Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.     

Particle size distribution and dissolution properties of metals in cyclone fly ash

The particles in the examined cyclone fly ash were all smaller than 0.25 mm. in diameter, and particles smaller than 0.075 mm. in diameter accounted for 88.4 % of the ash weight. This result indicates that cyclone fly ash consists of particles with a small diameter. The metals in the cyclone fly ash were enriched in small particles. The highest concentrations for zinc, copper, lead, cadmium and molybdenum in the cyclone fly ash were found in the smallest particle size fraction (< 0.075 mm.) and for Barium, chromium, nickel, Vanadium and Cobalt in the second to smallest particle size fraction (0.075-0.125 mm.). From an environmental and toxicological standpoint, the smallest particles are of the greatest concern when ash is handed at landfill disposal sites (transport and disposal especially in stormy weather conditions), and some studies have reported risks to workers from prolonged exposure to ash. The results of the comparison of various dissolution methods for metals showed that the digestion procedures with nitric acid alone (USEPA 3051) or with a mixture of nitric acid + hydrogen peroxide (USEPA 3050B) slightly underestimated the metal concentrations in the cyclone fly ash. Although the use of hydrofluoric acid is often necessary for the determination of a number of elements associated with siliceous minerals, its use can result in loss of trace elements during dissolution.     

Paleogeothermal gradient in the boskovice furrow

Summary A coalification data set from the first seam of the Rosice-Oslavany coal district in the Boskovice furrow was used to estimate the temperature gradient prevailing within the furrow during Autunian sedimentation. An appreciable scatter of the data reflects the complicated history of the sedimentary region. The northern part of the district displays a higher degree of coalification. The results of the evaluation suggest that the region ceased to subside in the upper Autunian, and that the extent of the post-Autunian erosion does not exceed 500 metres. This version of the burial history, which is consistent with geological data, yields a temperature paleogradient of 76 mK/m for the northern part and of 72 mK/m for the southern part of the district. The gradients estimated are higher than those prevailing during the Carboniferous sedimentation in the Central Bohemian Basin (45 – 53 mK/m), lower than values found for the Ostrava Formation in the Upper Silesian Basin during its Namurian A sedimentation (about 95 mK/m), but comparable with values evaluated for the Karviná Formation of the same basin deposited during the Namurian B - C and Westphalian A (60 – 77 mK/m).Dedicated to the Memory of Professor Karel P     

Behavioural-geographical aspects of environmental quality

The behavioural approach in human geography accentuates the view of quality of the environment through man and his value orientations. The quality of environment from the point of view of human experience raises behavioural-geographical questions that are the core of the presented topic. Aspects of environmental imaginations and sensations as well as human value system are presented as variables affecting the structure of the perceived environment and human spatial behaviour. In this context, the authors present results of two behavioural studies that correspond to new models of man and environment from the viewpoint of a behavioural approach. The suggested humanistic approach in behavioural geography emphasizes above all the emotional aspect of the relationship between man and environment, which through environmental values, spatial sensations, and meanings, leads to human spatial behaviour.     

Generalized theory of impacts in particulate systems

The theory of collisional systems is generalized for an arbitrary geometry and forces acting in the system, mixtures of different particle types, friction, small deviations from the ideal spherical form, axial rotation, finite size of particles and gravitational interactions. Terms for the formation of new particles and destruction of old ones are also included, and other unspecified parameters can be introduced. Although some approximations are made to simplify the basic equations and to avoid excessive numerical interactions, a comparison with computer simulations shows a good agreement. The tests were continued up to the optical thickness = 5.     

New Universities and their cities, the case of Vaasa, Finland

University activities began in Finland in 1640 when the University of Turku was founded. Later it was transferred to Helsinki, the new capital of Finland. The turn of the century saw the emergence of new university level institutions in Helsinki and Turku. The explosion of the Finnish university system took place after the Second World War. Now there are 20 university level institutes. Consequently the access to university studies and other services has improved greatly. The university centre of Vaasa belongs to the new wave of universities founded from 1960 on. In the city there are now 4 units, one Finnish speaking, two Swedish speaking and one bilingual. This reflects the language structure of the area. All of the universities have had their individual development features. The Finnish speaking University of Vaasa is the biggest one. The main impact of the Vaasa universities is the participation in the rising of the level of education in Finland and its effect on economy and other development. The research institute of Vaasa University has served the surrounding areas and nation through applied research projects. The continuing education centre has served the areas firms with many kinds of tailored courses for the management. In the humanistics influence has been through specialised language courses and multilingual immersion. A newspaper university is one of the new forms of impact. The city has an Academic axis going through the innermost part of the city. It is divided clearly into two Finnish and one Swedish speaking area.     

