Vostok-2 gold-base-metal-tungsten skarn deposit,Central Sikhote-Alin,Russia

Vostok-2—East Russia’s largest skarn deposit of high-grade sulfide-scheelite ore with substantial base-metal and gold mineralization—was formed during the Mesozoic orogenic epoch of evolution of the Far East marginal continental system as an element of the gold-tin-tungsten metallogenic belt. The deposit is related to the multistage monzodiorite-granodiorite-granite complex pertaining to the ilmenite series and spatially associated with a minor granodiorite porphyry (?) stock, which bears petrological features transi- tional to those of intrusive rocks occurring at Au-W and Au deposits. The hydrothermal metasomatic alteration of host rocks evolved from pyroxene skarn via retrograde postskarn and propylitic (hydrosilicate) metasomatic rocks to the late, low-temperature quartz-sericite metasomatic rocks often with albite, chlorite, carbonate, and apatite. The mineral assemblages of skarn and postskarn metasomatic rocks correspond to those at the reduced-type tungsten skarn deposits. Zoning of the postskarn metasomatic rocks is controlled by granodiorite stock. The hydrothermal metasomatic alteration was accompanied by development of mineralization from scheelite via sulfide-scheelite with pyrrhotite and chalcopyrite to the gold-base-metal-scheelite assemblage with arsenopyrite, Bi-Sb-Te-Pb-Zn sulfides and sulfosalts. Several scheelite generations are recognized. Scheelite of the late generations is enriched in Eu, as is typical of gold deposits. The associated gold mineralization comprises both native gold varying in fineness and Au-bearing arsenopyrite. The significant gold mineralization emphasizes genetic links of this deposit with intrusion-related Au-W and Au deposits of the reduced type.     

Mesozoic subduction of the paleo-pacific plate along the eastern margin of the Xing-Meng orogenic belt北大核心CSCD

The eastern pari of the Xing-Meng Orogenic Belt( XMOB )consists of the Lesser Xing'an-Zhangguangcai Range Orogenic belt, the Bureya-Jiamusi-khanka Block and the Sikhote-Alin accretionary belt. This area is located between the Paleo-Asian oceanic and Paleo-Pacific tectonic regimes. Recent researches imply that the Paleo-Pacific subduction might have begun since early Permian and influenced the both sides of the Mudanjiang Fault during Triassic, which generated a N-S trending magmatic belt and accretionary complexes, such as the Heilongjiang Complex. In Late Jurassic to Early Cretaceous, some tectono st rati graph ic terranes were produced in Sikhote-Alin, which were then dismembered and migrated northwards in late Early Cretaceous by sinistral strike-slip faults. The continental margin parallel transportion weakened subduction-related magmatism in NE China which was under an extensional setting. However, in Lite Cretaceous, the Paleo-Pacific subduction was re-Activated in the eastern XMOB, which contributed to the magmatism in Sikhote-Alin.     

南岭东段岩前钨矿床地质特征及成岩成矿时代

岩前钨矿位于南岭东西向构造与滨太平洋北北东向构造带的交汇复合部位,南岭成矿带东段北部。主要矿床类型有矽卡岩型白钨矿和石英脉型黑钨矿,矿体产于燕山早期花岗岩内外接触带内。在区域地质和矿床地质研究的基础上,采用LA-ICP-MS 锆石U-Pb 法和辉钼矿Re-Os等时线方法,对与成矿关系密切的岩前花岗岩和含矿石英脉中辉钼矿进行精确定年,获得花岗岩的单颗粒锆石U-Pb谐和年龄加权平均值为(160.6±0.72) Ma,黑钨矿化石英脉中的辉钼矿为(159.2 ±2.3) Ma。这一成果揭示,花岗岩的就位年龄与含矿石英脉的形成几乎在相同热过程完成。结合前人研究,进一步得出南岭地区160~150 Ma成岩成矿作用主要分布于南岭中东段,成岩成矿作用与华南地区东部岩石圈大规模伸展的构造运动力学背景有关。岩前钨矿与区内盘古山、画眉坳、柿竹园等著名矿床具有相同的成矿时代、成矿背景和相似的成矿条件,属同一个成矿亚系列,预测岩前钨矿具有较大的找矿潜力,重点突破对象为内接触带石英脉型和接触交代矽卡岩型钨多金属矿体。     

