Worldwide distribution and significance of secondary microbial methane formed during petroleum biodegradation in conventional reservoirs

Around half of world’s endowment of in-place oil and bitumen experienced biodegradation, which is now believed to be largely an anaerobic methanogenic process. However, the distribution and scale of methanogenic biodegradation in the world’s petroleum accumulations and the significance of its terminal product, secondary microbial methane, in the global gas endowment and carbon cycle are largely unknown. Here, I present geological and geochemical criteria to recognize secondary microbial methane in conventional petroleum reservoirs. These include the presence of biodegraded oil (as pools, legs or shows) in the reservoir or down-dip, the relatively dry (methane dominated) gas containing methane with δ¹³C values between −55‰ and −35‰ and, most importantly, CO₂ with δ¹³C > +2‰. Based on these criteria, the presence of secondary microbial methane is apparent in 22 basins, probable in 12 basins and possible in six basins worldwide. Reservoirs apparently containing secondary microbial methane are mostly Cenozoic and clastic and occur at depths of 37-1834 m below surface/mudline and temperatures of 12-71 °C. Using the current global endowment of in-place oil and bitumen and reasonable assumptions about conversion of oil into methane during biodegradation, I estimated that ∼65,500 tcf of secondary microbial methane could have been generated in existing worldwide accumulations of oil and bitumen through their geological history. From 1461-2760 tcf in-place (845-1644 tcf recoverable) of secondary microbial methane may be accumulated as free and oil-dissolved gas in petroleum reservoirs. I also updated the inventory of primary microbial methane and estimated that the global primary microbial gas endowment (free and oil-dissolved) is from 676-797 tcf in-place (407-589 tcf recoverable). Secondary microbial methane may account for ∼5-11% of the global conventional recoverable gas endowment and appears more abundant than primary microbial gas (∼3-4% of the global gas endowment). Most of the generated secondary microbial methane probably is aerobically and anaerobically oxidized to CO₂ in the overburden above petroleum reservoirs. However, some secondary microbial methane may escape from shallow reservoirs into the atmosphere and affect present and past global climate.     

Properties of Magnetic Neutral Line Gradients and Formation of Filaments

We investigate the gradients of magnetic fields across neutral lines (NLs) and compare their properties for NLs with and without chromospheric filaments. Our results show that there is a range of preferred magnetic field gradients where the filament formation is enhanced. On the other hand, a horizontal gradient of the magnetic field across an NL alone does not appear to be a single factor that determines if a filament will form (or not) in a given location.     

Cosmological radiative transfer codes comparison project – I. The static density field tests

Radiative transfer (RT) simulations are now at the forefront of numerical astrophysics. They are becoming crucial for an increasing number of astrophysical and cosmological problems; at the same time their computational cost has come within reach of currently available computational power. Further progress is retarded by the considerable number of different algorithms (including various flavours of ray tracing and moment schemes) developed, which makes the selection of the most suitable technique for a given problem a non-trivial task. Assessing the validity ranges, accuracy and performances of these schemes is the main aim of this paper, for which we have compared 11 independent RT codes on five test problems: (0) basic physics; (1) isothermal H  ii region expansion; (2) H  ii region expansion with evolving temperature; (3) I-front trapping and shadowing by a dense clump and (4) multiple sources in a cosmological density field. The outputs of these tests have been compared and differences analysed. The agreement between the various codes is satisfactory although not perfect. The main source of discrepancy appears to reside in the multifrequency treatment approach, resulting in different thicknesses of the ionized-neutral transition regions and the temperature structure. The present results and tests represent the most complete benchmark available for the development of new codes and improvement of existing ones. To further this aim all test inputs and outputs are made publicly available in digital form.     

Estimating Sensible and Latent Heat Fluxes over an Inland Water Body Using Optical and Microwave Scintillometers

Boundary-Layer Meteorology - Observations of turbulent heat fluxes over inland water bodies are scarce despite being critical to adequate lake parametrization for numerical weather forecast and...     

