相山碎斑熔岩岩石特征及其成因探讨

相山主体岩石碎斑熔岩在岩石成因、岩相归属上长期以来有多种不同的看法,原因在于碎斑熔岩边缘相具有熔结凝灰岩甚至是凝灰岩的特点,过渡相具有熔岩的特征,中间相具有潜火山岩的特征,并且各种相之间呈渐变过渡关系。笔者从碎斑熔岩的岩石矿物组成,稀土、微量元素及同位素特征,提出了碎斑熔岩是由基底变质岩重熔而形成的观点。从斑晶钾长石的低结构态和出溶机理,认为碎斑熔岩的形成环境接近于火山岩和潜火山岩,而与深成岩差别较大。碎斑熔岩中斑晶多呈碎裂状,与火山口内隐爆作用有关,因此将该岩石归属于火山侵出相。     

江西相山碎斑熔岩成因和钾长石亚显微结构

相山碎斑熔岩含铁铝榴石(1340g/T)、红柱石等岩浆结晶副矿物,具S型火山岩地球化学和Nd、Sr、O同位素组成的特征。据光学测定和X光粉晶衍射测定,斑晶钾长石主要是高正长石或低透长石,有序参数δ′=-0.32—-0.01。在透射电镜下,出溶的细钠长石页片由共格拐点分解形成,成分波长约50—100nm;出溶的宽钠长石页片由无应力离溶作用形成,页片宽50—200nm。结果表明,碎斑熔岩是在火山环境下形成,而不是在深成环境下形成。     

福安地区碎斑熔岩的基本特征及成因

福安地区碎斑熔岩的形成受北东向火山基底断裂控制，具有明显的分带现象，由中心到边缘可划分出酸性粒状碎斑熔岩、中酸性粒状碎斑熔岩、中酸性霏细状碎斑熔岩、酸性霏细状碎斑熔岩、酸性隐晶状碎斑熔岩等岩石类型，是晚侏罗世火山活动衰亡时期岩浆以侵出一溢流形式活动的产物。碎斑熔岩与同期潜火山岩、流纹质晶屑熔结凝灰岩(熔离型)是同源岩浆分异及演化的结果，在空间上构成三相一体的共生组合地质体。     

福建古田-溪尾碎斑熔岩体的基本特征及成因

古田—溪尾地区碎斑熔岩体的形成受北东向基底断裂带控制,具明显水平和垂直分带。由中心到边缘可划分出中酸性、酸性粒状碎斑熔岩,霏细状、隐晶状碎斑熔岩等４种岩石类型,是晚侏罗世火山活动衰亡和火山机构塌陷时期岩浆侵出—溢流相的产物。碎斑熔岩与同期潜花岗斑岩、流纹质晶屑凝灰岩是同源岩浆分异及演化的结果,在空间上构成三相一体的共生组合体。     

关于赣中相山矿田相山“碎斑熔岩”

赣中相山矿田相山杂岩体的主体岩石——"碎斑熔岩"的成因和命名,长期看法不一,主要观点有火山喷发成因、火山溢流成因、火山侵出成因、潜火山侵入成因等,本文通过综述"碎斑熔岩"的岩石学和相带特征,结合剥蚀程度、密度垂向变化研究成果,论述了"碎斑熔岩"不是火山岩而是侵入岩的成因观点。同时,对相山是否存在潜火山岩提出了质疑,探讨了相山"碎斑熔岩"的形成深度问题。认为"碎斑熔岩"命名为碎斑花岗斑岩更符合其侵入成因特点。     

福建古田——溪尾碎斑熔岩体的基本特征及成因

古田－溪层地区碎斑熔岩体的形成受北东向基底断裂带控制,具明显水平和垂直分带,由中心到边缘可划分出中酸性,酸性粒状碎斑熔岩,霏细状,隐晶状碎斑熔岩等４种岩石类型,是晚侏罗世火山活动衰亡和火山机构塌陷时期岩浆侵出－溢流相的产物。碎斑熔岩与同期潜花岗斑岩,流纹质晶屑凝灰岩是同源岩浆分异及演化的结果,在空间上构成三相一体的共生组合体。     

