides a near-monthly resolved proxy record of South Pacific climate variability over the last ~300 years. Here we show that two distinct interdecadal, quasi-periodic time components with periods of ~80 and ~25 years can be identified in this time series by Singular Spectrum Analysis. Their associated spatial patterns in the global sea surface temperature (SST) field show notable differences. Whereas the multidecadal component is associated with a global SST pattern that was recently associated with solar forcing on multidecadal timescales, the bidecadal component is associated with a well known pattern of Pacific decadal to interdecadal SST variability.