Geochemistry of the Rare Earth elements in spilites from the oceanic and continental crust

Analytical data including major elements, the Rare Earths, Ni, Cu, Zn, Rb, and Sr are presented for twenty-three spilites from the Mid-Atlantic Ridge, the Hercynian part of the Variscan geosyncline in Germany, and several localities in Switzerland. Low grade metamorphism (up to approximately 400° C) and spilitization of basaltic rocks apparently do not alter the original Rare Earth element (REE) distributions. This fact permits comparison of the spilites and unaltered tholeiitic basalts from the Mid-Atlantic Ridge. The relative REE distributions thus appear suitable for delineating the original basalt types of spilites formed by metamorphism. The spilites from the Hercynian part of the Variscan geosyncline have a REE distribution pattern which is characteristic of continental tholeiites. It is thus probable that during the formation of this geosyncline the principal magma extruded was of tholeiitic composition and that these rocks were later converted to spilites by metamorphism.     

Dated Paleontological cave sites of Central Europe from Late Middle Pleistocene to early Upper Pleistocene (OIS 5 to OIS 8)

Caves are terrestrial depositories that preserve a large variety of organic and inorganic remains. These may contain important Quaternary climatic and ecological information. Most of the faunal remains, however, cannot be linked to any Interglacial or Glacial period exclusively. Reliable dating of such remains is therefore required. Experience has, however, shown that ESR dating of speleothems or ²³⁰Th/U dating of bones are of disputable value. Only TIMS-²³⁰Th/U dating of speleothems appears to yield reliable ages. Dating the bottom and top of speleothem layers permit assigning Pleistocene faunal remains to the OIS chronology if the deposition of the speleothems and the faunal remains are clearly correlated. Care must be taken to consider the depositional situation of each site before interpreting any age dates. In this paper we present an overview of all numerically dated paleontological cave sites in Central Europe between OIS 5 and OIS 8. A total of 25 strata were dated from 13 sites, most of them deposited during OIS 5; the rest belonging to OIS 6 and 7. Numerically dated paleontological sites older than OIS 8 are not known.     

Geochemical Constraints of the Ediacaran Volcano-Sedimentary Succession of the Sa’al Metamorphic Complex at Wadi Zaghra, South Sinai, Egypt

The volcano-sedimentary succession around Wadi Zaghra in Sinai, at the northernmost segment of the Arabian Nubian Shield, comprises volcanic rocks interbedded with rather immature sediments. The succession is dominated by intermediate to silicic volcanics of medium-to high-K calc-alkaline affinity. It is divided into two units, the lower unit includes intermediate rocks and dacites interbedded with graywackes, semi-pelites and pelites and topped by polymict conglomerates. This unit is subjected to folding and regional metamorphism(up to garnet zone) and is intruded by quartz diorite-granodiorite inducing, locally, low-pressure contact thermal metamorphism. The unmetamorphosed upper unit encompasses acid volcanics intercalated with litharenite, sublitharenite and minor arenite. The rhyolites of this unit pertain to the highly fractionated granites and are characterized by an agpaitic index(NK/A) ranging from 0.87 to 0.96. They may reflect either extensive interaction of subduction-related magmas with the continental crust or a change in the tectonic regime. The present lithological and geochemical characteristics of the studied sediments together with available zircon ages indicate rather distal provenance of their detritus. This detritus comprises fluvial-alluvial sediments accumulated in the intermontane basins, which are half-grabens or tilted fault blocks. The tectonic setting of the depositional basins is active continental margin and continental island arcs. Geochemical patterns of the Zaghra volcano-sedimentary succession indicate their correlation with the Dokhan Volcanics-Hammamat Clastics sequence of the Eastern Desert of Egypt. Also, the Zaghra volcanics display geochemical similarities with those exposed in Sinai, at the Rutig, Ferani and Iqna Shar'a areas. The Zaghra succession is dated as Ediacaran but is not related either to the ensimatic island arc assemblage or to the rift-related assemblage formed during the early stages of the break-up of Rodinia as previously thought.     

