Development of crystallographic preferred orientations by nucleation and growth of new grains in experimentally deformed quartz single crystals

Deformation experiments have been carried out to investigate the effect of dynamic recrystallisation on crystallographic preferred orientation (CPO) development. Cylindrical samples of natural single crystals of quartz were axially deformed together with 1 vol.% of added water and 20 mg of Mn₂O₃ powder in a Griggs solid medium deformation apparatus in different crystallographic orientations with compression direction: (i) parallel to <c>, (ii) at 45° to <c> and 45° to <a> and (iii) parallel to <a>. The experiments were performed at a temperature of 800 °C, a confining pressure of 1.2 GPa, a strain rate of  10^− 6 s^− 1, to bulk finite strains of  14–36%. The deformed samples were analysed in detail using optical microscopy, electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). Two different microstructural domains were distinguished in the deformed samples: (i) domains with undulatory extinction and deformation lamellae, and (ii) domains with new recrystallised grains. Within the domains of undulatory extinction, crystal-plastic deformation caused gradual rotations of the crystal lattice up to  30° away from the host orientation. New recrystallised grains show a strong CPO with c-axis maxima at  45° to the compression direction. This is the case in all experiments, irrespective of the initial crystallographic orientation. The results show that c-axes are not continuously rotated towards the new maxima. The new grains thus developed through a mechanism different from subgrain rotation recrystallisation. New grains have a subeuhedral shape and numerous microcavities, voids, fluid channels and fluid inclusions at their grain boundaries. No host control is recorded in misorientation axes across their large angle grain boundaries. New grains might have been created by nucleation from solution in the μm-scale voids and microfractures. The CPO most likely developed due to preferred growth of the freshly precipitated grains with orientations suitable for intracrystalline deformation at the imposed experimental conditions.     

The importance of three centuries of land-use change for the global and regional terrestrial carbon cycle

Large amounts of carbon (C) have been released into the atmosphere over the past centuries. Less than half of this C stays in the atmosphere. The remainder is taken up by the oceans and terrestrial ecosystems. Where does the C come from and where and when does this uptake occur? We address these questions by providing new estimates of regional land-use emissions and natural carbon fluxes for the 1700–2000 period, simultaneously considering multiple anthropogenic (e.g. land and energy demand) and biochemical factors in a geographically explicit manner. The observed historical atmospheric CO₂ concentration profile for the 1700 to 2000 period has been reproduced well. The terrestrial natural biosphere has been a major carbon sink, due to changes in climate, atmospheric CO₂, nitrogen and management. Due to land-use change large amounts of carbon have been emitted into the atmosphere. The net effect was an emission of 35 Pg C into the atmosphere for the 1700 to 2000 period. If land use had remained constant at its distribution in 1700, then the terrestrial C uptake would have increased by 142 Pg C. This overall difference of including or excluding land-use changes (i.e. 177 Pg C) comes to more than half of the historical fossil-fuel related emissions of 308 Pg C. Historically, global land-use emissions were predominantly caused by the expansion of cropland and pasture, while wood harvesting (for timber and fuel wood) only played a minor role. These findings are robust even when changing some of the important drivers like the extent of historical land-use changes. Under varying assumptions, land-use emissions over the past three centuries could have increased up to 20%, but remained significantly lower than from other sources. Combining the regional land-use and natural C fluxes, North America and Europe were net C sources before 1900, but turned into sinks during the twentieth century. Nowadays, these fluxes are a magnitude smaller than energy- and industry-related emissions. Tropical regions were C neutral prior to 1950, but then accelerated deforestation turned these regions into major C sources. The energy- and industry-related emissions are currently increasing in many tropical regions, but are still less than the land-use emissions. Based on the presented relevance of the land-use and natural fluxes for the historical C cycle and the significance of fossil-fuel emissions nowadays, there is a need for an integrated approach for energy, nature and land use in evaluating possible climate change mitigation policies.     

What do near-term observations tell us about long-term developments in greenhouse gas emissions?

