会昌早白垩世橄榄玄粗岩(shoshonite)成因的元素及Sr-O-Nd-Pb同位素地球化学证据

根据赣南会昌地区中基性火山岩高碱、富钾、低钛、贫铁,岩石中斜长石斑晶具钾长石环边,基质中存在大量钾长石微晶,以及富集轻稀土元素和大离子亲石元素等矿物岩石地球化学特征,确切厘定会昌地区的中基性火山岩为橄榄玄粗岩安粗岩组合,属典型的大陆板内橄榄玄粗岩系列火山岩。对会昌橄榄玄粗岩进行了RbSr同位素定年研究,确定其全岩RbSr等时线年龄为107.3±2.3Ma。 会昌橄榄玄粗岩系火山岩SrONdPb 同位素组成的特征为: 偏高的 ISr(0.7098~0.7115); 较低的δ18O值(5.3‰~7.0‰);中等的εNd(t)(-0.61~-3.60); 富放射性成因铅((206Pb/204Pb)i=17.32~18.29, (207Pb/204Pb)i=15.34~15.65, (208Pb/204Pb)i =37.51~38.60)。会昌橄榄玄粗岩的Δ7/4Pb值为-7.8~+16.8(平均值为+5.42), Δ8/4Pb值为27.3~97.3 (平均值为68.04), ΔSr值为96.2~114.1 (平均值为104.3),这表明存在典型的Dupal 同位素异常。根据SrO, SrNd, SrPb, NdPb, PbPb同位素相关特征, 判明会昌橄榄玄粗岩是由亏损地幔端元(DM)和岩石圈富集地幔端元(EM)在源区混合形成的。按SrNd双变量二元混合模型计算得出源区物质中亏损地幔端元和富集地幔端元所占份额各占50%左右。会昌早白垩世橄榄玄粗岩系火山岩带的形成反映了华南板块内部在燕山晚期发生的一起重要的伸展构造事件     

板内橄榄玄粗岩(shoshonite)地幔流体交代作用及成因的元素地球化学证据:以赣南会昌橄榄玄粗岩为例

根据稀土元素和微量元素ICP-MS分析结果,通过对流体作用敏感的元素对比值(U/Th、Pb/Ce、Ba/La、Cs/Rb和Ce/Y等)的研究对比,为赣南会昌橄榄玄粗岩的形成有地幔流体交代作用参与提供了重要的地球化学证据.应用主元素氧化物(K2O、Na2O、FeOT、CaO、MgO和TiO2)与SiO2的变异分析,判明会...     

可可西里雄鹰台中新世橄榄安粗质火山岩的成因

可可西里雄鹰台火山熔岩的全岩K-Ar年龄为11.1-12.8Ma,SiO2含量为55.28%-58.65%,K2O含量为3.52%-4.42%，属橄榄安粗岩系列，主要岩类为橄榄安粗岩和安粗岩，富集轻稀土（LREE）和大离子亲石元素（K、Rb,Cs,Sr,Ba,U,Th)，Sr同位素比值（^87Sr/^86Sr)较高，在0.7082-0.7086之间，Nd同位素比值（^143Nd/^144Nd)较低，在0.51236-0.51243之间，^206Pb/^204Pb,^207Pb/^204Pb,^208Pb/^204Pb的比值大体分别在18.58-18.70,15.60-15.68,37.98-38.33之间变化，微量元素和同位素地球化学示踪研究表明，火山岩源区为富集的地幔类型（EMⅡ），该类型地幔的形成与缝合带的成因有关，火内岩在时空及成因上与昆仑南缘断裂的活动有密切的关系。     