Mineralogical and geochemical patterns of urban surface soils, the example of Pforzheim, Germany

This study presents a combined geochemical and mineralogical survey of urban surface soils. Many studies on urban soils are restricted to purely chemical surveys in order to investigate soil pollution caused by anthropogenic activities such as traffic, heating, industrial processing, waste disposal and many more. In environmental studies, chemical elements are often distinguished as lithogenic and anthropogenic elements. As a novel contribution to those studies, the authors combined the analysis of a broad set of chemical elements with the analysis of the main mineralogical phases. The semi-quantification of mineralogical phases supported the assignment of groups of chemical elements to lithogenic or anthropogenic origin. Minerals are important sinks for toxic elements. Thus, knowledge about their distribution in soils is crucial for the assessment of the environmental hazards due to pollution of urban soils. In Pforzheim, surface soils (0–5 cm depth) from various land use types (forest, agriculture, urban green space, settlement areas of various site densities) overlying different geological units (clastic and chemical sediments) were investigated. Urban surface soils of Pforzheim reflect to a considerable degree the mineral and chemical composition of parent rocks. Irrespective of the parent rocks, elevated concentrations of heavy metals (Zn, Cu, Pb, Sn, Ag) were found in soils throughout the whole inner urban settlement area of Pforzheim indicating pollution. These pollutants will tend to accumulate in inner urban surface soils according to the available adsorption capacity, which is normally higher in soils overlying limestone than in soils overlying sandstone. However, inner urban surface soils overlying sandstone show elevated concentrations of carbonates, phyllo-silicates and Fe and elevated pH values compared with forest soils overlying sandstone. Thus, in comparison to forest soils overlying sandstones, inner urban soils overlying sandstone affected by pollution concurrently possess elevated concentrations of mineral phases typically providing relatively high adsorption capacities for heavy metals.     

On the relationship between vegetation and climate in tropical and northern Africa

Vegetation cover is a crucial component of the Earth’s climate system but, still, our understanding of the mechanisms governing the reciprocal influence between atmosphere and vegetation is limited. In this study, we investigate the unilateral atmospheric impact on vegetation cover in tropical and northern Africa, differentiated into regions with different circulation regimes and into detailed land-cover classes. In contrast to former studies, climate predictors from a regional climate model are used as input for a multiple regression model. Climate models provide consistent data without gaps at high spatial resolution, a considerably larger set of available climate variables and the perspective to transfer the statistical relationships to future projections, e.g., in the context of anthropogenic climate change. Indeed, robust climate predictors which drive up to 70 % of observed interannual vegetation variability could be extracted from the climate model. Besides precipitation and temperature, global radiation, and relative humidity play an important role. The statistical transfer functions are plausible in terms of the affected regions and land-cover classes and draw a rather complex picture of the atmosphere–vegetation relation in Africa.     

A unified assessment of marine Mediterranean assemblages: a lesson from benthic hydroids

Hydroids are important components of the communities of rocky bottom shallow coastal areas. The hydrozoan fauna of the Mediterranean Sea is probably one of most investigated in the world, with lots of faunistic and biogeographical studies. However, quantitative studies using the same sampling methodology and controlled sampling effort have been restricted to areas in the Western and Central Mediterranean. We compared hydroid assemblages in four areas of the Mediterranean Sea, from the Gulf of Cádiz to the South Adriatic Sea, following the same sampling and quantification methodology. Our analysis showed the dominant Atlantic character of the assemblages of the Gulf of Cádiz and the South Alboran Sea because of the influence of the inflowing Atlantic waters. Conversely, the hydroid assemblages of the North Alboran Sea were more similar to the assemblages in the Ligurian and in the South Adriatic, and with a number of species ranking between the observed in these two Mediterranean zones. Fourteen species were identified as making the most significant contributions to characterizing the Mediterranean hydroid species pool from a quantitative point of view. These taxa include species previously named as typical components of the Mediterranean hydroid fauna as well as those only recently recorded in the region (Eudendrium moulouyensis) and invaders such as Clytia hummelincki.     

