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1.
云南中旬岛弧是我国西南三江构造火成岩带中义敦岛弧的组成部分,中甸岛弧是我国重要的斑岩型和夕卡岩型铜矿的产地.烂泥塘-雪鸡坪-春都-阿热为西斑岩带,岩体分布较为集中;高赤坪-红山-洛吉为中斑岩带,欠虽-地苏嘎-松诺-普朗及其以东地区为东斑岩带.  相似文献   

2.
滇西北中甸松诺含矿斑岩的锆石SHRIMP U-Pb年龄及地质意义   总被引:9,自引:1,他引:8  
位于义敦岛弧南端的中甸岛弧中广泛发育印支期斑岩及斑岩型和矽卡岩型铜矿床。松诺(或称松诺力赞)复式岩体位于东斑岩带中部,由石英闪长玢岩、黑云石英二长斑岩、闪长玢岩和含矿石英二长斑岩组成,其南部为普朗超大型斑岩铜矿床,北部为地苏嘎铜矿点。本文对含矿石英二长斑岩进行了岩相学和锆石SHRIMPU-Pb定年研究,结果表明所有锆石颗粒自形较好且均发育规则的韵律环带,Th含量为180~854μg/g,U含量为270~709μg/g,Th/U比值为0.77~1.24,为典型岩浆成因锆石。获得了含矿石英二长斑岩的侵位年龄为220.9±3.5Ma(n=9,MSWD=1.6),这与中甸岛弧洋壳俯冲造山作用的时限(210~235Ma)相吻合。  相似文献   

3.
地苏嘎印支期斑岩体位于中甸岛弧东斑岩带的北端,岩性为石英闪长玢岩,与普朗超大型斑岩铜矿的成矿岩体同属于甘孜—理塘洋壳俯冲作用晚期岩浆活动的产物。全岩地球化学特征显示,地苏嘎石英闪长玢岩具有中等的SiO2含量,较高的Al2O3及全碱(K2O+Na2O)含量。全岩亏损高场强元素,富集大离子亲石元素,稀土元素配分曲线呈典型的右倾状,显示出轻稀土富集、重稀土相对亏损的特点。主量元素和微量元素成矿指示方面的研究结果表明:与普朗38个与成矿有关的石英闪长玢岩的全岩数据相比,地苏嘎石英闪长玢岩具有相对较低的SiO2和Y含量、较高的∑REE和(La/Yb)N比值,但二者的Al2O3/(CaO+Na2O+K2O)比值及MnO含量差别不大。在成矿与非成矿斑岩的SiO2- Al2O3/(CaO+Na2O+K2O)和Y-MnO图解中,地苏嘎石英闪长玢岩与普朗石英闪长玢岩数据投图结果类似。此外,地苏嘎斑岩体在物探异常、化探异常及遥感影像特征上具有明显的矿化标志,同时岩体的剥蚀深度小于侵位深度,有利于矿床的保存。以上研究结果表明地苏嘎斑岩体具有成为斑岩型铜矿床的潜力。  相似文献   

