Fractures,hydrothermal alterations and permeability in the Soultz Enhanced Geothermal System

Borehole studies of the Soultz-sous-Forêts granite are dedicated to deep geothermics. The hydraulic properties of the reservoir are mainly controlled by the occurrence of some altered cataclastic shear zones showing a low natural permeability characterized by the occurrence of brines. Those zones show a fracture cluster organisation with sealed fractures of various types (post-filled joints, sheared fractures, veins). The main hydrothermal deposits observed within the permeable zones are geodic quartz, carbonates, illite and more locally sulphides. The fracture wall–rocks are intensely transformed: dissolution of igneous minerals, crystallization of new minerals, porosity and permeability increase. It is important to characterize the newly-formed minerals in order to choose the reagents used to improve the permeability of the exchanger by chemical stimulations. This article represents a synthesis of the studies completed by the authors between 1990 and 2008 on the fracture networks, hydrothermal alterations and mineral crystallizations they induced and data about the flow pathways in the exchanger.     

Structure of the low permeable naturally fractured geothermal reservoir at Soultz

The permeability of the granite geothermal reservoir of Soultz is primarily related to major fracture zones, which, in turn, are connected to dense networks of small-scale fractures. The small-scale fractures are nearly vertical and the major direction is about N0°E. This direction differs from that of the Rhine Graben, which is about N20°E to N45°E in northern Alsace. A total of 39 fracture zones, with a general strike of N160°E, have been identified in six wells between 1400 and 5000 m depth. These fracture zones are spatially concentrated in three clusters. The upper cluster at 1800–2000 m True Vertical Depth (TVD) is highly permeable. At 3000–3400 m TVD, the intermediate cluster in composed of a dense network developed in an altered matrix and forms the upper reservoir. In the lower part of the wells, the deeper cluster appears as a fractured reservoir developed within a low permeable matrix. Fracture zones represent a key element to take into account for predicting the geothermal reservoir life time submitted to various thermo-hydromechanical and chemical processes generated by hydraulic or chemical stimulations and by hydraulic circulation tests related to long-term exploitation.     

3D model of fracture zones at Soultz-sous-Forêts based on geological data,image logs,induced microseismicity and vertical seismic profiles

This study presents a new deterministic 3D model of the fracture zones observed in the granitic reservoir of the Soultz European geothermal project. The major fracture zones encountered around 6 wells (4550, EPS1, GPK1, GPK2, GPK3 and GPK4) consist in 53 main structures that are located and characterized in terms of size and orientation: 39 fracture zones, 8 microseismic structures and 6 structures derived from vertical seismic profiles are represented in the 3D model using Discrete Fracture Network tools of the gOcad modelling platform (Paradigm?, Earth Decision?). This work illustrates the complexity of 3D fracture zone correlation and interpretation in crystalline rock masses characterized at meter scale (borehole) and at the reservoir scale (kilometer) thanks to geophysical imaging techniques.     

Geochemische Untersuchungen an einem Vorkommen von Fasersteinsalz

Zusammenfassung Am Beispiel des Fasersteinsalzes wird untersucht, ob die Verteilung des im NaCl eingebauten Broms Rückschlüsse auf den Wachstumsvorgang und die Herkunft der für das Wachstum benötigten Lösungen zuläßt. NachSchmidt undMügge erfolgt das Wachstum der Fasern an ihrer Basis. Wenn dieser Vorgang stimmt, sollte der Br-Gehalt in den älteren Teilen des Fasersteinsalzes (in der Mitte der Kluft gelegen) niedriger sein als in den zuletzt gebildeten Partien der Kluftfüllung (an der Kluftwand gelegen). Tatsächlich konnte an dem natürlichen Fasersteinsalz festgestellt werden, daß der Br-Gehalt im Steinsalz von der Mitte der Kluft zum Rand zunimmt. Auch die Lösungszufuhr kann nach diesem Befund nur in Form von Porenlösungen aus dem Nebengestein erfolgt sein. Aus dem Br-Gehalt des Fasersteinsalzes wurde die Br-Konzentration in den Porenlösungen mit 3,5 · 10^–1 Gew.- % berechnet.

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Summary The distribution of bromine replacing chlorine in fibrous halite of the potash salt mine Marie Louise (Elsaß, France) was determined in order to examine the crystallisation process of this halite. The contents of bromine increase in the cleavage filling of the fibrous halite from the central part to the contact with the marl. The cause of this distribution is the growth of the fibre perpendicular to its base during the opening of the cleavage. The fibrous halite crystallizes from pore solutions originating in the marl rock. The calculation showed that the bromine content in the solution was about 0.35 wt.- %.

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Herrn Prof. Dr. Dr. h. c.C. W. Correns zum 70. Geburtstag gewidmet.     

A history of fire and vegetation in northeastern Minnesota as recorded in lake sediments

The record of charcoal in lake sediments indicates that fire has always been an important ecological factor in the forest history of northeastern Minnesota. The annually laminated sediments of Lake of the Clouds permit precise dating of the charcoal peaks and record the changes in the influx of various pollen types. A detailed record of the past 1000 yr shows that the average frequency of fire is approximately 60–70 yr, with a range of about 20–100 yr. The amount of charcoal in sediments dating between 1000-500 y.a. is consistently higher than that for the last 500 yr, although the fire frequency for the two periods was not appreciably different. Pollen analysis shows no change or only short-term changes in the percentages of major pollen types following charcoal peaks.     

