Stable silicon isotopes of groundwater, feldspars, and clay coatings in the Navajo Sandstone aquifer, Black Mesa, Arizona, USA

We present some of the first analyses of the stable isotopic composition of dissolved silicon (Si) in groundwater. The groundwater samples were from the Navajo Sandstone aquifer at Black Mesa, Arizona, USA, and the Si isotope composition of detrital feldspars and secondary clay coatings in the aquifer were also analyzed. Silicon isotope compositions were measured using high-resolution multi-collector inductively coupled mass spectrometry (HR-MC-ICP-MS) (Nu1700 & NuPlasma HR). The quartz dominated bulk rock and feldspar separates have similar δ³⁰Si of −0.09 ± 0.04‰ and −0.15 ± 0.04‰ (±95% SEM), respectively, and clay separates are isotopically lighter by up to 0.4‰ compared to the feldspars. From isotopic mass-balance considerations, co-existing aqueous fluids should have δ³⁰Si values heavier than the primary silicates. Positive δ³⁰Si values were only found in the shallow aquifer, where Si isotopes are most likely fractionated during the dissolution of feldspars and subsequent formation of clay minerals. However, δ³⁰Si decreases along the flow path from 0.56‰ to −1.42‰, representing the most negative dissolved Si isotope composition so far found for natural waters. We speculate that the enrichment in ²⁸Si is due to dissolution of partly secondary clay minerals and low-temperature silcretes in the Navajo Sandstone. The discovery of the large range and systematic shifts of δ³⁰Si values along a groundwater flow path illustrates the potential utility of stable Si isotopes for deciphering the Si cycling in sedimentary basins, tracing fluid flow, and evaluating global Si cycle.     

Diurnal variation of electron density in Saturn’s ionosphere: Model comparisons with Saturn Electrostatic Discharge (SED) observations

Using the Saturn Thermosphere Ionosphere Model (STIM), we present a study of the diurnal variation of electron density, with a focus on comparisons with peak electron densities (N_MAX) inferred from the low-frequency cutoff of radio emission due to lightning in the lower atmosphere, called Saturn Electrostatic Discharges (SEDs). It is demonstrated that photochemistry in Saturn’s ionosphere cannot reproduce the SED-inferred diurnal variation in N_MAX unless additional production and loss sources outside of the current best estimates are considered. Additional explanations of the SED-inferred diurnal variation of N_MAX are presented and analyzed, such as the possibility that the low-frequency cutoff seen in SEDs is due to the presence of sharp low-altitude layers of plasma, as frequently seen in radio occultation measurements. Finally, we outline the observational constraints that must be fulfilled by any candidate explanations of the SED-inferred diurnal variation of N_MAX.     

High Resolution Köppen‐Geiger Classifications of Paleoclimate Simulations

The development and application of an algorithm to compute Köppen‐Geiger climate classifications from the Coupled Model Intercomparison Project (CMIP) and Paleo Model Intercomparison Project (PMIP) climate model simulation data is described in this study. The classification algorithm was applied to data from the PMIP III paleoclimate experiments for the Last Glacial Maximum, 21k years before present (yBP), Mid‐Holocene (6k yBP) and the Pre‐Industrial (0k yBP, control run) time slices. To infer detailed classification maps, the simulation datasets were interpolated to a higher resolution. The classification method presented is based on the application of Open Source Software, and the implementation is described with attention to detail. The source code and the exact input data sets as well as the resulting data sets are provided to enable the application of the presented approach.     

Bau und Entwicklung des Harznordrandes bei Bad Harzburg

Zusammenfassung Konglomeratische Oberkreidesandsteine im Raum Bad Harzburg wurden auf ihren Geröll- und Leitmineralgehalt hin untersucht. Aus der Leitmineralverteilung ergibt sich die stratigraphische Stellung der Emscher- und Senonvorkommen zueinander; aus der Geröllführung geht hervor, daß der Brockengranit bereits im Oberemscher im Erosionsniveau lag und die Aufrichtungszone mesozoischer Gesteine am Harznordrand auch im Schimmerwaldgebiet bis zum Quadratensenon übertage vorhanden war, obwohl sie heute hier nicht mehr zu finden ist. Ursache dieser Erscheinung ist ein Schollenabbruch aus dem Dach des Ilsenburggranits, der an der Wende Granulaten-Quadratensenon erfolgte und zu einer lokalen Überfahrung der Aufrichtungszone geführt hat. Die geologische Neuaufnahme des Paläozoikums nördlich des Ilsenburggranites stellt die heutigen Lagerungsverhältnisse dieses Gebietes klar; sie werden bei der Rekonstruktion der ursprünglichen Lagerung und des Bewegungsvorganges zugrunde gelegt, dessen Ergebnis die teilweise Überdeckung des Vorlandes ist. Ein ähnlicher Vorgang liegt auch am benachbarten Okervorsprung der Harznordrandlinie vor.Unter Berücksichtigung der Ergebnisse neuer Tiefbohrungen im Subherzyn wird eine Auffassung von Ablauf und Ursachen tektonischer Vorgänge in diesem Raum entwickelt, die der herrschenden Meinung in zahlreichen Punkten widerspricht:Eine echte Faltung des Subherzyns im Mesozoikum, die bisher vermutete starke Nordbewegung der Harzscholle und eine ausschließliche Bindung tektonischer Vorgänge in diesem Gebiet an orogene Phasen wird abgelehnt.Auslösender Vorgang aller tektonischen Erscheinungen im Subherzyn ist eine vertikale Differentialbewegung der Harz- und Vorlandscholle, die sich seit Ausgang des Paläozoikums gleichsinnig, aber mit örtlich und zeitlich wechselnder Intensität, abspielt.     

