The control of soil pollution in China has become an issue, and in this study, a compound contaminated site was selected and focus on the site and its nearby environment, organochlorine pesticides (OCPs) were investigated in both soil (top and deep soil) and air samples. The main pollutants in top soils at site are dichlorodiphenyltrichloroethane (DDTs, 0.05–104 mg/kg d.w., avg: 14.5 mg/kg d.w.) and hexachlorobenzene (HCB, 0.02–4.85 mg/kg d.w., avg: 0.72 mg/kg d.w.) which is in accordance with its production history. As for the deep soils, ΣOCPs at site were found concentrated at workshops especially the technical pesticide workshop (5.29–22.1 mg/kg d.w., avg: 9.15 mg/kg d.w.) and the history DDTs’ workshop (4.00–64.8 mg/kg d.w., avg: 20.4 mg/kg d.w). Around site, OCPs were mainly concentrated at layers of −20 cm and the −40 cm and decreased with distance being far away, at 5000 m, the ΣOCPs was comparable with normal agriculture soil (22.1−91.4 ng/g d.w., avg: 55.4 ng/g d.w.). ΣOCPs in the air samples ranged 64.6–823 ng/m3 (avg: 459 ng/m3) at site and 9.93–176 ng/m3 (avg: 50.8 ng/m3) around site which are all dominated with DDTs and HCHs. Soil–air exchange fugacity was calculated to judge the transportation of the OCPs and the results showed soils at the site and its nearby areas (within 5000 m) are releasing most of the OCPs into air, and accordingly through evaluation, inhalation was found to be the major source for human health risk, which is a great threat to the workers at site and the nearby residents.
The intraseasonal variability(ISV) of sea level anomalies(SLAs) along the southern coast of Java and its interannual modulation were studied based on a gridded SLA product produced from the Archiving, Validation, and Interpretation of Satellite Oceanography dataset. This ISV is induced by the propagation of intraseasonal Kelvin waves derived from the central equatorial Indian Ocean(EIO). Wavelet analysis and empirical mode decomposition of intraseasonal SLAs along the southern coast of Java showed interannual variability, with weaker ISV events during El Ni years and positive Indian Ocean Dipole(IOD) years than during normal years. This interannual modulation of the ISV is influenced by the El Ni-Southern Oscillation teleconnection via the Walker Circulation and eastern Indian Ocean upwelling connected to IOD events. The anomalously weaker Walker Circulation during El Ni events generates anomalous surface easterlies over the central-eastern tropical Indian Ocean that produce upwelling Kelvin waves in the EIO and offshore water transport along the southern coasts of Sumatra and Java, resulting in negative SLAs along the southern coast of Java. These negative SLAs damp the positive SLAs induced by the eastward propagation of downwelling Kelvin waves from the central EIO during the following March–May of El Ni years. Similar features of SLAs and sea surface wind anomalies also occur during positive IOD years. Consequently, the sea level ISV along the southern coast of Java is weaker in El Ni and positive IOD years. 相似文献