Holocene and Pleistocene sea-level indicators at the coast of Jericoacoara,Ceará, NE Brazil

Beach-rock exposures provide a record of Holocene sea-level rise along the 560-km-long northeast-facing coast of Ceará, Brazil, that differs from the record available along the other 4300 km of Brazilian coastline further south. Whereas documentation is available from southern Brazil to show Holocene sea levels as much as 5 m above today's level, our observations along the northeastern coast indicate that sea level here was not above the present-day level during the Holocene. Near Jericoacoara, about 240 km northwest of Fortaleza, characterized by strong surf, Precambrian rocks crop out from under a temporary cover of sand in small protected locations with less surf. Here in this upper tidal zone beach rock is being formed, while it is being dismembered synchronously by erosion at lower tide levels. This shows a rising sea level. Along the entire coast of Ceará west of Ponta Grossa the absence of beach rock higher than spring tide level indicates that sea-level was not above its present-day level during the Holocene.Notches in bedrock situated between 2 m and 6 m above spring-tide high-water level that we formerly described as Holocene, are now believed to be Sangamonian.     

Carbonate diagenesis and feldspar alteration in fracture-related bleaching zones (Buntsandstein,central Germany): possible link to CO<Subscript>2</Subscript>-influenced fluid–mineral reactions

Fracture-related bleaching of Lower Triassic Buntsandstein red beds of central Germany was related to significant carbonate diagenesis and feldspar alteration caused by CO₂-rich fluids. Using cathodoluminescence microscopy and spectroscopy combined with electron microprobe analysis and stable carbon isotope study, two major fluid–mineral interactions were detected: (1) zoned, joint-filling calcites and zoned pore-filling calcite cements, the latter replacing an earlier dolomite, were formed during bleaching. During the calcite formation and dolomite–calcite transformation, iron was incorporated into the calcite cement crystal cores due to Fe availability from the coeval bleaching. The dedolomitisation was ultimately associated with a volume increase. The related permeability decrease implies a certain degree of sealing and increasing retention of CO₂, and the volume increase offers a minor CO₂ sink. Carbonate-rich sandstone, therefore, can provide advantages for underground CO₂ storage especially when situated in the fringes of the reservoir. (2) Alkali-feldspar alteration due to the bleaching fluids is reflected in cathodoluminescence spectra predominantly by the modulation of a brown luminescence emission peak (~620 nm). This peak represents a newly discovered effect related to alkali-feldspar alteration not solely associated with bleaching. Its modulation by the bleaching is interpreted to be due to Na depletion or a lattice defect in the Si–O bonds of the SiO₄-tetrahedron. Alteration reflected by this luminescence feature has a destructive effect on the feldspars implying the possibility of diminished rock integrity due to bleaching and, hence, CO₂-rich fluids. Two further CL spectral changes related to bleaching occur, (a) decreased intensity between around 570 nm assigned to Mn-depletion, and (b) increased amplitude and wavelength shift of the red (~680 nm) band. Converging evidence from carbonate and feldspar diagenesis, stable carbon isotope data and analysis of fracture directions suggests that CO₂ fluids contributed to a significant extent to the bleaching phenomena and alteration in the studied Buntsandstein strata.     

Flood disaster subcultures in The Netherlands: the parishes of Borgharen and Itteren

The Netherlands knows a persistent threat of flooding. To adapt to this dangerous reality, the Dutch have cultivated what disaster research literature has labeled ‘disaster subcultures’ or a set of cultural (tangible and intangible) tools to deal with the recurrent hazard. While there is abundant attention for the way the Dutch ‘coastal’ and ‘low-lying’ communities deal with the recurrent threat of (coastal) flooding, less is known about the way the Dutch ‘high-lands’ deal with the yearly threat of (fluvial) flooding. This article presents the findings of an explorative research endeavor (2011–2013) aimed at discerning if the disaster subculture concept has contemporary relevance in the Netherlands, particularly with respect to flooding, and if so, whether applying this lens would reveal more about the nature of existing disaster subcultures. Because less is known about the Dutch ‘high-lands,’ we chose to look into the existence and attributes of disaster subcultures in the parishes Borgharen and Itteren, which experience a systematic threat of flooding. Our findings suggest that the disaster subculture lens is valuable as it enables the empirical appreciation of disaster subcultures, even in a small country like the Netherlands, and it unveiled elements of these neighboring parishes’ flood reality that otherwise might have gone unnoticed and that seem central to understanding these two parishes’ levels of vulnerability and resilience. It is our contention that the concept ‘disaster subculture’ makes a greater understanding possible of the cultural context from which vulnerability and resilience to specific and recurrent threats emerge.     

