Exploring the Moon's surface for remnants of the lunar mantle 1. Dunite xenoliths in mare basalts. A crustal or mantle origin?

Remotely sensed observations from recent missions (e.g., GRAIL, Kaguya, Chandrayaan‐1) have been interpreted as indicating that the deep crust and upper mantle are close to or at the lunar surface in many large impact basins (e.g., Crisium, Apollo, Moscoviense). If this is correct, the capability of either impact or volcanic processes to transport mantle lithologies to the lunar surface should be enhanced in these regions. Somewhat problematic to these observations and interpretations is that examples of mantle lithologies in the lunar sample collection (Apollo Program, Luna Program, lunar meteorites) are at best ambiguous. Dunite xenoliths in high‐Ti mare basalt 74275 are one of these ambiguous examples. In this high‐Ti mare basalt, olivine occurs in three generations: olivine associated with dunite xenoliths, olivine megacrysts, and olivine microphenocrysts. The dunite xenoliths are anhedral in shape and are generally greater than 800 μm in diameter. The interior of the xenoliths are fairly homogeneous with regard to many divalent cations. For example, the Mg# (Mg/Mg + Fe × 100) ranges from 82 to 83 in their interiors and decreases from 82 to 68 over the 10–30 μm wide outer rim. Titanium and phosphorus X‐ray maps of the xenolith illustrate that these slow diffusing elements preserve primary cumulate zoning textures. These textures indicate that the xenoliths consist of many individual olivine grains approximately 150–200 μm in diameter with low Ti, Al, and P cores. These highly incompatible elements are enriched in the outer Fe‐rich rims of the xenoliths and slightly enriched in the rims of the individual olivine grains. Highly compatible elements in olivine such as Ni exhibit a decrease in the rim surrounding the xenolith, an increase in the incompatible element depleted cores of the individual olivine grains, and a slight decrease in the “interior rims” of the individual olivine grains. Inferred melt composition, liquid lines of descent, and zoning profiles enable the reconstruction of the petrogenesis of the dunite xenoliths. Preservation of primary magmatic zoning (Ti, P, Al) and lack of textures similar to high‐pressure mineral assemblages exhibited by the Mg‐suite (Shearer et al. 2015) indicate that these xenoliths do not represent deep crustal or shallow mantle lithologies. Further, they are chemically and mineralogically distinct from Mg‐suite dunites identified from the Apollo 17 site. More likely, they represent olivine cumulates that crystallized from a low‐Ti mare basalt at intermediate to shallow crustal levels. The parent basalt to the dunite xenolith lithology was more primitive than low‐Ti basalts thus far returned from the Moon. Furthermore, this parental magma and its more evolved daughter magmas are not represented in the basalt sample suite returned from the Taurus‐Littrow Valley by the Apollo 17 mission. The dunite xenolith records several episodes of crystallization and re‐equilibration. During the last episode of re‐equilibration, the dunite cumulate was sampled by the 74275 high‐Ti basalt and transported over a period of 30–70 days to the lunar surface.     

Comparison of AnnAGNPS and SWAT model simulation results in USDA‐CEAP agricultural watersheds in south‐central Kansas