Ozone production due to emissions from vegetation burning

Ozone has been observed in elevated concentrations by satellites over areas previously believed to be background. There is meteorological evidence, that these ozone plumes found over the Atlantic Ocean originate from vegetation fires on the African continent.In a previous study (DECAFE-88), we have investigated ozone and assumed precursor compounds over African tropical forest regions. Our measurements revealed large photosmog layers at altitudes from 1.5 to 4 km. Both chemical and meteorological evidence point to savanna fires up to several thousand km upwind as sources.Here we describe ozone mixing ratios observed over western Africa and compare ozone production ratios from different field measurement campaigns related to vegetation burning. We find that air masses containing photosmog ingredients require several days to develop their oxidation potential, similar to what is known from air polluted by emissions from fossil fuel burning. Finally, we estimate the global ozone production due to vegetation fires and conclude that this source is comparable in strength to the stratospheric input.     

Analysis of COMPTEL gamma-ray burst locations and spectra

In its first three years of operation, the COMPTEL instrument on theCompton Gamma-Ray Observatory has measured the locations (mean accuracy 1°) and spectra (0.75-30 MeV) of 18 gamma-ray bursts and continues to observe new events at a rate of 1/month. With good angular resolution and sensitivity at MeV energies, the growing COMPTEL burst catalog is an important new piece of evidence in the on-going GRB mystery. The COMPTEL burst locations are consistent with an isotropic distribution of sources, yet the spatial coincidence of two of the bursts indicates the possibility of repetition. The COMPTEL burst spectra are in most cases consistent with a single power law model with spectral index in the range 2–3. However, two bursts show evidence of a spectral break in the MeV range. Measurement of rapid variability at MeV energies in the stronger bursts provides evidence that either the sources are nearby (within the Galaxy) or the gamma-ray emission is relativistically beamed. We present an overview of analysis results obtained from the COMPTEL burst catalog concentrating on the search for burst repetition and the implications of highly variable MeV emission.     

Coalescing neutron stars as gamma ray bursters?

We investigate the dynamics and evolution of coalescing neutron stars. The three-dimensional Newtonian equations of hydrodynamics are integrated by the Piecewise Parabolic Method on an equidistant Cartesian grid. The code is purely Newtonian, but does include the emission of gravitational waves and their back-reaction. The properties of neutron star matter are described by the equation of state of Lattimer and Swesty (1991). Energy loss by all types of neutrinos and changes of the electron fraction due to the emission of electron neutrinos and antineutrinos are taken into account by an elaborate neutrino leakage scheme. We simulate the coalescence of two identical, cool neutron stars with a baryonic mass of 1.6M and a radius of 15 km and with an initial center-to-center distance of 42 km. The initial distributions of density and electron concentration are given from a model of a cold neutron star in hydrostatic equilibrium. We investigate three cases which differ by the initial velocity distribution in the neutron stars. The orbit decays due to gravitational-wave emission and after one revolution the stars are so close that dynamical instability sets in. Within 1 ms the neutron stars merge into a rapidly spinning (P 1 ms), high-density body ( 10¹⁴ g/cm³) with a surrounding thick disk of material with densities 10¹⁰ – 10¹² g/cm³ and orbital velocities of 0.3-0.5 c. The peak emission of gravitational waves has a maximum luminosity of a few times 10⁵⁵ erg/s and is reached for about 1 ms. The amplitudes of the gravitational waves are close to 3 10^–23 at a distance of 1 Gpc and the typical frequency is near the dynamical value of the orbital motion of the merging neutron stars of 2 KHz. In a post-processing step, the rate of neutrino-antineutrino annihilation is calculated from the neutrino luminosities generated during the hydrodynamical simulations. We find the integral annihilation rate to be a few 10⁵⁰ erg/s during the phase of strongest neutrino emission, which is too small to generate the observed bursts considering the fact that the merged object of about 3M will most likely collapse to a black hole within milliseconds.