4.
云南普朗印支期超大型斑岩铜矿床:岩石学及年代学特征   总被引:44,自引:14,他引:44  
曾普胜  李文昌  王海平  李红 《岩石学报》2006,22(4):989-1000
普朗斑岩铜矿位于云南西北晚三叠世义敦岛弧南段的滇西中甸弧内。义敦岛弧北部产有著名的呷村式黑矿型块状硫化物矿床,南部大量发育斑岩型铜矿床,普朗斑岩铜矿床即是其中的典型代表。普朗矿床由南、北两个复式岩体(矿段)组成,两个矿段均由一系列NW向构造控制的石英闪长玢岩、石英二长斑岩小岩株组成,是普朗铜矿区的主体,探明铜矿石量1.6亿吨,铜平均品位0.57%,铜金属量114万吨,伴生金金属量28.80吨,金品位0.18g/t;钼6399吨,品位0.004%。普朗斑岩铜矿床远景储量400万吨以上,为一个具有超大型规模远景储量的斑岩型铜矿床。普朗斑岩体容矿围岩SiO_2>56%,MgO 1.34%~2.73%,Sr 661×10~(-6)~909×10~(-6),Y 10.78×10~(-6)~17.92×10~(-6),Yb 1.07×10~(-6)~1.87×10~(-6),LREE富集,δEu 0.83~0.93,Sr/Y比值22~64,K_2O/Na_2O比值0.52,具有与洋壳俯冲产生的埃达克岩(Ⅰ型埃达克岩)相似的地球化学特征。普朗斑岩铜矿形成于印支期,在我国斑岩铜矿床中具有其特殊性(不同于青藏高原喜马拉雅期斑岩铜矿带,如冈底斯斑岩铜矿带、玉龙斑岩带等;也不同于古亚洲成矿域的海西期斑岩铜矿带,如土屋-延东斑岩铜矿带,以及中国东部的燕山期斑岩铜矿带,如德兴斑岩铜矿),无论对中甸岛孤带的基础地质还是矿产资源评价预测的研究,该类矿床都具有重要的意义。普朗斑岩铜矿床含矿黑云石英二长斑岩的钾硅酸盐化(黑云母化和钾长石化)的成矿热液活动时间为235.4±2.4Ma~221.5±2.0Ma之间,石英-辉钼矿阶段的辉钼矿成矿(Re-Os)年龄大致为213±3.8 Ma;对矿区主矿体的热液黑云母单矿物的~(40)Ar/~(39)Ar测年,无论是含铜钼的矿化岩体,还是仅含铜的斑岩体,其成矿年龄(坪年龄)变化于为214.58±0.91Ma至216.0±1Ma之间,与辉钼矿Re-Os年龄非常接近,为晚三叠世诺利期。这表明普朗斑岩铜矿床的成矿作用在印支期完成。  相似文献   

5.
滇西北中甸松诺含旷斑岩的锆石SHRIMP U-Pb年龄及地质意义   总被引:8,自引:1,他引:7  
位于义敦岛弧南端的中甸岛弧中广泛发育印支期斑岩及斑岩型和矽卡岩型铜矿床.松诺(或称松诺力赞)复式岩体位于东斑岩带中部,由石英闪长玢岩、黑云石英二长斑岩、闪长玢岩和含矿石英二长斑岩组成,其南部为普朗超大型斑岩铜矿床,北部为地苏嘎铜矿点.本文对含矿石英二长斑岩进行了岩相学和锆石SHRIMP U-Pb 定年研究,结果表明所有锆石颗粒自形较好且均发育规则的韵律环带,Th 含量为 180~854 μg/g,U 含量为270~709μg/g,Th/U 比值为 0.77~1.24,为典型岩浆成因锆石.获得了含矿石英二长斑岩的侵位年龄为220.9±3.5Ma(n=9,MSWD= 1.6),这与中甸岛弧洋壳俯冲造山作用的时限(210~235 Ma)相吻合.  相似文献   

6.
滇西北中旬松诺含矿斑岩的锆石SHRIMP U-Pb年龄及地质意义   总被引:3,自引:1,他引:2  
位于义敦岛弧南端的中甸岛弧中广泛发育印支期斑岩及斑岩型和矽卡岩型铜矿床.松诺(或称松诺力赞)复式岩体位于东斑岩带中部,由石英闪长玢岩、黑云石英二长斑岩、闪长玢岩和含矿石英二长斑岩组成,其南部为普朗超大型斑岩铜矿床,北部为地苏嘎铜矿点.本文对含矿石英二长斑岩进行了岩相学和锆石SHRIMP U-Pb 定年研究,结果表明所有锆石颗粒自形较好且均发育规则的韵律环带,Th 含量为 180~854 μg/g,U 含量为270~709μg/g,Th/U 比值为 0.77~1.24,为典型岩浆成因锆石.获得了含矿石英二长斑岩的侵位年龄为220.9±3.5Ma(n=9,MSWD= 1.6),这与中甸岛弧洋壳俯冲造山作用的时限(210~235 Ma)相吻合.  相似文献   

