煤矸石肥料

煤矸石随煤炭生产而产生。日积月累,在矿区形成矸石山,既侵占良田。又污染环境。近年来,一些地区已有利用煤矸石制作建筑材料和提取有用物质,但用量有限。因此,进一步研究利用煤矸石,使大量煤矸石变废为宝,有十分重要的意义。煤炭科学研究总院西安分院对澄合、韩城矿区煤矸石进行了调查、采样,分析了矸石的岩石类型、矿物成分、化学成分、研制了矸石肥料,测试了矸肥     

重庆市矸石山环境地质灾害效应及稳定性分析

煤矸石是我国排放量及积存量最大的工业废弃物。我国现有矸石山1500余座,累计存量约34亿t。矸石排放量的持续增加造成严重的地质灾害隐患。论文分析了矸石山的污染效应、自燃效应、占地效应、爆炸效应、结构侵蚀效应、失稳效应及景观破坏效应系列环境地质灾害效应。为避免矸石山失稳所造成的危害,对重庆地区的矿区进行现场调研踏勘。根据其结果对影响矸石山稳定的因素及几种失稳模式进行了分析,并在此基础上,依据塑性极限分析原理,针对矸石山边坡失稳主要形式,利用极限分析上限定理推出了矸石山边坡稳定堆积高度的计算公式,并采用在重庆地区矿区调研踏勘及现场直剪试验所得到的参数进行计算,做出对应表格及曲线。其结果可作为确定矸石山实际堆放高度的理论依据。     

自然矸石山治理技术

在分析煤矸石山自燃机理、总结国内现有治理方法的基础上，提出采用钻孔注浆技术为主的方法治理自燃煤矸石山特别是堆积量超千万ｔ的大型自燃矸石山。结合山西阳泉二矿自燃矸石山特点，介绍了具体的实施方案及效果。     

贵州省毕节地区煤矸石特征及综合利用分析

研究分析了毕节地区部分矿区煤矸石的特征,指出该区煤矸石总的特点是SiO2、Fe2O3、CaO含量偏高,Al2O3偏低,但不同矿区有一定的差异。根据煤矸石的成分特征,指出了毕节地区煤矸石的利用方向,如制作水泥、新型墙体材料、空心砌块、陶粒（轻骨料、多孔骨料）、铸石,回收铝产品,生产肥料,利用矸石发电及用作筑路材料等。对其在综合利用方面存在的问题进行了分析,认为毕节地区煤矸石的综合利用具有广阔前景。     

固体废弃物的生态环境效应分析——以兖济滕矿区煤矸石为例

兖济滕矿区煤矸石长期露天堆放,既造成大量土地资源浪费,又造成矿区水体、土壤、大气等环境污染,是不容忽视的环境污染源地。从矿区煤矸石的化学成份和矿物成份分析可以看出,煤矸石的化学成份以SiO2为主,其次为Al2O3;矿物成份以高岭石为主,其次为石英。选用大量测试数据对煤矸石中有害微量元素对水环境、土壤环境的污染效应进行了研究,认为：煤矸石在酸性条件下淋溶析出的重金属的含量均超过了生活饮用水标准;碱性条件下,除Cu、Zn、As外,其余的也超过了地面水环境质量V类水的标准：煤矸石回填区的As、Cu、Pb、Zn四种重金属对矿区水环境影响不明显;填矸石的汇水区以及矸石山附近的水井水化学类型已由重碳酸型转变为硫酸型,部分区域已经受到了SO4^2-、总硬度、固形物的污染;矿区煤矸石堆放对附近土壤的影响并不显著,但某些有毒有害的重金属元素远远大于背景值,植物在土壤中对其吸收与积累可能形成潜在危害性。最后指出了降低煤矸石污染、提高煤矸石的综合利用才是解决矿区固体废弃物生态环境效应的主要途径。     

贵州水城地区煤矸石中微量元素综合利用评价

煤矸石中富含各种微量元素,其中很多元素都具有综合利用潜力,如在高镓矸石中,微量元素Ga含量可达到工业利用品位。矸石中也富含一些对植物生长有益的微量元素,这有利于利用煤矸石制作肥料和矸石山的复垦,但矸石中有些微量重金属元素含量过高时也会对环境造成一定的影响。为了更深入的查明煤矸石中微量元素的利用潜力和对环境的影响程度,选择重要产煤区水城为研究区域,对多个煤矿的煤矸石开展综合利用研究工作,采用ICP—MS对煤矸石中微量元素进行分析,并对煤矸石微量元素利用进行了综合评价。通过分析,认为Ag、co、Ga、zr、Nb和sc等6种微量元素有较大综合利用潜力,矸石中富含cu、zn、c0和M04种对植物生长有益的微量元素,但矸石中的cu、Ni、zn和Cr含量是对照背景值的2—3倍,可能会对环境造成一定的影响。     