Skarn mineralogy and trace elements of scheelite in Xianglushan tungsten deposit,Jiangxi Province,South China and their implications for mineralization processSCIEI北大核心CSCD

江西省香炉山钨矿是江南古陆斑岩-矽卡岩钨多金属成矿带内具有代表性的早白垩世矽卡岩型钨矿床。矿床的WO3储量约为22万t,平均品位约为0.641%。矿床的矿体以似层状和透镜状产出于燕山期黑云母花岗岩和寒武系杨柳岗组泥灰岩的接触带。本文在详细厘定成矿阶段矿物组合的基础上,对不同阶段产出的不同世代的白钨矿开展了原位LA-ICP-MS微量元素的系统测试。香炉山钨矿床可以划分为四个成矿阶段:矽卡岩阶段、退化蚀变阶段、石英-硫化物-白钨矿阶段和方解石-萤石阶段。根据各阶段矿物组合及与白钨矿共生关系,本次研究划分出四个阶段六个世代的白钨矿,分别为阶段Ⅰ白钨矿(产于云英岩中)、阶段Ⅱa和阶段Ⅱb白钨矿(产于退化蚀变岩)、阶段Ⅲa和阶段Ⅲb白钨矿(产于硫化物条带,Ⅲa为白钨矿核部,Ⅲb为白钨矿边部)和阶段Ⅳ白钨矿(产于石英-硫化物-白钨矿脉)。白钨矿的球粒陨石标准化稀土元素配分图有下凹型(阶段Ⅰ、阶段Ⅱa、阶段Ⅲb)、右倾型(阶段Ⅳ)和下凹右倾型(阶段Ⅲa)。各阶段白钨矿的微量元素特征表明,香炉山钨矿床白钨矿的∑REE含量高于世界上绝大部分脉状金和钨矿床,也高于我国华南地区钨多金属矿床。白钨矿中REE3+与Ca2+主要的替代机制为3Ca2+=2REE3++Ca(为一个Ca空位)。白钨矿的REE和Eu异常由流体决定,可以用来示踪流体的演化过程,Eu的活动主要以Eu2+为主。香炉山钨矿床为还原性矿床,不同阶段白钨矿中Mo等元素含量的变化指示流体演化各阶段的还原性强弱有波动。不同阶段白钨矿的稀土和微量元素特征有较大变化。香炉山白钨矿稀土元素的超常富集原因和机制仍有待进一步研究和探讨。     

Distribution of fluorite deposits in Japanese Islands

The occurrence of fluorite deposits in Japan is limited in the provinces characterized by tin and tungsten mineralization within Southwest Japan. The deposits were formed near acidic igneous rocks of Cretaceous to Tertiary age. The ores in limestone are generally associated with skarn and metallic ore minerals such as cassiterite, scheelite and chalcopyrite. Granitic rocks in the provinces are the ilmenite-series (Ishihara, 1977) having enhanced fluorine contents and high initial strontium ratios. A reducing condition of the ilmenite-series granitic magma may have been more favorable for the concentration of fluorine in the residual magma because of the crystallization of relatively Fe-rich mafic minerals. Presence of thick crust bearing carbonaceous matter at the site of magmatism could have involved in the enrichment of fluorine as well as the reducing condition.     

