Trends in 1,4-Dioxane Analyses: Implications for Identification and Characterization of Contaminated Groundwater Sites

1,4-Dioxane is a contaminant of emerging concern, and there is significant uncertainty about how its environmental occurrence in groundwater is being assessed given the various analytical methods available. This study compiled public sampling records from 2000 to 2019 that included >106,000 analyses of 1,4-dioxane from 822 different U.S. sites. The 1,4-dioxane detection frequency in the entire dataset (including all methods) was 45%, and the median detected concentration was 10 μg/L, highlighting the dilute nature of 1,4-dioxane in environmental media and the importance of selecting methods with adequate sensitivity. The annual distribution of samples analyzed by each method type confirmed a shift towards methods designed for semi-volatile compounds (Method 8270 and Method 8270 SIM) that exhibited consistently lower reporting limits (median reporting limit for each year typically ≤1 μg/L). In contrast, the method designed for volatile compounds (Method 8260) exhibited less sensitivity for 1,4-dioxane (median reporting limit per year between 40 and 100 μg/L) and its use declined significantly over time with increasing use of the moderately sensitive Method 8260 SIM in later years. This shift contributed to an increase in the 1,4-dioxane detection frequency over time, with a strong correlation between the annual detection frequency and the median reporting limit. Sites where 1,4-dioxane was analyzed but not detected overwhelmingly used less-sensitive methods that may not have been adequate for the expected concentration levels. Given the sub-μg/L groundwater criteria issued for 1,4-dioxane by some regulatory agencies, more sensitive and accurate methods will be increasingly needed to assess compliance.     

Radio Emission of Flares and Coronal Mass Ejections

We review recent progress on our understanding of radio emission from solar flares and coronal mass ejections (CMEs) with emphasis on those aspects of the subject that help us address questions about energy release and its properties, the configuration of flare?–?CME source regions, coronal shocks, particle acceleration and transport, and the origin of solar energetic particle (SEP) events. Radio emission from electron beams can provide information about the electron acceleration process, the location of injection of electrons in the corona, and the properties of the ambient coronal structures. Mildly relativistic electrons gyrating in the magnetic fields of flaring loops produce radio emission via the gyrosynchrotron mechanism, which provides constraints on the magnetic field and the properties of energetic electrons. CME detection at radio wavelengths tracks the eruption from its early phase and reveals the participation of a multitude of loops of widely differing scale. Both flares and CMEs can ignite shock waves and radio observations offer the most robust tool to study them. The incorporation of radio data into the study of SEP events reveals that a clear-cut distinction between flare-related and CME-related SEP events is difficult to establish.     

Early Jurassic basal sauropodomorpha dominated tracks from Guizhou,China: Morphology,ethology, and paleoenvironment

The newly discovered large(350 m^2) Yantan dinosaur tracksite, in the Lower Jurassic Ziliujing Formation of Guizhou Province, China, reveals at least 250 footprints of which ~97 can be resolved into trackways of sauropodomorphs. All the trackways are sub parallel likely indicating gregarious behavior. One theropod track(cf. Grallator) was recorded. The sauropodomorph tracks predominantly represent quadrupedal progression(Morphotype A), and footprint morphology is similar to the ichnospecies Liujianpusshunan, characterized by outward pes rotation. Three trackways indicate bipedal progression, and two of these(Morphotype B) indicate inward pes rotation, accompanied by elongate pes digit scratch marks. For the latter phenomenon three possible scenarios are discussed:(1) significant rotation changes accompanying changes in gait,(2) swimming behavior,(3) formation of undertracks.Sedimentological evidence indicates the tracks were made on a linguloid rippled, muddy, immature sandstone substrate characterized by significant differences in substrate consistency across the trackbearing surface. Microbially induced sedimentary structures(MISS) characterized by distinctive wrinkle marks indicate a stressed, probably semi-arid, paleoenvironment that was not conducive to habitation by invertebrate organisms. This is consistent with other evidence that Lower Jurassic sauropodomorph tracks are often associated with semi-arid paleoenvironments.     

