含硫化合物对不同土壤硝化作用和N2O排放的影响

研究发现,甲硫氨基酸对土壤氮的影响有别于其他氨基酸,为了探究这种影响差异是否与含硫有关,以3种不同pH值土壤:东北黑土(D)、福建红壤(F)、河南碱性土壤(H)为研究对象,设置对照(CK,0 mg·N·kg~(-1))、添加甲硫氨基酸(Met,40 mg·N·kg~(-1))、半胱氨酸(Cys,40 mg·N·kg~(-1))、硫酸钠(S,91 mg·S·kg~(-1))4个处理在室内培养21天,分析各土壤的硝化过程和N_2O排放。结果表明:与CK相比,Met和Cys处理的净氨化速率在土壤D和F显著升高,在H土壤中为负值,S处理变化不明显;Met和Cys处理显著提高了H土壤净硝化速率403.6%和312.0%,显著降低了F土壤146.4%和122.4%,而在S处理变化不明显。可见含硫氨基酸添加促进酸性土壤氨化、抑制硝化作用,但对碱性土壤影响相反。在CK和S处理中,土壤净硝化速率表现为DFH,而在Met和Cys中则表现为HDF,有机硫和无机硫影响不同,在有机硫化合物处理中,净氨化速率和净硝化速率分别与土壤pH值呈负相关和正相关关系。然而在无机硫化合物处理中,净氨化速率与土壤pH值呈正相关关系,pH对净硝化速率没有影响。Met和Cys处理的N_2O产生速率显著升高,S处理与CK差异不明显,说明有机含硫化合物促进了N_2O的释放,尤其是F土壤。由于N_2O是硝化作用的产物,因此,F土壤硝态氮降低可能与硝态氮保持有关,并不是限制了硝化。     

沙漠人工植被区蒸腾测定

利用表面覆盖油毡的大型非称重式蒸渗池和LI1600气孔计测定油蒿(Artemisiaordosica)和柠条(Caraganakorshinskii)的蒸腾,比较了两种测定方法是否存在差异。结果表明蒸渗池表面自油毡覆盖至试验结束,油蒿、柠条和流沙处理0~150cm土层土壤含水量都增加,尤其流沙处理土壤含水量上升最明显;油蒿与柠条的冠幅、新梢长和叶面积指数均增加;由于中子仪探测不到蒸渗池底部40cm厚的砾石层的水分,导致了对照流沙处理测定结果不合常规。测定日期不同,LI1600气孔计测定的蒸腾速率的变化趋势和值也不同,但油蒿和柠条的变化步调是一致的,油蒿的蒸腾速率普遍高于柠条的;用多项式拟合得到蒸腾速率日变化曲线均达到显著水平(P < 0.05)。通过单位换算统一和尺度转换,蒸渗池和LI1600气孔计测定结果进行方差分析,表明物种间(油蒿和柠条)差异达显著水平(P < 0.05),测定方法间(蒸渗池和LI1600气孔计)差异不显著;从而说明本研究以叶面积指数和植物冠层盖度为基础,进行叶片水平与种群水平间的尺度转换是可行的。     

荒漠土壤氧化亚氮排放及其驱动因素研究进展

氧化亚氮(N₂O)具有寿命长、增温潜势高且对臭氧层破坏性大等特点,陆地生态系统是其产生的主要来源。温度升高、降水变化以及由此引起的土壤中多种生物过程的改变,会促进或抑制N₂O排放,进而对环境产生深远影响。基于此,本文回顾和总结了有关国内外荒漠区土壤N₂O排放的研究进展,分析了荒漠土壤N₂O的产生-排放过程及排放通量,并详细综述了环境因子、土壤生物和非生物因素对荒漠土壤N₂O排放的影响机制。结果表明：荒漠土壤N₂O排放由硝化作用和反硝化作用主导,且具有明显的季节特征,具体表现为生长季排放量高,非生长季排放量低甚至为负。在总结已有研究的基础上,展望了荒漠区土壤N₂O排放的研究方向及亟待解决的问题：(1)基于同位素示踪技术及分子生物学技术探究微生物及相关功能基因对荒漠土壤N₂O产生和消耗的影响;(2)探究不同时间尺度(日、月、季节以及年际)多因素交互作用下荒漠土壤N₂O排放规律;(3)完善荒漠生态...     