广西油麻坡钨钼矿床成岩成矿年代学研究及其地质意义

广西博白_岑溪断裂带位于钦杭成矿带南段,既是一条长期活动的地体边界断裂带,也是一条岩浆活动频繁的W_Mo_Sn_Pb_Zn_Sb_Au_Ag多金属成矿带。文章以该带中的广西博白县油麻坡矽卡岩型钨钼矿床为研究对象,在详细的岩性鉴别和划分的基础上,对矿区内花岗岩类进行了单颗粒锆石LA_ICP_MS锆石U_Pb测年,获得深灰色花岗斑岩的等时线年龄为(479.7±3.9)Ma,灰色黑云母花岗闪长岩为(109.7±1.1)Ma,浅灰色细粒白云母花岗岩为(103.3±1.2)Ma。辉钼矿Re_Os测年获得加权平均年龄为(97.4±1.9)Ma。由此可见,油麻坡岩体为一个复式岩体,由早奥陶世(加里东期)的花岗斑岩和早白垩世(燕山晚期)的黑云母花岗闪长岩和细粒白云母花岗岩组成,其中,黑云母花岗闪长岩构成油麻坡岩体的主体。钨钼矿形成于早白垩世晚期(即燕山晚期),与黑云母花岗闪长岩和白云母花岗岩密切相关。这些高精度测年数据的获得,进一步表明博白断裂带是一条长期活动的断裂,其在加里东期已经活动,并伴有岩浆岩的侵位。燕山晚期,该断裂重新复活,并导致大量的岩浆活动和一定强度的W_Mo_Sn_Pb_Zn_Sb_Au_Ag成矿作用,形成由多个大_中型矿床组成的多金属成矿带。博白_岑溪成矿带属于华南100~80 Ma大规模成矿的一部分,成矿背景与华南地区白垩纪的地壳伸展、钦杭成矿带的再次裂陷有关。     

湘中曹家坝大型钨矿床的主要矽卡岩矿物学特征及其地质意义

矽卡岩矿物特征是确定矽卡岩矿床成因的关键证据之一。曹家坝钨矿床是湘中盆地新探明的大型钨矿床,矿体呈似层状产于中泥盆统棋梓桥组灰岩与跳马涧组碎屑岩之间硅钙界面附近。矿区内发育大量矽卡岩矿物,但是未见到岩浆岩。文章通过钻孔编录、矿物的显微特征和电子探针分析,确定了曹家坝钨矿床的成因类型。研究表明曹家坝钨成矿作用与矽卡岩关系密切;石榴子石存在早、晚2个阶段,早阶段石榴子石以钙铝榴石和钙铁榴石为主,晚阶段以钙铝榴石和铁铝榴石-锰铝榴石为主;辉石以钙铁辉石为主;绿泥石主要是铁镁绿泥石。根据矽卡岩的矿物特征,结合发育磁黄铁矿和伴生金矿化等特征,提出曹家坝钨矿床可能是还原性远端矽卡岩型钨矿床。     

安徽铜陵凤凰山夕卡岩型铜矿床中辉钼矿Re-Os同位素年龄及其地质意义

铜陵矿集区是我国长江中下游Cu-Au-Fe-Mo成矿带中最重要的有色金属基地之一,凤凰山矿床是铜陵矿集区的重要组成部分,为一个典型的夕卡岩型铜矿床。本文利用Re-Os同位素定年方法对凤凰山铜矿床进行了成矿时代测定,获得了辉钼矿的Re-Os同位素模式年龄范围为139.1±2.4～142.0±2.2Ma,等时线年龄为141.1±1.4Ma,与矿区内石英二长闪长岩和花岗闪长岩SHRIMP锆石U-Pb年龄(144.2±2.3Ma)相吻合,也与铜陵地区其他矿田的成矿时代基本一致,可能为岩石圈减薄事件的成矿响应。     