内蒙古正镶白旗碎斑熔岩岩石学特征及其岩相划分

白旗碎斑熔岩为不规则穹状体,可分为边缘玻质碎斑熔岩、过渡霏细碎斑熔岩、中心粒状碎斑熔岩和根部花岗斑岩四个岩性带。从玻质碎斑熔岩到粒状碎斑熔岩,斑晶碎裂度逐渐减弱,珠边结构在粒状碎斑熔岩中最发育,根部花岗斑岩与正常次火山岩相近。碎斑熔岩中钾长石有序度低,指示了岩石高温成因特征。白旌碎斑熔岩属太平洋岩系钙碱质系列,原始岩浆由来源于上地幔和下地壳熔体的混熔作用形成。     

斑铜矿—黄铜矿体系出溶结构的实验及在天然矿石成因上的应用

导言本项研究是关于斑铜矿—黄铜矿连晶的出溶结构,因为这种组合在铜矿床中是普遍出现的,而且许多这类的组合被解释为出溶结构(Brett 1964,Ramdohr 1969)。如果把这些自然产出的结构与之在受控制的实验条件形成的结构比较,就能够更好地了解它们的成因。Schwatz(1931a)曾经在这方面作过努力。他使用密封的但是没有抽成真空的硼硅酸玻璃试管,用自然产出的斑铜矿—黄铜矿共生组合使之在高于475℃的温度下均一化,再让它     

浙江建德钦堂大理岩矿床地质特征及控矿条件分析

石炭系上统黄龙组为浙江省重要的非金属矿床含矿层位。建德钦堂大理岩矿床由黄龙组石灰岩受热接触变质作用形成,规模达大型。大理岩矿体位于黄龙组中部,呈单斜产出,受碎斑熔岩破坏,矿体内部结构较复杂。矿石质量较稳定,CaO平均含量为54.8%,白度平均为90.6%,盐酸不溶物含量较低。原岩成分是影响大理岩矿石质量的决定因素,原岩方解石含量高、成分均一有利于形成优质大理岩矿石;碎斑熔岩侵出过程中形成的冷凝壳起到保温作用,不断上涌的岩浆为方解石重结晶提供了持续热源,二者是形成矿床的必要条件。     

香港世界地质公园核心景观—碎斑熔岩石柱林特征(二)

<正>本刊2015年第1期介绍了香港世界地质公园大面积出露的粮船湾组碎斑熔岩共有的特征之一为普遍发育柱状节理,本文继续介绍其共有的其它特征:(1)与围岩呈侵出接触关系。.碎斑熔岩本质上属熔岩,但其下部通过火山通道与岩浆房相连,因而与围岩呈侵出接触关系,接触面内倾,不同于侵入岩的外倾接触面。在清水湾半岛的龙虾湾等地,可见粮船湾组碎斑熔岩(Kkh)与槟榔     

海南文昌二辉橄榄岩中辉石出溶结构的结晶学取向分析

本文用电子背散射衍射技术(electron backscatter diffraction,EBSD)测试了海南文昌玄武岩中二辉橄榄岩包体中的辉石主晶与其出溶片晶的结晶学取向关系。结合电子探针成分测试,得出:单斜辉石(透辉石)主晶中出溶了两组不同方向的片晶,一组为斜方辉石(顽火辉石-易变辉石)片晶,另一组为单斜辉石(普通辉石)片晶。由于出溶片晶在EBSD测试切面上体现为以线状体,因此需要找到一种方法将线状体所代表的片晶的晶面符号推算出来。本文介绍了一种利用吴氏网进行坐标系旋转的"晶带相交法",该方法可以作图推算出溶片晶的晶面符号。根据"晶带相交法"得出,斜方辉石(顽火辉石-易变辉石)出溶片晶为(100),单斜辉石(普通辉石)出溶片晶为~(401)。根据前人的研究资料,出溶片晶~(401)可能指示最小出溶压力为9.5~12.5GPa。出溶片晶的结晶学取向涉及到主晶与出溶体的晶体结构匹配关系,并且与出溶温度-压力有关,因此出溶片晶的结晶学取向分析具有晶体化学理论意义和反映地质温压过程的实际意义。这种"晶带相交法"可以推广应用于其他矿物出溶结构的结晶学取向研究中。     

