Measurements of the 44-μm band of H2O ice deposited on amorphous carbon and amorphous silicate substrates

We present 20–110 µm absorbance spectra of H₂O ice, deposited on amorphous carbon and silicate substrates, obtained over the 10–140 K temperature range. The measurements have been carried out in a manner that simulates the deposition, warming and cooling of H₂O ice mantles on interstellar and circumstellar grains. For H₂O ice films deposited on these substrates we find (i) similar 44-µm-band peak wavelength temperature dependences, (ii) no bandshape differences in the respective spectra, and (iii) a structural phase transition occurring between 120 and 130 K. In comparison with published data obtained using a polyethylene substrate, the 52-µm feature (the longitudinal optical mode) observed in our spectra is less prominent. This suggests the presence of material-dependent substrate effects that can alter the appearance of the H₂O far-infrared spectrum. The crystallization temperature of H₂O ice films deposited on our amorphous silicate substrate is significantly different from that reported by Moore et al. (1994) , who found crystallization temperatures down to < 20 K for ice also deposited on an amorphous silicate substrate. This is attributed to differences in the surface structures of the respective substrates. This may indicate that, at least in the context of laboratory measurements, substrate material composition is not as significant as substrate surface structure.     

Overtones of silicate and aluminate minerals and the 5–8 μm ice bands of deeply embedded objects

The distinct patterns, relatively low intensities and peak positions of overtone-combination bands of silicates and oxides suggest that the 5–8 μm spectral region can provide clues for the dust composition when near optically thick conditions exist for the 10-μm silicate feature. We present 1000–2500 cm⁻¹ room-temperature laboratory spectra obtained from powders of silicate, aluminate and nitride minerals and silicate glasses. The spectra exhibit overtone absorption bands with mass absorption coefficients ∼100 times weaker than the fundamentals. These data are compared with the 5–8 μm spectra of deeply embedded young stellar objects observed with the Short Wavelength Spectrometer on the Infrared Space Observatory . Fits of the laboratory data to the observations, after subtraction of the 6.0-μm H₂O ice feature and the 6.0-μm feature identified with organic refractory material, indicate that crystalline melilite (a silicate) or metamict hibonite (a radiation-damaged crystalline aluminate) may be responsible for much of the 6.9-μm absorption feature in the observations, with melilite providing the best match. A weaker 6.2-μm absorption in the young stellar object spectra is well matched by the spectra of hydrous crystalline amphibole silicates (actinolite and tremolite). Relative abundances of Si–O in room-temperature amphiboles to low-temperature H₂O ice are in the range 0.46–3.9 and in melilite are in the range 2.5–8.6. No astronomical feature was matched by the overtones of amorphous silicates because these bands are too broad and peak at the wrong wavelength. Hence, this analysis is consistent with the 10-μm features of these objects being due to a mixture of crystalline and amorphous silicates, rather than only amorphous silicates.     

Crystalline water ice in OH32.8–0.3

The 2.2–200 μm spectrum of OH32.8–0.3 has been modelled. Mie theory and radiative transfer models of the 3-μm band of H₂O ice are consistent with a strongly crystalline structural phase. This is also confirmed by the presence of a 44/62-μm band complex analogous to that of laboratory crystalline H₂O ice analogues. The highly ordered phase may be the result of direct crystallization upon deposition as has been theorized by Kouchi et al. At the large total optical depths typical of the radiative transfer models for this object (τ_9.7∼ 40), we find no significant difference between the Mie theory and radiative transfer models of the 3-μm band. On the other hand, large differences are found for the 9.7-μm silicate band. In contrast to Mie theory extinction profiles, those computed via radiative transfer modelling indicate that the 12-μm H₂O ice band (the so-called librational band) is substantially attenuated. This, in addition to the inherent broadness and weakness of the 12-μm ice band, may explain why this band has not been clearly identified in observational spectra of oxygen–rich evolved objects.     

