Early formed regional antiforms and synforms that fold younger matrix schistosities: their effect on sites of mineral growth

In the metamorphic cores of many orogenic belts, large macroscopic folds in compositional layering also appear to fold one or more pervasive matrix foliations. The latter geometry suggests the folds formed relatively late in the tectonic history, after foliation development. However, microstructural analysis of four examples of such folds suggests this is not the case. The folds formed relatively early in the orogenic history and are the end product of multiple, near orthogonal, overprinting bulk shortening events. Once large macroscopic folds initiate, they may tighten further during successive periods of sub-parallel shortening, folding or reactivation of foliations that develop during intervening periods of near orthogonal shortening. Reactivation of the compositional layering defining the fold limbs causes foliation to be rotated into parallelism with the limbs.Multiple periods of porphyroblast growth accompanied the multiple phases of deformation that postdated the initial development of these folds. Some of these phases of deformation were attended by the development of large numbers of same asymmetry spiral-shaped inclusion trails in porphyroblasts on one limb of the fold and not the other, or larger numbers of opposite asymmetry spirals on the other limb, or similar numbers of the same asymmetry spirals on both limbs. Significantly, the largest disparity in numbers from limb to limb occurred for the first of these cases. For all four regional folds examined, the structural relationships that accompanied these large disparities were identical. In each case the shear sense operating on steeply dipping foliations was opposite to that required to originally develop the fold. Reactivation of the folded compositional layering was not possible for this shear sense. This favoured the development of sites of approximately coaxial shortening early during the deformation history, enhancing microfracture and promoting the growth of porphyroblasts on this limb in comparision to the other. These distributions of inclusion trail geometries from limb to limb cannot be explained by porphyroblast rotation, or folding of pre-existing rotated porphyroblasts within a shear zone, but can be explained by development of the inclusion trails synchronous with successive sub-vertical and sub-horizontal foliations.     

The early Caledonian (Finnmarkian) event reassessed in Finnmark: Ar/Ar cleavage age data from NW Varangerhalvøya, N. Norway

The relative significance of early (Finnmarkian) and late (Scandian) Caledonian deformation in N. Norway is uncertain. Early studies suggested pervasive Finnmarkian deformation whilst later results indicated a restricted Finnmarkian domain. The present work suggests it was more widespread than accepted and that inter Finnmarkian–Scandian deformation occurred. ⁴⁰Ar/³⁹Ar dating of 2–6 and 6–11 μm pelitic fractions from the lower to mid-greenschist facies Tanahorn Nappe (five samples; base Middle Allochthon) and the epizone Løkvikfjellet and Barents Sea Groups (three samples; North Varanger Region) in the north Scandinavian Caledonides show slightly discordant spectra. Most spectra from the Tanahorn Nappe preserve possible evidence of an early Caledonian event in the high temperature steps, with recoil/excess Ar effects in the low temperature steps; no pre-Caledonian relict component has been recorded. The results indicate Finnmarkian deformation continued to 460 Ma, with Scandian reactivation at 425–415 Ma. From the North Varanger Region, a strongly crenulated sample yielded plateau ages (444–442 Ma); means of combined young steps from weakly to uncrenulated samples gave 470–450 Ma, suggesting penetrative strike-slip deformation occurred in the late Finnmarkian to inter-Finnmarkian–Scandian period. No Scandian ages were recorded in the North Varanger Region. Reassessment of published data from the Laksefjord Nappe and Gaissa Thrust Belt suggests they were affected by Finnmarkian deformation.     

Neoarchaean magmatism and metamorphism of the western granulites in the central domain of the Mozambique belt, Tanzania: U–Pb shrimp geochronology and PT estimates

U–Pb sensitive high resolution ion microprobe (SHRIMP) dating of zircons from charnockitic and garnet–biotite gneisses from the central portion of the Mozambique belt, central Tanzania indicate that the protolith granitoids were emplaced in a late Archaean, ca. 2.7 Ga, magmatic event. These ages are similar to other U–Pb and Pb–Pb ages obtained for other gneisses in this part of the belt. Zircon xenocrysts dated between 2.8 and 3.0 Ga indicate the presence of an older basement. Major and trace element geochemistry of these high-grade gneisses suggests that the granitoid protoliths may have formed in an active continental margin environment. Metamorphic zircon rims and multifaceted metamorphic zircons are dated at ca. 2.6 Ga indicating that these rocks were metamorphosed some 50–100 my after their emplacement. Pressure and temperature estimates on the charnockitic and garnet–biotite gneisses were obscured by post-peak metamorphic compositional homogenisation; however, these estimates combined with mineral textures suggest that these rocks underwent isobaric cooling to 800–850 °C at 12–14 kbar. It is considered likely that the granulite facies mineral assemblage developed during the ca. 2.6 Ga event, but it must be considered that it might instead represent a pervasive Neoproterozoic, Pan African, granulite facies overprint, similar to the ubiquitous eastern granulites further to the east.     

