ENHANCING THE DECONVOLUTION OF NOISY CHROMATOGRAPHIC DATA BY JANSSON''S METHOD

In previous papers Jansson's method was found to be successful at deconvolving severely overlapped gaschromatographic peaks.In the most recent paper the method was evaluated with respect to quantitativeaceuracy,peak area and retention time repeatability.The problems associated with deconvolving noisydata and some alternatives which can improve the ability of Jansson's method to deconvolve noisy dataare discussed.These alternatives include presmoothing the data with a nine-point,third-order polynomialfilter and data reblurring.This paper will test these methods on peaks with various degrees of resolutionand signal-to-noise ratios.     

The Gifford Creek Ferrocarbonatite Complex, Gascoyne Province (Western Australia): a Putative Link to the 1075 Ma Warakurna Large Igneous Province

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打造过硬品牌 以彰显地质公园在UNESCO世界级名录中的特殊地位——PPF理念(“过去—现在—将来”理念)

目前世界地质公园网络(GGN)共有90个成员, 分布在27个国家和地区, 尽管在这个网络建立过程中, 联合国教科文组织起着关键作用, 但在过去十多年里, 其与地质公园的关系只能被定义为“特别支持”, 眼下两者的关系应该在一个国际倡议或计划下被正式化, 这将有利于进一步提高地质公园的管理、交流合作和资源利用。实现该目标, 就要清晰地阐明地质公园核心的独有特色, 使地质公园与联合国教科文组织已实施的计划形成互补, 不会产生冲突或重叠。本文介绍的PPF理念将会是一个有效的方法, 以此创建一个过硬的品牌, 彰显地质公园在UNESCO世界级名录中的特殊地位。     

区域气候模式RegCM3在华东地区夏季的10年回报和2010年业务预报

利用国家气候中心全球海气耦合模式(BCC_CM1.0)嵌套区域气候模式RegCM3进行了近10年(1998-2007年)夏季回报及2010年华东夏季实时业务预报。从10年回报的模拟平均状况来看,模式基本能反映出中国东部夏季的平均状况,模式回报的夏季气温分布与实况较为相似,但回报的夏季降水量分布形态与实况有一定差异。使用国家气候中心六级Ps评分及简化的Ps评分对模式10年回报进行了评估。结果表明,该模式对华东地区夏季气温和降水有一定的跨季度预报能力,温度和降水10年平均Ps评分分别为69.9和60.9;对华东地区南部的气温及其东南部的降水有较好的回报效果。利用该模式进行了2010年夏季实时业务预报,预报检验表明,模式预报的2010年夏季温度距平和降水距平百分率分布与实况较为一致,夏季温度和降水的Ps评分分别为71.4和55.3;对影响较为严重的气候事件如江西降水极端偏多等也进行了准确预报。     

Release of mercury from intertidal sediment to atmosphere in summer and winter

The release of mercury from intertidal sediment to atmosphere was studied based on the simulated experiment. The experiment samples were collected from the Haibo Estuary (S1) and the Licun Estuary (S2) of the Jiaozhou Bay in China,which are seriously polluted with mercury. The results show that the mercury in sediment releases rapidly to atmosphere under solar radiation. After 8 hours of solar radiation,mercury concentrations decrease from 5.62 μg/g and 2.92 μg/g to 2.34 μg/g and 1.39 μg/g in S1 and S2 sediments respectively in summer,and decrease from 5.62 μg/g and 2.92 μg/g to 4.58 μg/g and 2.13 μg/g respectively in winter. The mercury species in the sediment change markedly under solar radiation. The concentrations of mercury bound to organic matter decrease significantly from 2.73 μg/g to 0.31 μg/g in S1 and from 2.07 μg/g to 0.31 μg/g in S2,and the released mercury mainly comes from mercury bound to organic matter. Mercury flux shows distinguishing characteristic of diurnal change,and it increases rapidly in the morning with the rising of solar radiation intensity,but decreases in the afternoon. The mercury flux increases with sediment temperature and solar radiation intensity. The rapid release of mercury in intertidal sediment plays an important role in the regional mercury cycle.     

New Aspects of Extragalactic Globular Clusters

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EXPERIMENTAL DESIGN IN CHEMOMETRICS

Chemometrics is defined as the application of mathematical and statistical methods to chemical systems.Systems theory is seen to be useful for organizing and categorizing the inputs to and outputs fromchemical systems.Advances in measurement science in the 1950s and 1960s,particularly in analyticalchemistry,created a need for a multivariate approach to data analysis.Early chemometrics emphasizedthe use of structure-finding methods for existing data sets.In many instances,data sets can be obtainedfrom designed experiments.Such data sets are more likely to contain the desired information and the datacan usually be acquired at less cost.Renewed interest in statistical process control will provide many new,more robust data sets in the future.