Thermal desorption of water ice in the interstellar medium

Water (H₂O) ice is an important solid constituent of many astrophysical environments. To comprehend the role of such ices in the chemistry and evolution of dense molecular clouds and comets, it is necessary to understand the freeze-out, potential surface reactivity and desorption mechanisms of such molecular systems. Consequently, there is a real need from within the astronomical modelling community for accurate empirical molecular data pertaining to these processes. Here we give the first results of a laboratory programme to provide such data. Measurements of the thermal desorption of H₂O ice, under interstellar conditions, are presented. For ice deposited under conditions that realistically mimic those in a dense molecular cloud, the thermal desorption of thin films (≪50 molecular layers) is found to occur with zeroth-order kinetics characterized by a surface binding energy, E _des, of 5773 ± 60 K, and a pre-exponential factor, A , of 10^30 ± 2 molecules cm⁻² s⁻¹. These results imply that, in the dense interstellar medium, thermal desorption of H₂O ice will occur at significantly higher temperatures than has previously been assumed.     

2–16 μm spectroscopy of micron-sized enstatite (Mg,Fe)2Si2O6 silicates from primitive chondritic meteorites

We present mid-infrared spectra from individual enstatite silicate grains separated from primitive type 3 chondritic meteorites. The 2–16 μm transmission spectra were taken with microspectroscopic Fourier-transform infrared (FT-IR) techniques as part of a project to produce a data base of infrared spectra from minerals of primitive meteorites for comparison with astronomical spectra. In general, the wavelength of enstatite bands increases with the proportion of Fe. However, the wavelengths of the strong En₁₀₀ bands at 10.67 and 11.67 decrease with increasing Fe content. The 11.67-μm band exhibits the largest compositional wavelength shift (twice as large as any other). Our fits of the linear dependence of the pyroxene peaks indicate that crystalline silicate peaks in the 10-μm spectra of Herbig AeBe stars, HD 179218 and 104237, are matched by pyroxenes of En₉₀₋₉₂ and En₇₈₋₈₀, respectively. If these simplistic comparisons with the astronomical grains are correct, then the enstatite pyroxenes seen in these environments are more Fe-rich than are the forsterite (Fo₁₀₀) grains identified in the far-infrared which are found to be Mg end-member grains. This differs from the general composition of type 3 chondritic meteoritic grains in which the pyroxenes are more Mg-rich than are the olivines from the same meteorite.     

The SCUBA HAlf Degree Extragalactic Survey – VI. 350-μm mapping of submillimetre galaxies

A follow-up survey using the Submillimetre High-Angular Resolution Camera (SHARC-II) at 350 μm has been carried out to map the regions around several 850-μm-selected sources from the Submillimetre HAlf Degree Extragalactic Survey (SHADES). These observations probe the infrared (IR) luminosities and hence star formation rates in the largest existing, most robust sample of submillimetre galaxies (SMGs). We measure 350-μm flux densities for 24 850-μm sources, seven of which are detected at ≥2.5σ within a 10 arcsec search radius of the 850-μm positions. When results from the literature are included the total number of 350-μm flux density constraints of SHADES SMGs is 31, with 15 detections. We fit a modified blackbody to the far-IR (FIR) photometry of each SMG, and confirm that typical SMGs are dust-rich  ( M _dust≃ 9 × 10⁸ M_⊙)  , luminous  ( L _FIR≃ 2 × 10¹² L_⊙)  star-forming galaxies with intrinsic dust temperatures of ≃35 K and star formation rates of  ≃400 M_⊙ yr⁻¹  . We have measured the temperature distribution of SMGs and find that the underlying distribution is slightly broader than implied by the error bars, and that most SMGs are at 28 K with a few hotter. We also place new constraints on the 350-μm source counts, N ₃₅₀(>25 mJy) ∼ 200–500 deg⁻².     