长白山圆池泥炭氮元素分布特征及其影响因素分析

通过对长白山圆池4个泥炭剖面样品的分析,揭示了其氮元素分布规律。在圆池选取4个具有代表性的采样点,利用泥炭采样器采取新鲜泥炭样品。分析结果表明,4个泥炭剖面氮元素含量在0.014%~3.353%之间;剖面间相比较,其中贫营养泥炭整体含氮量较低;4个泥炭剖面的氮元素分布呈现明显规律,受泥炭上层不同植物、泥炭水分和有机质含量等因素的影响,泥炭剖面中氮元素累积峰可能出现在剖面的表层(0~5cm)或中间层(10~20cm);泥炭剖面氮元素与有机质呈极显著的正相关;泥炭剖面C/N比值变化在9.51~66.98之间,部分剖面层位C/N比值异常高,表明该层位碳的累积速度显著高于氮元素。     

长白山圆池泥炭沼泽演变及环境信息记录

通过分析长白山圆池泥炭剖面总有机碳含量、总正构烷烃含量、奇偶优势指数、(C23+C25)含量和2C31/(C27+C29)比值,讨论了泥炭发育不同时期植物输入情况,同时结合210Pb测年建立的年代序列来探讨该区的气候变化规律.研究结果显示,约1400年前,气候干冷,圆池尚没有出现沼泽化;1400年开始,气候稍暖,少量植物输入,圆池开始沼泽化;约从1860年至今,气候逐步转暖,大量植物输入,圆池沼泽化速度加快.     

土壤N2O排放研究进展

N2O不仅是一种重要的温室气体，而且还可以破坏臭氧层。随着人类活动的增加，其在大气中的浓度不断上升，对环境的影响也更加严重，因此，N2O的排放日益成为环境研究的热点问题。土壤是N2O的重要排放源。本文综合分析了土壤N2O排放研究的进展情况，主要包括：土壤N2O产生及排放的机理；影响N2O排放的主要因素；土壤N2O排放的时空特征以及全球N2O排放的模型估计；最后提出了今后的研究方向。     

应用常规气象观测资料估算塔里木盆地水面蒸发量

根据阿克苏水平衡站1999年至2002年非冻结期(4月至10月)20m^2蒸发池的蒸发量及常规气象观测资料，采用斜率关联度分析法分析了各气象要素对水而蒸发的影响程度，建立了计算水而蒸发量的经验公式，结果表明：(1)气象要素对20m^2蒸发池月平均蒸发量的影响程度从大到小的排列顺序为饱和水汽压差、气温、水面温度、空气饱和差、风速、实际水汽压、大气压、相对湿度；(2)20m^2蒸发池蒸发量与饱和水汽压差、空气湿度饱和差、气温、水面温度、风速、水汽压成正比关系；而与气压、相对湿度成反比关系；(3)所有回归方程都达到极显著水平，可供塔里木盆地缺测资料地区选用。     

盐湖太阳能的利用─太阳池

详细综述了太阳池的一般原理、大阳池的用途、太阳池的建造和运行、太阳池的主要理论、特殊大阳池技术、及大阳池的国内外研究应用状况．     

溶液结构的X射线衍射：3.粉末衍射仪液体样品池溶窗口强度校正的相对透明因

从衍射几何出发，推导出０－２０型Ｘ射线衍射仪液体样品池窗口强度校正的相对透明因子，解释了由于超厚液体样品池上的窗口的吸收，反射法引起的低角强度损失和透射法引起的高角强度损失，获得了令人满意的校正结果。     

溶液结构的X射线衍射──3.粉末衍射仪液体样品池窗口强度校正的相对透明因子

从衍射几何学出发，推导出0－2θ型X射线衍射仪液体样品池窗口强度校正的相对透明因子，解释了由于超厚液体样品池上的窗口的吸收，反射法引起的低角强度损失和透射法引起的高角强度损失，获得了令人满意的的校正结果。     

