The Mesoproterozoic basement in the southern Baltic Sea: insights from the G 14–1 off-shore borehole

The continuation of the Mesoproterozoic basement of the southern Fennoscandian Shield is documented in the G 14–1 off-shore borehole, northeast of the island of Rügen, where crystalline rocks of monzogranitic composition occur beneath flat-lying early Palaeozoic sediments at a depth of approximately 2,000 m. The greenish-grey, or partly reddish-grey, granites show a slightly porphyritic texture marked by plagioclase crystals or aggregates in a groundmass dominated by fresh microcline. Chloritized biotite occurs as a subordinate mafic phase. Ductile and brittle deformation is indicated by a weak foliation and the occurrence of several cataclastic zones, respectively. Major and trace element geochemistry suggest that these rocks are K-rich calc-alkaline granites and represent a restite-poor melting product of a granodioritic protolith. The low MgO, Cr, Ni and Co concentrations and relatively high content of accessory phases (apatite, zircon) point to formation of water undersaturated, high temperature (>900 °C) melts at low degrees of partial melting. Although the G 14 granite lacks hornblende, in contrast to most of the granites from Bornholm, it seems geochemically related to them. Analysed samples mostly fit an intermediate position between the Rønne and Vang granitoids, which both belong to a group of Mesoproterozoic intrusions showing partial ductile deformation. (Y+Nb) vs. Rb plots suggest that all these granitic rocks were generated in intracratonic conditions. A genetic relationship between them and contemporaneously intruded Karlshamn-group granites in Blekinge, eastern Scania and Småland is supported by intrusion age of 1,460±3 Ma obtained from Pb-Pb isotope ratios measured on single zircons of the G 14 granite.     

Gem corundum deposits of Madagascar: A review

Madagascar is one of the most important gem-producing countries in the world, including ruby and sapphires. Gem corundum deposits formed at different stages in the geological evolution of the island and in contrasting environments. Four main settings are identified: (1) Gem corundum formed in the Precambrian basement within the Neoproterozoic terranes of southern Madagascar, and in the volcano-sedimentary series of Beforona, north of Antananarivo. In the south, high-temperature (700 to 800 °C) and low-pressure (4 to 5 kbar) granulites contain deposits formed during the Pan-African orogenesis between 565 and 490 Ma. They accompany mafic and ultramafic complexes (ruby deposits of the Vohibory group), skarns at the contact between Anosyan granites and the Proterozoic Tranomaro group (sapphire deposits of the Tranomaro–Andranondambo district), and shear-zone corridors cross-cutting feldspathic gneisses, cordieritites and clinopyroxenites in the Tranomaro, Vohimena and Androyan metamorphic series (biotite schist deposits of Sahambano and Zazafotsy, cordieritites of Iankaroka and Ambatomena). The circulation of fluids, especially along discontinuities, allowed in-situ alkaline metasomatism, forming corundum host rocks related to desilicified granites, biotitites, “sakenites” and “corundumites”. (2) Gem corundum also occurs in the Triassic detrital formations of the Isalo group, as giant palaeoplacers in the Ilakaka–Sakaraha area. Here, sapphires and rubies may come from the metamorphic granulitic terranes of southern Madagascar. (3) Gem corundum deposits occur within the Neogene-Quaternary alkali basalts from Ankaratra (Antsirabe–Antanifotsy area) and in the Ambohitra Province (Nosy Be, Ambato and Ambondromifehy districts). Primary deposits are rare, except at Soamiakatra where ruby in gabbroic and clinopyroxenite xenoliths within alkali-basalts probably derive from mantle garnet peridotites. The blue-green-yellow sapphires typical of basaltic fields are always recovered in palaeoplacer (in karst formed upon Jurassic limestones from the Montagne d'Ambre, Antsiranana Province) and alluvial and soil placers (Ankaratra volcanic massif). (4) Deposits occur within Quaternary eluvial, colluvial and alluvial concentrations, such as high-quality rubies from the Andilamena and Vatomandry deposits.     