Long-term scenarios developed by integrated assessment models are used in climate research to provide an indication of plausible long-term emissions of greenhouse gases and other radiatively active substances based on developments in the global energy system, land-use and the emissions associated with these systems. The phenomena that determine these long-term developments (several decades or even centuries) are very different than those that operate on a shorter time-scales (a few years). Nevertheless, in the literature, we still often find direct comparisons between short-term observations and long-term developments that do not take into account the differing dynamics over these time scales. In this letter, we discuss some of the differences between the factors that operate in the short term and those that operate in the long term. We use long-term historical emissions trends to show that short-term observations are very poor indicators of long-term future emissions developments. Based on this, we conclude that the performance of long-term scenarios should be evaluated against the appropriate, corresponding long-term variables and trends. The research community may facilitate this by developing appropriate data sets and protocols that can be used to test the performance of long-term scenarios and the models that produce them.     

The comparability of carbonatitic fluid inclusions in ijolites with natrocarbonatite lava

The composition of carbonate, sulphate, halide and other phases trapped as fluid inclusions in apatite crystals in ijolite and urtite from sub-volcanic complexes in East Africa have been determined using the electron micro-probe. The bulk composition of these inclusions is alkali-rich and closely comparable to the natrocarbonatite lava from the active volcano of Oldoinyo Lengai in N. Tanzania. The inclusions are interpreted as having been originally immiscible alkali carbonate-rich droplets within a nephelinitic melt. The evidence suggests that magma of the composition of natrocarbonatite lava is that most likely for the parent magma during carbonatite petrogenesis.     

Rift zone reorganization through flank instability in ocean island volcanoes: an example from Tenerife, Canary Islands

The relationship between rift zones and flank instability in ocean island volcanoes is often inferred but rarely documented. Our field data, aerial image analysis, and ⁴⁰Ar/³⁹Ar chronology from Anaga basaltic shield volcano on Tenerife, Canary Islands, support a rift zone—flank instability relationship. A single rift zone dominated the early stage of the Anaga edifice (~6–4.5 Ma). Destabilization of the northern sector led to partial seaward collapse at about ~4.5 Ma, resulting in a giant landslide. The remnant highly fractured northern flank is part of the destabilized sector. A curved rift zone developed within and around this unstable sector between 4.5 and 3.5 Ma. Induced by the dilatation of the curved rift, a further rift-arm developed to the south, generating a three-armed rift system. This evolutionary sequence is supported by elastic dislocation models that illustrate how a curved rift zone accelerates flank instability on one side of a rift, and facilitates dike intrusions on the opposite side. Our study demonstrates a feedback relationship between flank instability and intrusive development, a scenario probably common in ocean island volcanoes. We therefore propose that ocean island rift zones represent geologically unsteady structures that migrate and reorganize in response to volcano flank instability.Editorial responsibility: T. DruittThis revised version was published online in February 2005 with typographical corrections and a changed wording.     

Sr and Pb isotopic composition of five USGS glasses (BHVO-2G, BIR-1G, BCR-2G, TB-1G, NKT-1G)

Sr isotopic compositions and Rb / Sr ratios of three USGS glasses (BHVO-2G, BIR-1G, BCR-2G) are identical to those of the original USGS reference materials. NKT-1G and TB-1G give values of 0.70351 and 0.70558, respectively. Pb isotopic ratios were measured by the standard-sample bracketing technique on an MC-ICP-MS, which give results that are comparable in accuracy and reproducibility to double spike analyses. However, assessment of the reproducibility of the technique is hampered by inhomogeneous contamination of all USGS reference materials analysed. This contamination is likely to be the reason why the USGS glasses do not all have the same Pb isotopic composition as their unfused originals. Powdered glasses, distributed for characterisation of the glasses by bulk analytical techniques, do not all have the same Pb isotopic compositions as the solid glass material, and can therefore not be used for this purpose.     

Modeling large-scale cohesive sediment transport affected by small-scale biological activity

Biological activity on the bottom of the seabed is known to have significant influence on the dynamics of cohesive sediment on a small spatial and temporal scale. In this study, we aim to understand the large-scale effects of small-scale biological activity. Hereto, effects of biology are quantitatively incorporated into the process-based sediment transport module of Delft3D. This Bio-mud model is used to study cohesive sediment transport and deposition patterns in the Western Wadden Sea for a period of 1 year to capture seasonal changes.     