铁铜内电解基质与曝气对人工湿地除污的影响

为探究不同铁铜内电解基质在不同曝气条件下对人工湿地污水的净化效果,构建表流人工湿地床,以研究4种铁铜内电解基质(质量比1:0、1:0.05、1:0.1、1:0.2)在不同曝气条件下(气水比3:1、6:1、9:1、12:1、15:1)对人工湿地污水的COD、TN、TP去除率的影响。结果表明:不同铁铜内电解基质对COD、TN、TP的去除效果有显著差异。随着内电解基质中铜比例的提高,COD、TN、TP的去除率均有升高的趋势。随着气水比的提高,TP去除率呈先升后降的趋势。铁铜内电解基质与曝气条件之间的交互作用对COD、TN、TP去除效果影响不显著。研究发现,当气水比为9:1时,铁铜内电解基质(质量比1:0.2)的净污效果最好。     

北京市杨镇一中人工湿地设计及污水处理效果

针对北京市农村地区居民居住相对分散、生活污水集中处理难度大的状况,在北京市杨镇一中,建立了经济且简便易行的用于处理污水的人工湿地。该人工湿地由地埋式一体化预处理、多级复合式人工湿地系统、景观湿地系统三部分组成。通过单元实验,对人工湿地的填料结构、植物选择、布水设计、水位调节、湿地防堵系统设计、预处理系统设计进行了创新,研究了1d、2d和3d水力停留时间对污水中有机物处理效应的影响,并开展了人工湿地基质堵塞实验、冬季保温措施研究以及人工湿地脱氮除磷效果研究。结果表明,比较而言,1d和3d的水力停留时间不利于有机物的去除,2d的水力停留时间有利于有机物的去除;人工湿地0～10m的水平距离内,0～5cm、30～35cm、60～65cm深度的基质的堵塞差异显著(n=10,p<0.05),从水平上看,在0m、2m、4m处基质的堵塞最为明显,因此,在更换人工湿地基质时,只需更换0～4m内的基质;棚膜+蒲席覆盖系统去除污水中总氮的效果要优于结冰盖系统,更适宜于北方使用;预处理系统、人工湿地系统、景观湿地系统三部分共同处理污水,优势互补,能使处理后的出水符合北京市水污染排放标准一级B限值。     

东北屯人工湿地污水处理系统的设计与应用

从人工湿地规划设计的角度出发,依据地表水环境质量标准,以现有废弃渠道、坑塘为基础,通过开挖回填、调坡整治、基础压实等措施,建立了衡水市故城县郑口镇东北屯人工湿地污水处理系统。该系统包括前池、沉淀池、垂直流湿地、生态塘湿地、表面流湿地和蓄水池。探讨了人工湿地渗滤处理系统的主要设计参数;采用Freundlich公式、Kikuth公式和有关经验公式,分析了渗滤系统对污水生化需氧量、总氮、总磷的处理效果;研究了处理系统中垂直流、生态塘渗流和表面流的污染物去除率;针对水质、水量和环境温度3个主要因素进行了敏感性分析,给出了渗滤系统敏感性分析结果,并与湿地去污实验结果进行了比较,变化趋势基本一致。研究结果表明:①人工湿地规划设计应进行敏感性分析,以便更好地制定系统的控制运行预案;②湿地出水口高度应能够调节,以便控制湿地床体的"饱和"状态,充分发挥湿地渗滤、微生物的作用;③北方人工湿地的去污效果,受季节性影响较大,应采取塑料大棚或秸秆覆盖进行保温,在冬季,塑料大棚能够使湿地温度维持在13.3℃以上,日照时间基本不减少,湿地植物可正常生长;④当进水的生化需氧量浓度超过75mg/L时,应减小进水负荷,控制污染物总量在湿地高效处理范围内;⑤当日污水处理量超过3000m3/d时,应提高集污渠、前池、沉淀池的临时蓄存水位。     

