Structural investigation of the synthetic CaAn(PO4)2 (An = Th and Np) cheralite-like phosphates

The crystallographic structures of the synthetic cheralite, CaTh(PO₄)₂, and its homolog CaNp(PO₄)₂ have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO₄ (Ln = La to Gd). The space group is P2₁/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO₄)₂ are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R _wp = 4.87%, R _p = 3.69% and R _B = 3.99%. For CaNp(PO₄)₂, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R _wp = 6.74%, R _p = 5.23%, and R _B = 6.05%. The results indicate significant distortions of bond length and angles of the PO₄ tetrahedra in CaTh(PO₄)₂ and to a lesser extent in CaNp(PO₄)₂. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO₄)₂. A comparison with the isostructural compounds LnPO₄ (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca²⁺ and Th⁴⁺ introduces a distortion of the PO₄ tetrahedra.     

Atlas of Japan (East) Sea hydrographic properties in summer, 1999

Hydrographic properties from CTD and discrete bottle sample profiles covering the Japan (East) Sea in summer, 1999, are presented in vertical sections, maps at standard depths, maps on isopycnal surfaces, and as property–property distributions. This data set covers most of the Sea with the exception of the western boundary region and northern Tatar Strait, and includes nutrients, pH, alkalinity, and chlorofluorocarbons, as well as the usual temperature, salinity, and oxygen observations.     

EN photographic Perseids

Many Perseid meteors were photographed in the Czech part of the European Fireball Network during the activity of the new strong and sharp maximum on August 12, 1993. Basic data on many of them were evaluated and radiants, atmospheric trajectories and some orbital elements are presented here and compared with atmospheric and orbital data of regular Perseids, which were photographed outside the new activity in 1993 and preceding years. No substantial difference between these two groups of Perseid meteors was found.     

Problems connected with the tangential metric coefficient in the Schwarzschild metric: A possible solution

Four situations are shown where the Schwarzschild metric cannot be used or is subject to unsurmountable problems. The first is the question of a metric useful for PPN-formalism checking different gravitational theories. The second problem occurs in connection with Mach's principle, when the flatness of the spacetime inside a massive hollow sphere is a generally accepted solution. The metrical discontinuity on the same spherical shell is a third problem. The fourth one is the anisotropy of the mass-energy of a test particle in the gravitational field. Three principles for solution are proposed:

1. The space is not dilated, but rather contracted, in the gravitational field; then the measurement-rods are shorter and measured distances have greater magnitudes.
2. The potential energy is to be related to a potential level where a stationary observer is placed and the general relativistic potential must be used.
3. A new metric must be introduced which is distinct from the Schwarzschild metric, so that the space in the gravitational field is warped isotropically.

Then the problems stated are shown to be easily solvable.     

新疆和田河水资源利用与绿色走廊生态建设研究

水是和田河绿色走廊形成与演变最重要的因素。虽然和田河径流量年际变化比较平稳．但年内径流量洪枯季节差异十分悬殊，人工调配水资源的难度较大。随着人类开发利用水资源规模扩大．水资源时空分布格局发生变化，中上游人工绿洲面积扩大，下游绿色走廊植被衰竭，土地荒漠化日趋严重，走廊生态环境持续恶化。文章分析了和田河水资源变化对下游绿色走廊兴衰的影响过程，提出了合理利用水资源、保护绿色走廊生态环境的对策建议。     

Optimal Model for Geoid Determination from Airborne Gravity

Two different approaches for transformation of airborne gravity disturbances, derived from gravity observations at low-elevation flying platforms, into geoidal undulations are formulated, tested and discussed in this contribution. Their mathematical models are based on Green's integral equations. They are in these two approaches defined at two different levels and also applied in a mutually reversed order. While one of these approaches corresponds to the classical method commonly applied in processing of ground gravity data, the other approach represents a new method for processing of gravity data in geoid determination that is unique to airborne gravimetry. Although theoretically equivalent in the continuous sense, both approaches are tested numerically for possible numerical advantages, especially due to the inverse of discretized Fredholm's integral equation of the first kind applied on different data. High-frequency synthetic gravity data burdened by the 2-mGal random noise, that are expected from current airborne gravity systems, are used for numerical testing. The results show that both approaches can deliver for the given data a comparable cm-level accuracy of the geoidal undulations. The new approach has, however, significantly higher computational efficiency. It would be thus recommended for real life geoid computations. Additional errors related to regularization of gravity data and the geoid, and to accuracy of the reference field, that would further deteriorate the quality of estimated geoidal undulations, are not considered in this study.     

地震学家必须开始预报地震

去年，我一直从事某项活动，对于这项活动，有些地震专家认为是荒唐的，有人说是愚蠢的，有人说是真好笑，也有人说是在浪费时间。我做了什么事情会引起如此多同事的这些看法呢?噢，我所从事的活动就是主张进行一些定期的和频繁的地震预报。我公开为新英格兰，并私下为加州的一些同事     

High‐temperature gold‐copper extraction with chloride flux in lava tubes of Tolbachik volcano (Kamchatka)

Subvolcanic environments in supra‐subduction zones are renowned for hosting epithermal deposits that often contain electrum and native gold, including bonanza examples. This study examined mineral assemblages and processes occurring in shallow‐crust volcanic settings using recent eruption (2012–2013) of the basaltic Tolbachik volcano in the Kamchatka arc. The Tolbachik eruptive system is characterized by an extensive system of lava tubes. After cessation of magma input, the tubes maintained the flow of hot oxidized gases that episodically interacted with the lava surfaces and sulphate‐chloride precipitates from volcanic gases on these surfaces. The gas‐rock interaction had strong pyrometamorphic effects that resulted in the formation of molten salt, oxidized (tenorite, hematite, Cu‐rich magnesioferrite) and skarn‐like silicate mineral assemblages. By analogy with experimental studies, we propose that a combination of these processes was responsible for extraction of metals from the basaltic wall rocks and deposition of Cu‐, Fe‐ and Cu‐Fe‐oxides and native gold.