Petrology of the uppermost upper mantle deduced from spinel-lherzolite and harzburgite nodules at Calton Hill,Derbyshire

A suite of protogranular- to porphyroclastic-textured spinel lherzolites and harzburgites from the Lower Carboniferous ankaramite vent at Calton Hill has been investigated for trends of modal variation and mineral composition and for variation in calculated bulk composition. The results indicate that the nodules are accidental xenoliths derived from a source at approximately 45 km depth and at 950 °C, i.e. within the mantle but above the Low Velocity Zone. The lherzolites and harzburgites have a complex petrogenetic history involving initital formation as residues from partial melting of peridotite; it is proposed that the residues were then admixed with veins of pyroxenite, followed by a complex series of metamorphic cycles of mineral reaction and exsolution, deformation, recrystallization and annealing and finally by rupture and incorporation in the ankaramite. During ascent to the surface chrome diopside in some nodules has undergone partial, incongruent melting to form a less sodic pyroxene and a soda-rich basalt melt.     

A fertile harzburgite–garnet lherzolite transition: possible inferences for the roles of strain and metasomatism in upper mantle peridotites

Porphyroclastic enstatite in a garnet lherzolite xenolith from the Monastery Mine kimberlite, South Africa, has exsolved pyrope garnet, Cr-diopside and Al-chromite, and the specimen is interpreted as representing a transition from fertile harzburgite, (containing high Ca-Al-Cr enstatite) to granular garnet lherzolite. Although the exsolved phases occur in morphologically different forms (fine and coarse lamellae; equant, ripened grains), indicating textural disequilibrium, the exsolved grains are very constant in composition, indicating chemical equilibrium. Theoretically, the exsolution could have been due to a fall in temperature, but the close association of exsolution and deformation of the host enstatite suggests that exsolution was also aided by straining of the enstatite lattice. The phase compositions can be broadly matched with those in other mantle peridotites, except that all phases are characterised by a virtual absence of Ti. In the garnet and diopside Ti, Co, Zr and most of the REE are lower than in published analyses of garnet and diopside in both granular and sheared garnet lherzolites from Southern African kimberlites, and diopside/garnet partitioning for Sr and the REE is higher. Comparison with the trace element chemistry of an enstatite from a fertile harzburgite indicates that, except for Nb, the trace element content and distribution found in the Monastery phases could arise by isochemical exsolution from such an enstatite. On the assumption that (a) the Monastery specimen represents a transition from harzburgite to garnet lherzolite, and (b) many garnet lherzolites are of exsolution origin (as suggested by their modal compositions), the inference is that most garnet lherzolites, and not just the sheared variety, have been subject to varying degrees of Ti, Zr, Sr and REE metasomatism.     

大别山北部榴辉岩的退变质特征及其地质意义

研究了大别山北部榴辉岩的变质岩岩石学。结果表明，该区榴辉岩相变质作用可分为早期(超高压)和晚期(高压)两个阶段，并在折返过程中形成了一系列特征性的退变质显微构造。其中，退变质结构主要包括：(1)由于压力降低而出溶形成的一些定向针状或叶片状矿物包裹体，如钠质单斜辉石中石英及石榴子石中的金红石、单斜辉石和磷灰石等；(2)冠状体或后成合晶，特别是石榴子石外围发育两期(“双层”)后成合晶；(3)反应边或退变边，如绿辉石的透辉石退变边、透辉石的角闪石退变边和金红石的钛铁矿退变边等。这些退变质结构为本区榴辉岩高级变质岩的快速折返过程和抬升历史提供了强有力的岩石学依据；石榴子石中针状矿物出溶体进一步证明研究区榴辉岩早期经历了超高压变质作用，峰期变质压力应大干4．0GPa，甚至可能达到5～7GPa或更高。     

Clinopyroxene phenocrysts (with green salite cores) in trachybasalts: implications for two magma chambers under the Kokchetav UHP massif, North Kazakhstan