The simulation of surface flow dynamics using a flow-path network model

This paper proposes a flow-path network (FPN) model to simulate complex surface flow based on a drainage-constrained triangulated irregular network (TIN). The TIN was constructed using critical points and drainage lines extracted from a digital terrain surface. Runoff generated on the surface was simplified as ‘water volumes’ at constrained random points that were then used as the starting points of flow paths (i.e. flow source points). The flow-path for each ‘water volume’ was constructed by tracing the direction of flow from the flow source point over the TIN surface to the stream system and then to the outlet of the watershed. The FPN was represented by a set of topologically defined one-dimensional line segments and nodes. Hydrologic variables, such as flow velocity and volume, were computed and integrated into the FPN to support dynamic surface flow simulation. A hypothetical rainfall event simulation on a hilly landscape showed that the FPN model was able to simulate the dynamics of surface flow over time. A real-world catchment test demonstrated that flow rates predicted by the FPN model agreed well with field observations. Overall, the FPN model proposed in this study provides a vector-based modeling framework for simulating surface flow dynamics. Further studies are required to enhance the simulations of individual hydrologic processes such as flow generation and overland and channel flows, which were much simplified in this study.     

目的地旅游业能源消耗流动过程与测评体系

构建旅游业能源消耗测评体系是推动旅游地节能减排中亟需解决的科学问题。本文首先界定旅游业能源消耗的概念与介绍资源流理论的基本内涵。其次,运用资源流理论,分析能源在区域旅游系统的横向流动与纵向流动,从能源生产与运输过程、能源消耗过程、能源消耗后效应过程三个方面分析旅游地旅游业能源消耗流动过程。第三,从界定原则、地域范围、产业范围三方面界定旅游地旅游业能源消耗测评的系统边界。最后,设计旅游地旅游业能源消耗测评框架,从直接能源消耗与间接能源消耗两方面构建旅游地旅游业能源消耗测评体系。     

Numerical modelling of flow structures over idealized transverse aeolian dunes of varying geometry

A Computational Fluid Dynamics (CFD) model (PHOENICS™ 3.5) previously validated for wind tunnel measurements is used to simulate the streamwise and vertical velocity flow fields over idealized transverse dunes of varying height (h) and stoss slope basal length (L). The model accurately reproduced patterns of: flow deceleration at the dune toe; stoss flow acceleration; vertical lift in the crest region; lee-side flow separation, re-attachment and reversal; and flow recovery distance. Results indicate that the flow field over transverse dunes is particularly sensitive to changes in dune height, with an increase in height resulting in flow deceleration at the toe, streamwise acceleration and vertical lift at the crest, and an increase in the extent of, and strength of reversed flows within, the lee-side separation cell. In general, the length of the separation zone varied from 3 to 15 h from the crest and increased over taller, steeper dunes. Similarly, the flow recovery distance ranged from 45 to >75 h and was more sensitive to changes in dune height. For the range of dune shapes investigated in this study, the differing effects of height and stoss slope length raise questions regarding the applicability of dune aspect ratio as a parameter for explaining airflow over transverse dunes. Evidence is also provided to support existing research on: streamline curvature and the maintenance of sand transport in the toe region; vertical lift in the crest region and its effect on grainfall delivery; relations between the turbulent shear layer and downward forcing of flow re-attachment; and extended flow recovery distances beyond the separation cell. Field validation is required to test these findings in natural settings. Future applications of the model will characterize turbulence and shear stress fields, examine the effects of more complex isolated dune forms and investigate flow over multiple dunes.     

中国城市网络等级结构特征及组织模式——基于铁路和航空流的比较

交通流是反映城市间社会经济联系的重要表征,被广泛应用于城市网络研究中。基于2010年中国城际铁路与航空客流OD数据,本文从城市节点、流量、子网络视角对中国城市网络的结构特征与组织模式进行了比较研究,发现：① 铁路与航空流视角下的中国城市网络均呈现出以北上广为顶层节点的空间等级结构体系,但除顶层结构外两种网络结构差异较大。② 城市网络体系中的铁路流联系表现出空间邻近性特征,而航空流联系则主要受到城市节点的规模大小与职能属性的影响。③ 铁路流的首位联系受省级行政区划的制约,航空流的首位联系空间跨度大,形成了若干具有垂直层间联系的地域子系统。④ 铁路网络拥有具有显著地域特征的7个子网络,而航空网络中则不存在明显的子网络。技术经济特征与管理体制是造成铁路与航空两种网络特征差异的主要原因。     