Höhenwinde auf dem Seeweg Kapverdenregion — La Plata

Zusammenfassung Durch die Deutsche Atlantische Expedition auf «Meteor» 1925–27 und das maritim-aerologische Werk der Deutschen Seewarte wurden zahlreiche Höhenwindmessungen auf dem Atlantischen Ozean gewonnen. Die Bearbeitung dieses Materials, für das Gebiet südlich von 20° Nordbreite und die Messungen bis 1937, geschieht im Rahmen des Meteorwerkes, in Band XVI als Fortsetzung von Band XV-Kriegsereignisse und Schwierigkeiten der Nachkriegszeit haben die Veröffentlichung leider stark verzögert. Für die vorliegende Mitteilung werden einige Teilergebnisse ausgewählt, die sich auf den Seeweg nach Südamerika beziehen; als Beitrag zur Gewinnung erforderlicher quantitativer Daten über die allgemeine Zirkulation.Für die Höhenstufen 4–5, 9–10 und 14–15 km werden die mittleren Windelemente und die Streuung der Windgeschwindigkeiten behandelt. Es wird die Schichtung der Luftströmungen im Vertikalprofil des Seeweges für 0–15 km Höhe gegeben. Auf die Struktur des Urpassates (der tropischen Ostströmung) und der tropischen Westwindschicht der hohen Troposphäre in den verschiedenen Jahreszeiten wird näher eingegangen.

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Summary By the German Atlantic Expedition on the «Meteor», 1925–1927, and the marine-aerological work of the Deutsche Seewarte numerous upper air wind measurements were gained from the Atlantic. The evaluation of this material for the area in the south of 20° northern latitude and of the measurements up to 1937 is done within the scale of the «Meteorwerk», vol. XVI as a continuation of vol. XV. In consequence of war events and the difficulties of the time after the war the publication has been delayed considerably. For the information on hand, some partial results are selected which refer to the route to South America; as a contribution for gaining necessaryquantitative data on the general circulation.For the levels 4–5, 9–10, and 14–15 km the average wind elements and the dispersion of the wind velocities are treated. The stratification of air currents in the vertical profile of the route is given for the height of 0–15 km. It is entered into particulars of the structure of the «Urpassat» (tropical easterlies), and the tropical West-wind layer of the upper troposphere in various seasons.

     

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Ohne Zusammenfassung     

Morphometric and geological conditions for sediment accumulation in the Udava River,Outer Carpathians,Slovakia

The accumulation of sediment in river channels is a phenomenon that is not only influenced by the channel morphology, but also by the physical and geographical characteristics and the endogenous and exogenous processes taking place in the catchment. This paper presents an analysis of the impact the changes in lithological conditions have on the morphological and morphometric parameters of the Udava River channel and their relation to the channel accumulation forms representative of the river’s longitudinal profile as well as of its planform. Results document when accumulation forms occur and what is their spatial distribution within the longitudinal and cross-sectional river profiles. More resistant structures created sections with a lower degree of sedimentation, while in depression segments the degree of sedimentation was higher. With the increase in longitudinal slope, the impact of channel width on the average channel bar size increased. Also a difference in the accumulation was observed between the left and right bank which could be possibly explained by the impact of Coriolis force.     