This study was conducted under the USDA‐Conservation Effects Assessment Project (CEAP) in the Cheney Lake watershed in south‐central Kansas. The Cheney Lake watershed has been identified as ‘impaired waters’ under Section 303(d) of the Federal Clean Water Act for sediments and total phosphorus. The USDA‐CEAP seeks to quantify environmental benefits of conservation programmes on water quality by monitoring and modelling. Two of the most widely used USDA watershed‐scale models are Annualized AGricultural Non‐Point Source (AnnAGNPS) and Soil and Water Assessment Tool (SWAT). The objectives of this study were to compare hydrology, sediment, and total phosphorus simulation results from AnnAGNPS and SWAT in separate calibration and validation watersheds. Models were calibrated in Red Rock Creek watershed and validated in Goose Creek watershed, both sub‐watersheds of the Cheney Lake watershed. Forty‐five months (January 1997 to September 2000) of monthly measured flow and water quality data were used to evaluate the two models. Both models generally provided from fair to very good correlation and model efficiency for simulating surface runoff and sediment yield during calibration and validation (correlation coefficient; R², from 0·50 to 0·89, Nash Sutcliffe efficiency index, E, from 0·47 to 0·73, root mean square error, RMSE, from 0·25 to 0·45 m³ s^?1 for flow, from 158 to 312 Mg for sediment yield). Total phosphorus predictions from calibration and validation of SWAT indicated good correlation and model efficiency (R² from 0·60 to 0·70, E from 0·63 to 0·68) while total phosphorus predictions from validation of AnnAGNPS were from unsatisfactory to very good (R² from 0·60 to 0·77, E from ? 2·38 to 0·32). The root mean square error–observations standard deviation ratio (RSR) was estimated as excellent (from 0·08 to 0·25) for the all model simulated parameters during the calibration and validation study. The percentage bias (PBIAS) of the model simulated parameters varied from unsatisfactory to excellent (from 128 to 3). This study determined SWAT to be the most appropriate model for this watershed based on calibration and validation results. Copyright © 2008 John Wiley & Sons, Ltd.     

Internal structure of a trough blowout, determined from migrated ground-penetrating radar profiles

Ground‐penetrating radar (GPR) was used to investigate the relationship between the geomorphological development of a large aeolian trough blowout and the stratigraphy and internal sedimentary structure of its associated deposits. Although analogous, many of the data‐processing techniques routinely applied in seismic reflection are very rarely applied in GPR studies. In this study, a simple migration program was used that significantly enhanced the quality of GPR images from a large trough blowout at Raven Meols on the Sefton coast, northwest England. These improvements aided subsequent data interpretation, which was achieved through application of the principles of radar stratigraphy. GPR shows the pre‐blowout dunes to have a complex internal structure that suggests they were formed in the presence of at least a partial vegetation cover. Subsequent to stabilization of these dunes a thin soil developed. This dune soil forms an important radar sequence boundary and delineates a complex topography beneath the depositional lobe of the blowout. The internal structure of the depositional lobe of the blowout does not conform to a model of simple radial foreset deposition, as derived from contemporary process studies reported in the literature. Instead, the pattern of deposition has been extensively modified by the antecedent dune topography and by varying spatial and temporal exposure to important sand‐transporting winds that is partly controlled by interactions between the regional wind pattern and local dune morphology. Trough blowout deposits in coastal aeolian sedimentary sequences are likely to be recognized by the presence of laterally continuous packets of relatively high‐angle cross‐strata, which often display a spatially‐variable radial dip pattern that is only very poorly or partially developed. In addition, a soil, or other surface representing a significant hiatus in dune deposition, is likely to underlie the blowout deposits, the topography of which will show a clear relationship to the dip and orientation of the overlying cross‐strata.     

Mahafir: A water harvesting system in the Eastern Jordan (Badia) Eesert

There are many different water harvesting systems in the Middle East and the operation of one type, the mahafir, was investigated in the Badia Region of Jordan. Mahafir are crescent and rectangular shaped excavations dug into the playa surface, now filled with sediment. Their previous volumes were estimated through topographical survey of the surrounding earth mounds. The average depth of the mahafir was found to be 3.2 m; storing a total water volume of 111,619 m³ at Maharouta and 55,005 m³ at Anka. The mahafir only occupy 4% of the playa surface and their source of water is primarily direct rainfall onto the playa surface augmented by runoff from adjacent slopes. Taking annual rainfalls as an input from 1963 to 1992 and even assuming rainfall harvesting is only 10% effective it appears that the full water storage potential of the mahafir could be met in most years.     

A basalt-trachyte-phonolite series from Ua Pu,Marquesas Islands,Pacific Ocean

The paper describes a suite of volcanic and intrusive rocks from Ua Pu, one of the Marquesas Islands, situated in the central Pacific Ocean. The rocks comprise alkali olivine basalts, hawaiites, mugearites, trachytes, and phonolites. Their petrographic characters are briefly described and 24 new chemical analyses presented. The rocks fall into a sodic and a potassic series, since some rocks are richer in K₂O than Na₂O, whilst the phonolites have exceptionally high total alkali contents.The differentiation of the series is discussed and special attention is paid to the phonolites in which icositetrahedral pseudomorphs occur. It is concluded that these pseudomorphs are probably after analcime rather than leucite.     

