东秦岭商丹带北侧新元古代埃达克质花岗岩及其地质意义

东秦岭商丹构造带北侧的商南花岗岩体和吊庄花岗岩体属于钙碱性系列,具有岛弧花岗岩特征。这些岩石富Na2O(3.54％～5.52％)、贫K2O(0.75％～3.46％)、Na2O/K2O比值为1.09～6.16,SiO2含量＞56％(61.84％～74.57％),Al2O3含量变化于13.41％～19.01％,多数≥15％,MgO含量均小于3％(0.65％～2.41％),Mg#为43.87～66.12,低Y(＜18×10-6, 为1.90×10-6～18.4×10-6)和Yb(＜1.9×10-6为0.27×10-6～2.27×10-6),Sr含量高(350×10-6～830×10-6),多数大于400×10-6,Sr/Y比值在25.29～216.71之间,大于20～40;LREE富集,HREE亏损,多数La/Yb比值＞20(47.60～110.93),(La/Yb)N＞20(32.09～99.13),不显Eu异常或有弱的Eu正异常,大离子亲石元素(Rb、Ba、Th、Sr)相对富集,高场强元素(如Nb、Ta、Zr、Hf、Ti)相对亏损。同位素组成表明,花岗岩体具有相对低的143Nd/144Nd比值(0.512127～0.512134),与商南松树沟蛇绿岩的143Nd/144Nd比值(0.512651～0.512917)比较接近,εNd(t)为正值(+1.23～+2.51),暗示源岩以N-MORB为主。这些地球化学特征与洋壳俯冲MORB的部分熔融形成的埃达克质岩相似,表明这些晋宁期的花岗岩类可能属于埃达克质岩。研究表明,商丹地区埃达克质花岗岩类与新元古代沿商丹带-线曾发育有一个以松树沟蛇绿岩和黑河玄武岩为代表的古洋盆(古秦岭洋)向北发生俯冲消减作用有关,造成古洋壳俯冲板片MORB岩石部分熔融而形成。     

滇川西部金沙江石炭纪蛇绿岩SHRIMP测年:古特提斯洋壳演化的同位素年代学制约

本文应用SHRIMP方法精确测定了金沙江蛇绿岩带中蛇绿岩的辉长岩和斜长岩、呈脉状产于辉长岩和变质橄橄岩中的斜长花岗岩、以及呈岩株状侵入蛇绿岩中的花岗闪长岩的锆石U-Pb年龄,提供了古特提斯洋壳演化的年代学制约。滇西之用层状角闪辉长岩的年龄为328±8Ma,书松斜长岩为329±7Ma,白马雪山辉长岩为282～285Ma,它们可能反映了海底扩张不同阶段的时代。研究还表明,在这些辉长岩和斜长岩中,部分锆石记录了375～352Ma的略老的年龄,暗示蛇绿岩浆活动可能始于晚泥盆世。在金沙江蛇绿岩中,滇西娘九丁斜长花岗岩和川西雪堆斜长花岗岩,具有高硅低钾的成分特征。但是,这些岩石的REE总量高,LREE富集;Sr初始值高,达0.7058～0.7070;在其锆石组成中,存在继承锆石。这些证据表明斜长花岗岩中存在陆壳物质的混染,可能与洋壳俯冲消减有关。娘九丁斜长花岗岩的年龄为285±6Ma,雪堆斜长花岗岩为300±5Ma,记录了古特提斯洋壳俯冲消减事件。滇西吉义独花岗闪长岩,呈岩株状侵入蛇绿岩中,年龄为263±6Ma,限定了蛇绿混杂岩的年代上限。     