Probleme der Lagerstättenlehre

Ohne Zusammenfassung     

Late Pleistocene outburst floods from Issyk Kul,Kyrgyzstan?

Elevated shorelines and lake sediments surrounding Issyk Kul, the world's second largest mountain lake, record fluctuating lake levels during Quaternary times. Together with bathymetric and geochemical data, these markers document alternating phases of lake closure and external drainage. The uppermost level of lake sediments requires a former damming of the lake's western outlet through the Boam gorge. We test previous hypothesised ice or landslide dam failures by exploring possible links between late Quaternary lake levels and outbursts. We review and recompile the chronology of reported changes in lake site, and offer new ages of abandoned shorelines using ¹⁴C in bivalve and gastropod shells, and plant detritus, as well as sand lenses in delta and river sediments using Infrared Stimulated Luminescence. Our dates are consistent with elevated lake levels between ~45 ka and 22 ka. Cosmogenic ¹⁰Be and ²⁶Al exposure ages of fan terraces containing erratic boulders (>3 m) downstream of the gorge constrain the timing of floods to 20.5–18.5 ka, postdating a highstand of Issyk Kul. A flow‐competence analysis gives a peak discharge of >10⁴ m³ s^–1 for entraining and transporting these boulders. Palaeoflood modelling, however, shows that naturally dammed lakes unconnected to Issyk Kul could have produced such high discharges upon sudden emptying. Hence, although our data are consistent with hypotheses of catastrophic outburst floods, average lake‐level changes of up to 90 mm yr^–1 in the past 150 years were highly variable without any outbursts, so that linking lake‐level drops to catastrophic dam breaks remains ambiguous using sedimentary archives alone. This constraint may readily apply to other Quaternary lakes of that size elsewhere. Nonetheless, our reconstructed Pleistocene floods are among the largest reported worldwide, and motivate further research into the palaeoflood hydrology of Central Asia. Copyright © 2017 John Wiley & Sons, Ltd.     

The first field-based descriptions of pumping-induced saltwater intrusion and upconing

Development of the ideas about the equilibrium between freshwater and saline water has received considerable attention in the literature, but little has been written so far about the earliest scientific works about well salinization. Based on a review of the literature from the second half of the 19th century and the early 20th century, this historical note explores how insights into groundwater abstraction and saltwater intrusion developed, and examples of the earliest field studies are provided. Fundamental research was driven by the need for increasing water supply, but the progress of science did not lead to sustainable management practices everywhere. Research outcomes were shared between scientists of different countries, marking the beginning of coastal hydrogeology as a scientific specialization in the first decade of the 20th century.     

Inverse modeling and uncertainty analysis of potential groundwater recharge to the confined semi-fossil Ohangwena II Aquifer,Namibia

The identification of potential recharge areas and estimation of recharge rates to the confined semi-fossil Ohangwena II Aquifer (KOH-2) is crucial for its future sustainable use. The KOH-2 is located within the endorheic transboundary Cuvelai-Etosha-Basin (CEB), shared by Angola and Namibia. The main objective was the development of a strategy to tackle the problem of data scarcity, which is a well-known problem in semi-arid regions. In a first step, conceptual geological cross sections were created to illustrate the possible geological setting of the system. Furthermore, groundwater travel times were estimated by simple hydraulic calculations. A two-dimensional numerical groundwater model was set up to analyze flow patterns and potential recharge zones. The model was optimized against local observations of hydraulic heads and groundwater age. The sensitivity of the model against different boundary conditions and internal structures was tested. Parameter uncertainty and recharge rates were estimated. Results indicate that groundwater recharge to the KOH-2 mainly occurs from the Angolan Highlands in the northeastern part of the CEB. The sensitivity of the groundwater model to different internal structures is relatively small in comparison to changing boundary conditions in the form of influent or effluent streams. Uncertainty analysis underlined previous results, indicating groundwater recharge originating from the Angolan Highlands. The estimated recharge rates are less than 1% of mean yearly precipitation, which are reasonable for semi-arid regions.