江西永平铜矿床蚀变矿化分带、矿石组构及成矿过程

江西永平铜矿床位于江山-绍兴断裂带南缘、北武夷山燕山早期岩浆岩与海西期-印支期信江断裂坳陷带接合带,是一个伴生S-W-Pb-Zn多矿种的层状铜矿床。逆冲推覆构造控制着矿区内晚古生代地层、燕山期岩浆岩及矿体的空间分布,即基底周潭群逆冲推覆到晚古生界地层上,燕山早期黑云母花岗岩-花岗闪长岩、石英斑岩、花岗斑岩等沿逆冲推覆断面侵入,矿体呈层状产在矽卡岩化石炭系叶家湾组中。矿体围岩主要是石榴石矽卡岩、千枚状页岩及矽卡岩化大理岩。本文从矽卡岩分带、矿石组构等方面来刻画永平铜矿成矿精细过程。永平铜矿矿区的探采工程揭示,以火烧岗岩体为中心向外,蚀变矿物组合、石榴石颜色及矽卡岩的含矿性等表现出明显的分带规律,即从岩体到围岩有:石榴石→透辉石→硅灰石矽卡岩矿物分带;红色→棕色→绿色的石榴石颜色分带;矽卡岩含矿性先增加后降低,其中矿体主要在(红)棕色石榴石矽卡岩呈条带状或网脉状产出。矽卡岩型和变质砂页岩型矿石的矿石矿物组成均与硫化物-石英大脉(～10m)中矿石矿物组成相同或相似,均为黄铁矿-白钨矿-(方铅矿)-闪锌矿-黄铜矿,且生成顺序一致,说明矿区内不同类型的矿石是同一成矿热液体系在不同围岩类型及控矿构造中的产物。永平铜矿成矿过程可划分为石榴石、(磁)赤铁矿阶段、白钨矿阶段、铁铜硫化物阶段、铅锌硫化物阶段和碳酸盐阶段等六个阶段,其中石榴石阶段形成矽卡岩分带,在该阶段晚期形成磁黄铁矿-铁闪石-(黄铜矿)-石英块状矿石;(磁)赤铁矿阶段发育磁铁矿、赤铁矿;白钨矿阶段形成白钨矿及少量黑钨矿;铁铜硫化物阶段是铜硫矿主要矿化阶段,形成块状及脉状黄铜矿矿石;铅锌硫化物阶段是成矿晚期阶段;碳酸盐阶段代表原生成矿过程结束。     

锡霍特-阿林成矿带金属矿床成矿作用的演化

锡霍特-阿林构造带由兴凯地块、老爷岭-格罗杰科岛弧和东锡霍特-阿林造山带3个构造单元组成.其金属矿床成矿作用可分为3期：里菲纪末期至志留纪末,在兴凯区形成了喷流-沉积为主的铁（锰）矿、铅锌矿及岩浆热液型锡矿;二叠纪中期,在老爷岭-格罗杰科岛弧地区形成了浅成低温热液型金（银）矿和变质热液型金矿;侏罗纪至古近纪末,在东锡霍特-阿林构造带中形成了夕卡岩型钨床、浅成低温热液型金（银）矿、夕卡岩型及脉状硼矿和铅锌矿、脉状金矿等矿床.     

Molybdenite Re–Os,titanite and garnet U–Pb dating of the Magushan skarn Cu–Mo deposit,Xuancheng district,Middle–Lower Yangtze River Metallogenic Belt

