基于Pitzer模型的25℃时NaCl-SrCl2-H2O和KCl-SrCl2-H2O体系溶解度计算

用Pitzer离子相互作用模型计算了25℃时NaCl-SrCl2-H2O体系和KCl-SrCl2-H2O体系的溶解度并绘制了相图,计算值与实验值相符合。结果表明,Pitzer模型能够用于含锶水盐体系的溶解度计算。     

三元体系Na_2B_4O_7-NaHCO_3-H_2O和Na_2CO_3-NaBO_2-H_2O等温溶解度研究

作为研究四元体系Ｎａ２Ｂ４Ｏ７－Ｎａ２ＣＯ３－ＮａＨＣＯ３－ＮａＢＯ２－Ｈ２Ｏ的开端，测定了三元体系Ｎａ２Ｂ４Ｏ７－ＮａＨＣＯ３－Ｈ２Ｏ和Ｎａ２ＣＯ３－ＮａＢＯＨ２－Ｈ２Ｏ在０℃、１５℃－４５℃时的溶解度，绘制了相应的组成－性质图。两个三元体系的溶度图在研究温度范围内均属于低共饱型，平衡固相为组分化合物或其水合物。     

MgCl_2·6H_2O的热分解

在马福炉中不同加热条件下研究了MgCl_2·6H_2O的热分解。得出的结论是,温度上升到450℃时,形成 MgOHCl;该化合物虽然在此温度下是稳定的,但在550℃时不稳定。已经发现 MgCl_2·6H_2O 热分解形成 MgO 和 HCl 的最好温度范围是在700—750℃,加热时间是90—120分钟。     

三元体系Na2B4O7—NaHCO3—H2O和Na2CO3—NaBO2—H2O等温溶解研究

作为研究四元体系Na2B4O7-Na2CO3-NaHCO3-NaBO2-H2O的开端，测定了三元体系Na2B4O7-NoHCO3-H2O和Na2CO3-NaBOH2-H2O在0℃，15℃，45℃时的溶解度，绘制了相应的组成－性质图。两个三元体系的溶度图在研究温度范围内均属于低共饱型，平衡固相为组分化合物或其水合物。     

25 ℃ NaCl-Na2SO4-C2H5OH-H2O体系相平衡及应用研究

溶析结晶法是无机盐分离纯化的重要方法之一。通过等温溶解平衡法测定了两个三元体系 NaCl-CH3CH2OH-H2O,Na2SO4-CH3CH2OH-H2O和一个四元体系 NaCl-Na2SO4-CH3CH2OH-H2O的部分溶解度数据,并根据溶解度数据绘制了相图。通过对实验数据的分析得出以下结论: 1)随着乙醇含量的增加硫酸钠和氯化钠的单盐含量均下降。 2)随着乙醇含量的增加硫酸钠和氯化钠共饱和溶液中两盐的含量均下降,但是趋势有所不同,氯化钠的下降趋势较缓和,而硫酸钠一开始下降速度比较快之后趋于平缓。 3)乙醇含量为 10%时硫酸钠和氯化钠的溶解度差值最大,大于纯水中两盐溶解度差值,这为溶析结晶法分离氯化钠和硫酸钠奠定了理论基础。 4)设计了溶析结晶法分步分离盐硝的路线,并用相图进行了分析计算,结果表明硫酸钠和氯化钠的一次循环收率分别为 68.68%、66.61%。     

盐水-盐平衡的热力学I.25℃时 NaCl-KCl-MgCl2-CaCl_2-H_2O 和 NaCl-MgSO_4-H_2O 体系

发展了一种浓盐水的热力学模型。该模型能够预示在25℃和1大气压下许多普通蒸发盐矿物在氯化物——硫酸盐水中的溶解度。该模型假定,在含水电解质混合物中平均化学计算的离子活度系数的行为,可用 Scatchard 偏离函数以及 Harned定律来描述。在含有一种盐和水的溶液中,其活度系数可用下式表示:logγ_±=-|z_ z_-|AI~(1/2)/( a°BI~(1/2)) 2(V_ V_-/V)(?)I,式中 a°和(?)得自数据回归的盐特殊参数。在几种电解质和水的混合物中,第 i 种组份的(?)可用下式求得:(?)=(?) ∑_(aijyj) j=1,n j≠i,式中 aij 是表示组份 i 和组份 j 相互作用的恒定混合参数,yj 是第 j 组份的离子强度分数。水的活度系数由 Gibbs-Duhem 积分式求得。而且不需要任何附加的参数和假设。在本论文中,求取了 NaCl-KCl-MgCl_2-CaCl_2-H_2O 和 NaCl-MgSO_4-H_2O 体系在25℃和大气压条件下的参数。这些体系中算得的溶解度曲线和预示的不变点溶液组成均与实验数据很一致。此模型具有灵活性,并容易推广到其他体系和更高的温度。     