阿吾拉勒东部巩乃斯林场橄榄玄粗岩岩石地球化学特征及地质意义

西天山阿吾拉勒地区东部巩乃斯附近晚石炭世大哈拉军山组中分布着典型的橄榄玄粗岩,该岩石具高K_2O(3.09%～4.26%)、K_2O/Na_2O(0.67～1.20)和高Al_2O_3(20.30%～20.50%)特征,但是其成因还没有得到很好的限制。巩乃斯橄榄玄粗岩由具较富集的Sr-Nd同位素组成((~(87)Sr/~(86)Sr)_I=0.704 471～0.704 784;εNd (t)=3.76～3.83),说明其源自于富集地幔源区。通过地球化学数据模拟发现该橄榄玄粗岩起源于尖晶石二辉橄榄地幔,相对于岩石圈地幔具较低的Ba/Rb和高Rb/Sr,结合其较高Th/Nb (1.93～1.99)比值和Th (11.63×10~(-6)～12.18×10~(-6))含量,指示岩石富钾的特征很可能与再循环俯冲沉积物的加入有关;该岩石的高铝含量特征是由于岩浆中水含量较高导致斜长石结晶较晚形成的,而岩浆富水的特征可能与俯冲板片后撤导致板片脱水加强有关。结合该岩石地球化学特征和区域地质背景,认为巩乃斯橄榄玄粗岩形成于俯冲-碰撞转换阶段,是西天山地区构造体制转换阶段岩浆作用的产物。     

赣中早白垩世橄榄玄粗岩（Shoshonite）系列火山岩的厘定及成因研究

对赣中地区打鼓顶组第四岩性段中基性火山岩的岩石-地球化学特征系统研究表明,这一岩性段的火山岩具有高碱、 富钾、低钛、贫铁以及富集轻稀土和大离子亲石元素等特征,据此厘定其为橄榄玄粗岩-安粗岩组合,属典型的大陆板内橄 榄玄粗岩系列火山岩。这套火山岩的全岩Rb-Sr等时年龄为（138±8.8） Ma, I Sr偏高,中等的εN（d t）,富放射性成因铅。盛 源盆地及邻区橄榄玄粗岩系列火山岩的△7/4Pb值为14~19.6（ 平均值为16）,△8/4Pb值为70.5~97（ 平均值为89.2）,△Sr值为 121.5~161.8（ 平均值为136.3）,显示存在典型的Dupal同位素异常。根据Sr-Nd,Sr-Pb,Nd-Pb,Pb-Pb同位素相关性分析,判 明赣中地区橄榄玄粗岩是由亏损地幔端元（DM）和岩石圈富集地幔端元（LEM）在源区混合形成的。按Nd,Sr双变量二元 混合方程式计算,得出源区物质中亏损地幔端元（DM）和岩石圈富集地幔端元（LEM）所占份额分别为37%（平均值）和 63%（ 平均值）。赣中地区早白垩世橄榄玄粗岩系火山岩的形成反映了华南板块内部在燕山晚期发生的一起重要的伸展构造 事件。     

赣南会昌橄榄玄粗岩矿物组合特征及成因研究

赣南会昌地区中基性火山岩的斜长石斑晶具有钾长石环边,基质中存在大量钾长石微晶的矿物组合特征,为其归属于橄榄玄粗岩系列提供了矿物学证据。基质中钾长石微晶与斜长石微晶共存暗示了会昌橄榄玄粗岩的地幔源区混合成因,与根据Sr-Nd-O-Pb同位素地球化学特征研究得到的结果一致。电子探针分析表明会昌橄榄玄粗岩中的角闪石属于钙质角闪石亚类,为镁绿钙闪石。采用3种钙质角闪石Al地质压力计及CaO地质温度计估算会昌橄榄玄粗岩中角闪石的形成压力约为8.03×108Pa,温度为985℃。角闪石的晶体化学特征表明会昌镁绿钙闪石形成于上地幔,从而为会昌橄榄玄粗岩的幔源成因提供了重要依据。     