Raman scattering and X-ray diffraction study of the thermal decomposition of an ettringite-group crystal

 A Raman scattering and X-ray diffraction study of the thermal decomposition of a naturally occurring, ettringite-group crystal is presented. Raman spectra, recorded with increasing temperature, indicate that the thermal decomposition begins at ≈55 °C, accompanied by dehydration of water molecules from the mineral. This is in contrast to previous studies that reported higher temperature breakdown of ettringite. The dehydration is completed by 175 °C and this results in total collapse of the crystalline structure and the material becomes amorphous. The Raman scattering results are supported by X-ray diffraction results obtained at increasing temperatures. Received: 9 July 2001 / Accepted: 14 August 2002     

Evidence for fullerenes in solid bitumen from pillow lavas of Proterozoic age from Mítov (Bohemian Massif, Czech Republic)

Andesitic pillow lavas containing biogenic, solid bitumen (SB) are a constituent of a Neoproterozoic volcanosedimentary sequence (Teplá-Barrandian unit, Bohemian Massif) in the Mítov area of the Czech Republic. A black shale formation that is crosscut by these andesitic basalts is 565 Ma old. Carbon disulfide extracts of two powdered samples of SB contain 0.2 and 0.3 ppm of C₆₀, respectively, as determined by high-pressure liquid chromatography. The peak assignment based on retention time is fully supported by high-resolution electron ionization mass spectrometry (EI-MS). No C₇₀ was detected, nor was C₆₀ found in two other SB samples from this locality. Other investigated carbonaceous samples from Bohemia (coals and anthracites of Upper Paleozoic age and anthraxolite, graphitoids, and graphite of Upper Proterozoic age) did not contain fullerenes at concentrations above the detection limit of 0.01 ppm. The absence of C₆₀ in these samples was confirmed by EI-MS. The proposed mechanism of fullerene formation involves a primary algal phase, generation of a hydrocarbonaceous mixture in the course of thermal evolution of the sedimentary series, and their high-temperature transformation related to the extrusion of basalt. An important feature for fullerene conservation was the enclosure of fullerenes in SB with a structure similar to glasslike carbon, where the fullerene was protected against oxidation.     

New observations on the relative sea level and deglacial history of Greenland from Innaarsuit, Disko Bugt

Relative sea level (RSL) data derived from isolation basins at Innaarsuit, a site on the south shores of the large marine embayment of Disko Bugt, West Greenland, record rapid RSL fall from the marine limit (ca. 108 m) at 10,300-9900 cal yr B.P. to reach the present sea level at 3500 cal yr B.P. Since 2000 cal yr B.P., RSL rose ca. 3 m to the present. When compared with data from elsewhere in Disko Bugt, our results suggest that the embayment was deglaciated later and more quickly than previously thought, at or slightly before 10,300 cal yr B.P. The northern part of Disko Bugt experienced less rebound (ca. 10 m at 6000 cal yr B.P.) compared with areas to the south. Submergence during the late Holocene supports a model of crustal down-warping as a result of renewed ice-sheet growth during the neoglacial. There is little evidence for west to east differences in crustal rebound across the southern shores of Disko Bugt.     

A bilinear approximation of the surface relief in terrain correction computations

A new method is presented for the computation of the gravitational attraction of topographic masses when their height information is given on a regular grid. It is shown that the representation of the terrain relief by means of a bilinear surface not only offers a serious alternative to the polyhedra modeling, but also approaches even more smoothly the continuous reality. Inserting a bilinear approximation into the known scheme of deriving closed analytical expressions for the potential and its first-order derivatives for an arbitrarily shaped polyhedron leads to a one-dimensional integration with – apparently – no analytical solution. However, due to the high degree of smoothness of the integrand function, the numerical computation of this integral is very efficient. Numerical tests using synthetic data and a densely sampled digital terrain model in the Bavarian Alps prove that the new method is comparable to or even faster than a terrain modeling using polyhedra.     

Geoid determination using adapted reference field, seismic Moho depths and variable density contrast

 The traditional remove-restore technique for geoid computation suffers from two main drawbacks. The first is the assumption of an isostatic hypothesis to compute the compensation masses. The second is the double consideration of the effect of the topographic–isostatic masses within the data window through removing the reference field and the terrain reduction process. To overcome the first disadvantage, the seismic Moho depths, representing, more or less, the actual compensating masses, have been used with variable density anomalies computed by employing the topographic–isostatic mass balance principle. In order to avoid the double consideration of the effect of the topographic–isostatic masses within the data window, the effect of these masses for the used fixed data window, in terms of potential coefficients, has been subtracted from the reference field, yielding an adapted reference field. This adapted reference field has been used for the remove–restore technique. The necessary harmonic analysis of the topographic–isostatic potential using seismic Moho depths with variable density anomalies is given. A wide comparison among geoids computed by the adapted reference field with both the Airy–Heiskanen isostatic model and seismic Moho depths with variable density anomaly and a geoid computed by the traditional remove–restore technique is made. The results show that using seismic Moho depths with variable density anomaly along with the adapted reference field gives the best relative geoid accuracy compared to the GPS/levelling geoid. Received: 3 October 2001 / Accepted: 20 September 2002 Correspondence to: H.A. Abd-Elmotaal     

A new approach to verify the model core with idealized experiments

Summary ?A newly developed ocean general circulation model has been tested and verified with some idealized experiments. Generally two types of idealized experiments have been done here. First types are called as “symmetric experiments” and second types are called as “transport experiments”. The first types of experiment help to correct the model core and any deficiency from boundary conditions. The second types of experiment are the type of validation experiment. In both the experiments there are no continents, so in the first type of experiments where symmetric forcings are provided one can expect that model should maintain the symmetric nature. In the second type of experiments one can expect that model should respond correctly to the wind forcings, if no wind curl is present in the wind forcing there will be no circulation in the extratropics and if there is no wind the equator there will be no circulation. The model reproduces the possible envisaged results of these experiments and gives the confidence for performing the realistic integration. Received February 20, 2002; accepted July 7, 2002 Published online: February 20, 2003