Groundwater chemistry of Al under Dutch sandy soils: Effects of land use and depth

Aluminium has received great attention in the second half of the 20th century, mainly in the context of the acid rain problem mostly in forest soils. In this research the effect of land use and depth of the groundwater on Al, pH and DOC concentration in groundwater under Dutch sandy soils has been studied. Both pH and DOC concentration play a major role in the speciation of Al in solution. Furthermore, the equilibrium with mineral phases like gibbsite, amorphous Al(OH)₃ and imogolite, has been considered. Agricultural and natural land use were expected to have different effects on the pH and DOC concentration, which in turn could influence the total Al concentration and the speciation of Al in groundwater at different depths (phreatic, shallow and deep). An extensive dataset (n = 2181) from the national and some provincial monitoring networks on soil and groundwater quality was used. Land use type and groundwater depth did influence the pH, and Al and DOC concentrations in groundwater samples. The Al concentration ranged from <0.4 μmol L⁻¹ at pH > 7 to 1941 μmol L⁻¹ at pH < 4; highest Al concentrations were found for natural-phreatic groundwater. The DOC concentration decreased and the median pH increased with depth of the groundwater. Natural-phreatic groundwater showed lower pH than the agricultural-phreatic groundwater. Highest DOC concentrations were found for the agricultural-phreatic groundwater, induced by the application of organic fertilizers. Besides inorganic complexation, the NICA-Donnan model was used to calculate Al³⁺ concentrations for complexation with DOC. Below pH 4.5 groundwater samples were mainly in disequilibrium with a mineral phase. This disequilibrium is considered to be the result of kinetic constraints or equilibrium with organic matter. Log K values were derived by linear regression and were close to theoretical values for Al(OH)₃ minerals (e.g. gibbsite or amorphous Al(OH)₃), except for natural-phreatic groundwater for which lower log K values were found. Complexation of Al with DOC is shown to be an important factor for the Al concentrations, especially at high DOC concentrations as was found for agricultural-phreatic groundwater.     

Ecohydrological parameters indicating different types of shallow groundwater

Ecohydrology, the interdisciplinary field of research directed to the application of hydrological knowledge to landscape ecology, is introduced to evaluate a test data set of 412 analyses of groundwater samples from 60 locations in a Dutch coversand area, numerically classified into 17 water types. Three types of simple groundwater quality classification are identified: single parameter, combined parameter and multiparameter.

Single quality parameters like pH, electrical conductivity (EC) and ion concentration values, are rarely used in ecohydrology. The representation of the complex conditional relationships between groundwater and the living part of ecosystems with these parameters is unsatisfactory, as also proved with the test data set. It is difficult to differentiate groundwater types reliably on the basis of one single parameter.

Combined quality parameters which are widely used are a pH-EC plot, a plot of pHCO₃ vs. (pH-pCa), after Kemmers, and an IR-EC plot after van Wirdum, where the ionic ratio (IR) is a Ca/(Ca + Cl) ratio. The latter two parameters indicate the residence time of the groundwater sampled as well as the hydrochemical conditions related to vegetation distribution and development. The IR is very popular for discriminating between atmocline (precipitation-like) and lithocline (long-residence groundwater-like) water types. In the test data set, objections to its use are discussed with regard to the conditions assumed in its application. Especially in the intermediate IR range, which should indicate potentially marked ecologic gradients, its theoretical basis is narrow. However, general relationships can be deduced from the IR-EC plot. In the test data set as well as in the general Dutch setting, the transformation of atmocline into lithocline water types determines to a large extent ecosystem diversity, although a third, metacline, pollution-induced water type increasingly interferes.

Finally, multiparameter classification of groundwater types is discussed. Statistical classification gives good results but is site specific. It is recomended that efforts be combined in the search for an internationally applicable composite classification adapted to ecohydrological research.