草桃背矿床白垩纪橄榄玄粗岩与铀成矿关系

赣南会昌断陷盆地沿石城-寻乌深断裂分布一条白垩纪橄榄玄粗岩系列的火山岩带。草桃背大型铀矿床内出露大富足岩体中-粗粒黑云母花岗岩及早白垩世晚期到晚白垩世早期橄榄玄粗岩系列火山岩。大富足花岗岩体岩石w(SiO₂)平均为74.67％,碱总量(w（K₂O+Na₂O）)平均为7.99％,w(K₂O)>w(Na₂O),w(CaO)平均为0.54％,w(Al₂O₃)>w(CaO+Na₂O+K₂O),属高钾钙碱性岩石系列。橄榄玄粗系列火山岩岩石w(SiO₂)为45.78 %~59.78 %,w(K₂O+Na₂O)平均为7.37%,K₂O/Na₂O平均为1.02,w(TiO₂)平均为0.86%, 全铁质量分数平均为7.09%,属偏碱性橄榄玄粗质火山岩类。草桃背铀矿床赋矿岩性为橄榄玄粗岩、碎裂花岗岩及隐爆角砾岩。赋存于碎裂花岗岩及隐爆角砾岩中铀矿石化学成分,与围岩花岗岩成分相似;赋存于橄榄玄粗岩中铀矿石,Fe₂O₃+Fe₂O、CaO、MgO不同程度地带出,w(SiO₂)明显增高,表明橄榄玄粗岩在成矿过程中,通过输出大量Fe、Mg、Ca等阳离子而促进铀离子从含矿溶液中沉淀。草桃背矿床的铀矿化与充填在草桃背火山口的橄榄玄粗岩关系密切,在时间上相近、在空间上相伴、在成生上相关,受橄榄玄粗岩岩浆系列热动力的影响,铀元素发生活化、转移或物质交换而成矿,成岩成矿时代属早白垩世晚期到晚白垩世早期。从草桃背铀矿床岩石学、地球化学及赋矿特征入手,总结了铀成矿是富铀矿的花岗岩基底、北东向构造及火山作用结合的产物,橄榄玄粗岩提供热源,并指出半岭、上寮、小富足等地段是寻找草桃背式铀矿床的极有利地区。     

长江中下游地区晚中生代橄榄玄粗岩系列火山岩:年代学格架、地球化学特征及成因讨论

长江中下游地区晚中生代橄榄玄粗岩系列火山岩发育在宁芜、庐枞、溧水和怀宁四个火山岩盆地内,该系列的火山岩地球化学性质上以相对富碱、高K、明显富集Rb、Th、U、K等强不相容元素和轻稀土元素,亏损高场强元素Nb、Ta和Ti为特征。Ba和Sr的特征在不同盆地内随岩性的不同表现各异,表明斜长石的分离结晶可能在这些盆地内岩浆演化过程中起着一定的作用。这些盆地内橄榄玄粗岩系列火山岩的部分地球化学性质(如Ce/Yb比值)与大多数发育在大陆环境下的橄榄玄粗岩系列岩石不同,而类似于大洋岛弧环境内的同类岩石,可能意味着区内由于岩石圈的减薄,软流圈地幔上涌到了相对较浅的部位,控制源区部分熔融的主要是尖晶石相地幔岩。这些火山岩的Sr、Nd同位素组成总体处于扬子克拉通岩石圈地幔附近,指示它们的母岩浆主要是由富集的岩石圈地幔部分熔融形成的。但盆地所处的构造位置对岩浆的性质也有显著的影响,指示地壳基底物质的混染也不同程度存在。区内榄玄粗岩系列火山活动持续的时间很短,主要集中在约128~134 Ma左右,峰值约130Ma,其成因的动力学机制可能与晚中生代发生在中国东部的岩石圈减薄事件有关,橄榄玄粗岩系列火山岩盆地所在地带对应着长江中下游地区岩石圈减薄的中心部位。     

长江中下游晚中生代橄榄玄粗岩系列火山岩:年代学格架、地球化学特征及成因讨论

长江中下游晚中生代橄榄玄粗岩系列火山岩发育在宁芜、庐枞、溧水和怀宁四个火山岩盆地内,该系列的火山岩地球化学性质上以相对富碱、高K、明显富集Rb、Th、U、K等强不相容元素和轻稀土元素,亏损高场强元素Nb、Ta和Ti为特征。Ba和Sr的特征在不同盆地内随岩性的不同表现各异,表明斜长石的分离结晶可能在这些盆地内岩浆演化过程中起着一定的作用。这些盆地内的橄榄玄粗岩系列火山岩的部分地球化学性质(如Ce/Yb比值)与大多数大陆环境下的橄榄玄粗岩系列岩石不同,而类似于大洋岛弧内的,可能意味着区内由于岩石圈的减薄,软流圈地幔上涌到了相对较浅的部位,控制源区部分熔融的主要是尖晶石相地幔岩。这些火山岩的Sr、Nd同位素组成总体处于扬子克拉通岩石圈地幔附近,指示这些橄榄玄粗质母岩浆主要是由富集的岩石圈地幔部分熔融形成的。但盆地所处的构造位置对岩浆的性质也有显著的影响,指示地壳基底物质的混染也不同程度存在。区内榄玄粗岩系列火山活动持续的时间很短,主要集中在约128134 Ma左右,峰值约130 Ma,其成因的动力学机制可能与晚中生代发生在中国东部的岩石圈减薄事件有关。     

