Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field

Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid,     

Source time-function as discriminant using empirical Green’s function

Since the sign up of CTBT (Comprehensive Test Ban Treaty), the nuclear monitoring and distinguishing has gained great attention by the treaty countries. Seismology is one of the primary technical means available for monitoring compliance to a CTBT. However, there does not exist a single criterion, so far, that can effectively distinguish explorations from earthquakes. It has been known that source time function (abbreviated to STF) of an underground nuclear explosion contains important p…     

REE and (э)Nd of clay fractions in sediments from the eastern Pacific Ocean: Evidence for clay sources

Clay fractions in the non-calcareous surface sediments from the eastern Pacific were analyzed for clay minerals, REE and 143Nd/144Nd. Montmorillonite/illite ratio (M/I ratio), total REE contents ((REE), LREE/HREE ratio and cerium anomaly (бCe) may effectively indicate the genesis of clay minerals. Clay fractions with M/I ratio >1, бCe (0.85, (REE (400 μg/g, LREE/HREE ratio (4, and REE patterns similar to those of pelagic sediments are terrigenous and autogenetic mixed clay fractions and contain more autogenetic montmorillonite. Clay fractions with M/I ratio <1, бCe=0.86 to 1.5, ΣREE=200 to 350 μg/g, LREE/HREE ratio (6 and REE distribution patterns similar to that of China loess are identified as terrigenous clay fraction. The 143Nd/144Nd ratios or (э)Nd values of clay fractions inherit the features of terrigenous sources of clay minerals. Clay fractions are divided into 4 types according to (э)Nd values. Terrigenous clay minerals of type I with the (э)Nd values of -8 to -6 originate mainly from North American fluvial deposits. Those of type II with the (э)Nd values of -9 to -7 are mainly from the East Asia and North American fluvial deposits. Those of type III with (э)Nd values of -6 to -3 could come from the central and eastern Pacific volcanic islands. Those of type IV with (э)Nd values of -13 to -12 may be from East Asia eolian. The terrigenous and autogenetic mixed clay fractions show patchy distributions, indicating that there are volcanic or hot-spot activities in the eastern Pacific plate, while the terrigenous clay fractions cover a large part of the study area, proving that the terrigenous clay minerals are dominant in the eastern Pacific.     

Characteristics and genesis of maghemite in Chinese loess and paleosols: Mechanism for magnetic susceptibility enhancement in paleosols

Morphological characteristics and microstructures of magnetic minerals extracted from Chinese loess and paleosols were investigated using powder X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). Our results indicate that maghemite in loess–paleosol sequences was transformed from magnetite through oxidation of magnetite. Maghemite transformed from eolian magnetite during chemical weathering has low-angle grain boundaries among maghemite nano-crystals. Some nano-crystalline maghemites with nanoporous texture resulted from microbe-induced precipitation of magnetite or transformation of poorly crystalline ferric Fe (oxy)hydroxides in presence of Fe-reducing bacteria. Aggregates of euhedral maghemite nano-crystals were transformed from magnetite magnetosomes. Both microbe-induced nanoporous magnetite and microbe-produced magnetite magnetosomes are directly related to microbial activities and pedogenesis of the paleosols. It is proposed that the formation of nano-crystalline maghemite with superparamagnetic property in paleosol results in the enhancement of magnetic susceptibility, although the total amount (weight percent) of magnetic minerals in both paleosol and loess units is similar. Our results also show that nano-crystalline and nanoporous magnetite grains prefer to transform into maghemite in semi-arid soil environments instead of hematite, although hematite is a thermodynamically stable phase. This result also indicates that a decrease in crystal size will increase stability of maghemite. It is also inferred that surface energy of maghemite is lower than that of hematite.     

High-Altitude CUSP: The Extremely Dynamic Region in Geospace

The high-altitude dayside cusps (both northern and southern) are extremely dynamic regions in geospace. Large diamagnetic cavities with significant fluctuations of the local magnetic field strength have been observed there. These cusp diamagnetic cavities are always there day after day and are as large as 6 R_E Associated with these cavities are charged particles with energies from 20 keV up to 10 MeV. The intensities of the cusp energetic ions have been observed to increase by as much as four orders of the magnitude when compared with regions adjacent to the cusp which includes the magnetosheath. Their seed populations are a mixture of ionospheric and solar wind particles. The measured energetic ion fluxes in the high-altitude cusp are higher than that in both the regions upstream and downstream from the bow shock. Turbulent electric fields with an amplitude of about 10 mV/m are also present in the cusp, and a cusp resonant acceleration mechanism is suggested. The observations indicate that the dayside high-altitude cusp is a key region for transferring the solar wind mass, momentum, and energy into the Earth’s magnetosphere.     

区域生态地球化学评价核心与对策

生态地球化学是地学与土壤学、农业、环境学和生态学等多学科交叉融合产生的新学科,是地球化学领域新的发展方向。区域生态地球化学评价是在区域地球化学调查基础上,针对影响流域/区带生态系统安全性的元素异常而开展的一项评价和研究工作。多目标区域地球化学调查获得的海量高精度地球化学数据,可为环境质量评价提供背景值、为土地的质量和生态管护提供地球化学依据;调查还发现了一系列影响流域生态安全性的元素异常,针对异常元素分布特征,区域生态地球化学评价将开展异常元素追踪和成因甄别、生态效应评价和生态系统安全性的预警预测等项评价和研究工作。文章论述了区域地球化学调查成果,介绍了区域地球化学评价的思路,阐述了区域生态地球化学评价的主要问题与对策。     

中国海相油气田勘探实例(之一) 四川盆地罗家寨大型气田的发现和探明

罗家寨气田发现于2000年,是四川盆地迄今为止发现的储量规模最大的一个气田,2002年探明储量为581.08×108m3。其下三叠统飞仙关组储层由碳酸盐岩蒸发台地边缘优质鲕粒滩白云岩构成,圈闭面积大,构造幅度高,具有一定的埋藏隐蔽性。论述了气田的发现和探明过程,气藏地质的特征,以及对碳酸盐岩气藏勘探的启示。     

当前国际水文学科技术领域的研究方向

根据联合国有关机构发布的公报和世界各国近年来的学术研究情况，整理出了近期水文学科在地表水、地下水、水质、水资源系统、大气～土壤～植被、大陆侵蚀、冰雪、遥感技术和示踪技术等领域的热门研究课题，在一定程度上反映了当前国际上水文学科的研究和发展方向，对国内同行有一定的参考价值。     

Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.     

Microorganisms in Lianxian lateritic gold deposit in Guangdong and their effects on leaching of heavy metals

Microorganisms in the lateritic profiles of the Lianxian gold deposit in Guangdong were cultured, isolated and identified. The microorganisms include bacteria such as Bacillus, Enterobacter, Pseudomonas, Lactobacillus, Actinetobacter, Aeromona, Listeria, Agrobacteriura, Cotyttebacteriurn, and Moraxella, fungi such as Penicillium, Alter naria, Cladosporium, Saccharcornyces, Mucor, and the chemoautotrophic Thiobacillu.~. It is shown in a leaching experiment that the microorganisms can accelerate the leaching of Cu, Cd, Zn, and that the G- bacteria are most efficient for leaching Cu, Zn and the G^ bacteria are better for leaching Cd.