贺根山缝合带白音呼舒奥长花岗岩锆石U-Pb年龄、地球化学特征及构造意义

本文以出露于贺根山缝合带梅劳特乌拉蛇绿岩北侧的白音呼舒奥长花岗岩体为研究对象,通过野外地质调查和岩石学、地球化学、锆石LA- ICP- MS U- Pb年代学研究,探讨其成因、构造环境及二连—贺根山洋俯冲消亡过程。岩石地球化学研究表明,白音呼舒岩体富硅（SiO2=66. 50%~73. 04%）、高铝（Al2O3=15. 11%~16. 75%）、富钠（Na2O=3. 50%~6. 16%）、低钾（K2O=1. 46%~2. 38%）,相对高锶（Sr=167. 0×10-6~441. 0×10-6）、低钇（Y=5. 30×10-6~9. 51×10-6）,富集Ba、Sr等大离子亲石元素和LREE,亏损Nb、Ta、Ti、P等高场强元素和HREE,无明显Eu异常。岩石学和岩石地球化学特征表明,白音呼舒侵入岩体属于英云闪长岩—奥长花岗岩—花岗闪长岩(Tonalite—Trondhjemite—Granodiorite,TTG)岩系,与高Si 高锶低钇中酸性岩（Adakite,埃达克岩）类似,形成于大洋俯冲带岛弧环境,为俯冲洋壳脱水熔融的产物。锆石LA- ICP- MS U- Pb测年表明,白音呼舒奥长花岗岩体的形成年龄为309. 2 ±1. 6 Ma,表明该岩体侵位于晚石炭世,反映了贺根山缝合带晚石炭世大洋俯冲带TTG岩浆作用事件。结合二连—贺根山缝合带石炭纪蛇绿岩、石炭纪—二叠纪岛弧型岩浆岩和中生代后造山A型岩浆岩的时空分布与演化关系,表明古亚洲洋二连—贺根山洋盆在晚石炭世并未关闭,而是处于大洋俯冲消减和陆壳增生过程中。     

甘肃北山红石山地区晚石炭世英云闪长岩锆石U- Pb年龄、地球化学特征及构造意义

本文以出露于红石山—百合山蛇绿混杂岩带南侧的英云闪长岩体为研究对象,通过野外地质调查和岩石学、地球化学、锆石LA- ICP- MS U- Pb年代学研究,探讨其成因、构造环境及红石山洋俯冲消亡过程。岩石地球化学研究表明,红石山南英云闪长岩体富硅（SiO2=63. 95%～66. 22%）、高铝（Al2O3=15. 31%～16. 61%）、富钠（Na2O=3. 73%～4. 33%）、低钾（K2O=1. 00%～1. 85%）,相对高锶（Sr=246. 0×10-6～417. 0×10-6）、低钇（Y=8. 83×10-6～11. 80×10-6）,富集Rb、Sr等大离子亲石元素和LREE,亏损Nb、Ta、Ti、P等高场强元素,HREE相对亏损,无明显Eu异常。岩石学和岩石地球化学特征表明,为俯冲洋壳脱水熔融的产物。锆石LA- ICP- MS U- Pb测年表明,红石山南英云闪长岩体的形成年龄为306. 9～309. 9 Ma,表明该岩体侵位于晚石炭世,反映了红石山—百合山缝合带晚石炭世大洋俯冲带岩浆作用事件,进一步约束了红石山洋俯冲时限。结合红石山—百合山缝合带石炭纪蛇绿岩、石炭纪—二叠纪岛弧型岩浆岩和早二叠世末期（275 Ma）的辉长岩和花岗岩侵位及早—中二叠世双堡塘组下部的角度不整合均反映了红石山洋盆的闭合过程（辛后田等,2020）,表明红石山洋盆在晚石炭世并未关闭,而是处于大洋俯冲消减和陆壳增生过程中。     

大别山超高压变质带燕山期花岗岩地球化学特征及成因探讨

依据花岗岩类的岩性组合、产出状况、结构、侵位机制和地球化学特征等,将大别山超高压变质带中燕山期花岗岩大致可以划分为两大类一类为高钾钙碱性系列,以大同岩体和司空山早、主期岩体为代表,岩性为花岗闪长岩-二长花岗岩,表现为SiO2＞56%,Al2O3一般≥14%,MgO＜3%富集LREE,低HREE和Y、Yb(如Y＜18×10-6,Yb＜1.9×10-6),高Sr、Ba,高La/Yb＞39和Sr/Y≥30,Sr、Eu异常不明显,与Adakite岩相似;另一类属正常钙碱性系列,以英山尖岩体为代表,岩性以二长花岗岩为主,具有高硅、低铝的特点,一般SiO2>70%,Al2O3＜14%,LREE略显亏损,HREE略显富集和高Y、Yb(如Y＞18×10-6,Yb＞1.9×10-6),低Sr和La/Yb＜10、Sr/Y＜10,Sr、Eu负异常明显.高钾钙碱性花岗岩可能为增厚的下地壳部分熔融的产物,正常钙碱性花岗岩可能为正常的地壳重熔形成.     