Thermal and transport properties of mantle rock at high pressure: Applications to super-Earths

In the present study, the temperature- and pressure-dependent transport and thermal properties, i.e., viscosity, phonon thermal conductivity, thermal expansivity and heat capacities, as well as electronic and radiative thermal conductivities, have been derived for the mantles of super-Earths. These properties are necessary to understand the interior dynamics and the thermal evolution of those planets. We assume that the mantles consist of MgSiO₃ perovskite (pv), but we discuss the effects of the post-perovskite transition, and we elaborate on an addition of periclase MgO and incorporated Fe. However, MgO is found to only significantly influence the phonon thermal conductivity – the viscosities, heat capacities and thermal expansivities of pv and MgO remain comparable. We use the Keane theory of solids, which takes into account the behavior of solid matter at the infinite pressure limit, adopt the Keane equations of state, and adjust for pv and MgO by comparison with experimental high-pressure and high-temperature data. We find the theory of the infinite pressure limit of Keane to be in excellent agreement with recent ab initio studies and experiments. To calculate the melting curve, we further use the Lindemann–Stacey scaling law and fit it to available experimental data. The best data fitting melting temperature for pv reaches 5700 K at 135 GPa and increases to 20,000 K at 1.1 TPa, corresponding to the core-mantle boundary of a 10 Earth mass super-Earth (10M_Earth). We find the pv adiabatic temperature (with a potential temperature of 1700 K) to reach 2570 K at 135 GPa and 5000 K at 1.1 TPa. To calculate the pressure-and temperature-dependent viscosity, we use the semi-empirical homologous temperature scaling to relate enthalpy change, and hence viscosity, to the melting temperature. We find that the resulting activation volume of pv decreases from 2.8 cm³/mol at 25 GPa to 1.4 cm³/mol at 1.1 TPa-resulting in a viscosity increase by ～15 orders of magnitude through the adiabatic mantle of a 10M_Earth planet. Furthermore, the thermal expansivity (of pv and MgO) decreases by a factor of eight, and the total thermal conductivity (phonon, radiative and electronic) of an Earth-like pv/MgO composite increases by a factor of seven through an adiabatic mantle of a 10M_Earth super-Earth. At higher temperatures, i.e., for super-adiabatic temperature profiles, the electronic and radiative thermal conductivities strongly increase and dominate the conductive heat transport. All findings indicate an increase of heat transfer solely by conduction in the lower mantles of super-Earths. Thus our results disagree with Earth-biased full-mantle convection assumptions made by previous models for super-Earths, and additionally raise questions about the differentiation of massive rocky exoplanets and their ability to generate magnetic fields or sustain plate tectonics.     

<Superscript>87</Superscript>Sr/<Superscript>86</Superscript>Sr anomalies in Late Cretaceous-Early Tertiary strata of the Cauvery basin,south India: Constraints on nature and rate of environmental changes across K-T boundary

The Ariyalur-Pondicherry sub-basin of the Cauvery basin comprises a near complete stratigraphic record of Upper Cretaceous-Lower Tertiary periods. Earlier studies have documented variations of clay mineral assemblages, change in microtexture of siliciclasts and many geochemical and stable isotopic anomalies far below the Cretaceous-Tertiary boundary (KTB) in these strata. This paper documents the occurrences of two positive ⁸⁷Sr/⁸⁶Sr anomalies preceding K-T boundary in this basin and discusses plausible causes. Analysis of trace elemental and stable isotopic profiles, sedimentation history, petrography and mineralogy of the rocks reveal that while both the anomalies may be due to increased detrital influx caused by sea level and climatic changes, the second anomaly might have been influenced by Deccan volcanism which in turn predated KTB. Record of such anomalies preceding K-T boundary supports the view of multi-causal step-wise extinction of biota across KTB.