Limits on the 2.2-μm contrast ratio of the close-orbiting planet HD 189733b

We obtained 238 spectra of the close-orbiting extrasolar giant planet HD 189733b with resolution   R ∼ 15 000  during one night of observations with the Near-Infrared High-Resolution Spectrograph (NIRSPEC), at the Keck II Telescope. We have searched for planetary absorption signatures in the  2.0–2.4 μm  region where H₂O and CO are expected to be the dominant atmospheric opacities. We employ a phase-dependent orbital model and tomographic techniques to search for the planetary absorption signatures in the combined stellar and planetary spectra. Because potential absorption signatures are hidden in the noise of each single exposure, we use a model list of lines to apply a spectral deconvolution. The resulting mean profile possesses a signal-to-noise ratio (S/N) that is 20 times greater than that found in individual lines. Our spectral time series thus yields spectral signatures with a mean S/N = 2720. We are unable to detect a planetary signature at a contrast ratio of  log₁₀( F _p/ F _*) =−3.40  , with 63.8 per cent confidence. Our findings are not consistent with model predictions which nevertheless give a good fit to mid-infrared observations of HD 189733b. The 1σ result is a factor of 1.7 times less than the predicted 2.185-μm planet/star flux ratio of  log₁₀( F _p/ F _*) ∼−3.16  .     

The initial conditions of isolated star formation – VII. Spitzer mapping of pre-stellar cores

We have retrieved Spitzer archive data of pre-stellar cores taken with the Multiband Imaging Photometer for Spitzer (MIPS) at a wavelength of 160 μm. Seventeen images, containing 18 cores, were constructed. Flux densities were measured for each core, and background estimates were made. Mean off-source backgrounds were found to be 48 ± 10 MJy sr⁻¹ in Taurus and 140 ± 55 MJy sr⁻¹ in Ophiuchus. Consistency was found between the MIPS 170-μm and ISOPHOT 160-μm calibrations. Fourteen cores were detected both by MIPS and by our previous submillimetre surveys. Spectral energy distributions were made for each core, using additional 24- and 70-μm data from the Spitzer data archive, as well as previous infrared and submillimetre data. Previous temperature estimates were refined, and new temperature estimates were made where no Infrared Space Observatory ( ISO ) data exist. A temperature range of 8–18 K was found for the cores, with most lying in the range 10–13 K. We discount recent claims that a large number of pre-stellar cores may have been misclassified and in fact contain low-luminosity protostars detectable only by Spitzer . We find no new protostars in our sample other than that previously reported in L1521F. It is shown that this has a negligible effect on pre-stellar lifetime estimates.     

Comparison of 13CO line and far-infrared continuum emission as a diagnostic of dust and molecular gas physical conditions – I. Motivation and modelling

Determining temperatures in molecular clouds from ratios of CO rotational lines or from ratios of continuum emission in different wavelength bands suffers from reduced temperature sensitivity in the high-temperature limit. In theory, the ratio of far-infrared (FIR), submillimetre or millimetre continuum to that of a ¹³CO (or C¹⁸O) rotational line can place reliable upper limits on the temperature of the dust and molecular gas. Consequently, FIR continuum data from the COBE /Diffuse Infrared Background Experiment (DIRBE) instrument and Nagoya 4-m  ¹³CO  J = 1 → 0  spectral line data were used to plot  240 μm/¹³CO  J = 1 → 0  intensity ratios against 140/240 μm dust colour temperatures, allowing us to constrain the multiparsec-scale physical conditions in the Orion A and B molecular clouds.
The best-fitting models to the Orion clouds consist of two components: a component near the surface of the clouds that is heated primarily by a very large scale (i.e. ∼1 kpc) interstellar radiation field and a component deeper within the clouds. The former has a fixed temperature and the latter has a range of temperatures that vary from one sightline to another. The models require a dust–gas temperature difference of 0 ± 2 K and suggest that 40–50 per cent of the Orion clouds are in the form of dust and gas with temperatures between 3 and 10 K. The implications are discussed in detail in later papers and include stronger dust–gas thermal coupling and higher Galactic-scale molecular gas temperatures than are usually accepted, and an improved explanation for the N (H₂)/ I (CO) conversion factor. It is emphasized that these results are preliminary and require confirmation by independent observations and methods.     