西藏札佐晚白垩世中期埃达克岩年代学、地球化学及其构造意义

为解释南冈底斯晚白垩世埃达克质岩石成因及其地球动力学机制,本文对西藏扎囊县札佐地区二长花岗岩开展了锆石U-Pb年代学、Hf同位素和全岩地球化学分析。札佐二长花岗岩锆石U-Pb定年为80.43±0.62 Ma,其SiO₂为66.19%~66.84%,Al₂O₃为15.17%~15.48%,MgO为1.67%~1.91%,Mg#为47.4~51.5,K₂O为3.86%~4.09%,A/CNK=0.91~1.01,属准铝质高钾钙碱性岩石。岩石轻稀土富集明显,高Sr（492×10^-6~670.2×10^-6）,低Y（8.27×10^-6~14.99×10^-6）,Yb（1.07×10^-6~1.79×10^-6）,高Sr/Y（35.0~81.0）,高La/Yb（17.4~21.4）,弱负Eu异常,具埃达克岩地球化学特征。相对富集大离子亲石元素（LILE）,亏损高场强元素（HFSE）和重稀土。锆石ε_Hf（t）值为10.5~14.1,单阶段Hf模式年龄（t_DM1）为184.8~326.1 Ma,平均为203.4 Ma,二阶段Hf模式年龄（t_DM2）为247.2~476.0 Ma,平均为287.1 Ma,略大于侵位年龄,指示岩浆物质来源于俯冲洋壳,并可能卷入俯冲沉积物。岩石中地幔组分印记Mg#值和相容元素Ni、Cr含量较高,表明熔体在上升过程中与上覆地幔楔发生反应。研究分析表明,在新特提斯洋洋脊俯冲作用下,高温热流透过板片窗导致洋壳（及俯冲沉积物）部分熔融形成札佐埃达克质二长花岗岩。同时表明,在80 Ma左右,新特提斯洋仍处于洋脊俯冲阶段。     

俯冲陆壳部分熔融形成埃达克质岩浆

在岛弧背景,埃达克质岩浆形成于俯冲洋壳板片的部分熔融已得到共识,但在大陆碰撞背景,埃达克质岩浆是否形成于俯冲陆壳的部分熔融尚未有研究报导。对祁连山东南部关山花岗岩（229 Ma）的地球化学和岩石成因研究提供了俯冲陆壳部分熔融形成埃达克质岩浆的一个实例。关山花岗岩以高K（K2O=4.12%~5.16%,K2O/Na2O=0.97~1.64）、高Sr/Y比值（13.6~84.1）、低Y （6.8×10-6 ~15.7×10-6 ）和低HREE（eg. Yb=0.62×10-6~1.31×10-6）为特征,并具有强分异的稀土元素组成模式[（La/Yb）N=17.5~41.6]和演化的Sr-Nd同位素组成[初始87Sr/86Sr=0.70587~0.70714, εNd（t）=-10.9~-5.16, tDM=1.10~1.49 Ga]。这些地球化学特征表明关山花岗岩属于大陆型（C型）埃达克质岩石,而明显不同于俯冲洋壳板片或底侵玄武质下地壳部分熔融形成的埃达克岩。关山花岗岩Pb-Sr-Nd同位素组成与商丹断裂北侧的祁连山前寒武纪基底岩石、早古生代火山岩和花岗岩类存在显著差异,但类似于商丹断裂南侧秦岭早中生代花岗岩类的Pb-Sr-Nd同位素组成,由此认为具有埃达克质的关山花岗岩的岩浆来自于南部俯冲陆壳物质的部分熔融,并提出了大陆碰撞背景中埃达克质岩浆产生的一个新的地质模型。     

