Ferrian tourmaline from Bungonia,New South Wales

New chemical, X‐ray and cell dimension data are presented for ferrian tourmaline in quartz‐tourmaline rock at three localities near Bungonia, New South Wales. The tourmaline is fine‐grained, normally euhedral, and forms up to 90% of the rock. It shows restricted solid solution between dravite and ferridravite, although some grains are zoned and others have an irregular, bipartite chemical variation. Tourma‐linisation is interpreted as being.related to late‐stage volatile emanations from the Marulan Batholith.     

Elemental damping formulation: an alternative modelling of inherent damping in nonlinear dynamic analysis

To date, nonlinear dynamic analysis for seismic engineering predominantly employs the classical Rayleigh damping model and its variations. Though earlier studies have identified issues with the use of this model in nonlinear seismic analysis, it still remains the popular choice for engineers as well as for software providers. In this paper a new approach to modelling damping is initiated by formulating the damping matrix at an elemental level. To this regard, two new elemental level discrete damping models adapted from their global counterparts are proposed for its application in nonlinear dynamic analysis. Implementation schemes for these newly proposed models using Newmark incremental method and revised Newmark total equilibrium method is outlined. The performance of these proposed models, compared to existing models, is illustrated by conducting nonlinear dynamic analyses on a four story RC frame designed to Eurocodes. The incremental dynamic analysis study presented in the paper illustrates the fact that both the proposed models seem to produce more reliable results from an engineering perspective in comparison to the global models. It is also shown that the proposed elemental damping models lead to smaller and more realistic damping moments in the plastic hinges. Furthermore, these models could be easily included in existing software frameworks without adding noticeably to the computational effort. The computation time required for these models is approximately equivalent to the one required when using the tangent Rayleigh damping matrix with constant coefficients.     

Glacier reconstruction and mass‐balance modelling as a geomorphic and palaeoclimatic tool

The reconstruction of former mountain glaciers has long been used to examine the implications of rapid climate shifts, for example at the last glacial–interglacial transition, and for evaluating asynchronous behaviour of mountain glaciers compared with mid‐latitude ice sheets during the Late Quaternary. Glacier reconstruction has also been used as a source of palaeoclimatic information, based on the recognition of empirical relationships between glaciers and climate. This paper reviews the application and implications of a recently revised method of glacier reconstruction (Carr and Coleman, 2007 ), based around glaciological principles of mass‐balance. This study examines how this approach can be used to test geomorphological interpretations of former mountain glaciation and also to infer precipitation fields at sites of former glaciation. Sites of Younger Dryas niche and icefield glaciation in the British Isles demonstrate how this method can verify interpretations of marginal glaciation and begin to understand the different behaviour of outlet glaciers within the same environmental regime. Examination of a site of former niche glaciation in Southern Africa demonstrates how glacier reconstruction may be used to infer annual and seasonal precipitation values and strongly supports the idea that winter precipitation in Lesotho and SE South Africa was substantially greater than present‐day values during the last glacial cycle. Copyright © 2010 John Wiley & Sons, Ltd.     

Conditioning temperature‐index model parameters on synoptic weather types for glacier melt simulations

Temperature‐index models are widely favoured as a pragmatic means of simulating glacier melt because of their generally good performance, computational simplicity and limited demands for in situ data. However, their coefficients are normally treated as temporally stationary, unrealistically assuming a constancy of the prevailing weather. We address this simplification by prescribing model coefficients as a function of synoptic weather type, in a procedure that utilizes reanalysis data and preserves the minimal data requirements of temperature‐index models. Using a cross‐validation procedure at Vestari Hagafellsjökull, Iceland, and Storglaciären, Sweden, we demonstrate that applying transient model coefficients, for three temperature‐index models, results in statistically significant increases in the skill with which melt is modelled: Median simulation improvements in the Nash–Sutcliffe efficiency coefficient of 7.3 and 23.6% are achieved when hourly and daily melt totals are evaluated respectively. Our weather‐type modelling approach also yields insight to processes driving parameter variability, revealing dependence that is consistent with a priori considerations of the surface energy balance. We conclude that incorporating weather types into temperature‐index models holds promise for improving their performance, as well as enhancing understanding variability in coefficient values. Copyright © 2014 John Wiley & Sons, Ltd.     