A shallow though extensive H2 2.122-μm imaging survey of Taurus–Auriga–Perseus – I. NGC 1333, L1455, L1448 and B1

We discuss wide-field near-infrared (near-IR) imaging of the NGC 1333, L1448, L1455 and B1 star-forming regions in Perseus. The observations have been extracted from a much larger narrow-band imaging survey of the Taurus–Auriga–Perseus complex. These H₂ 2.122-μm observations are complemented by broad-band K imaging, mid-IR imaging and photometry from the Spitzer Space Telescope , and published submillimetre CO   J = 3–2  maps of high-velocity molecular outflows. We detect and label 85 H₂ features and associate these with 26 molecular outflows. Three are parsec-scale flows, with a mean flow lobe length exceeding 11.5 arcmin. 37 (44 per cent) of the detected H₂ features are associated with a known Herbig–Haro object, while 72 (46 per cent) of catalogued HH objects are detected in H₂ emission. Embedded Spitzer sources are identified for all but two of the 26 molecular outflows. These candidate outflow sources all have high near-to-mid-IR spectral indices (mean value of  α∼ 1.4  ) as well as red IRAC 3.6–4.5 μm and IRAC/MIPS 4.5–24.0 μm colours: 80 per cent have [3.6]–[4.5] > 1.0 and [4.5]–[24] > 1.5. These criteria – high α and red [4.5]–[24] and [3.6]–[4.5] colours – are powerful discriminants when searching for molecular outflow sources. However, we find no correlation between α and flow length or opening angle, and the outflows appear randomly orientated in each region. The more massive clouds are associated with a greater number of outflows, which suggests that the star formation efficiency is roughly the same in each region.     

Probing the surfaces of interstellar dust grains: the adsorption of CO at bare grain surfaces

A solid-state feature was detected at around 2175 cm⁻¹ towards 30 embedded young stellar objects in spectra obtained using the Infrared Spectrometer and Array Camera at the European Southern Observatory Very Large Telescope. We present results from laboratory studies of CO adsorbed at the surface of zeolite wafers, where absorption bands were detected at 2177 and 2168 cm⁻¹ (corresponding to CO chemisorbed at the zeolite surface) and 2130 cm⁻¹ (corresponding to CO physisorbed at the zeolite surface), providing an excellent match to the observational data. We propose that the main carrier of the 2175-band is CO chemisorbed at bare surfaces of dust grains in the interstellar medium. This result provides the first direct evidence that gas–surface interactions do not have to result in the formation of ice mantles on interstellar dust. The strength of the 2175-band is estimated to be  ∼4 × 10⁻¹⁹ cm  molecule⁻¹. The abundance of CO adsorbed at bare grain surfaces ranges from 0.06 to 0.16 relative to H₂O ice, which is, at most, half of the abundance (relative to H₂O ice) of CO residing in H₂O-dominated ice environments. These findings imply that interstellar grains have a large (catalytically active) surface area, providing a refuge for interstellar species. Consequently, the potential exists for heterogeneous chemistry to occur involving CO molecules in unique surface chemistry pathways not currently considered in gas grain models of the interstellar medium.     

Correlated spectral variability in brown dwarfs

Models of brown dwarf atmospheres suggest they exhibit complex physical behaviour. Observations have shown that they are indeed dynamic, displaying small photometric variations over time-scales of hours. Here, I report results of infrared (0.95–1.64 μm) spectrophotometric monitoring of four field L and T dwarfs spanning time-scales of 0.1–5.5 h, the goal being to learn more about the physical nature of this variability. Spectra are analysed differentially with respect to a simultaneously observed reference source in order to remove Earth-atmospheric variations. The variability amplitude detected is typically 2–10 per cent, depending on the source and wavelength. I analyse the data for correlated variations between spectral indices. This approach is more robust than single band or  χ²  analyses, because it does not assume an amplitude for the (often uncertain) noise level (although the significance test still assumes a shape for the noise power spectrum). Three of the four targets show significant evidence for correlated variability. Some of this can be associated with specific features including Fe, FeH, VO and K  i , and there is good evidence for intrinsic variability in H₂O and possibly also CH₄. Yet some of this variability covers a broader spectral range which would be consistent with dust opacity variations. The underlying common cause is plausibly localized temperature or composition fluctuations caused by convection. Looking at the high signal-to-noise ratio stacked spectra, we see many previously identified spectral features of L and T dwarfs, such as K  i , Na  i , FeH, H₂O and CH₄. In particular, we may have detected methane absorption at 1.3–1.4 μm in the L5 dwarf SDSS 0539−0059.     