煤矸石山的危害及植被生态重建途径探讨

长期的采矿活动使煤矿区大量的煤矸石堆积形成煤矸石山,成为矿区环境污染和恶化的主要因素之一。煤矸石山对矿区造成的危害主要包括引发火灾、破坏矿区景观、污染环境、形成地质灾害等。提出了植被生态重建治理煤矸石山的措施,其主要技术手段包括煤矸石山立地条件分析、山地整形、基质改良、植物种类选择和栽培等。通过合理的规划设计,最终实现矸石山稳定的植被生态系统。      

煤矿塌陷区覆土造地综合研究——以新庄孜矿为例

以新庄孜矿为例,针对覆土造地过程中,煤矸石充填可能带来的重金属元素的迁移污染作了相关分析。采用煤矸石充填塌陷区,既减少矸石山占地面积,又能在塌陷区覆土造地;同时,填埋矸石有利于保护环境,防止环境污染,具有较大的经济效益、社会效益和环境效益,对淮南矿区覆土造地及工农业持续发展具有重要的示范意义。      

自燃矸石山治理技术

在分析煤矸石山自燃机理、总结国内现有治理方法的基础上,提出采用钻孔注浆技术为主的方法治理自燃煤矸石山特别是堆积量超千万t的大型自燃矸石山。结合山西阳泉二矿自燃矸石山特点,介绍了具体的实施方案及效果。      

徐州沛县某矿煤矸石工程地质特性试验及地基稳定性分析

近年来,煤矿区用煤矸石回填、碾压后作为建筑地基基础得到了广泛的应用。以徐州沛县某矿煤矸石新鲜样品和回填多年的矸石(1#、2#)样品为例,对煤矸石的颗粒组成、矿物成份及其胀缩性进行分析,结果发现:新鲜矸石颗粒在10mm以上的含量较大,而1#、2#矸石颗粒级配在10mm以下的含量相对较大;煤矸石岩性成份主要为砂岩和泥岩,矸石样品中的粘土矿物有高岭石、绿泥石、伊利石、伊蒙混层和蒙脱石等,新鲜煤矸石中I/M混层和伊利石的含量与1#、2#矸石相比明显高出许多,因而具有较大的膨胀性;1#、2#矸石膨胀性很小,但是在遇水情况下仍具有一定的膨胀性。对煤矸石地基的破坏机理及作用过程进行了分析,并提出用矸石作地基基础时应注意的问题,认为采取适当的措施煤矸石回填地基作为建筑地基是安全可行的。     

矿产资源开发中矿山地质环境问题响应差异性研究——以陕西潼关、大柳塔及辽宁阜新矿区为例

以陕西潼关、大柳塔及辽宁阜新矿区为例,采用对比分析的方法研究矿产资源开发中矿山地质环境问题差异性响应的主要因素。上述3个矿区矿产资源开发中矿山地质环境问题主要包括：20世纪90年代以前,陕西潼关金矿区是中国矿产资源开发秩序十分混乱的矿区之一,地下开采的采矿废石随意堆排导致了极为严重的矿山泥石流地质灾害及其隐患,＂三废＂无序排放导致土壤、河水及其底泥的重金属及氰化物污染严重,严重影响人体健康;地处生态环境脆弱带的陕西大柳塔煤矿区,20年大型机械化地下煤炭资源开采导致大面积地面塌陷及其链生的地下水含水层破坏严重,但矿区土地沙漠化程度总体没有呈现加重的趋势,水土环境重金属呈轻度污染;具有百年开发历史的辽宁阜新煤矿区,露天开采使土地生态破坏严重、边坡滑坡灾害频发、土地压占与破坏突出,地下开采引起的地面塌陷对地表建筑物及人居安全影响严重,但相对于金属矿区,该矿区水土环境重金属污染相对轻得多。对比上述3个矿区矿山地质环境问题,得到其差异性响应主要因素：矿产资源种类、原生地质环境条件、开采方式及矿山环境保护意识等。     

The impact of disposal and treatment of coal mining wastes on environment and farmland

In China, coal mining wastes have traditionally been dumped in cone-shaped heaps that have the potential to pollute air, soil and water environments and landscapes through dust generation, leachate production, self-ignition and as a consequence of an absence of vegetation cover. Since 1980s, the disposal technique for coal mining wastes has been changing and in many instances the wastes are now transported directly to subsided land as a fill to enable the reuse of that land. Thus, today, both coal mining waste dumps from the past and filled subsided lands are in existence. However, the comparative impacts of these different disposal techniques on the environment and farmland productivity have not been studied in detail. Using Dongtan (DT), Nantun (NT) and Xinglongzhuang (XLZ) coal mines as examples, the components of coal mining wastes and their potential pollution contribution to soil, surface water and ground water are tested in-situ. The results show that contaminants are released after self-ignition and weathering of coal mining wastes, but they are not above the allowable environmental standards. However, despite these findings, more and closer attention needs to be paid to the mobility, transportation and accumulation of these contaminants in the environment over time.     

