Post-depositional 137Cs Mobility in the Sediments of Three Shallow Coastal Lagoons, SW England

We present ¹³⁷Cs profiles for three low lying coastal lagoons in Southwest England that show a decline in activity with sediment depth. ¹³⁷Cs inventories are lower than expected by comparison with local reference inventories despite the fact that sampling was undertaken in the deep-water zone of each lake where sediment and ¹³⁷Cs focusing would be expected. At all three locations, lake sediment ⁷Be and unsupported ²¹⁰Pb (²¹⁰Pb_un) inventories are not significantly lower than the local reference inventory. ¹³⁷Cs inventories in the study cores range from 38 to 95% of local reference inventories. The standing water level and mud: water interface at two sites are below maximum tide level and, at all three sites, salinity increases significantly in the water columns between low and high tide and in the pore waters of the underlying sediments. We suggest that the difference in hydrostatic pressure between sea level and standing water levels in the lagoons forces salt water up through the sediment column and that monovalent cations (especially Na⁺ and K⁺) replace ¹³⁷Cs on exchange sites leading to the upward migration and loss of ¹³⁷Cs. Rising sea levels may therefore contribute to remobilisation and release of ¹³⁷Cs to the aquatic environment from the sediments of coastal lagoons.     

Lake Sediment Core Records of Sulphur Accumulation and Sulphur Isotopic Composition in Central Ontario, Canada Lakes

Stable isotopic compositions and concentrations of total sedimentary sulphur (S) were determined in cores from 6 lakes in the acid-sensitive Muskoka-Haliburton region of south-central Ontario. The isotopic composition of S in deep sediment (> ~ 20 cm) was approximately constant in all lakes, and indicated a pre-industrial δ ³⁴S value between +4.0 and +5.3‰, which is similar to current bulk deposition. Similarly, total S concentrations in deep sediment were relatively low (1.9–5 mg S g⁻¹ dwt) and approximately constant with depth within cores. All lakes exhibited up-core increases in total S and decreases in δ ³⁴S at a depth corresponding to the beginning of industrialization in the Great Lakes region ( ~ 1900), resulting in a generally reciprocal depth pattern between total S concentration and δ ³⁴S ratios. While initial shifts in total S and δ ³⁴S were likely due to enhanced SO₄ reduction of newly available anthropogenic SO₄, both the magnitude and pattern of up-core S enrichment and shifts in δ ³⁴S varied greatly among lakes, and did not match changes in S deposition post 1900. Differences between lakes in total S and δ ³⁴S were not related to any single hydrologic (e.g., residence time) or physical (e.g., catchment-area-to-lake area ratio) lake characteristic. This work indicates that sediment cores do not provide consistent records of changes in post-industrial S deposition in this region, likely due to redox-related mobility of S in upper sediment.     

Palaeomagnetism of the teschenitic rocks (Lower Cretaceous) in the Outer Western Carpathians of Poland: constraints for tectonic rotations in the Silesian unit

Results of palaeomagnetic investigations of the Lower Cretaceous teschenitic rocks in the Silesian unit of the Outer Western Carpathians in Poland bring evidence for pre-folding magnetization of these rocks. The mixed-polarity component reveals inclinations, between 56° and 69°, which might be either of Cretaceous or Tertiary age. Apparently positive results of fold and contact tests in some localities and presence of pyrhotite in the contact aureole suggest that magnetization is primary, although a Neogene or earlier remagnetization cannot be totally excluded since inclination-only test between localities gives 'syn-folding' results. Higher palaeoinclinations (66°–69°) correlate with a younger variety of teschenitic rocks dated for 122–120 Ma, while lower inclinations (56°–60°) with an older variety (138–133 Ma). This would support relatively high palaeolatitudes for the southern margin of the Eurasian plate in the late part of the Early Cretaceous and relatively quick northward drift of the plate in this epoch, together with the Silesian basin at its southern margin. Declinations are similar to the Cretaceous–Tertiary palaeodeclinations of stable Europe in the eastern part of the studied area but rotated ca. 14°–70° counter-clockwise in the western part. This indicates, together with older results from Czech and Slovakian sectors of the Silesian unit, a change in the rotation pattern from counter-clockwise to clockwise at the meridian of 19°E. The rotations took place before the final collision of the Outer Carpathians nappe stack with the European foreland.     