7.
中甸浪都铜矿位于印支期义敦岛弧南段的中甸岛弧,浪都二长斑岩体出露于矿区中北部,呈岩株状侵入于曲嘎寺组砂岩、灰岩中.本文应用LA-ICP-MS分析了二长斑岩中锆石的微量元素组成和U-Pb同位素年龄.获得该二长斑岩成岩年龄为223±1 Ma,与近几年报道的中甸岛弧晚三叠世中酸性侵入岩的Rb-Sr、K-Ar、锆石U-Pb年龄基本一致,属同一构造期的产物.该二长斑岩中锆石的ΣREE值为1168.55×10-6~2125.76×10-6,较集中.结合岩石主量、微量元素组成,我们认为其岩浆为地幔和部分地壳混熔作用形成,是甘孜-理塘洋在晚三叠世向西俯冲消减过程中形成的岛弧型花岗质岩石.该二长斑岩中锆石的REE球粒陨石标准化配分模型具有强烈的Ce正异常和中度的Eu负异常,指示其成岩岩浆具有较高的氧逸度,结合浪都矿区铜矿化与该岩体密切的时空关系和成因联系,表明岩浆的较高氧逸度对该矿区矽卡岩-斑岩型铜矿化具有重要意义.  相似文献   

8.
近年来,随着普朗和红山-红牛等大型-超大型铜矿的投产,滇西北格咱地区已成为我国重要的铜资源勘查开发基地,在该区寻找类似“普朗-红山式”斑岩-矽卡岩型大型-超大型铜多金属矿床是本区找矿勘查的热点。本次在开展松诺地区铜资源远景调查的基础上,对松诺含矿石英闪长玢岩开展了锆石U-Pb年代学研究,结果显示石英闪长玢岩体锆石U-Pb年龄分别为229.7±1.1Ma和222.3±0.7Ma,早于矿区石英二长斑岩体,为晚三叠世岩浆活动的产物。石英闪长玢岩和石英二长斑岩岩石地球化学特征显示,为准铝-弱过铝质的高钾钙碱性系列I型花岗岩,稀土元素配分曲线均表现为轻稀土元素富集,重稀土元素相对亏损,具弱的负Eu异常,富集Rb、Ba等大离子亲石元素,亏损Ta、Nb、Ti等高场强元素。综合岩相学、岩石化学、锆石Hf同位素和全岩Sr-Pb同位素等特征,认为松诺含矿斑岩体形成于印支期甘孜-理塘洋壳向西俯冲的岩浆弧环境,岩浆源区为俯冲流体交代的岩石圈富集地幔,岩浆上升过程经历了壳源沉积物质混染。矿区具备弧环境斑岩型铜多金属矿床的成矿条件,且蚀变矿化强烈,找矿前景良好,值得进一步深入研究和开展勘查工作。  相似文献   

9.
云南普朗斑岩铜矿蚀变带成矿流体特征及其成矿意义   总被引:7,自引:2,他引:5  
云南普朗铜矿位于义敦—中甸岛弧带南缘,是近年来我国发现的一个大中型斑岩铜矿床。该矿床具有典型的斑岩铜矿蚀变分带,由中心向外依次为钾硅化带、绢英岩化带、青盘岩化带。对矿区不同蚀变带中的石英流体包裹体进行了岩相学观察、均一温度测量和激光拉曼探针成分分析。均一温度测量结果表明,从普朗斑岩铜矿床钾硅化带到绢英岩化带再到青盘岩化带,成矿流体的平均均一温度从274.4℃到236.4℃再到203.0℃,呈明显下降趋势,可能与天水参与成矿有关。同时,激光拉曼探针成分分析结果表明,普朗斑岩铜矿床矿化期间的成矿流体属于富硫富氯流体,这种温度较高且富硫富氯的成矿流体在钾硅化带和绢英岩化带发生矿化作用将导致成矿物质强烈富集成矿。  相似文献   

10.
位于义敦岛弧南端的中甸岛弧已成为我国又一重要的斑岩铜矿产地,其中雪鸡坪中型斑岩铜矿床产于西斑岩带,普朗超大型斑岩铜矿床产于东斑岩带.详细对比研究了这两个斑岩铜矿床矿床地质,含矿斑岩的岩石化学、地球化学以及年代学等特征,认为:①两者的元素组成非常相似,如稀土配分形式均为轻稀土元素富集型,亏损重稀土元素和Y,富集Sr、K、Rb、Ba、Th等大离子亲石元素,亏损Nb、Ta、Zr、Hf、Ti等高场强元素,显示了埃达克岩的地球化学特征,表明它们可能是俯冲的甘孜--理塘洋壳部分熔融的产物,并受到地壳物质的混染;②中甸岛弧的结构及时空演化保持了义敦岛弧的共性,发育完整的沟-弧-盆体系,其中东斑岩带属于外弧,而西斑岩带属于内弧,中斑岩带及零星分布的属都蛇绿混杂岩产于弧间盆地.  相似文献   