273.15 到 308.15 K下二元体系（LiCl-H2O 和 MgCl2-H2O）和三元体系（LiCl-MgCl2-H2O）的体积性质研究

用高精度振动管在 273.15 至 308.15 K 的温度范围内以 5 K 的间隔对两个二元系统（LiCl-H2O 和 MgCl2-H2O）和三元系统（LiCl-MgCl2-H2O）的密度进行了实验测定密度计。基于 Vogel-Fulcher-Tamman (VFT) 方程,对 LiCl(aq) 和 MgCl2(aq) 密度与温度和摩尔浓度的相关方程的系数进行了参数化。 Young的理想混合规则被成功地应用于基于相关的二元解性质关联三元系统的密度。根据二元和三元体系的体积特性数据,根据 Pitzer 离子相互作用理论,得到 Pitzer 单盐参数和混合离子相互作用参数。在本工作中确定了三元体系在恒定离子强度下的混合体积 (ΔVm)。     

K2O·MgO·6B2O3·10H2O的热化学研究

在大约１ｍｏｌ·ｄｍ－３的盐酸水溶液中测定了Ｋ２Ｏ·ＭｇＯ·６Ｂ２Ｏ３·１０Ｈ２Ｏ的溶解焓。结合已获得的其它热化学数据，得出Ｋ２Ｏ·ＭｇＯ·６Ｂ２Ｏ３·１０Ｈ２Ｏ的标准摩尔生成焓为－（１２２５０．３５±９．６８）ｋＪ·ｍｏｌ－１，并利用“基团贡献法”计算出标准摩尔吉布斯自由能为－１１１０３ｋＪ·ｍｏｌ－１。从而计算出其标准摩尔生成熵和标准摩尔熵。     

Fluxes of CO2, CH4 and N2O from alpine grassland in the Tibetan Plateau

Using static chamber technique, fluxes of CO2, CH4 and N2O were measured in the alpine grassland area from July 2000 to July 2001, determinations of mean fluxes showed that co2 and N2O were generally released from the soil, while the alpine grassland accounted for a weak CH4 sink. Fluxes of CO2, CH4 and N2O ranged widely. The highest co2 emission occurred in August, whereas almost 90% of the whole year emission occurred in the growing season. But the variations of CH4 and N2O fluxes did not show any clear patterns over the one-year-experiment. During a daily variation, the maximum co2 emission occurred at 16:00, and then decreased to the minimum emission in the early morning. Daily pattern analyses indicated that the variation in co2 fluxes was positively related to air temperatures (R2=0.73) and soil temperatures at a depth of 5 cm (R2=0.86), whereas daily variations in CH4 and N2O fluxes were poorly explained by soil temperatures and climatic variables. co2 emissions in this area were much lower than other grasslands in plain areas.     

Fluxes of CO<Subscript>2</Subscript>, CH<Subscript>4</Subscript> and N<Subscript>2</Subscript>O from alpine grassland in the Tibetan Plateau

Using static chamber technique,fluxes of CO2,CH4 and N2O were measured in the alpine grassland area from July 2000 to July 2001,determinations of mean fluxes showed that CO2 and N2O were generally released from the soil,while the alpine grassland accounted for a weak CH4 sink.Fluxes of CO2,CH4 and N2O ranged widely.The highest CO2 emission occurred in August,whereas almost 90?of the whole year emission occurred in the growing season.But the variations of CH4 and N2O fluxes did not show any clear patterns over the one-year-experiment.During a daily variation,the maximum CO2 emission occurred at 16:00,and then decreased to the minimum emission in the early morning.Daily pattern analyses indicated that the variation in CO2 fluxes was positively related to air temperatures(R^2=0.73)and soil temperatures at a depth of 5 cm(R^2=0.86),whereas daily variations in CH4 and N2O fluxes were poorly explained by soil temperatures and climatic variables.CO2 emissions in this area were much lower than other grasslands in plain areas.     