Late Weichselian (Valdaian) and Holocene vegetation and environmental history of the northern Timan Ridge, European Arctic Russia

Lake and peat deposits from the Timan Ridge, Arctic Russia, were pollen analysed, reconstructing the vegetation history and paleoenvironment since the Last Glacial Maximum (LGM) 20–18,000 years ago. The sites studied are located inside the margins of a large paleolake of about 20 km², by us named Lake Timan. This lake developed in the Late Weichselian, more than 30,000 years after the deglaciation of this region, and was formed due to increased precipitation and warmer summers that accelerated the melting of stagnant ice within its catchment. The lake was drained during the early Holocene when the outlet rivers eroded the spillways. A new generation of much smaller lakes formed during the Holocene when the last remnants of buried glacier ice melted away causing the exposed floor of Lake Timan to subside. Since deglaciation, the following regional vegetation development has been recorded: (1) During the initial stage of Lake Timan, the dominant vegetation was discontinuous steppe/tundra, with patches of snow bed vegetation. (2) A dwarf-shrub tundra established during the Late Weichselian interstadial (Allerød), probably reflecting warmer and moister conditions. (3) The Younger Dryas cooling is recognised by a reversal to steppe/tundra and snowbeds on unstable mineral-soils, and higher palynological richness. (4) Soon after the transition into the Holocene, a birch-forest established on the Timan Ridge. (5) A cooling starting around 8200 cal.years BP initiated the deforestation of the exposed hills. In the most protected sites, birch trees persisted until later than 4000 years ago, reflecting a gradual development into the present treeless dwarf-shrub tundra.     

Precursory groundwater level changes in the period of activation of the weak intraplate seismic activity on the NE margin of the Bohemian Massif (central Europe) in 2005

tWe analyse continuous measurements of groundwater level in two deep wells VS-3 and V-28 at the experimental hydro-meteorological station situated on the NE margin of the Bohemian Massif, central Europe, characterized by the weak intraplate seismic activity. The aim of our study is to examine the relationships between changes in the groundwater level and earthquake occurrence. Based on the tidal and barometric response of the water level, we estimated selected elastic parameters of the observed aquifers: the shear modulus G, the Skempton ratio B, the drained matrix compressibility β and the undrained compressibility β_u. Using these parameters and assuming the homogeneous poroelastic material, we derived the sensitivity of the wells to the crustal volume strain. During the observation period from November 1998 to December 2005 we detected in the VS-3 well two pre-seismic steps, related to August 10, 2005 (M = 2.4) and October 25, 2005 (M = 3.3) earthquakes. Amplitudes of the recorded precursory changes (+6 cm and +15 cm) are several times higher than the values predicted from the theoretical precursory crustal strain and the strain sensitivity of the well. Therefore, we presume that the observed pre-seismic water level steps can be attributed to heterogeneity of poroelastic material. We consequently propose the hypothesis of the origin of precursory events based on the presumption of a sensitive site, at which the well is situated.     

Discriminating Fog and Rain at the Kilometre Scale Using the Extinction from Collocated Infrared and Microwave Scintillometers

Boundary-Layer Meteorology - We investigate the path-averaged visibility and discrimination of fog and rain events using a two-wavelength (near-infrared and microwave) scintillometer system. These...     

Residual and tidal circulation revealed by VHF radar surface current measurements in the southern Channel Isles region (English Channel)

Two very high-frequency radars (VHFRs), operating in the southern Channel Isles region (English Channel) in February–March 2003, provided a continuous 27-day long dataset of surface currents at 2 km resolution over an area extending approximately 20 km offshore. The tidal range in the region of study is one of the highest in the world and the coastal circulation is completely dominated by tides. The radar data resolve two modes which account for 97% of the variability of the surface current velocities, with the major contribution of the first mode. This mode accounts for oscillating tidal currents whereas the second mode represents motions emerging from the interaction of tidal currents with capes and islands (eddy in the vicinity of the Point of Grouin and jet south of Chausey). A fortnightly modulation of the modal amplitudes causes the exceptional (more than 600%) variability of currents which is well captured by the VHFR observations. The radar data revealed that tidal circulation in the region is flood-dominated with a strong asymmetry of current velocity curve. Wind events and fortnightly variability affect the course of tidal cycle by modifying the magnitude and duration of ebb and flood. In addition to expected features of coastal circulation (tidally dominated flow, eddies) and high wind-current coupling, the residual currents revealed a strong cross-shore structure in the mean and a significant variability which has the same order of magnitude.     

In Memoriam: Mikhail Konstantinovich Ivanov, 1945–2012

The guest editors Marc De Batist and Oleg Khlystov dedicate this special double issue of Geo-Marine Letters, presenting contributions from the 10th International Conference on Gas in Marine Sediments (September 2010, Lake Baikal, Russia), to the memory of Mikhail Konstantinovich Ivanov. The author of this In Memoriam is Alexei Suzyumov, former staff member of UNESCO responsible for the TTR program.