11.
The dissolution of H2O and CO2 in structurally dense, nominally anhydrous and non-carbonate oxide matrices such as MgO and CaO is reviewed. H2O and CO2 are treated as gaseous oxide components which enter into solid solution with the refractory oxide hosts. They form anion complexes associated with cation vacancy sites. Evidence is presented that OH? pairs which derive from the dissolution of H2O are subject to a charge transfer (CT) conversion into peroxy moieties and molecular hydrogen, O 2 2? ... H2. Because the O 2 2? moiety is small (O?-O? distance ≈ 1.5 Å) high pressure probably favors the CT conversion. Mass spectroscopic studies show that molecular H2 may be lost from the solid which retains excess oxygen in the form of O 2 2? , leading to the release of atomic O. The dissociation of O 2 2? moieties into a vacancy-bound O? state and an unbound O? state can be followed by measuring the internal redox reactions involving transition metal impurities, the transient paramagnetism of the O? and their effect on the d.c. conductivity. Evidence is presented that CO2 molecules dissolve dissociatively in the structurally dense oxide matrix, as if they were first to dissociate into CO+O and then to form separate solute moieties CO 2 2? and O 2 2? , both associated with cation vacancy sites. In the CO 2 2? moiety (C-O? distance 1.2–1.3 Å, OCO angle ≈ 130°) the C atom probably sits off center. The transition of the C atom into interstitial sites is accompanied by dissociation of the CO 2 2? moiety into CO? and O?. This transition can be followed by infrared spectroscopy, using OH? as local probes. Further support derives from magnetic susceptibility, thermal expansion, low frequency dielectric loss and low temperature deformation measurements. The recently observed emission of O and Mg atoms besides a variety of molecules such as CO, CO2, CH4, HCN and other hydrocarbons during impact fracture of MgO single crystals is presented and discussed in the light of the other experimental data.  相似文献   

12.
There are few inter-African country urban analyses because of the continent’s enormous size and socioeconomic diversity, language barriers, and wide variations in national and regional urban research capacity. Nevertheless, comparative urban studies are critical in understanding contemporary African urbanization. In this comparative spatial and temporal analysis of Ghana and Kenya’s urbanization, we find that both countries are urbanizing rapidly and are faced with many common urban problems. Moreover, Ghana is more urbanized than Kenya and has a larger indigenous urban imprint and a more widely dispersed urban pattern. Besides their physiographic and population conditions, we trace these countries’ convergent and divergent urban trends to their shared but unique experiences of colonialism, nationalism and globalization.  相似文献   

13.
煤中气孔和镶嵌结构及其在煤变质研究中的意义   总被引:1,自引:0,他引:1  
河南省禹县、新密和荥巩煤田山西组Ⅱ1煤的贫煤和无烟煤中,气孔发育。气孔形态有椭圆状(图版1)、圆状及不规则状(图版2),有的几个气孔连在一起呈大的朵状气孔(图版3)。此外,在荥巩煤田西部无烟煤中还发育有镀嵌结构(图版4)。   相似文献   