The Magushan skarn Cu–Mo deposit is a representative example of the skarn mineralization occurring within the Xuancheng ore district of the Middle–Lower Yangtze River Metallogenic Belt of eastern China. The precise age of an ore deposit is important for understanding the timing of mineralization relative to other geological events in a region and to fully place the formation of a mineral deposit within the geological context of other processes that occur within the study area. Here, we present new molybdenite Re–Os and titanite and andradite garnet U–Pb ages for the Magushan deposit and use these data to outline possible approaches for identifying genetic relationships in geologically complex areas. The spatial and paragenetic relationships between the intrusions, alteration, and mineralization within the study area indicates that the formation of the Magushan deposit is genetically associated with the porphyritic granodiorite. However, this is not always the case, as some areas contain complexly zoned plutons with multiple phases of intrusion or mineralization may be distal from or may not have any clear spatial relationship to a pluton. This means that it may not be possible to determine whether the mineralization formed as a result of single or multiple magmatic/hydrothermal events. As such, the approaches presented in this study provide an approach that allows the identification of any geochronological relationships between mineralization and intrusive events in areas more complex than the study area. Previously published zircon U–Pb data for the mineralization-related porphyritic granodiorite in this area yielded an age of 134.2 ± 1.2 Ma (MSWD = 1.4) whereas the Re–Os dating of molybdenite from the study area yielded an isochron age of 137.7 ± 2.5 Ma (MSWD = 0.43). The timing of the mineralizing event in the study area was further examined by the dating of magmatic accessory titanite and skarn-related andradite garnet, yielding U–Pb ages of 136.3 ± 2.5 Ma (MSWD = 3.2) and 135.9 ± 2.7 Ma (MSWD = 2.5), respectively. The dating of magmatic and hydrothermal activity within the Magushan area yields ages around 136 Ma, strongly suggesting that the mineralization in this area formed as a result of the emplacement of the intrusion. The dates presented in this study also provide the first indication of the timing of mineralization within the Xuancheng district. providing evidence of a close genetic relationship between the formation of the mineralization within the Xuancheng district and the Early Cretaceous magmatism that occurred in this area. This in turn suggests that other Early Cretaceous intrusive rocks within this region are likely to be associated with mineralization and should be considered highly prospective for future mineral exploration. This study also indicates that the dating of garnet and titanite can also provide reliable geochronological data and evidence of the timing of mineralization and magmatism, respectively, in areas lacking other dateable minerals (e.g., molybdenite) or where the relationship between mineralization and magmatism is unclear, for example in areas with multiple stages of magmatism, with complexly zoned plutons, and with distal skarn mineralization.     

胶东晚中生代三期成矿岩体和3. 5 Ga锆石的发现及成矿动力学背景

胶东地区在晚中生代发生了大规模岩浆活动和"爆发式"成矿作用。为了深入研究岩浆活动的时代及其对成矿的影响,本文在对胶东晚中生代花岗岩类侵入岩及大规模成矿作用进行综合分析基础上,选择福山邢家山钼钨矿区、栖霞香夼铅锌矿区和福山王家庄铜矿区,对成矿岩体进行锆石U-Pb同位素年龄测试。测试结果表明,幸福山斑状二长花岗岩体(邢家山矿区)和香夼花岗闪长斑岩体的SHRIMP锆石U-Pb同位素年龄分别为159.3±1.6Ma和130.4±1.2Ma,养虎山石英闪长玢岩体(王家庄矿区)的LA-ICP-MS锆石U-Pb年龄为116.1±5.1Ma和119.8±1.8Ma,由此确定了三期岩浆活动及与之相对应的三期成矿事件。在晚侏罗世幸福山岩体中测得了前寒武纪残余锆石的年龄信息,三组年龄分别为3548±12Ma、2472.9～2400Ma和2192～1725Ma,指示岩浆物质来源于前寒武纪结晶基底的再循环作用。3548±12Ma是胶东地区迄今为止获得的最大年龄值,指示胶东地区存在古太古代早期的古老结晶基底。综合分析认为,胶东晚侏罗世岩浆活动和160Ma±的成矿事件是华北克拉通与扬子克拉通碰撞造山后续过程的产物,形成于挤压构造背景;早白垩世早期的岩浆活动及130Ma±成矿事件与太平洋板块俯冲有关,形成于挤压向伸展转化背景;早白垩世中晚期岩浆活动形成于拉张环境,与华北克拉通破坏和岩石圈伸展减薄有关,由此产生的胶东热隆-伸展构造体系,为115Ma±的金、银及有色金属等热液矿床大规模爆发式成矿提供了有利成矿条件。     