Clinopyroxene phenocrysts in the Kokchetav trachybasalts are variable in composition and textures. Two distinctive cores are recognized: diopside cores and green salite cores. The diopside cores with Mg# of 80–90 are mantled by colorless salite rims with Mg# of 70–80. The green salite cores have especially low Mg# (<70) but high Al and Ti contents. A Mg-rich band (Mg#=82–90) usually occurs between a green salite core and its rim, and/or between a colorless salite mantle and its rim. Dissolution surfaces are observed on all textural variants. Two magma chambers are needed to explain the observed clinopyroxene phenocrysts. A deep chamber at about 120 km in the upper mantle in which diopside cores crystallized, and a shallow chamber at depths of less than 40 km in which diopside cores were resorbed and overgrown by salite rims or mantles. Magma mixing in the shallow chamber is responsible for the formation of dissolution surfaces between the diopside bands and the colorless salite mantles. The dissolution surfaces on the diopside cores formed in the shallow chamber as a result of pressure decrease. This magma evolution scenario is complicated by the occurrence of the crustal-origin green salite cores in diopsides. These green cores likely represent the relics of continental materials, which were captured in the deep chamber and partially re-melted. Our observations indicate that subducted continental materials were returned to the Earth's surface as a result of magmatism. This study therefore provides direct evidence of a link between subducted continental materials (slab) and magmatism in this orogenic belt.     

Mineral chemistry and zircon geochronology of xenocrysts and altered mantle and crustal xenoliths from the Aries micaceous kimberlite: Constraints on the composition and age of the central Kimberley Craton,Western Australia

The Neoproterozoic (∼ 820 Ma) Aries micaceous kimberlite intrudes the central Kimberley Basin, northern Western Australia, and has yielded a suite of 27 serpentinised ultramafic xenoliths, including spinel-bearing and rare, metasomatised, phlogopite–biotite and rutile-bearing types, along with minor granite xenoliths. Proton-microprobe trace-element analysis of pyrope and chromian spinel grains derived from heavy mineral concentrates from the kimberlite has been used to define a ∼ 35–40 mW/m² Proterozoic geotherm for the central Kimberley Craton. Lherzolitic chromian pyrope highly depleted in Zr and Y, and Cr-rich magnesiochromite xenocrysts (class 1), probably were derived from depleted garnet peridotite mantle at ∼ 150 km depth. Sampling of shallower levels of the lithospheric mantle by kimberlite magmas in the north and north-extension lobes entrained high-Fe chromite xenocrysts (class 2), and aluminous spinel-bearing xenoliths, where both spinel compositions are anomalously Fe-rich for spinels from mantle xenoliths. This Fe-enrichment may have resulted from Fe–Mg exchange with olivine during slow cooling of the peridotite host rocks. Fine exsolution rods of aluminous spinel in diopside and zircon in rutile grains in spinel- and rutile-bearing serpentinised ultramafic xenoliths, respectively, suggest nearly isobaric cooling of host rocks in the lithospheric mantle, and indicate that at least some aluminous spinel in spinel-facies peridotites formed through exsolution from chromian diopside. Fe–Ti-rich metasomatism in the spinel-facies Kimberley mantle probably produced high-Ti phlogopite–biotite + rutile and Ti, V, Zn, Ni-enriched aluminous spinel ± ilmenite associations in several ultramafic xenoliths. U–Pb SHRIMP ²⁰⁷Pb/²⁰⁶Pb zircon ages for one granite (1851 ± 10 Ma) and two serpentinised ultramafic xenoliths (1845 ± 30 Ma; 1861 ± 31 Ma) indicate that the granitic basement and lower crust beneath the central Kimberley Basin are at least Palaeoproterozoic in age. However, Hf-isotope analyses of the zircons in the ultramafic xenoliths suggest that the underlying lithospheric mantle is at least late Archean in age.     

Crystallization History of Primitive Deccan Basalt from Pavagadh Hill,Gujarat, Western India

The ‘Three Phenocryst Basalts’ (TPB) from Pavagadh hill constitute one of the most primitive basalts in Deccan traps. Electron microprobe analyses of phenocryst minerals from the TPB reveal that the Fo % of olivine varies from 89 to 68, the clinopyroxene grains are diopside/salite or augite and the Cr# [Cr/(Cr+Al)] in spinel is about 0.65. The An content of feldspar varies from 63 to 67. The mineral chemical data allow us to infer that olivine and spinel crystallized early, and when olivine attained Fo76–73%, the crystallization of clinopyroxene was initiated. Plagioclase crystallization occurred at the late stage. It is indicated that the source region of the TPB may possibly be undepleted mantle (lherzolite zone) at about 85 km depth and 27 kbar pressure, where Cr# of spinel is about 0.47.     