胶西北仓上、三山岛岩体二长花岗岩地球化学、锆石U-Pb年龄及Lu-Hf同位素研究

三山岛金成矿带位于胶西北金矿集区的西端,是胶东重要的金矿带,赋存有三山岛北部海域、三山岛、西岭、新立、仓上等大型、特大型金矿床,金矿的主要控矿围岩为二长花岗岩。本文通过对仓上金矿区片麻状黑云二长花岗岩、三山岛北侧似斑状黑云二长花岗岩的岩石地球化学、锆石LA- ICP- MS定年和Lu~Hf同位素组成测试和研究,讨论了该类岩石的地球化学类型、形成时代、岩浆源区与成因。岩石地球化学研究表明二长花岗岩具有高的SiO2(70.19%～76.36%)、全碱（Na2O+K2O=7.05%～8.19%）、Ba（>1573×10-6）、Sr（>738×10-6）、（La/Yb）N（>26.44）、Sr/Y（>121）、LILE /HFSE,低的Al2O3（13.41%～15.61%）、MgO（0.1%～0.84%）、Y（<6.05×10-6）、Yb（<0.53×10-6）以及相对平坦的HREE,无明显的铕异常,明显亏损Nb、Ta、P、Ti等高场强元素,显示出典型的高Ba-Sr花岗岩所具有的地球化学特征,属高Ba- Sr花岗岩。锆石LA- ICP- MS定年结果表明仓上、三山岛二长花岗岩年龄分别为131±1Ma和127±2Ma,与郭家岭型花岗岩具有相似的主量元素组成及稀土和微量元素分布模式,表明仓上、三山岛岩体为郭家岭型花岗岩。仓上、三山岛二长花岗岩岩浆锆石εHf(t)值为-25.2～-18.1,对应的Hf二阶段模式年龄TDM2为2.77～2.33Ga。从岩石学、地球化学和Lu- Hf同位素特征,并结合前人对郭家岭花岗岩成因研究成果,笔者认为仓上、三山岛二长花岗岩是陆壳酸性岩浆与幔源中基性岩浆混合而成。以壳源为主（主要来源于前寒武纪变质基底岩石,以新太古代-古元古代岩石为主）,由幔源中基性岩浆混合后经分异作用而成的同熔深成型花岗岩,总体上,形成于较高温度、深度的环境。     

华北板块北缘东段中三叠世构造演化——来自辽宁法库地区侵入岩的证据

本文对华北板块北缘东段辽宁北部法库地区中三叠世风歧堡岩体和靠陵沟岩体进行了岩相学、锆石U-Pb年代学、地球化学及Lu-Hf同位素研究。LA-ICP-MS锆石U-Pb测年结果显示,风歧堡岩体和靠陵沟岩体加权平均年龄分别为（241±1） Ma和（243±1） Ma,侵位时代为中三叠世。风歧堡岩体的Ba和Sr质量分数分别为（290.00×10^-6~484.00×10^-6）和（129.00×10^-6~338.00×10^-6）,Sr/Y值为13.27~28.17,Sr/Yb值为117.50~250.28;靠陵沟岩体具有较高的Ba质量分数（899.00×10^-6~1 300.00×10^-6）和Sr质量分数（772.00×10^-6~997.00×10^-6）,以及较高的Sr/Y值（67.47~78.21）和Sr/Yb值（661.81~781.32）,Y、Rb和Yb质量分数较低,分别为11.00×10^-6~14.70×10^-6、55.80×10^-6~78.40×10^-6、1.17×10^-6~1.39×10^-6,地球化学特征上具有高Ba-Sr花岗岩的特征。此外,凤歧堡岩体样品富集大离子亲石元素Rb和K,亏损高场强元素Nb、P、Ti和大离子亲石元素Ba;靠陵沟岩体样品富集大离子亲石元素Ba、K、Sr,亏损高场强元素Nb、P、Ti。凤歧堡和靠陵沟岩体样品Nb/Ta值（4.18~10.26）和Zr/Hf值（30.39~38.76）与地壳平均值相近,Ni、Co和Cr质量分数较低;岩石地球化学特征表明法库地区中三叠世花岗质岩浆源岩为壳源岩石。中三叠世—晚三叠世早期,华北板块北缘东段处于造山地壳加厚阶段。研究区中三叠世花岗岩的ε_Hf（t）值均为正值,亏损地幔二阶段模式年龄（T_DM2）为949~555 Ma,结合岩石地球化学特征,中三叠世花岗质岩浆源岩为造山地壳加厚过程中新元古代新生下地壳部分熔融的产物。     

adakite的地球化学特征及成因

本文通过综合近20年来国际上有关adakite(埃达克岩)的主要文献资料，对adakite的岩石地球化学特征、分布、形成环境和条件等做了总结。adakite是一类高铝的中酸性火山岩或侵入岩，主要特点是高Sr(400×10-6～2?000×10-6)，低Y和Yb(Y≤18×10-6，Yb≤1.9×10-6)，轻重稀土元素强烈分异，不具有明显的Eu负异常，K2O/Na2O比值低(<0.5)。adakite主要分布于环太平洋地区，少数分布于一些古老造山带中，它的形成主要与年轻的(<25Ma)俯冲洋壳的部分熔融有关，也可能与老的俯冲洋壳或底侵玄武岩的部分熔融、或者与增厚地壳的底部发生拆沉作用有关。熔融残留相主要是含榴角闪岩或榴辉岩，也可能为麻粒岩。实验岩石学及地质证据表明，具有adakite成分特征的岩浆可以在较宽的压力范围内(1.0～2.6GPa)形成。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.