黑龙江省乌拉嘎金矿赋矿花岗闪长斑岩锆石 U-Pb年龄、岩石成因及其地质意义

黑龙江省是我国著名金矿产区之一,发育多个浅成低温热液型金矿,它们与中生代陆相火山-次火山岩有密切的关系,但对这些陆相火山-次火山岩的成因缺乏系统研究,制约了本区金矿的成因认识和矿床勘查。本次研究采用先进的LA-ICP-MS锆石定年法、地球化学Sr-Nd-Pb同位素示踪等方法,对与乌拉嘎浅成低温热液金矿存在密切成因联系的次火山岩(花岗闪长斑岩)进行深入研究。LA-ICP-MS锆石定年法获得乌拉嘎矿区葡萄沟岩体及其南部含矿岩枝的成岩年龄分别为108.2±1.2Ma和106±1.1Ma,与区内宁远村组火山岩成岩时间基本相近,推断金矿成矿时代为早白垩世晚期,与东安金矿和高松山金矿为同期。岩石地球化学确定该岩体为高钾钙碱性(σ=1.83~2.18)偏铝质I型花岗岩特征,结合微量元素和Sr-Nd-Pb研究显示其具有活动陆缘弧岩浆岩特点,进一步得出岩浆源区和成矿物质具有来源于新元古代形成的镁铁质下地壳的部分熔融的属性。早白垩世时,中国东部处于伸展应力体制下,尤其黑龙江构造活动强烈,起源于新生下地壳重融的岩浆活动频繁,结合已有的浅成低温热液金矿床资料显示,推断区内具有巨大的成矿潜力。     

安徽青阳高家塝钨钼矿床成岩成矿时代及其地质意义

高家塝钨钼矿床赋存于皖南青阳-九华山复式岩体北东缘接触带附近,是安徽省目前探明的规模最大的层控矽卡岩型白钨矿矿床。本文采用LA-ICP-MS方法对高家塝矿区花岗闪长岩和细粒花岗闪长斑岩的锆石进行U-Pb同位素定年,得到年龄分别为144.9±1.2Ma和145±2.0Ma。通过辉钼矿Re-Os等时线定年方法,得到高家塝矿床成矿时代为146.1±4.8Ma。皖南地区燕山期发育两期钨钼成矿作用,分别为146~136Ma和134~128Ma,类似于长江中下游成矿带,分别形成于挤压向拉张转换区和岩石圈快速拆沉减薄的两种构造背景。通过与钦杭成矿带典型钨钼矿床的对比发现,皖南地区钨钼成矿事件集中于燕山期,而钦杭成矿带钨锡成矿事件具有多阶段性。皖南地区同样发育大量与钦杭成矿带相似的花岗岩类岩浆岩,然而到目前为止皖南地区发现的钨锡矿床主要与中酸性花岗闪长岩类密切相关,仅少数矿床与钦杭成矿带成矿岩浆岩(均为高分异的花岗岩类)相似,同时皖南地区锡矿床找矿的突破,表明了皖南地区具有寻找与花岗岩类相关的钨钼矿床和锡矿床的潜力。     