The bearing of phase equilibria in simple and complex systems on the origin and evolution of some well-documented garnet-websterites

The temperatures and pressures of subsolidus equilibration of garnet-websterites (garnet+clinopyroxene+orthopyroxene) can be determined to within 3 kilobars from alumina solubility properties of clinopyroxene (Herzberg, 1978) and orthopyroxene (Wood, 1974, 1975). These calculations require knowledge of the oxidation state of iron and the effect of alumina on the mutual solubility of the two pyroxenes. The conditions of total dissolution of exsolved garnet and orthopyroxene required to yield single-phase subcalcic clinopyroxenites from Salt Lake Crater and the French Pyrenees have been determined. Many of these clinopyroxenites were transported 20 to 60 km up the mantle column before exsolution was terminated. Such transport was probably accomplished by convective upwelling of hot mantle peridotite and its contained anatectic products, rather than by precipitation from ascending magmas.     

Subcalcic diopsides from kimberlites: Chemistry,exsolution microstructures,and thermal history

Twenty-six subcalcic diopside megacrysts (Ca/(Ca+ Mg)) = 0.280–0.349, containing approximately 10 mol% jadeite, from 15 kimberlite bodies in South Africa, Botswana, Tanzania, and Lesotho, have been characterized by electron microprobe analysis, X-ray-precession photography, and transmission electron microscopy. Significant exsolution of pigeonite was observed only in those samples for which Ca/(Ca+Mg)0.320. The exsolution microstructure consists of coherent (001) lamellae with wavelengths ranging from 20 to 31 nm and compositional differences between the hosts and lamellae ranging from 10 to 30 mol% wollastonite. These observations suggest that the exsolution reaction mechanism was spinodal decomposition and that the megacrysts have been quenched at various stages of completion of the decomposition process.Annealing experiments in evacuated SiO₂ glass tubes at 1,150° C for 128 hours failed to homogenize microstructure, whereas, at 5 kbar and 1,150° C for only 7.25 hours, the two lattices were homogenized. This pressure effect suggests that spinodal decomposition in the kimberlitic subcalcic diopside megacrysts can only occur at depths less than 15 km; the cause of the effect may be the jadeite component in the pyroxene. Apparent quench temperatures for the exsolution process in the megacrysts range from 1,250° C to 990° C, suggesting that decomposition must have commenced at temperatures of more than 1,000° C.These P–T limits lead to the conclusion that, in those kimberlites where spinodal decomposition has occurred in subcalcic diopside megacrysts, such decomposition occurred at shallow levels (<15 km) and, at the present erosion level, temperatures must have been greater than 1,000° C.     

Decompression and unmixing of crystals included in diamonds from the mantle transition zone

A suite of exceptional mineral inclusions in diamonds from the São Luiz river, Juina province, Brazil, shows a wide range of garnet/majorite mineral compositions co-existing with clinopyroxene; the overall bulk compositions are eclogitic. The inclusions have a wide variety of textural arrangements, but crystallographic data obtained by EBSD shows that each inclusion consists of a single garnet with constant crystallographic orientation whilst clinopyroxene grains have preferred orientation with relation to garnet {110} and <111>. This suggests that the inclusions were originally single phase majoritic garnets, and that they preserve various states of progressive unmixing (exsolution) into lower pressure garnet and clinopyroxene compositions during transport of the host diamonds towards the Earth’s surface. On the basis of high pressure–temperature experimental data some of the original majoritic garnets must have come from depths of 450 km or more, and therefore resided in the transition zone and asthenospheric upper mantle. Particularly extensive re-equilibration of many inclusions took place at depths of ca 180–200 km (probably close to the base of the continental lithosphere). The partially unmixed state of the inclusions provides a unique opportunity for using mineral diffusion data to roughly estimate the rate of transport through the asthenospheric upper mantle, and within error this rate is found to be broadly compatible with expected transport rates by upper mantle convection or plume flow.