Molecular fingerprinting of wetland organic matter using pyrolysis-GC/MS: an example from the southern Cape coastline of South Africa

Pyrolysis–gas chromatography mass spectrometry (py-GC/MS) allows the characterisation of complex macromolecular organic matter. In lakes and wetlands this can potentially be used to assess the preservation/diagenesis and provenance of sediment organic matter. It can complement palaeoenvironmental investigations utilising ‘bulk’ sediment variables such as total organic carbon (TOC) and TOC/total nitrogen ratios. We applied py-GC/MS analyses to a ~32,000-year sediment record from the southern Cape coastline of South Africa. We used the results to evaluate the sources and extent of degradation of organic matter in this semi-arid environment. Marked down-core changes in the relative abundance of multiple pyrolysis products were observed. Correspondence analysis revealed that the major driver of this down-core variability in OM composition was selective preservation/degradation. Samples comprising highly degraded OM are primarily confined to the lower half of the core, older than ~12,000 years, and are characterised by suites of low-molecular-weight aromatic pyrolysis products. Samples rich in organic matter, e.g. surface sediments, are characterised by products derived from fresh emergent or terrestrial vegetation, which include lignin monomers, plant-derived fatty acids and long-chain n-alkanes. Pyrolysates from the late glacial-early Holocene period, approximately mid-way down the core are characterised by distinct suites of long-chain n-alkene/n-alkane doublets, which may reflect the selective preservation of recalcitrant aliphatic macromolecules and/or enhanced inputs of the algal macromolecule algaenan/polymerised algal lipids. Increased TOC, lower δ¹³C and increased abundance of more labile lignin and fatty acid products at the same depths suggest this period was associated with increased lake primary productivity and enhanced inputs of terrestrial OM. TOC is the only ‘bulk’ parameter correlated with the correspondence analysis axes extracted from the py-GC/MS data. Distinct fluctuations in TOC/total nitrogen ratio are not explained by variation in organo-nitrogen pyrolysis products. Notwithstanding, the study suggests that py-GC/MS has potential to complement palaeolimnological investigations, particularly in regions such as southern Africa, where other paleoenvironmental proxy variables in sediments may be lacking or equivocal.     

Petrogenesis of basalt–trachyte lavas from Olmoti Crater, Tanzania

Olmoti Crater is part of the Plio-Pleistocene Ngorongoro Volcanic Highland (NVH) in northern Tanzania to the south of Gregory Rift. The Gregory Rift is part of the eastern branch of the East African Rift System (EARS) that stretches some 4000 km from the Read Sea and Gulf of Aden in the north to the Zambezi River in Mozambique. Here, we (1) characterize the chemistry and mineral compositions of lavas from Olmoti Crater, (2) determine the age and duration of Olmoti volcanic activity through ⁴⁰Ar/³⁹Ar dating of Olmoti Crater wall lavas and (3) determine the genesis of Olmoti lavas and the relationship to other NVH and EARS volcanics and (4) their correlation with volcanics in the Olduvai and Laetoli stratigraphic sequences.Olmoti lavas collected from the lower part of the exposed crater wall section (OLS) range from basalt to trachyandesite whereas the upper part of the section (OUS) is trachytic. Petrography and major and trace element data reflect a very low degree partial melt origin for the Olmoti lavas, presumably of peridotite, followed by extensive fractionation. The ⁸⁷Sr/⁸⁶Sr data overlap whereas Nd and Pb isotope data are distinct between OLS and OUS samples. Interpretation of the isotope data suggests mixing of enriched mantle (EM I) with high-μ-like reservoirs, consistent with the model of Bell and Blenkinsop [Bell, K., Blenkinsop, J., 1987. Nd and Sr isotopic compositions of East African carbonatites: implications for mantle heterogeneity. Geology 5, 99–102] for East African carbonatite lavas. The isotope ratios are within the range of values defined by Oceanic Island Basalt (OIB) globally and moderate normalized Tb/Yb ratios (2.3–1.6) in these lavas suggest melting in the lithospheric mantle consistent with other studies in the region.⁴⁰Ar/³⁹Ar incremental-heating analyses of matrix and anorthoclase separates from Olmoti OLS and OUS lavas indicate that volcanic activity was short in duration, lasting 200 kyr from 2.01 ± 0.03 Ma to 1.80 ± 0.01 Ma. The age of Olmoti activity overlaps with ages reported for Ngorongoro Caldera, implying contemporaneous activity of multiple NVH volcanic centers during part of the eruption interval.Olmoti is considered the source for the bulk of interbedded volcanics and volcaniclastic deposits that comprise much of the upper Bed I section of nearby Olduvai Gorge, and part of the Laetoli sequence, both known for their well preserved fossils and archaeological remains. Age and chemical data reported here are compatible with those derived from tephra and lava interbedded in Bed I at Olduvai Gorge and from the Olpiro Beds at Laetoli.     