华北克拉通南缘卢氏多金属矿集区硫化物Rb-Sr定年及地质意义

华北克拉通南缘秦岭成矿带发育大量金矿、钼矿及铅锌多金属矿床。卢氏多金属矿集区位于东秦岭成矿带,主要矿床有夜长坪钼钨矿、八宝山铁铜矿、楼房银铜矿、柳关铅锌矿等。其中楼房银铜矿为热液脉状多金属矿床,矿床赋存于太华群角闪斜长片麻岩中,矿体受构造蚀变破碎带控制,矿床中划分出两个成矿阶段:石英-黄铁矿-黄铜矿组合和石英-黄铁矿-方铅矿-闪锌矿-方解石组合,其中前者是铜成矿阶段,后者为铅锌成矿阶段。柳关铅锌矿为矽卡岩矿床,矿体产于官道口群白云岩与花岗斑岩岩体或隐爆角砾岩接触矽卡岩化带内,矿床划分出两个成矿阶段:透辉石-透闪石-阳起石-石榴石-磁铁矿组合和方铅矿-闪锌矿-黄铁矿-绿帘石-蛇纹石-石英-方解石组合,前者为磁铁矿成矿阶段,后者是铅锌成矿阶段。金属硫化物定年结果表明,楼房银铜矿黄铜矿Rb-Sr等时线年龄为127. 8±3. 1Ma(2σ,MSWD=1. 1),初始87Rb/86Sr为0. 710998±0. 000068;柳关铅锌矿黄铁矿Rb-Sr等时线年龄为124. 8±1. 6Ma(2σ,MSWD=1. 4),初始87Rb/86Sr为0. 711074±0. 000064。研究表明卢氏多金属矿集区内热液多金属矿床形成于早白垩世,其形成与区内早白垩世岩浆活动有关。综合区域地质研究,区内多金属矿床形成于早白垩世与克拉通破坏有关的构造环境。     

云南北衙地区钨矿化特征与找矿方向

云南北衙矿床是中国21世纪初新发现的超大型矽卡岩-斑岩型金多金属矿床之一,除已经勘查评价的Au、Fe、Cu、Pb、Zn等元素外,还伴生有一定量的W元素等有益组分。文章对北衙金多金属矿床万硐山矿段及外围马头湾和南大坪矿区中的钨矿化开展系统的岩石学和矿物学研究,初步查明了万硐山矿段和其外围矿床中的钨矿化特征。研究发现,这些矿区(段)的含钨矿物主要为白钨矿,在万硐山矿段和马头湾矿区还有少量的黑钨矿产出;钨矿化主要产于岩体与围岩地层接触部位的矽卡岩或其退化蚀变岩中,白钨矿多充填在石榴子石等矿物的晶体间隙,个别被石榴子石包裹(南大坪矿区);万硐山矿段和马头湾矿区中的白钨矿具有较高的w(Mo)。这些特征表明,北衙地区的钨矿化作用与典型矽卡岩型白钨矿矿床基本一致。万硐山矿段中白钨矿交代黑钨矿的过程与磁铁矿的结晶过程密切相关,暗示钨矿化与铁、金矿化作用是同一成矿作用的产物。北衙地区的区域土壤W元素地球化学异常具有良好的浓度分级,且部分异常中心与已知的矿床/点明显对应,说明北衙地区具有良好的钨矿找矿潜力,白钨矿和黑钨矿均可以作为找矿标志性矿物,而Mo元素地球化学异常则可以作为间接找矿标志。     

云南南秧田钨矿床流体包裹体特征及其意义

对南秧田矽卡岩型钨矿床的石英和石榴石流体包裹体的岩相学特征研究表明,与成矿有关的包裹体主要有3类:富液相、富气相和含子晶的多相包裹体。石英包裹体均一温度范围为232～337℃,盐度w(NaCl)=0.53%～9.98%;石榴石包裹体的均一温度范围为228～306℃,盐度w(NaCl)=6.45%～14.04%。激光拉曼探针分析表明,南秧田白钨矿的成矿流体中气相成分以H2O为主,含少量CO2、CH4、H2S和N2等气体,液相成分以H2O为主,属NaCl-H2O流体体系。成矿溶液的密度为0.72～0.87g/cm3,表明形成这种矽卡岩型矿床的成矿流体均属于中温、低盐度、低密度的流体。成矿压力为18～32MPa,成矿深度约为0.6～1.2km。石英包裹体水的δD为-72.16‰～-65.10‰,δ18O为7.98‰～8.45‰,钨矿床中硫化物δ34S为6.6‰。成矿流体主要来自燕山晚期的岩浆热液作用。     