Conceptual understanding of climate change with a globally resolved energy balance model

The future climate change projections are essentially based on coupled general circulation model (CGCM) simulations, which give a distinct global warming pattern with arctic winter amplification, an equilibrium land-sea warming contrast and an inter-hemispheric warming gradient. While these simulations are the most important tool of the Intergovernmental Panel on Climate Change (IPCC) predictions, the conceptual understanding of these predicted structures of climate change and the causes of their uncertainties is very difficult to reach if only based on these highly complex CGCM simulations. In the study presented here we will introduce a very simple, globally resolved energy balance (GREB) model, which is capable of simulating the main characteristics of global warming. The model shall give a bridge between the strongly simplified energy balance models and the fully coupled 4-dimensional complex CGCMs. It provides a fast tool for the conceptual understanding and development of hypotheses for climate change studies, which shall build a basis or starting point for more detailed studies of observations and CGCM simulations. It is based on the surface energy balance by very simple representations of solar and thermal radiation, the atmospheric hydrological cycle, sensible turbulent heat flux, transport by the mean atmospheric circulation and heat exchange with the deeper ocean. Despite some limitations in the representations of the basic processes, the models climate sensitivity and the spatial structure of the warming pattern are within the uncertainties of the IPCC models simulations. It is capable of simulating aspects of the arctic winter amplification, the equilibrium land-sea warming contrast and the inter-hemispheric warming gradient with good agreement to the IPCC models in amplitude and structure. The results give some insight into the understanding of the land-sea contrast and the polar amplification. The GREB model suggests that the regional inhomogeneous distribution of atmospheric water vapor and the non-linear sensitivity of the downward thermal radiation to changes in the atmospheric water vapor concentration partly cause the land-sea contrast and may also contribute to the polar amplification. The combination of these characteristics causes, in general, dry and cold regions to warm more than other regions.     

Analysis of the non-linearity in the pattern and time evolution of El Niño southern oscillation

In this study the observed non-linearity in the spatial pattern and time evolution of El Niño Southern Oscillation (ENSO) events is analyzed. It is shown that ENSO skewness is not only a characteristic of the amplitude of events (El Niños being stronger than La Niñas) but also of the spatial pattern and time evolution. It is demonstrated that these non-linearities can be related to the non-linear response of the zonal winds to sea surface temperature (SST) anomalies. It is shown in observations as well as in coupled model simulations that significant differences in the spatial pattern between positive (El Niño) versus negative (La Niña) and strong versus weak events exist, which is mostly describing the difference between central and east Pacific events. Central Pacific events tend to be weak El Niño or strong La Niña events. In turn east Pacific events tend to be strong El Niño or weak La Niña events. A rotation of the two leading empirical orthogonal function modes illustrates that for both El Niño and La Niña extreme events are more likely than expected from a normal distribution. The Bjerknes feedbacks and time evolution of strong ENSO events in observations as well as in coupled model simulations also show strong asymmetries, with strong El Niños being forced more strongly by zonal wind than by thermocline depth anomalies and are followed by La Niña events. In turn strong La Niña events are preceded by El Niño events and are more strongly forced by thermocline depth anomalies than by wind anomalies. Further, the zonal wind response to sea surface temperature anomalies during strong El Niño events is stronger and shifted to the east relative to strong La Niña events, supporting the eastward shifted El Niño pattern and the asymmetric time evolution. Based on the simplified hybrid coupled RECHOZ model of ENSO it can be shown that the non-linear zonal wind response to SST anomalies causes the asymmetric forcings of ENSO events. This also implies that strong El Niños are mostly wind driven and less predictable and strong La Niñas are mostly thermocline depth driven and better predictable, which is demonstrated by a set of 100 perfect model forecast ensembles.     

Walker circulation controls ENSO atmospheric feedbacks in uncoupled and coupled climate model simulations

Many climate models strongly underestimate the two most important atmospheric feedbacks operating in El Niño/Southern Oscillation (ENSO), the positive (amplifying) zonal surface wind feedback and negative (damping) surface-heat flux feedback (hereafter ENSO atmospheric feedbacks, EAF). This hampers a realistic representation of ENSO dynamics in these models. Here we show that the atmospheric components of climate models participating in the 5th phase of the Coupled Model Intercomparison Project (CMIP5) when forced by observed sea surface temperatures (SST), already underestimate EAF on average by 23%, but less than their coupled counterparts (on average by 54%). There is a pronounced tendency of atmosphere models to simulate stronger EAF, when they exhibit a stronger mean deep convection and enhanced cloud cover over the western equatorial Pacific (WEP), indicative of a stronger rising branch of the Pacific Walker Circulation (PWC). Further, differences in the mean deep convection over the WEP between the coupled and uncoupled models explain a large part of the differences in EAF, with the deep convection in the coupled models strongly depending on the equatorial Pacific SST bias. Experiments with a single atmosphere model support the relation between the equatorial Pacific atmospheric mean state, the SST bias and the EAF. An implemented cold SST bias in the observed SST forcing weakens deep convection and reduces cloud cover in the rising branch of the PWC, causing weaker EAF. A warm SST bias has the opposite effect. Our results elucidate how biases in the mean state of the PWC and equatorial SST hamper a realistic simulation of the EAF.     