Deformation of dry and wet sandstone targets during hypervelocity impact experiments,as revealed from the MEMIN Program

Abstract– Hypervelocity impact experiments on dry and water‐saturated targets of fine‐grained quartz sandstone, performed within the MEMIN project, have been investigated to determine the effects of porosity and pore space saturation on deformation mechanisms in the crater’s subsurface. A dry sandstone cube and a 90% water‐saturated sandstone cube (Seeberger Sandstein, 20 cm side length, about 23% porosity) were impacted at the Fraunhofer EMI acceleration facilities by 2.5 mm diameter steel spheres at 4.8 and 5.3 km s^?1, respectively. Microstructural postimpact analyses of the bisected craters revealed differences in the subsurface deformation for the dry and the wet target experiments. Enhanced grain comminution and compaction in the dry experiment and a wider extent of localized deformation in the saturated experiment suggest a direct influence of pore water on deformation mechanisms. We suggest that the pore water reduces the shock impedance mismatch between grains and pore space, and thus reduces the peak stresses at grain–grain contacts. This effect inhibits profound grain comminution and effective compaction, but allows for reduced shock wave attenuation and a more effective transport of energy into the target. The reduced shock wave attenuation is supposed to be responsible for the enhanced crater growth and the development of “near surface” fractures in the wet target.     

Magnetic and nuclear structure and thermal expansion of orthorhombic and monoclinic polymorphs of CoGeO3 pyroxene

CoGeO₃ was synthesized at 1,273 and 1,448 K using ceramic sintering techniques in the monoclinic and orthorhombic modification, respectively. The two compounds were analysed by magnetic susceptibility measurements and neutron diffraction in order to study magnetic ordering and spin structures at low temperature. The monoclinic form of CoGeO₃ has C2/c symmetry and orders magnetically below 36 K with a small negative paramagnetic Curie temperature θ _P = −4.6 (2) K. The magnetic structure can be described with k = (1, 0, 0) in the magnetic space group C2′/c′ having a ferromagnetic spin arrangement within the chains of M1 sites, but a dominating antiferromagnetic coupling between the chains. At the M1 sites the magnetic spins are aligned within the a–c plane forming an angle of 120° with the +a-axis and they are not parallel to the spins at M2. Here spins are also ferromagnetically coupled within, but antiferromagnetically coupled between the M1/M2 site bands. The orthorhombic phase of CoGeO₃ displays Pbca symmetry and transforms to an antiferromagnetically ordered state [θ _P = −18.6(2) K] below 33 K. The magnetic spin structure can be described with k = (0, 0, 0) in space group Pbca′ and it is similar to the one of the C2/c phase except that it is non-collinear in nature, i.e. there are components of the magnetic moment along all three crystallographic axes. Small magneto-elastic coupling is observed in the orthorhombic phase.     

Numerical simulation of subsurface characterization methods: application to a natural aquifer analogue

Information from an outcrop is used as an analogue of a natural heterogeneous aquifer in order to provide an exhaustive data set of hydraulic properties. Based on this data, two commonly used borehole based investigation methods are simulated numerically. For a scenario of sparse sampling of the aquifer, the process of regionalization of the borehole hydraulic conductivity values is simulated by application of a deterministic interpolation approach and conditioned stochastic simulations. Comparison of the cumulative distributions of particle arrival times illustrates the effects of the sparse sampling, the properties of the individual investigation methods and the regionalization methods on the ability to predict flow and transport behaviour in the real system (i.e. the exhaustive data set).