Fluxes of metals to a manganese nodule radiochemical,chemical, structural,and mineralogical studies

Fluxes of metals to the top and bottom surfaces of a manganese nodule were determined by combining radiochemical (²³⁰Th,²³¹Pa,²³²Th,²³⁸U,²³⁴U) and detailed chemical data. The top of the nodule had been growing in its collected orientation at 4.7 mm Myr^?1 for at least 0.5 Myr and accreting Mn at 200 μg cm^?2 kyr^?1. The bottom of the nodule had been growing in its collected orientation at about 12 mm Myr^?1 for at least 0.3 Myr and accreting Mn at about 700 μg cm^?2 yr^?1. Although the top of the nodule was enriched in iron relative to the bottom, the nodule had been accreting Fe 50% faster on the bottom.²³²Th was also accumulating more rapidly in the bottom despite a 20-fold enrichment of²³⁰Th on the top.The distribution of alpha-emitting nuclides calculated from detailed radiochemical measurements matched closely the pattern revealed by 109-day exposures of alpha-sensitive film to the nodule. However, the shape and slope of the total alpha profile with depth into the nodule was affected strongly by²²⁶Ra and²²²Rn migrations making the alpha-track technique alone an inadequate method of measuring nodule growth rates.Diffusion of radium in the nodule may have been affected by diagenetic reactions which produce barite, phillipsite and todorokite within 1 mm of the nodule surface; however, our sampling interval was too broad to document the effect. We have not been able to resolve the importance of nodule diagenesis on the gross chemistry of the nodule.     

Estimating growth rates of ferromanganese nodules from chemical compositions: implications for nodule formation processes

Using available information on the accretion rates and the bulk chemical compositions of oceanic ferromanganese nodules, it can be shown that the accumulation rate of manganese is proportional to the square of the accumulation rate of iron. This relationship has been used to derive an equation that predicts nodule growth rates from their chemical compositions. The equation accurately predicts growth rates up to about 50 mm/10⁶ yr, but yields incorrect rates for faster-growing concretions. From this relationship nodules underneath water of high primary productivity grow most rapidly and accumulate transition metals most rapidly; however, nodules from regions of highest primary productivity do not have the highest concentrations of nickel and copper. Reduction of manganese within the sediment column and remobilization of a fraction to the surface sediments adds manganese to nodules without substantially augmenting the supply of other transition elements. The addition of remobilized manganese to the nodule dilutes the concentrations of nickel, copper and iron, even though their rates of accumulation are also high.     

Plate tectonics and the fusion of Asia

The coincidence of orogenic belts containing zones of high pressure metamorphism, ophiolites and deepwater sediments with faunal province boundaries leads to the postulation of several sutural zones within Asia. About nine blocks are defined and it is suggested on the basis of palaeogeographical, palaeontological and tectonic evidence that Asia did not fuse completely until well into the Mesozoic.     

A contribution to Pleistocene chronology in southeast Essex,England

Parallel to the Essex coast north of the mouth of the Thames, a series of gravel spreads ranging in altitude from near sea level westward to more than 200 ft O.D. (mean sea level) proved to be the remnants of an abandoned Thames/Medway terrace system, rather than a series of “raised” beaches, as their location had suggested. The seaward side of the ancient river valley has subsequently been “captured” by subsidence.Evidence is given for five terraces, with surface levels between 5 and 75 ft O.D. Because of subsidence of the Essex coast, the terrace levels are not easily correlatable with either the Thames or Medway terrace levels. Temporal placement is attempted on the basis of one site in the 25 ft Barling terrace, which yielded a Middle Acheulian archaeological assemblage associated with a cool temperate fauna including an early form of mammoth. An ice wedge cast in the Barling terrace was filled with floodloam which weathered to a parabraunerde soil during an interglacial climate warmer than now. For these reasons man is thought to have lived on the floodplain of the Barling terrace either at the onset of the Wolstonian (Riss) glacial or during an interstadial of that stage. The question of possible linkages between Swanscombe and Clacton terraces is discussed.