Comparing the spatial structure of variability in two datasets against each other on the basis of EOF-modes

In analysis of climate variability or change it is often of interest how the spatial structure in modes of variability in two datasets differ from each other, e.g. between past and future climate or between models and observations. Often such analysis is based on Empirical Orthogonal Function (EOF) analysis or other simple indices of large-scale spatial structures. The present analysis lays out a concept on how two datasets of multivariate climate variability can be compared against each other on basis of EOF analysis and how the differences in the multivariate spatial structure between the two datasets can be quantified in terms of explained variance in the leading spatial patterns. It is also illustrated how the patterns of largest differences between the two datasets can be defined and interpreted. We illustrate this method on the basis of several well-defined artificial examples and by comparing our approach with examples of climate change studies from the literature. These literature examples include analysis of changes in the modes of variability under climate change for the sea level pressure (SLP) of the North Atlantic and Europe, the SLP of the Southern Hemisphere, the surface temperature of the Northern Hemisphere, the sea surface temperature of the North Pacific and for precipitation in the tropical Indo-Pacific.     

A new magnetostratigraphic framework for the Lower Miocene (Burdigalian/Ottnangian, Karpatian) in the North Alpine Foreland Basin

Oligocene–Miocene chronostratigraphic correlations within the Paratethys domain are still highly controversial. This study focuses on the late Early Miocene of the Swiss and S-German Molasse Basin (Late Burdigalian, Ottnangian–Karpatian). Previous studies have published different chronologies for this time interval that is represented by the biostratigraphically well constrained Upper Marine Molasse (OMM, lower and middle Ottnangian), Upper Brackish Molasse (OBM, Grimmelfingen and Kirchberg Formations, middle and upper Ottnangian to lower Karpatian, MN 4a–MN 4b) and Upper Freshwater Molasse (OSM, Karpatian–Badenian, MN 5). Here, we suggest a new chronostratigraphic framework, based on integrated magneto-litho-biostratigraphic studies on four sections and three boreholes. Our data indicate that the OBM comprises chrons 5D.1r and 5Dn (Grimmelfingen Fm), chron 5Cr (lower Kirchberg Fm) and the oldest part of chron 5Cn.3n (upper Kirchberg Fm). The OSM begins during chron 5Cn.3n, continues through 5Cn, and includes a long reversed segment that can be correlated to chron 5Br. The OMM-OSM transition was completed at 16.0 Ma in the Swiss Molasse Basin, while the OBM-OSM changeover ended at 16.6 Ma in the S-German Molasse Basin. As the lower Kirchberg Fm represents a facies of the Ottnangian, our data suggest that the Ottnangian–Karpatian boundary in the Molasse Basin is approximately at 16.8 Ma, close to the 5Cr–5Cn.3n magnetic reversal, and thus 0.4 Myr younger than the inferred age of 17.2 Ma used in recent Paratethys time scales. Notably, this would not be problematic for the Paratethys stratigraphy, because chron 5Cr is mainly represented by a sedimentation gap in the Central Paratethys. We also realise, however, that additional data is still required to definitely solve the age debate concerning this intriguing time interval in the North Alpine Foreland Basin. We dedicate this work to our dear friend and colleague Jean-Pierre Berger (8 July 1956–18 January 2012).     

Distribution of phosphine in the offshore area of the Southwest Yellow Sea,East Asia

Phosphine is a natural gaseous compound in the phosphorus biogeochemical cycle. This paper studies the spatial and temporal distributions of matrix-bound phosphine (MBP) and gaseous phosphine in the offshore area of the Southwest Yellow Sea, East Asia. The results show that MBP concentrations in marine surface sediments range from 0.69 ± 0.06 ng/kg (dry) to 179 ± 29 ng/kg (dry). Higher seasonal MBP concentrations in sediments are found in fall than in spring or winter in most sites. High MBP contents are observed in two fish-breeding areas. MBP concentrations decrease with distance to the coast, except in the southeast of the sampling area. MBP levels in marine sediments are found to be higher than those at several other places: freshwater sediments and soil, except eutrophic lakes. Gaseous phosphine contents in fall range from 0.14 ± 0.00 ng/m³ to 9.83 ± 0.97 ng/m³. No correlation is observed between MBP and gaseous phosphine.