草原土壤的碳氮含量及其与温室气体通量的相关性

通过采样分析研究内蒙古锡林流域温带草原土壤有机碳及全N的含量特征,探讨它们的含量与温室气体CO2、N2O、CH4通量的相关性。结果表明：沿470－150mm年降水梯度线，土壤表层（0－20cm）有机碳含量从2．38％递减到1．23％，全N含量从0．218％递减到0．136％，而且放牧和开垦都有使有机碳及全N含量降低的趋势；CO2通量与有机碳含量、全N含量、C／N及N2O通量显著相关，N2O通量与有机碳含量、C／N及CO2通量显著相关，且CO2和N2O的通量都有沿降水梯度递减的趋势；CH4通量与有机碳含量、全N含量、C／N、CO2通量及N2O通量都没有显著相关性。     

内蒙古温带半干旱羊草草原N2O通量及其影响因素

利用静态箱 -气相色谱法于 2 0 0 1～ 2 0 0 3年对内蒙古锡林河流域羊草草原进行了连续 2年的野外定位试验 ,获得羊草草原原状群落与土壤N2 O年排放通量分别在 3 91～ 4 71μgm- 2h- 1以及 5 5 0～ 10 0 3μgm- 2 h- 1范围内变动 ,证明内蒙古温带半干旱羊草草原生态系统是大气中N2 O的源 ;系统分析了羊草草原N2 O通量的季节变化、源汇特征以及关键的环境因子对草地N2 O通量的影响等 ,建立了N2 O通量与环境因子间的回归方程 ;并利用两年连续完整的观测数据对羊草草原N2 O年排放量进行了估算     

CO2 processes in an alpine grassland ecosystem on the Tibetan Plateau

In this paper, the CO2 concentrations profile from 1.5 m depth in soil to 32 m height in atmosphere were measured from July 2000 to July 2001 in an alpine grassland ecosystem located in the permafrost area on the Tibetan Plateau, which revealed that CO2 concentrations varied greatly during this study period. Mean concentrations during the whole experiment in the atmosphere were absolutely lower than the CO2 concentrations in soil, which resulted in CO2 emissions from the alpine steppe soil to the atmosphere. The highest CO2 concentration was found at a depth of 1.5 m in soil while the lowest CO2 concentration occurred in the atmosphere. Mean CO2 concentrations in soil generally increased with depth. This was the compositive influence of the increasing soil moistures and decreasing soil pH, which induced the increasing biological activities with depth. Temporally, the CO2 concentrations at different layers in air remained a more steady state because of the atmospheric turbulent milking. During the seasonal variations, CO2 concentrations at surface soil interface showed symmetrical patterns, with the lowest accumulation of CO2 occurring in the late winter and the highest CO2 concentration in the growing seasons.     

青藏高原高寒草原生态系统CO2过程研究

In this paper, the CO2 concentrations profile from 1.5 m depth in soil to 32 m height in atmosphere were measured from July 2000 to July 2001 in an alpine grassland ecosystem located in the permafrost area on the Tibetan Plateau, which revealed that CO2 concentrations varied greatly during this study period. Mean concentrations during the whole experiment in the atmosphere were absolutely lower than the CO2 concentrations in soil, which resulted in CO2 emissions from the alpine steppe soil to the atmosphere. The highest CO2 concentration was found at a depth of 1.5 m in soil while the lowest CO2 concentration occurred in the atmosphere. Mean CO2 concentrations in soil generally increased with depth. This was the compositive influence of the increasing soil moistures and decreasing soil pH, which induced the increasing biological activities with depth. Temporally, the CO2 concentrations at different layers in air remained a more steady state because of the atmospheric turbulent milking. During the seasonal variations, CO2 concentrations at surface soil interface showed symmetrical patterns, with the lowest accumulation of CO2 occurring in the late winter and the highest CO2 concentration in the growing seasons.     