安徽庐枞火山岩盆地橄榄玄粗岩系的地球化学特征及其对下扬子地区晚中生代岩石圈减薄机制的约束

庐枞盆地内的中生代火山-潜火山岩具高钾和相对富碱为特性,属典型的橄榄玄粗岩系列。它们在地球化学上表现出明显富集Rb、Th、U、K等强不相容元素和轻稀土元素,亏损高场强元素Nb和Ta的特征。Nd、Sr同位素组成总体位于富集型的扬子克拉通岩石圈地幔的范围内或其附近,显示其母岩浆主要是由富集型地幔部分熔融形成的。火山-潜火山岩的成分变异趋势显示橄榄玄粗质幔源岩浆在高压下(斜长石稳定压力之下,1.5GPa)经历过以单斜辉石和钛铁氧化物为主的矿物分离结晶作用。低压下矿物的分离结晶作用及上地壳物质的混染则不明显。这套火山-潜火山岩的部分地球化学性质(如Ce/Yb比值)类似于大洋岛弧内的橄榄玄粗岩,可能意味着区内由于岩石圈的减薄,软流圈地幔上涌到了岩石圈相对较浅的部位,控制源区部分熔融的主要是尖晶石相地幔岩。虽然局部(如靠近郯庐断裂的盆地西缘)可能存在着明显的热侵蚀,但"突发性的"机械拆沉是区内(乃至整个长江中下游地区)岩石圈减薄的主要机制。在整个晚中生代岩石圈减薄的过程中,这两种机制可能一直相互促进着。     

Uranium isotopic disequilibrium for groundwater classification: first results on complexe terminal and continental intercalaire aquifers in Southern Tunisia

A fractionation of uranium (U) series into parent–daughter pairs – ²³⁴U and ²³⁸U – always occurs in natural waters, and the disequilibria between these is commonly used as a tracer of groundwater flow. We report here an interpretation of the U-content and U isotope disequilibria in groundwater sampled from the deep Complexe Terminal and Continental Intercalaire aquifers of southern Tunisia. Variations in both the contents of these isotopes (0.006–2.4 ppb) and ²³⁴U/²³⁸U activity ratios (ARs) (1.7–15.4) were observed. The data could be plotted in two distinct fields of reciprocal U concentration versus ²³⁴U/²³⁸U AR according to groundwater flow and regional bedrock differences. An initial assessment aimed at verifying whether the results of this investigation support those of previous hydrogeological and isotope studies, thereby suggesting that the disequilibrium between U isotopes in groundwater may represent a useful tool for hydrogeological investigations of deep and fossil groundwater. In addition, the disequilibrium can be used for quantifying the recharge or mixing rates between different formations with the aim of delineating the preferential outflow pattern or determining residence times of waters.     

Dissolved Uranium and 234U/238U in the Yamuna and the Chambal Rivers, India

Dissolved uranium concentration and ²³⁴U/²³⁸U activity ratio have been measured in two distinctly different Indian drainage systems: the Yamuna headwaters in the Himalaya and the Chambal river system in the plains to study the weathering and mobility of uranium in these watersheds. The dissolved uranium in the Chambal river system ranges from 0.2 to 1.74 μg L⁻¹ during September (tail end of monsoon), whereas in the Yamuna river system, its concentration varies from 0.1 to 3.18 μg L⁻¹ during October (post-monsoon) and from 0.09 to 3.61 μg L⁻¹ in June (summer). In the Yamuna main stream, uranium is highest at its source and decreases steadily along its course, from 3.18 μg L⁻¹ at Hanuman Chatti to 0.67 μg L⁻¹ at Batamandi, at the base of the Himalaya. This decrease results mainly from mixing of the Yamuna mainstream with its tributaries, which are lower in uranium. The high concentration of uranium at Hanuman Chatti is derived from weathering of the Higher Himalayan Crystalline series (HHC) and associated accessary minerals, which may include uranium-mineralised zones. The ²³⁴U/²³⁸U activity ratios in the samples from the Chambal watershed are in the range of 1.15±0.05 to 1.67±0.04; whereas in the Yamuna the ratios vary from 0.95±0.03 to 1.56±0.07, during post-monsoon and from 0.98±0.01 to 1.30±0.03, during summer. The relatively high ²³⁴U/²³⁸U activity ratios in the Yamuna system are in its tributaries from the lower reaches viz., the Amlawa, Aglar, Bata, Tons and the Giri. It is estimated that ~9×10³ and ~12 × 10³ kg of dissolved uranium are transported annually from the Yamuna at Batamandi and the Chambal at Udi, respectively. This corresponds to uranium weathering rates of 0.9 and 0.09 kg U km⁻² y⁻¹ in the basins of the Yamuna and the Chambal headwaters. This study confirms that uranium weathering rate in the Himalaya is far in excess (by about an order of magnitude) of the global average value of ~0.08 kg U km⁻² y⁻¹.     