提高生态浮床系统脱氮除磷效率研究进展

生态浮床系统处理技术因具有投资少、易操作、无二次污染兼具良好景观性等优点而被广泛应用于各种类型污染水体的治理。生态浮床系统是一个复合生态工程系统,其对污染的去除机理是一个错综复杂的过程,填料、水生植物、水生动物和微生物共同发挥着重要作用。主要概述生态浮床系统的发展状况、脱氮除磷机理、限制因素及存在问题;重点概述以细菌固定化技术和曝气等方式的外在法和以改进生态浮床系统构造形式、筛选优势浮床植物等方式的内在法,来提高生态浮床系统脱氮除磷效率;展望了生态浮床污水处理系统未来的研究与应用前景。     

Scales of boundary resistance in coarse-grained channels: turbulent velocity profiles and implications

Gravel-bed surfaces are characterized by morphological features occurring at different roughness scales. The total shear stress generated by the flow above such surfaces is balanced by the sum of friction drag (grain stress) and form drag components (created by bed forms). To facilitate a better understanding of total resistance and bed load transport processes, there is a need to mathematically separate shear stress into its component parts. One way to do so is to examine the properties of vertical velocity profiles above such surfaces. These profiles are characterized by an inner layer that reflects grain resistance and an outer layer that reflects total resistance. A flume-based project was conducted to address these concerns through systematically comparing different roughness scales to ascertain how increased roughness affects the properties of vertical velocity profiles. Great care was taken to create natural roughness features and to obtain flow data at a high spatial and temporal resolution using an Acoustic Doppler Velocimeter.Average vertical velocity profiles above each roughness scale were clearly segmented. The vertical extent of the inner flow region was directly related to the scale of roughness present on the bed (and independent of flow depth), increasing with increased roughness. On a rough but rather uniform “plane” bed made of heterogeneous coarse sediments (with no bed forms), the shape of the velocity profile was clearly dominated by the local variations in grain characteristics. When pebble clusters were superimposed, the average shear stress in the outer flow region increased by 100% from the plane bed conditions. The ratio of inner grain shear stress to outer total shear stress for this pebble cluster experiment was 0.18 under shallow flow conditions and 0.3 under deep flow conditions. The grain stress component that should be used in bed load transport equations therefore appears to vary in these experiments between 15% and 30% of the total channel stress, increasing with decreased resistance. Roughness height (K_s/D₅₀) values at the grain scale for the plane bed and pebble cluster experiments were 0.73 and 0.63, respectively. These are values that should be used in flow resistance equations to predict grain resistance and grain stress for bed load transport modeling.     

Field measurements of three-dimensional hydraulics in a step-pool channel

We investigated the effects of morphologic position and discharge on flow structure in a steep (0.10 m/m) mountain channel by collecting three-dimensional measurements of time-averaged and turbulent velocity components with a SonTek FlowTracker Handheld ADV (acoustic Doppler velocimeter) on a 30-m reach of a step-pool channel in the Colorado Rockies. Velocity profiles were measured at morphologic positions characteristic of steep channels (above steps, step lips, base of steps, pools, cascades, runs), and at five different discharges. A marked three-dimensionality of flow structure was documented in East St. Louis Creek. Velocities in the streamwise component were the largest contributors to overall velocity vector magnitudes; cross-stream and vertical components contributed averages of 20% and 15%, respectively, to overall vector magnitudes. Turbulence intensities were especially multi-dimensional, however, with large contributions to turbulent kinetic energy from the vertical component of velocity. Analysis of variance indicated that discharge and morphologic position significantly affected mean streamwise velocities, with substantially higher velocities upstream from steps than in pools. Discharge and morphology effects on cross-stream and vertical velocity components, however, were not significant. Discharge and morphologic position also significantly affected turbulence intensities for all flow components, with the greatest turbulence intensities occurring in pools and at high discharges. These results illustrate the strong discharge-dependence of hydraulics in step-pool channels, where relative submergence of bedforms changes rapidly with discharge, and the substantial spatial variation in hydraulics created by step-pool sequences.