吉林四平三家子钨矿床闪长玢岩脉与钨矿化关系探讨

四平三家子钨矿床是近年来在东北地区发现的一个矽卡岩型白钨矿矿床。矿区内脉岩发育,闪长玢岩脉空间上控制着钨矿体的产出,与钨矿化空间关系密切,是该区重要的找矿标志。该闪长玢岩为成矿前脉岩。结合闪长玢岩、成矿花岗岩体以及钨矿石的微量元素、稀土元素分析,认为三家子钨矿区内的闪长玢岩脉与成矿花岗岩体、钨矿石主要微量元素含量具有一定的相似性,稀土元素组成具有可比性,成因上应属同源关系。     

鄂东南铁铜矿集区铜山口铜(钼)矿床40Ar/39Ar年代学及对区域成矿作用的指示

铜山口铜-钼矿床发育有夕卡岩型和斑岩型两类矿化,是鄂东南矿集区内典型的夕卡岩-斑岩复合型矿床。成矿作用与铜山口花岗闪长斑岩岩株和大冶群碳酸盐岩有关,矿体主要沿两者的接触带分布。本文利用激光阶段加热技术分别对两类矿化有关的蚀变矿物金云母和绢云母进行40Ar／39Ar年龄测定。结果表明,铜山口矿区经历了两次蚀变一矿化事件:铜山口矿床成矿作用发生于约143±0．3 Ma,而矿区东南缘的牛鼻峰石英二长斑岩的热液蚀变发生于约129 Ma。牛鼻峰石英二长斑岩的侵位及蚀变对铜山口矿床斑岩型矿化的部分地段产生热扰动, 导致绢云母40Ar／39Ar年龄比实际矿化蚀变年龄偏年轻。铜山口矿区两次蚀变-矿化年龄分别与长江中下游成矿带早晚两期成岩成矿事件(145-133 Ma和130-120 Ma)一致。岩石圈伸展及幔源玄武质岩浆底侵作用可能是区域上大规模岩浆活动与成矿作用的深部地球动力学因素。     

Palladium, Platinum and Gold Concentrations in Fengshan Porphyry Cu–Mo Deposit, Hubei Province, China

Abstract: The Fengshan porphyry-skarn copper–molybdenum (Cu–Mo) deposit is located in the south-eastern Hubei Province in east China. Cu–Mo mineralization is hosted in the Fengshan granodiorite porphyry stock that intruded the Triassic Daye Formation carbonate rocks in the early Cretaceous (~140 Ma), as well as the contact zone between granodiorite porphyry stock and carbonate rocks, forming the porphyry-type and skarn-type association. The Fengshan granodiorite stock and the immediate country rocks are strongly fractured and intensely altered by hydrothermal fluids. In addition to intense skarn alteration, the prominent alteration types are potassic, phyllic, and propylitic, whereas argillation is less common. Mineralization occurs as veins, stock works, and disseminations, and the main ore minerals are chalcopyrite, pyrite, molybdenite, bornite, and magnetite. The contents of palladium, platinum and gold (Pd, Pt and Au) are determined in nine samples from fresh and mineralized granodiorite and different types of altered rocks. The results show that the Pd content is systematically higher than Pt, which is typical for porphyry ore deposits worldwide. The Pt content ranges from 0.037 to1.765 ppb, and the Pd content ranges between 0.165 and 17.979 ppb. Pd and Pt are more concentrated in porphyry mineralization than skarn mineralization, and have negative correlations with Au. The reconnaissance study presented here confirms the existence of Pd and Pt in the Fengshan porphyry-skarn Cu–Mo deposit. When compared with intracontinent and island arc geotectonic settings, the Pd, Pt, and Au contents in the Fengshan porphyry Cu–Mo deposit in the intracontinent is lower than the continental margin types and island are types. A combination of available data indicates that Pd and Pt were derived from oxidized alkaline magmas generated by the partial melting of an enriched mantle source.