The 3.3-μm PAH emission band of the Red Rectangle

A new analysis of long-slit CGS4 United Kingdom Infrared Telescope spectra of the 3.3-μm feature of the Red Rectangle and its evolution with offset along the NW whisker of the nebula is presented. The results support a proposed two-component interpretation for the 3.3-μm feature with peak wavelengths near 3.28 and 3.30 μm. Both components exhibit a small shift to shorter wavelength with increasing offset from the central star which, by comparison with laboratory studies, is consistent with a decrease in the temperature of the carriers with distance from HD 44179. The two-component approach is also applied to 3.3-μm data for the Red Rectangle, Orion Bar D2 and Orion Bar H2S1 from Infrared Space Observatory Short Wavelength Spectrometer (SWS) studies.     

Ice in the Southern Coalsack

To better understand the conditions under which ice mantles form on grains in molecular clouds, three globules in the Southern Coalsack have been searched for the presence of H₂O ice. Given the total lack of star formation in the Coalsack, it is an ideal site for studying unprocessed icy molecular mantles. In our sample of eight field stars lying behind the Coalsack we detect strong H₂O ice absorption in the lines of sight to two stars and possible weak absorption in four others. We estimate H₂O ice column densities or upper limits for these lines of sight. Compared to dark clouds such as Taurus, the Coalsack H₂O ice column densities are lower than expected given the quiescent nature of the Coalsack region. It is possible that the chemical evolution of the Coalsack may simply be at too early a stage for significant ice mantles to appear on the grains, except perhaps in the densest parts of some of the globules. Alternatively, the presence or absence of ice absorption may be related to the distribution of dust along each line of sight, specifically, the relative contributions of dense globules and a more extended diffuse component. For example, our observations are consistent with an ice threshold extinction similar to that observed in the Taurus dark cloud if extinction amounting to   A _V∼5  towards Globules 2 and 3 arises in the extended component. Globule 1 appears to have no extended component.     

Measurement of the Sunyaev–Zel'dovich increment in massive galaxy clusters

We have detected the Sunyaev–Zel'dovich (SZ) increment at 850 μm in two galaxy clusters (Cl 0016+16 and MS 1054.4−0321) using the Submillimetre Common User Bolometer Array (SCUBA) on the James Clerk Maxwell Telescope. Fits to the isothermal β model yield a central Compton y parameter of  (2.2 ± 0.7) × 10⁻⁴  and a central 850-μm flux of  Δ I ₀= 2.2 ± 0.7 mJy beam⁻¹  in Cl 0016. This can be combined with decrement measurements to infer   y = (2.38 ±^0.36_0.34) × 10⁻⁴  and   v _pec= 400±¹⁹⁰⁰₁₄₀₀ km s⁻¹  . In MS 1054 we find a peak 850-μm flux of  Δ I ₀= 2.0 ± 1.0 mJy beam⁻¹  and   y = (2.0 ± 1.0) × 10⁻⁴  . To be successful such measurements require large chop throws and non-standard data analysis techniques. In particular, the 450-μm data are used to remove atmospheric variations in the 850-μm data. An explicit annular model is fit to the SCUBA difference data in order to extract the radial profile, and separately fit to the model differences to minimize the effect of correlations induced by our scanning strategy. We have demonstrated that with sufficient care, SCUBA can be used to measure the SZ increment in massive, compact galaxy clusters.     

Near-infrared imaging polarimetry of Cygnus A

We present a 2.2-μm polarization image of the nuclear regions of Cygnus A. The degree of polarization in the central 1 arcsec is (4.1±0.50) per cent, at a position angle of (23.6±3.6)°, approximately perpendicular to the axis of the radio jet.
Modelling of the results suggests that at this wavelength the polarization along the line of sight to the central source is most likely produced by dichroism, through an A _v∼40 mag, with the polarization in surrounding regions produced by scattering. For this model, the K -band luminosity of the central source is calculated to be ∼2×10⁴⁴ erg s⁻¹.     