The petrogenesis of Merensky Reef potholes at the Western Platinum Mine, Bushveld Complex: Sr-isotopic evidence for synmagmatic deformation

Potholes represent areas where the normally planar PGE-rich Merensky Reef of the upper Critical Zone of the Bushveld Complex transgresses its footwall, such geometric relationships being unusual in layered intrusions. The recognition of vertical dykes of Merensky pyroxenite in the footwall suggests downward collapse of crystal mush into pull-apart sites resulting from tensional deformation due to the loading effects of major new magma additions. In contrast, crosscutting anorthosite veins display physical and isotopic evidence of upward emplacement. The Merensky Reef and its footwall have distinct initial Sr-isotope ratios (R ₀ > 0.7066 and <0.7066, respectively), which may be used to constrain these processes related to pothole formation. Merensky Reef in potholes (R ₀ = 0.7069−0.7078) shows no isotopic evidence of assimilation of, or reaction with, footwall material. Discrete, discordant replacement bodies of anorthosite extend from the footwall lithologies to cross-cut the Merensky Reef and its hanging wall. The initial Sr-isotope ratio in these replaced rocks is totally reset to footwall values (R ₀ = 0.7066), and immediately adjacent stratiform lithologies are slightly modified towards footwall values. In contrast, Neptunian pyroxenitic (Merensky) dykes cross-cutting the footwall lithologies, with a large surface area to volume ratio, and low Sr content, do not display footwall-like Sr-isotope initial-ratios (R ₀ = 0.7077), and thus show no evidence for assimilation of or reaction with footwall material. Furthermore, pegmatoidal replacement pyroxenite (“replacement pegmatoid”), at the base of the Merensky Reef within potholes, has a high initial-ratio (R ₀ > 0.7071), and so models of pervasive metasomatism by footwall material are not applicable. This isotopic evidence indicates that there was no active interaction of footwall material with the overlying magma during, or after, the formation of Merensky Reef potholes, a basic tenet of existing pothole formation hypotheses involving footwall mass-transfer. In contrast, the isotopic data are entirely consistent with an extensional model for pothole formation, with the more radiogenic Merensky magma migrating laterally to fill extensional zones in the footwall layers. Received: 11 October 1997 / Accepted: 21 December 1998     

Quantitative phosphorus measurement: A field test procedure for archaeological site analysis at Piedras Negras,Guatemala

Currently there is a wide interest in the use of chemical analyses for the evaluation of anthropogenically altered soils and other archaeological deposits. Because soil phosphorus levels increase in areas of human habitation, and leave a permanent signature that can only be removed by erosion of the soil itself, phosphorus mapping has become a popular field procedure to indicate areas of habitation where overt evidence of ancient occupance is absent. We have developed a methodology to obtain accurate acid‐extractable phosphorus concentrations (mg/kg) in calcareous soils under the primitive field conditions of Piedras Negras, Guatemala. Predicated on Mehlich‐II acid extractant and colorimetric methods, this procedure processed 36 samples per hour at very low cost per sample. Based on eight replicate measurements of a group of samples, the coefficient of variation of the procedure was 8.3%. Subsequent analysis of 35 soil samples in a controlled laboratory revealed a moderate correlation of 0.44 between the Mehlich‐extractable phosphorus and total phosphorus. The correlation was 0.91 between the Mehlich procedure and Olsen bicarbonate extractable phosphorus, indicating that Mehlich‐based results are similar to those obtainable using a traditional extractable phosphorus method on soils of neutral to alkaline pH. There was a moderate correlation between Mehlich P and ring‐test rating (r = 0.42). The wider dynamic range of the Mehlich extraction, coupled with the use of a battery‐operated colorimeter, facilitated the finding of a refuse midden within an area of phosphate enriched soils. Further tests indicated that phosphorus concentrations measured in the field deviated by only 7% from those made under controlled laboratory conditions. © 2000 John Wiley & Sons, Inc.     

Hydraulic Conductivity Calibration of Logging NMR in a Granite Aquifer,Laramie Range,Wyoming

In granite aquifers, fractures can provide both storage volume and conduits for groundwater. Characterization of fracture hydraulic conductivity (K) in such aquifers is important for predicting flow rate and calibrating models. Nuclear magnetic resonance (NMR) well logging is a method to quickly obtain near-borehole hydraulic conductivity (i.e., K_NMR) at high-vertical resolution. On the other hand, FLUTe flexible liner technology can produce a K profile at comparable resolution but requires a fluid driving force between borehole and formation. For three boreholes completed in a fractured granite, we jointly interpreted logging NMR data and FLUTe K estimates to calibrate an empirical equation for translating borehole NMR data to K estimates. For over 90% of the depth intervals investigated from these boreholes, the estimated K_NMR are within one order of magnitude of K_FLUTe. The empirical parameters obtained from calibrating the NMR data suggest that “intermediate diffusion” and/or “slow diffusion” during the NMR relaxation time may occur in the flowing fractures when hydraulic aperture are sufficiently large. For each borehole, “intermediate diffusion” dominates the relaxation time, therefore assuming “fast diffusion” in the interpretation of NMR data from fractured rock may lead to inaccurate K_NMR estimates. We also compare calibrations using inexpensive slug tests that suggest reliable K_NMR estimates for fractured rock may be achieved using limited calibration against borehole hydraulic measurements.