Re-evaluation of focal depths and source mechanisms of selected earthquakes in the Afar depression

We present a stepwise inversion procedure to assess the focal depth and model earthquake source complexity of seven moderate-sized earthquakes  (6.2 > M _w > 5.1)  that occurred in the Afar depression and the surrounding region. The Afar depression is a region of highly extended and intruded lithosphere, and zones of incipient seafloor spreading. A time-domain inversion of full moment tensor was performed to model direct P and SH waves of teleseismic data. Waveform inversion of the selected events estimated focal depths in the range of 17–22 km, deeper than previously published results. This suggests that the brittle–ductile transition zone beneath parts of the Afar depression extends more than 22 km. The effect of near-source velocity structure on the moment tensor elements was also investigated and was found to respond little to the models considered. Synthetic tests indicate that the size of the estimated, non-physical, non-isotropic source component is rather sensitive to incorrect depth estimation. The dominant double couple part of the moment tensor solutions for most of the events indicates that their occurrence is mainly due to shearing. Parameters associated with source directivity (rupture velocity and azimuth) were also investigated. Re-evaluation of the analysed events shows predominantly normal faulting consistent with the relative plate motions in the region.     

Diatom evidence for autochthonous artifact deposition in the Valsequillo region, Puebla, Mexico during the Sangamonian (sensu lato = 80,000 to ca. 220,000 yr BP and Illinoian (220,000 to 430,000 yr BP))

Fossil diatoms in the Valsequillo area are important in supplying adequate paleoecological evidence for the in situ deposition (in the absence of strong water currents necessary for the displacement and redeposition) of artifacts as large as those at the Hueyatlaco Archaeological Site. The paleoecology of lacustrine diatom-bearing samples from four nearby localities in the Valsequillo region all correlated with numerous diatomaceous samples from the Hueyatlaco Site (Puebla, Mexico) and indicate an autochthonous deposition of the artifacts at that site. This correlative evidence is consistent with a deposition in Sangamonian to Illinoian time and is based on the relationships of percentages of taxa in categories of the current, pH, and halobian spectra in six lines of correlation of samples between the Hueyatlaco Site and the four localities.     

Environmental Changes at the Desert Margin: An Assessment of Recent Paleolimnological Records in Lake Qarun, Middle Egypt

Lake Qarun has been profoundly affected by a combination of human activities and climatic changes during the past 5000 years. Instrumental records available for the 20th century show that during most of this period both lake water level and salinity increased and that by the late 1980s lake water salinity was approximately that of seawater. Sediment cores (c. 1 m long) were collected from this shallow (Z_max 8.4 m) saline lake in 1998 and the master core (QARU1) was used to examine the potential of paleolimnology for reconstructing the recent environmental history of the site. According to ¹³⁷Cs and ²¹⁰Pb radio-assay, the recent sediment accumulation rate in QARU1 was around 5 mm year⁻¹ during the latter half of the 20th century but radionuclide levels were low. Spheroidal carbonaceous particles (SCPs) were present in the upper c. 30 cm of QARU1 and indicates contamination by low level particulate pollution, probably beginning around 1950. The record of exotic pollen (Casuarina) indicated that sediment at 51–52 cm depth dated to around 1930. Otherwise the pollen spectra indicated a strongly disturbed landscape with high ruderals and increased tree planting particularly since c. 1950. Diatom records were strongly affected by taphonomic processes including reworking and differential preservation but typical marine diatoms increased after the 1920s. Instrumental records show that the lake became more saline at this time. Freshwater taxa were present at approximately similar abundances throughout the core. This distribution probably reflected a combination of processes. Reworking of ancient freshwater diatomites is one likely source for freshwater diatoms in QARU1 but some taxa must also be contributed via the freshwater inflows. Overall, the diatom stratigraphy indicated increasingly salinity since the 1920s but provided no firm evidence of lake eutrophication. Diatom inferred salinity reconstructions were in only partial agreement with instrumental records but inferred for the lower section of the core (pre 20th century to the 1960s) accord with measured water salinity values. Surficial sediments of Lake Qarun contain environmental change records for the 20th century period but high sediment accumulation rate and pollen reflect the high degree of human disturbance in the region. Because of poor preservation and evidence of reworking, the relationships between diatom records and past water quality changes require careful interpretation, especially in the upper section of the core. Nevertheless, early to mid 20th century measurements of increasing lake water salinity are well supported by sediment records, a change that is probably linked to ingress of saline ground water