Determination of Reference Values for NIST SRM 610–617 Glasses Following ISO Guidelines

We present new reference values for the NIST SRM 610–617 glasses following ISO guidelines and the International Association of Geoanalysts’ protocol. Uncertainties at the 95% confidence level (CL) have been determined for bulk‐ and micro‐analytical purposes. In contrast to former compilation procedures, this approach delivers data that consider present‐day requirements of data quality. New analytical data and the nearly complete data set of the GeoReM database were used for this study. Data quality was checked by the application of the Horwitz function and by a careful investigation of analytical procedures. We have determined quantitatively possible element inhomogeneities using different test portion masses of 1, 0.1 and 0.02 μg. Although avoiding the rim region of the glass wafers, we found moderate inhomogeneities of several chalcophile/siderophile elements and gross inhomogeneities of Ni, Se, Pd and Pt at small test portion masses. The extent of inhomogeneity was included in the determination of uncertainties. While the new reference values agree with the NIST certified values with the one exception of Mn in SRM 610, they typically differ by as much as 10% from the Pearce et al. (1997) values in current use. In a few cases (P, S, Cl, Ta, Re) the discrepancies are even higher.     

Temperature and heat flux changes at the base of Laurentide ice sheet inferred from geothermal data (evidence from province of Alberta,Canada)

International Journal of Earth Sciences - Using a previously published temperature log of the 2363-m-deep borehole Hunt well (Alberta, Canada) and the results of its previous interpretation, the...     

BAM‐S005 Type A and B: New Silicate Reference Glasses for Microanalysis

To test whether the silicate reference glasses BAM‐S005‐A and BAM‐S005‐B from BAM (The Federal Institute for Materials Research and Testing, Germany) are suitable materials for microanalysis, we investigated the homogeneity of these reference glasses using the microanalytical techniques EPMA, LA‐ICP‐MS and SIMS. Our study indicated that all major and most trace elements are homogeneously distributed at micrometre sampling scale in both types of glass. However, some trace elements (e.g., Cs, Cl, Cr, Mo and Ni) seem to be inhomogeneously distributed. We also determined the composition of BAM‐S005‐A and BAM‐S005‐B. The EPMA data of major elements confirmed the information values specified by the certificate. With the exception of Sr, Ba, Ce and Pb, our trace element data by LA‐ICP‐MS were also in agreement with the certified values within the stated uncertainty limits. The reasons for the discrepancy in these four elements are still unclear. In addition, we report new data for twenty‐two further trace elements, for which the concentrations were not certified. Based on our investigation, we suggest that both of these materials are suitable for many microanalytical applications.     

Comparative Evaluation of Single‐Well LNAPL Tracer Testing at Five Sites

Light nonaqueous phase liquid (LNAPL) tracer testing is a technique used to directly measure LNAPL flow in situ and evaluate LNAPL mobility and recoverability. The test method consists of adding a fluorescent oil‐soluble tracer to LNAPL within a well, isolating small volumes of LNAPL with known tracer concentrations for use as in‐well calibration standards, and measuring the rate of tracer concentration decline in the well over time. The test measures LNAPL flux through the well, which is directly related to LNAPL mobility and recoverability in the surrounding formation. Test results for a total of 29 wells at five sites are presented. Results from LNAPL tracer testing were comparable to results obtained through other methods, and the method offers a time‐averaged result measured over a relatively long period, in ambient conditions, and reflects the influences of heterogeneity and hydraulic changes. In some cases, tracer concentration decline followed unexpected patterns, and these data have led to a better understanding of test assumptions, mechanisms influencing tracer distribution, and options to improve test execution and data interpretation. Method improvements developed over the course of the field studies included refinement of pre‐test screening of LNAPL fluorescence and improvements to measurement equipment. Overall, the field studies confirmed the technical validity and usefulness of the LNAPL tracing technique to support LNAPL mobility and recoverability assessments.     

What can we hope to know about the symmetry properties of stellar magnetic fields?

We summarize evidence that neither dynamo theory nor the observational data give strong support to the idea that stellar magnetic fields must have dipolar rather than quadrupolar symmetry with respect to the stellar equator. We demonstrate that even the most basic model for magnetic stellar activity, i.e. the Parker migratory dynamo, provides many possibilities for the excitation of large-scale stellar magnetic fields of non-dipolar symmetry. We demonstrate the spontaneous transition of the dynamo-excited magnetic field from one symmetry type to another. We explore observational tests to distinguish between the two types of magnetic field symmetry, and thus detect the presence of quadrupolar magnetic symmetry in stars. Complete absence of quadrupolar symmetry would present a distinct challenge for contemporary stellar dynamo theory. We revisit some observations which, depending on further clarification, may already be revealing some properties of the quadrupolar component of the magnetic fields generated by stellar dynamos.     

Interaction of surface waves at very close wavenumbers

We show that interaction of two monochromatic waves at the water surface enters a different dynamic regime if their wavenumbers become very close. The study is conducted by means of a fully nonlinear wave model. In the course of evolution of the two waves, downshifting of the initial wave energy and growth of the first mode occur depending on wave steepness and dk/k. Behaviour of these features changes if dk/k?<?0.0025: both downshifting and growth rate become independent of dk/k, accompanied by rapid transfer of wave energy to large scales.     

Numerical modeling of 3D fully nonlinear potential periodic waves

A simple and exact numerical scheme for long-term simulations of 3D potential fully nonlinear periodic gravity waves is suggested. The scheme is based on the surface-following nonorthogonal curvilinear coordinate system. Velocity potential is represented as a sum of analytical and nonlinear components. The Poisson equation for the nonlinear component of velocity potential is solved iteratively. Fourier transform method, the second-order accuracy approximation of vertical derivatives on a stretched vertical grid and the fourth-order Runge–Kutta time stepping are used. The scheme is validated by simulation of steep Stokes waves. A one-processor version of the model for PC allows us to simulate evolution of a wave field with thousands degrees of freedom for hundreds of wave periods. The scheme is designed for investigation of nonlinear 2D surface waves, generation of extreme waves, and direct calculations of nonlinear interactions.     

Eigen analysis of tree-ring records: part 2, posing the eigen problem

The technique of expanding meteorological fields on eigenvectors of the field covariation matrix is popular. In this paper, we propose for the first time to use a mathematically similar technique to solve the main problem of dendrochronology: classifying variations in tree-ring records as either age- and microenvironment-dependent or climate-induced. Applying this technique to a sample of very long-lived Qilian junipers (Sabina przewalskii Kom.) from the Dulan region in western China, we demonstrate that the ring-width variations projected on the first eigenvector are age-dependent, but those projected on several of the first subsequent vectors are mainly climate-induced. In particular, the second and third projections capture multi-centennial climatic variations, and the variations projected on the fourth through seventh eigenvectors show periodic variations that are probably induced by the 178-year solar cycle. The projections on the smallest eigenvectors seem to be negligible.