Preservation of coal-waste geochemical markers in vegetation and soil on self-heating coal-waste dumps in Silesia,Poland

Occurrence and distributions of geochemical markers on vegetation and in soils covering two self-heating coal waste dumps were investigated with gas chromatography-mass spectrometry (GC–MS) and compared with those of bitumen expelled on the coal waste dump surface. Presence of biomarkers, alkyl aromatic hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), and such polar compounds as phenols indicate that components of self-heating coal wastes indeed migrate to soils and plants surface and their characteristic fingerprints can be applied in passive monitoring to investigate migration of contaminants from self-heating coal wastes. Moreover, results allow to discriminate between the Upper- and Lower Silesian coal basins, notwithstanding value shifts caused by heating. Mechanisms enabling the migration of geochemical compounds into soils include mixing with weathered coal-waste material, transport in gases emitted due to self-heating and, indirectly, by deposition of biomass containing geochemical substances. Transport in gases involves mostly lighter compounds such as phenols, methylnaphthalenes, methylbiphenyls, etc. Distributions and values of geochemical ratios are related to differences in their boiling temperatures in the case of lighter compounds but preserve geochemical features in the case of heavier compounds such as pentacyclic trierpanes.     

Investigation of pyrite oxidation and acid mine drainage characterization associated with Razi active coal mine and coal washing waste dumps in the Azad shahr–Ramian region,northeast Iran

Acid mine drainage (AMD) pollution is considered to be the most serious water pollution problem in mining areas. AMD containing iron sulfates and other components can affect the receiving water bodies. Pyrite oxidation and AMD generation can be considered as important processes that may take place in the wastes produced by coal mining and coal washing operations in the Golestan province (northeast Iran). The study area is characterized by appropriate atmospheric conditions that favor pyrite oxidation and the presence of a large amount of water bodies. This study attempts to consider pyrite oxidation and AMD generation in the Azad shahr–Ramian region. The impact of AMD on the quality of the surface water bodies was investigated by taking samples and analyzing them for hydro-geochemical parameters. Stiff and Piper diagrams were used to represent chemical analyses of water samples. The coal samples taken from different depths at four points on two different coal waste dumps were analyzed to find the fraction of pyrite that remained in the waste particles to investigate the pyrite oxidation process. A computational fluid dynamic package called PHOENICS was used to model pyrite oxidation process numerically. The results obtained from the geochemical analyses of water and coal samples and numerical simulation show pyrite oxidation and acid generation in the region. However, the presence of carbonate rocks raised the pH of the water samples. The drainages of the Razi mine may be recognized as natural alkaline mine drainages.     

The attenuation of chemical elements in acidic leachates from coal mineral wastes by soils

The chemical attenuation of acidity and selected elements (aluminum, arsenic, cadmium, cobalt, chromium, copper, fluorine, iron, manganese, nickel, and zinc) in acidic leachates from coal mineral wastes by four natural subsurface soils has been investigated using laboratory column methods Leachate solutions were allowed to percolate through the soils under simulated natural flow conditions, and the elemental concentrations in the influents and effluents were measured periodically Elemental retentions were substantial for all species except managanese, which was eluted in excess from all soils except the most calcareous Two processes appeared to operate in decreasing influent concentrations: (1) precipitation of solid phases caused by increased pH of the leachate as it percolated through the soil, and (2) adsorption of elements onto exchange and sorption sites naturally present in the soil and on iron and aluminum oxide precipitates formed in situ from leachate components because of the increased pH The soil property most important in retention was its alkalinity Thus, carbonaceous soils provide the best control material for acidic leachates from coal mineral wastes. Results show that natural soils can substantially reduce pollutant fluxes to the environment from acidic coal waste dumps and should be considered when selecting waste disposal sites Performed under the auspices of the U.S. Department of Energy     