14.
Using improved analytical techniques, which reduce the Re blanks by factors of 8 to 10, we report new Re-Os data on low Re and low PGE pallasites (PAL-anom) and IIIAB irons. The new pallasite samples nearly double the observed range in Re/Os for pallasites and allow the determination of an isochron of slope 0.0775 ± 0.0008 (T = 4.50 ± 0.04 Ga, using the adjusted λ187Re = 1.66 × 10−11 a−1) and initial (187Os/188Os)0 = 0.09599 ± 0.00046. If the data on different groups of pallasites (including the “anomalous” pallasites) are considered to define a whole-rock isochron, their formation would appear to be distinctly younger than for the iron meteorites by ∼60 Ma. Five IIIAB irons (Acuna, Bella Roca, Chupaderos, Grant, and Bear Creek), with Re contents ranging from 0.9 to 2.8 ppb, show limited Re/Os fractionation and plot within errors on the IIAB iron meteorite isochron of slope 0.07848 ± 0.00018 (T = 4.56 ± 0.01 Ga) and initial (187Os/188Os)0 = 0.09563 ± 0.00011. Many of the meteorites were analyzed also for Pd-Ag and show 107Ag enrichments correlated with Pd/Ag, requiring early formation and fractionation of the FeNi metal, in a narrow time interval, after injection of live 107Pd (t1/2 = 6.5 Ma) into the solar nebula. Based on Pd-Ag, the typical range in relative ages of these meteorites is ≤10 Ma. The Pd-Ag results suggest early formation and preservation of the 107Pd-107Ag systematics, both for IIIAB irons and for pallasites, while the younger Re-Os apparent age for pallasites suggests that the Re-Os system in pallasites was subject to re-equilibration. The low Re and low PGE pallasites show significant Re/Os fractionation (higher Re/Os) as the Re and PGE contents decrease. By contrast, the IIIAB irons show a restricted range in Re/Os, even for samples with extremely low Re and PGE contents. There is a good correlation of Re and Ir contents. The correlation of Re and Os contents for IIIAB irons shows a similar complex pattern as observed for IIAB irons (Morgan et al., 1995), and neither can be ascribed to a continuous fractional crystallization process with uniform solid-metal/liquid-metal distribution coefficients.  相似文献   

15.
利用GC-MS(气相色谱—质谱仪),对采自湖北清江流域和尚洞洞顶的土壤样品与洞内石笋样品进行分析,发现土壤中存在的七个系列单甲基支链烷烃在所有的石笋样品中均可以找到,呈现相似的分布模式,石笋中七个系列支链烷烃有可能来自洞穴滴水携带的土壤中的支链烷烃,但是也不能排除石笋原地生长的微生物的贡献。烷基环己烷的分布在土壤与石笋中呈现了相似的分布模式,但是主峰碳数有所变化,高碳数部分与低碳数部分的相对含量也发生了变化。主要原因可能是微生物选择性降解的结果,也有可能是土壤与石笋中微生物种类分布差异所造成的。本次研究初步显示了相对封闭稳定的洞穴沉积物与上覆土壤层中生物标志化合物的异同。   相似文献   

16.
At 31 sites in Finland the Zn content was determined of the epiphytic lichen Hypogymnia physodes (L.) Nyl. growing on pine and birch, the terricolous lichen Cladina spp. in pine bark, and the inner part of birch bark. The anomalous contents of Zn in H. physodes on pine and Cladina spp. in soil appeared to be strongly related to sulphide ore deposits. Anthropogenic Zn correlated closely with S and Fe in H. physodes on pine and with Fe in Cladina spp. The binding of geogenic Zn was related to iron hydroxides, and was attributed to the different uptake mechanism of S in these lichens. Elevated values of Zn in H. physodes on birch were due to both geogenic and anthropogenic sources. Zinc in pine bark increased with the Zn content in H. physodes and reached a limiting value.  相似文献   

17.
Stabilities of amphibole and chlorite in mafic and ultramafic compositions have been considered in the model system CaO+MgO+Al2O3+SiO2+H2O. From topological arguments two petrogenetic grids have been constructed. Although available experimental data in CMASH are compatible with the grid in which amphibole reacts out before chlorite in model ultramafic compositions for the pressure range 6 to 15 kbar, naturally observed mineral assemblages and some experimental data in more complex systems favour the other grid in which chlorite reacts out before amphibole at all pressures. This discrepancy between natural and model systems is due to differential movement of the dehydration equilibria of the two hydrates reflecting the variation of activity of H2O or of components other than CMASH.  相似文献   