CO<Subscript>2</Subscript> processes in an alpine grassland ecosystem on the Tibetan Plateau

In this paper, the CO2 concentrations profile from 1.5 m depth in soil to 32 m height in atmosphere were measured from July 2000 to July 2001 in an alpine grassland ecosystem located in the permafrost area on the Tibetan Plateau, which revealed that CO2 concentrations varied greatly during this study period. Mean concentrations during the whole experiment in the atmosphere were absolutely lower than the CO2 concentrations in soil, which resulted in CO2 emissions from the alpine steppe soil to the atmosphere. The highest CO2 concentration was found at a depth of 1.5 m in soil while the lowest CO2 concentration occurred in the atmosphere. Mean CO2 concentrations in soil generally increased with depth. This was the compositive influence of the increasing soil moistures and decreasing soil pH, which induced the increasing biological activities with depth. Temporally, the CO2 concentrations at different layers in air remained a more steady state because of the atmospheric turbulent milking. During the seasonal variations, CO2 concentrations at surface soil interface showed symmetrical patterns, with the lowest accumulation of CO2 occurring in the late winter and the highest CO2 concentration in the growine seasons.     

中亚热带2种天然林表层土壤N2O排放速率

运用静态箱-气相色谱法对中亚热带地区米槠天然林和阿丁枫天然林土壤N2O排放速率进行了1年（2012年1月—2013年1月）原位观测,分析了土壤温度及含水量对土壤N2O排放速率的影响,并探讨土壤无机N含量变化与土壤N2O排放速率的关系。结果表明,观测期间,2种天然林均表现为大气N2O排放源,米槠天然林和阿丁枫天然林平均土壤N2O排放速率分别为7.29μg·m^-2·h^-1、7.41μg·m^-2·h^-1;米槠天然林和阿丁枫天然林土壤N2O排放速率季节变化明显,最高排放速率均出现在夏季6月,分别为16.51μg·m^-2·h^-1、18.86μg·m^-2·h^-1;2个林分N2O排放速率最低值分别出现在2012年1月和2012年9月,分别为3.04μg·m^-2·h^-1和2.17μg·m^-2·h^-1。2种天然林土壤N2O排放速率均与土壤温度无显著相关性,与土壤含水量显著正相关（P〈0.05）;2种天然林土壤N2O排放速率与NH4＋含量均无显著相关性,米槠天然林和阿丁枫天然土壤N2O排放速率与NO3-含量分别呈显著负相关和显著正相关（P〈0.05）。研究结果表明,土壤含水量及NO3-含量的变化对中亚热带天然林土壤N2O排放速率有着重要的影响。     

三江平原不同土地利用方式下湿地土壤CO2通量研究

利用暗箱-气相色谱法,同步测量了三江平原几种主要生态类型湿地土壤原始的小叶章草甸白浆土、毛果苔草泥炭沼泽土、已垦旱作草甸白浆土和人工水田草甸白浆土,进行CO2排放通量的对比研究.结果表明不同土地利用方式下,旱作草甸白浆土土壤CO2排放通量最大,平均值为775.38mg/(m2@h);小叶章草甸白浆土土壤次之,平均值为439.02mg/(m2@h);人工水稻田草甸白浆土土壤CO2通量最小,平均值为128.96mg/(m2@h);毛果苔草泥炭沼泽土土壤CO2排放通量介于小叶章草甸白浆土土壤和水稻田草甸白浆土土壤之间,平均值为247.08mg/(m2@h).湿地开垦为旱田,使湿地"碳汇"功能减弱或丧失,变成"碳源";湿地开垦为水田,是比较合理的湿地农业利用方式.     

三江平原湿地CH4、N2O的地-气交换特征

利用暗箱-气相色谱法对三江平原3种具有代表性的湿地类型（常年积水的毛果苔草沼泽、季节性积水的小叶章湿草甸和灌丛湿地）进行了为期两年的CH⁴和N²O现场同步观测。结果表明,湿地全年CH⁴和N²O通量有明显的季节和年际变化,与温度和土壤水分条件密切相关。在发生季节性干旱的年份,生长季（5月¹0月）CH⁴排放通量峰值出现在6月和8月,呈双峰型;而在降水充沛的年份,CH⁴排放通量峰值出现在6、7月份,呈单峰型。冰冻期（11月到次年4月）CH⁴排放通量十分的微弱,其中灌丛湿地表现为负排放。3种类型湿地N²O通量一般在非冰冻期表现为排放,呈双峰型,5月份融化期为第一个高峰期,7、8月为第二个高峰期,冰雪覆盖期表现为吸收。湿地CH⁴和N²O通量在春季的融冻期,存在此消彼长的现象。