NOAA卫星探测数据对B-模式分析预报系统性误差的影响

本文报告极轨气象卫星探测数据对B-模式的海平面气压场预报和500hPa高度预报的系统性误差的影响.主要结果是:(1)B-模式预报海平面气压的强度偏弱,即高压系统太低,低压太高;(2)500hPa高度预报的系统性误差情况不如海平面气压场误差情况明显.但也能发现槽区的高度预报不够低,而脊区的高度预报不够高;(3)应用卫星数据对B-模式分析预报系统的预报有正作用,对海洋上的地面低压和500hPa槽区附近的系统性误差有明显减小,但对其它地区天气系统预报的正负影响参差不齐,其作用难下结论。     

Gravity changes accompanying volcanic activity at Pacaya volcano, Guatemala

Gravity changes of up to 1.2 ± 0.1 mgal (1 standard deviation) were measured at three points within 400 m of an active vent on Pacaya volcano, Guatemala during eleven days of January, 1975. For five continuous days gravity varied inversely with the average muzzle velocity of ejecta, the frequency of volcanic explosions, and the frequency of volcanic earthquakes. The gravity changes are most reasonably interpreted as the product of intravolcanic movements of magma with masses one to two orders of magnitude larger than any flow ever erupted from the volcano. However, elevation changes and/or combination of elevation and mass distribution changes could also have been an important factor in effecting the observed gravity variations. Because we lack elevation control on the gravity stations, we are unable to unequivocally conclude which factor or which combination of factors produced the gravity changes. The study indicates the possibility of gravity monitoring of hazardous volcanoes as a predictive tool, and as an added means for investigating the internal mechanism of volcanic eruptions.     

Back-arc spreading: Trench migration, continental pull or induced convection?

Mechanisms of the opening of back-arc systems are analyzed. Limited focal mechanisms of intraplate earthquakes are used to determine the stress regime of an overriding plate. Preliminary analyses show that compressive deviatoric stresses exist in the plate except near the spreading center. Based on this observation “trench suction” does not appear to be the primary force that drives back-arc spreading, since it will result in tensional deviatoric stresses within the overriding plate. Even though “continental pull” is able to satisfy the stress requirements, it does not appear to be a likely mechanism either because of the initiation and subsequent symmetric spreading difficulty associated with such a mechanism. The mechanism we favor is the one that involves the induced convective current in the mantle wedge immediately above the slab. Calculations show that the induced flow is able to generate sufficient stress to break up the overriding lithosphere if the tectonic stresses of the region are favorable. Both trench suction and continental pull may help to provide such a favorable tectonic stress regime.     

Sedimentary iron monosulfides: Kinetics and mechanism of formation

The reaction between hydrous iron oxides and aqueous sulfide species was studied at estuarine conditions of pH, total sulfide, and ionic strength to determine the kinetics and formation mechanism of the initial iron sulfide. Total, dissolved and acid extractable sulfide, thiosulfate, sulfate, and elemental sulfur were determined by spectrophotometric methods. Polysulfides, S₄^2? and S₅^2?, were determined from ultraviolet absorbance measurements and equilibrium calculations, while product hydroxyl ion was determined from pH measurements and solution buffer capacity.Elemental sulfur, as free and polysulfide sulfur, was 86% of the sulfide oxidation products; the remainder was thiosulfate. Rate expressions for the reduction and precipitation reactions were determined from analysis of electron balance and acid extractable iron monosulfide vs time, respectively, by the initial rate method. The rate of iron reduction in moles/liter/minute was given by $\text{d(}\text{reduction}\text{Fe)}\text{dt}\text{= kS}{}_{\mathrm{t}}{}^{0.5}\text{(J}{}^{\mathrm{+}}\text{)}{}^{0.5}\text{A}{}_{\mathrm{FeOOH}}{}^1$ where S_t was the total dissolved sulfide concentration, (H⁺) the hydrogen ion activity, both in moles/ liter; and A_FeOOH the goethite specific surface area in square meters/liter. The rate constant, k, was 0.017 ± 0.002m^?2 min^?1. The rate of reduction was apparently determined by the rate of dissolution of the surface layer of ferrous hydroxide. The rate expression for the precipitation reaction was $\text{d(FeS)}\text{dt}\text{= kS}{}_{\mathrm{t}}{}^1\text{(H}{}^{\mathrm{+}}\text{)}{}^1\text{A}{}_{\mathrm{FeOOH}}{}^1$ where $\text{d(FeS)}\text{dt}$ was the rate of precipitation of acid extractable iron monosulfide in moles/liter/minute, and k = 82 ± 18 mol^?1l²m^?2 min^?1.A model is proposed with the following steps: protonation of goethite surface layer; exchange of bisulfide for hydroxide in the mobile layer; reduction of surface ferric ions of goethite by dissolved bisulfide species which produces ferrous hydroxide surface layer elemental sulfur and thiosulfate; dissolution of surface layer of ferrous hydroxide; and precipitation of dissolved ferrous specie and aqueous bisulfide ion.