ISOLATION, PURIFICATION AND CHARACTERIZATION OF THE HYDROGEN EVOLUTION PROMOTING FACTOR OF HYDROGENASE OF SPIRULINA PLATENSIS

A component (s-factor) with obvious promoting effect on hydrogen evolution of hydrogenase has beenisolated and extracted from a Cell=free preparation of Spirulina platensis.The effect of the s-factor in the re-action system is similar to that of Na_2S_2O_4, but is coupled with ligh. The s-factor has the maximumabsorption peak at 620 nm in the oxidized state, at 590 nm in the reduced state. The partially purifieds-factor showed two bands by SDS-PAGE and is distinctly different from phycocyanin,which has nochange of oxidized state and reduced state absorption spectra, and also has no promoting effect onhydrogenase of Spirulina platensis under the light.     

新疆塔中南坡奥陶系的地层缺失和沉积相变化

按照奥陶系内部6个组沉积的时间片段拟定塔中南坡不同区块存在不同程度的缺失。部分关键层段的牙形石和几丁虫组合特征证明一间房组和恰尔巴克组在塔中部分井区是存在的,但恰尔巴克组的分布范围最狭窄。总体上,塔中南坡隆起区地层缺失较多,古城墟隆起基本完整。据缺失状况和岩相展布,显示塔中南坡的沉积单元具有由东往西迁移的特征,且各时段迁移的距离与速度存在较大差异。     

Evolution of subcontinental lithospheric mantle beneath eastern China: Re–Os isotopic evidence from mantle xenoliths in Paleozoic kimberlites and Mesozoic basalts

The ages of subcontinental lithospheric mantle beneath the North China and South China cratons are less well-constrained than the overlying crust. We report Re–Os isotope systematics of mantle xenoliths entrained in Paleozoic kimberlites and Mesozoic basalts from eastern China. Peridotite xenoliths from the Fuxian and Mengyin Paleozoic diamondiferous kimberlites in the North China Craton give Archean Re depletion ages of 2.6–3.2 Ga and melt depletion ages of 2.9–3.4 Ga. No obvious differences in Re and Os abundances, Os isotopic ratios and model ages are observed between spinel-facies and garnet-facies peridotites from both kimberlite localities. The Re–Os isotopic data, together with the PGE concentrations, demonstrate that beneath the Archean continental crust of the eastern North China Craton, Archean lithospheric mantle of spinel- to diamond-facies existed without apparent compositional stratification during the Paleozoic. The Mesozoic and Cenozoic basalt-borne peridotite and pyroxenite xenoliths, on the other hand, show geochemical features indicating metasomatic enrichment, along with a large range of the Re–Os isotopic model ages from Proterozoic to Phanerozoic. These features indicate that lithospheric transformation or refertilization through melt-peridotite interaction could be the primary mechanism for compositional changes during the Phanerozoic, rather than delamination or thermal-mechanical erosion, despite the potential of these latter processes to play an important role for the loss of garnet-facies mantle. A fresh garnet lherzolite xenolith from the Yangtze Block has a Re depletion age of ∼1.04 Ga, much younger than overlying Archean crustal rocks but the same Re depletion ages as spinel lherzolite xenoliths from adjacent Mesozoic basalts, indicating Neoproterozoic resetting of the Re–Os system in the South China Craton.     

松辽盆地尚家—太平川地区石油地质条件及勘探方向分析

通过对尚家—太平川地区构造演化、烃源岩特征、沉积特征、储盖组合、油水关系及油藏类型和油气成藏特征的分析,研究了本区的石油地质条件,认为烃源岩具有较好的生、排烃能力,分流河道砂体为油气聚集提供较好的沉积环境,良好的储盖组合有利于油气的聚集与保存。研究区没有统一油水界面,尚家地区以岩性—构造油藏为主,太平川地区以构造—岩性油藏为主。区内扶余—杨大城子油层油气成藏受有效性圈闭、优势运移通道、过剩压力、储集条件和构造诱导作用控制。据上述认识确定了研究区下一步的勘探方向,并已在指导勘探实践中取得了较好的效果。     

藏北高原夏季边界层加热(冷却)特征初探

利用GAME-Tibet1998年加强观测期安多探空观测资料与CAMP-Tibet2004年加强观测期那曲探空资料, 分析了藏北高原夏季大气边界层加热(冷却)特征. 结果表明: 夏季, 藏北高原大气边界层的大气加热(冷却)率的逐日变化特征明显, 晴天时较大, 多云和降雨时较小. 白天大气加热率和夜晚大气冷却率的平均值都基本相当, 印证了大气能量守恒.     