18.
Aqueous extraction contributes to the formation and weathering of planetary materials and renders electrolytes such as phosphate available for biology. In this context, the solubility of phosphate is measured in planetary materials, represented by the Mars meteorites Nakhla, Dar al Gani 476 (DaG 476), Elephant Morraine 79001 (EETA 79001), and terrestrial analogs, and in the Murchison CM2 and Allende CV3 carbonaceous chondrites. The Mars meteorites contain high levels of phosphate that is readily extracted by water, up to 15 mg kg−1 in Nakhla and DaG 476 and 38 mg kg−1 in EETA 79001, while the terrestrial analogs and the carbonaceous chondrites contain 0.5 to 6 mg kg−1. Correspondingly, high phosphate concentrations of 4 to >28 mg L−1 are obtained in extracts of the Mars meteorites at high solid/solution ratios, exceeding the concentrations of 0.4 to 2.0 mg L−1 in the extracts of the terrestrial analogs. A wide range of planetary conditions, including N2 and CO2 atmospheres, solid/solution ratios of 0.01 to 1.0 kg L−1, extraction times of 1 to 21 d, and temperatures of 20 to 121°C affect the amounts of extractable phosphate by factors of only 2 to 5 in most materials. Phosphate-fixing capacity and exchangeable phosphate are assessed by the isotopic exchange kinetics (IEK) method, which quantifies the amount of P isotopically exchangeable within 1 min (E1min) and between 1 min and 3 months (E1min-3m) and the amount of P that cannot be exchanged within 3 months (E>3m). The IEK results show that the DaG 476 Mars meteorite and terrestrial analogs have low P-fixing capacities, while the carbonaceous chondrites have high P-fixing capacities. Aqueous processing under early planetary CO2 atmospheres has large effects on the available phosphate. For example, the fraction of total P that is exchangeable in 3 months increases from 1.6 to 11%, 13 to 51.6%, and 43.9 to 90.4% in the DaG 476 Mars meteorite, Allende, and Murchison, respectively. The results show that solutions with high phosphate concentrations can form in the pores of planetary lava ash and basalts and in carbonaceous asteroids and meteorites. These solutions can help prebiotic synthesis and early microbial nutrition. The Martian and carbonaceous chondrite materials contain sufficient phosphate for space-based agriculture.  相似文献   

19.
The evolution of the border region of part or all of a craton, on the basis of geological data gathered from Mexico, may best be described in terms of geotectonic cycles. These consist, in chronological order, of (1) an orthogeosynclinal phase (eu- and miogeosynclines) with or without initial magmatic activity, (2) an anatexitic phase consisting of batholith emplacement with attendant regional metamorphism in the eugeosyncline and deposition of a clastic or flysch wedge over the miogeosyncline, (3) an orogenic phase consisting principally of the folding and thrusting of the sediments of the miogeosyncline together with the clastic or flysch wedge against the foreland, and (4) a taphrogenic or block-faulting phase accompanied by (a) accumulation of post-orogenic debris or molasse, (b) subsequent magmatic activity consisting largely of igneous extrusions with fewer intrusions, and (c) final magmatic activity consisting of igneous extrusions. A region that has gone through the above phases of a geotectonic cycle may be termed a structural belt. In the post-Precambrian geologic history of Mexico, three geotectonic cycles are recognized: one occurred along the Pacific border of Mexico between Cambrian and middle Jurassic (?) time (Jaliscoan geotectonic cycle), the second occurred along the present Gulf of Mexico border of the country at the same time (Huastecan geotectonic cycle), and the third occurred over the entire country from the United States border to the Guatemalan border between Late Jurassic and Pliocene time (Mexican geotectonic cycle). The early Mesozoic clastic rocks in northwestern Mexico may signify a fourth geotectonic cycle in that region. In the three recognized geotectonic cycles, however, the geologic record shows only two orogenic phases, one of which occurred in late Paleozoic time in an arcuate belt along the eastern side of Mexico (Coahuilan orogeny), and the other in early Tertiary time in a belt traversing central Mexico from the United States border to the Guatemalan border (Hidalgoan orogeny).  相似文献   

20.
银川平原地下水资源开发与植被变化   总被引:4,自引:0,他引:4  
植被状况的变化是反映区域性生态环境状况的重要指标。地下水是影响植被变化的主要因素。宁夏地处干旱半干旱地带,是全国生态系统最脆弱的省区之一。2000年后,随着宁夏黄河引水量的减小,水资源的不合理应用使银川平原的生态植被出现了退化的趋势。本文利用MODIS-NDVI遥感数据,对银川平原2000~2004年间的植被变化趋势进行了研究。在此基础上,对引用黄河水量及多年地下水位的变化对植被的影响进行了分析,并对适宜于植被发育的地下水位埋深进行了探讨。  相似文献   

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