Water in the near-infrared spectrum of comet 8P/Tuttle

High-resolution spectra of comet 8P/Tuttle were obtained in the frequency range 3449.0–3462.2 cm⁻¹ on 2008 January 3 ut using CGS4 with echelle grating on United Kingdom Infrared Telescope. In addition to observing solar pumped fluorescent lines of H₂O, the long integration time (152 min on target) enabled eight weaker H₂O features to be assigned, most of which had not previously been identified in cometary spectra. These transitions, which are from higher energy upper states, are similar in character to the so-called SH lines recorded in the post Deep Impact spectrum of comet Tempel 1. We have identified certain characteristics that these lines have in common, and which in addition to helping to define this new class of cometary line give some clues to the physical processes involved in their production. Finally, we derive an H₂O rotational temperature of     and a water production rate of  (1.4 ± 0.3) × 10²⁸  molecules s⁻¹.     

Infrared mapping of the dust disc around Vega

ISOPHOT has been used to perform high-resolution 60-μm scans of Vega, and these have been compared with those from γDra, to obtain a Gaussian width of 22±2 arcsec. The dust disc around Vega has been mapped, resolving it at 60 and 90 μm with ISOPHOT. At 90 μm a Gaussian width of 36±3 arsec has been derived. In addition, multi-filter photometry is presented, at 25, 60, 80, 100, 120, 150, 170 and 200 μm. The data are fitted by a modified blackbody with a temperature of 73 K [ Q (λ)∝1/λ^1.1]. The dust disc has a luminosity L _IR/ L _*∼3×10⁻⁵. Using a distance of 7.8 pc, 22 arcsec corresponds to a distance of 86 au, and 36 arcsec to a distance of 140 au.     

Unlocking the Keyhole: H2 and PAH emission from molecular clumps in the Keyhole Nebula

To better understand the environment surrounding CO emission clumps in the Keyhole Nebula, we have made images of the region in H₂ 1–0 S(1) (2.122-μm) emission and polycyclic aromatic hydrocarbon (PAH) emission at 3.29 μm. Our results show that the H₂ and PAH emission regions are morphologically similar, existing as several clumps, all of which correspond to CO emission clumps and dark optical features. The emission confirms the existence of photodissociation regions (PDRs) on the surface of the clumps. By comparing the velocity range of the CO emission with the optical appearance of the H₂ and PAH emission, we present a model of the Keyhole Nebula whereby the most negative velocity clumps are in front of the ionization region, the clumps at intermediate velocities are in it and those which have the least negative velocities are at the far side. It may be that these clumps, which appear to have been swept up from molecular gas by the stellar winds from η  Car, are now being overrun by the ionization region and forming PDRs on their surfaces. These clumps comprise the last remnants of the ambient molecular cloud around η Car.     

The simultaneous detection of 22- and 321-GHz H2O maser emission towards the symbiotic Mira R Aquarii

We report high spatial and spectral resolution measurements of masers towards R Aqr and H1−36, both of which are examples of the sub-class of symbiotic stars that contain a long-period Mira-type variable. Our observations have resulted in the first detection of 321-GHz H₂O maser action towards a symbiotic Mira — R Aqr. Comparison with simultaneous 22-GHz H₂O maser data suggests that the masers do not have the same properties as those in the circumstellar envelopes of field Miras. R Aqr's 22-/321-GHz peak flux density and luminosity ratios are low, as is the line width ratio. Continuum and spectral-line maps indicate that the 22-GHz maser and free–free emission are aligned. Three mechanisms can reproduce the data with varying degrees of success. All three lead naturally to normal levels of maser emission in SiO and 321-GHz H₂O and anomalously weak OH and 22-GHz H₂O masers. In the most convincing model, UV radiation and a fast wind from the companion remove the Mira's envelope of dusty, molecular gas, leaving a relatively small cavity of dense, neutral material within a large, ionized nebula. Excitation temperatures suggest that 321-GHz masers are normally excited close to the Mira whilst 22-GHz masers are more remote; in R Aqr, therefore, the 22-GHz masers do not form under optimum conditions. Instead, we see weak and narrow lines that form closer to the Mira, consistent with our high-resolution maps.