东天山黄山-镜儿泉过铝花岗岩矿物学、地球化学及年代学研究

对东天山黄山-镜儿泉一带黄山南、镜儿泉、图拉尔根沟三个过铝花岗岩作了岩相学、矿物学、地球化学、sr-Nd同位素和锆石U-Pb年代学研究.锆石U-Pb LA-ICP-MS原位定年测得黄山南岩体结晶年龄为259.9±1.4Ma(MSWD=0.86),图拉尔根沟岩体结晶年龄为275.4±8.3Ma(MSWD=29),均侵位于二叠纪碰撞后伸展环境.三个过铝花岗岩均具有低锶同位素初始比值(Isr=0.6969～0.70396)、高εNd(t)值( 5.5～ 7.2)以及年轻的亏损地幔单阶段模式年龄(tDM=0.48～0.56Ga),表明其岩浆源区均为来源于亏损地幔的新生地壳岩石.这种新生地壳岩石可能为偏酸性的火山岩.三个岩体的矿物学和地球化学可分为两类:一类以黄山南白云母花岗岩为代表,为强过铝花岗岩(A/CNK>1.1),强烈亏损Ba、sr和Ti而富集Cs、Rb和K,具有高的Rb/sr(2.03～14.5)和Al2O3/TiO2(110～1592),低的Nb/Ta(3.24～6.76)比值,其稀土元素配分曲线呈"V"字形,显示强烈铕亏损(Eu/Eu*=0.04～0.55),表明这类岩体的直接源岩以泥质岩为主.另一类以图拉尔根沟二云母花岗岩为代表,为弱过铝(1   

无外加流体、350℃和差异应力条件下硫化物再活化实验研究

红透山块状硫化物矿石主要成分为黄铁矿、磁黄铁矿、黄铜矿、闪锌矿和石英、角闪石、黑云母等脉石矿物。将此矿石烘干后作为试料置于岩石三轴应力试验机,在13h内将轴压、围压和温度分步升至1276MPa、414MPa和350℃,然后在空气中自然冷却至室温。实验产物中黄铁矿、石英、长石等以脆性碎裂为主,而磁黄铁矿、黄铜矿、闪锌矿和云母等以塑性变形为主。再活化的黄铜矿、磁黄铁矿和少量闪锌矿呈脉和网脉穿插黄铁矿碎斑。实验结果表明,即使没有外来流体加入．构造动力作用所导致的流体包裹体破坏所释出的流体,就足以使成矿物质发生活化转移和再活化。     

大凌河流域河道生态需水量估算

本文从大凌河流域存在的环境问题出发,分别估算了各水资源分区的河道生态需水量（包括生态基流量、自净需水和输沙需水）及各区的河道生态需水贡献量。提出了使用偏枯年（75％保证率）水文数据估算河道生态需水量的方法．弥补了Tennant法、枯水季最小流量法等方法计算结果偏大或偏小的不足。结果表明,大凌河的4个河段（建凌站以上、建凌站至朝阳站、朝阳站至义县站、义县站至锦县段）的河道分区需水量分别为0．55×10^8m^3、5．21×10^8m^3、3．9×10^8m^3和1．34×10×10^8m^3。锦县水文站以上河道生态需水总量11×10^8m^3,占地表水总资源量的59．75％,因此．大凌河地表水资源取用率应在40％以下。     

高速铁路路基黄土滑移变形的动力数值模拟

以郑(州)-西(安)高速铁路为例,选择典型路段(华阴、潼关、灵宝和偃师等),采集大量原状黄土样品,进行动三轴试验,获得一系列黄土动力学参数,如动弹模、动阻尼、残余应变等,进而建立高速铁路黄土路基动力学数值模型。按该线路地震危险性分析结果,合成8条人工地震波(50年10%和2%的超越概率水平),输入该动力学模型中进行计算。结果表明:黄土路基的横向和纵向变形都随着地震力的增大而增大,从而导致黄土滑移和震陷,这与现场激振试验及动三轴震陷试验结果基本一致。该结果为郑西高速铁路抗震陷和抗滑移设计提供了重要依据,并提出了切实可行的黄土抗震陷和滑移地基处理措施,已应用于该高速铁路的设计与施工中。     

中国东北依兰地区块状蓝片岩的地球化学特征

黑龙江省依兰地区分布的黑龙江杂岩被认为足具有缝合带性质的构造混杂岩,其中所含变基性火山熔岩中含有的变质矿物不具有定向组构特征,因此称之为块状蓝片岩.特征变质矿物--蓝闪石的大量出现表明其经历过高压低温变质作用.常量地球化学分析表明,其SiO2含量均在53%以下,TiO2含量超过2%,Na2O K2O的含量为2.77%～6.41%,Na2O的含量普遍大于K2O的含量,Na2O K2O-SiO2变异图显示其具有碱性玄武岩特征;痕量元素地球化学分析显示其轻重稀土元素分异明显,稀土元素配分曲线表现为轻稀土元素富集、重稀土元素亏损的右倾型.球粒陨石标准化图解中,不具有Eu的负异常;Nbx2-Zr/4-Y、Ti/100-Zr-Sr/2与Ba-Th-Nb-La图解的综合分析表明,块状蓝片岩具有碱性洋岛玄武岩(OIB)的特征,它们应是佳木斯地块与松嫩地块之间古洋壳俯冲过程的残留,这为探讨佳木斯陆块与松嫩陆块之间古老洋盆俯冲消减过程提供了重要依据.