Paleoenvironmental and Human Behavioral Implications of the Boegoeberg 1 Late Pleistocene Hyena Den, Northern Cape Province, South Africa

Boegoeberg 1 (BOG1) is located on the Atlantic coast of South Africa, 850 km north of Cape Town. The site is a shallow rock shelter in the side of a sand-choked gully that was emptied by diamond miners. Abundant coprolites, chewed bones, and partially digested bones implicate hyenas as the bone accumulators. The location of the site, quantity of bones, and composition of the fauna imply it was a brown hyena nursery den. The abundance of Cape fur seal bones shows that the hyenas had ready access to the coast. Radiocarbon dates place the site before 37,000 ¹⁴C yr ago, while the large average size of the black-backed jackals and the presence of extralimital ungulates imply cool, moist conditions, probably during the early part of the last glaciation (isotope stage 4 or stage 3 before 37,000 ¹⁴C yr ago) or perhaps during one of the cooler phases (isotope substages 5d or 5b) within the last interglaciation. Comparisons of the BOG1 seal bones to those from regional Middle Stone Age (MSA) and Later Stone Age (LSA) archeological sites suggest (1) that hyena and human seal accumulations can be distinguished by a tendency for vertebrae to be much more common in a hyena accumulation and (2) that hyena and LSA accumulations can be distinguished by a tendency for hyena-accumulated seals to represent a much wider range of individual seal ages. Differences in the way hyenas and people dismember, transport, and consume seal carcasses probably explain the contrast in skeletal part representation, while differences in season of occupation explain the contrast in seal age representation. Like modern brown hyenas, the BOG1 hyenas probably occupied the coast year-round, while the LSA people focused their coastal visits on the August–October interval when nine-to-eleven-month-old seals were abundant. The MSA sample from Klasies River Mouth Cave 1 resembles BOG1 in seal age composition, suggesting that unlike LSA people, MSA people obtained seals more or less throughout the year.     

Effect of selection and sequencing of representative wave conditions on process-based predictions of equilibrium embayed beach morphology

In order to decrease the simulation time of morphodynamic models, often-complex wave climates are reduced to a few representative wave conditions (RWC). When applied to embayed beaches, a test of whether a reduced wave climate is representative or not is to see whether it can recreate the observed equilibrium (long-term averaged) bathymetry of the bay. In this study, the wave climate experienced at Milagro Beach, Tarragona, Spain was discretized into ‘average’ and ‘extreme’ RWCs. Process-based morphodynamic simulations were sequenced and merged based on ‘persistent’ and ‘transient’ forcing conditions, the results of which were used to estimate the equilibrium bathymetry of the bay. Results show that the effect of extreme wave events appeared to have less influence on the equilibrium of the bay compared to average conditions of longer overall duration. Additionally, the persistent seasonal variation of the wave climate produces pronounced beach rotation and tends to accumulate sediment at the extremities of the beach, rather than in the central sections. It is, therefore, important to account for directional variability and persistence in the selection and sequencing of representative wave conditions as is it essential for accurately balancing the effects beach rotation events.     

Mars reconnaissance lander: Vehicle and mission design

There is enormous potential for more mobile planetary surface science. This is especially true in the case of Mars because the ability to cross challenge terrain, access areas of higher elevation, visit diverse geological features and perform long traverses of up to 200 km supports the search for past water and life. Vehicles capable of a ballistic ‘hop’ have been proposed on several occasions, but those proposals using in-situ acquired propellants are the most promising for significant planetary exploration. This paper considers a mission concept termed Mars Reconnaissance Lander using such a vehicle. We describe an approach where planetary science requirements that cannot be met by a conventional rover are used to derive vehicle and mission requirements.The performance of the hopper vehicle was assessed by adding estimates of gravity losses and mission mass constraints to recently developed methods. A baseline vehicle with a scientific payload of 16.5 kg and conservatively estimated sub-system masses is predicted to achieve a flight range of 0.97 km. Using a simple consideration of system reliability, the required cumulative range of 200 km could be achieved with a probability of around 80%. Such a range is sufficient to explore geologically diverse terrains. We therefore plot an illustrative traverse in Hypanis Valles/Xanthe Terra, which encounters crater wall sections, periglacial terrain, aqueous sedimentary deposits and a traverse up an ancient fluvial channel. Such a diversity of sites could not be considered with a conventional rover. The Mars Reconnaissance Lander mission and vehicle presents some very significant engineering challenges, but would represent a valuable complement to rovers, static landers and orbital observations.