Adverse effects of coal mine waste dumps on the environment and their management

Waste dumps generated from mining that exposes sulfur-bearing overburden can be active sources of acid generation with the potential to severely contaminate soils, surface and groundwater, and endanger both local and downstream ecosystems. A waste rock management strategy ensure that disposal of such material is inert or at least stable and contained, and minimizes the surface footprint of the wastes, and explores options for alternate uses. Reclamation of waste dumps is another or parallel alternative to decrease the potential for adverse effects. At the coal mining area of Karmozd in Iran, large volumes of wastes have been produced and disposed of without any specific care for the environment. In this paper, the impacts of waste dumps on the environment were identified and this was followed by a research program to determine the characteristics of the wastes, their acid generation potential, the availability of hazardous contaminants, and a prediction of their environmental impacts on the site. Data was collected from the target site and by comparing several reclamation alternatives using a Multi-Attribute Decision-Making technique, forestry was selected as the post-mining land use for the waste dumps. Preliminary evaluations indicated that Zelkava could be a useful tree species for this region.     

Utilization of leonardite and coal bottom ash for production of ceramic floor tiles

The aim of this research was to exploit leonardite and coal bottom ash (CBA), which are waste products from coal power plants, for investigating their potential as raw materials in the production of ceramic floor tiles. The developments of ceramic body were mixed with traditional raw materials. Different proportions of ceramic materials were studied in order to explore the proper composition with a variety of wastes containing leonardite and coal bottom ash from 20% up to 80%. Unglazed tiles were produced by shaping through dry pressing and single firing. The physical, chemical, and mechanical properties of the samples were investigated. The total waste (CBA and leonardite) contained in the production was close to 42.8%, and it presented properties that are adequate for it to be classified in groups within the ISO 13006 standard, and yielded the highest flexural strength which enabled the obtained ceramic floor tile bodies to satisfy the requirement to be classified in group BIIa. The chemical resistances of the products were classified in the category UA group which passed the minimum requirement for classification as chemical attack, set by standard EN 14411.     

城市垃圾的地质处置

城市固体废物（城市垃圾）是国际上现代化城市环境污染的主要污染源之一,发达国家非常注重固体废物地质处置的研究,这一领域是环境工程与水资源工作者研究的热点问题。我国城市垃圾对环境的污染非常严重,目前有三分之二的城市已形成“垃圾包围城市”的严重局面。随着经济的发展,我国城市固体废物的数量增长很快。如何处理庞大的城市垃圾将是关系到经济发展、水资源和环境保护的重大问题。本文介绍了我国城市垃圾的现状和目前国际     

Flow of top coal and roof rock and loss of top coal in fully mechanized top coal caving mining of extra thick coal seams

This study investigates the flow and caving characteristics of top coal and roof rock, as well as top coal loss pattern in the fully mechanized top coal caving mining of extra thick coal seams. The two dimensional discrete element numerical simulation software program, particle flow code (PFC), is used for the simulation of top coal caving and the inversion analysis. The original locations, distribution, and migration pattern of caved top coal and lost coal were obtained. The analysis shows that in the initial site of caving, the caved bodies are in the form of arc shaped strips in front of the working face. During the caving, caved bodies of different heights move towards the lower rear of the face at different speeds. The lost coal and caved roof rock are originally located at the interface between coal seam and roof, the lost coal is mainly distributed in the goaf on the floor. Behind the support, the caved top coal bodies originally are arc shaped strips, with the highest points located at the midline of the caving opening. The strips are more curved near the goaf than those near the support. During top coal caving, the strips successively cave, with the adjacent outer strip replacing the caved one. The variations of top coal loss and waste rock ratio with time reflect the different phases of top coal caving. In order to improve coal recovery and limit the amount of caved roof rock, the waste rock ratio should be controlled below 10 %. When the waste rock ratio reaches this value, the caving opening should be closed. This paper provides theoretical bases for the improvement of top coal recovery in the fully mechanized top coal caving mining of extra thick coal seams.     

Usage of chromite wastes as aggregate in foam concrete production

The rapidly developing mining sector in recent years has also brought environmental problems together. At the beginning of these problems are mine process wastes produced in high quantities from mines every year. The waste material at 90% and the concentrate chromite at 10% are obtained in the chromite ore enrichment plants. This significant amount of waste creates pollution in nature visually and physically. The aim of the study is to determine the advantages of using foamed concrete as a building material, to reduce the production cost of foamed concrete, to produce alternative solutions for rehabilitation, and to eliminate environmental pollution. The chromite enrichment wastes obtained from Fethiye, Köyce?iz, Denizli and Burdur regions were used as aggregates in the production of foamed concrete. In this study, compressive strength experiments were carried out according to TS EN 1354, thermal conductivity experiments were carried out according to TS EN 12664. As a result, it has been observed that chromite waste (dunite) can be used in the production of foamed concrete under certain conditions.