四川盆地北部砂岩型铀矿床矿物学特征与矿床成因

本文基于对四川盆地北部砂岩型铀矿体地表露头和坑道伽玛强度测量、铀矿物特征分析,通过样品岩矿测试与鉴定、扫描电镜分析等手段,对铀矿床(点)铀矿石的铀品位、矿物组成、化学成分、结构构造和铀的存在形式进行了研究。结果显示,铀矿石为钙质胶结岩屑石英细-中粒砂岩,其中岩屑以变质岩为主,含有火山岩和花岗岩碎屑,反映铀成矿物质来源于米仓山基底花岗岩和下震旦统铁船山组火山岩;铀矿物主要是铀石,少量沥青铀矿;铀矿石具交代结构,反映了铀矿床的后生富集成因。     

Biogeochemical processes of incorporation, transformation and migration of organic matter at the marine water-sediment interface: Simulation by C labelled compounds

The study of biogeochemical processes at the water-sediment interface must be able to explain the relatively small content of organic carbon in the sediment, compared to the calculated carbon flux in the oceans. The input of an organic molecule at the marine sediment surface (Gulf of Lion, France) was simulated by the injection of a ¹⁴C labelled molecule in the water of a preserved interface. A glutamic acid [¹⁴C(U)] simulated marine organic matter, whereas a catechol [¹⁴C(U)] represented continental organic material. The separation by successive acid and basic extractions of the remaining initial compounds and the resulting products showed the relative importance of biological (respiration, assimilation) and geochemical (adsorption on argillaceous particles and condensation in geopolymers) processes occurring at the water-sediment interface. The evaluation was supported by the determination of the geochemical (humic substances), hydrological (conditions of temperature and degree of oxygénation) and sedimentological characteristics of the environment studied and by the estimation of the benthic activity.     

岩溶洞穴次生碳酸盐沉积铀及其同位素组成古气候环境研究进展

洞穴沉积铀含量及其同位素初始234U/238U[（234U/238U)0]变化均与过去气候环境变化关系密切。文章分别对石笋中U含量和(234U/238U)0的气候意义进行统计分析发现,多数研究认为洞穴沉积U含量和(234U/238U)0可能指示土壤湿度和有效降水变化。然而,不管是对洞穴沉积的U含量还是(234U/238U)0,其气候环境意义解读还存在两种观点。但无论如何,这些研究成果都显示了洞穴沉积的U含量和(234U/238U)0是研究过去气候环境变化的重要替代指标。在未来的研究中,除了土壤环境和过程,还应关注U来源的相对贡献变化和其他微量元素与U元素的关系。这一指标可能在对东亚地区的大气粉尘活动和冬季风演化、地表生物量的变化研究等方面发挥重要作用。      

Timing of mineralization and deformation,Peak Au mine,Cobar, New South Wales∗

The ⁴⁰Ar/³⁹Ar dating of alteration muscovite from the Peak Au mine in the Early Devonian Cobar Basin, New South Wales, has distinguished two major episodes of mineralization. Veined (Pb‐Zn‐Cu‐Au) mineralization was broadly synchronous with cleavage formation during the post‐inversion, shortening deformation of the basin sedimentary rocks, and replacive Ag‐Pb‐Zn mineralization significantly postdates the latter event. Veined base metals (Pb‐Zn‐Cu) and Au associated with silicification were coeval with three stages of cleavage formation (D₁, D₂ and D₃) after basin inversion. The Cu‐Au phase of mineralization at the Peak Au mine which was broadly contemporaneous with the culmination of the cleavage‐forming events (D₃) and with the local development of high‐strain zones occurred at 401.5 ± 1.0 Ma (⁴⁰Ar/³⁹Ar on muscovite). This date is essentially coeval with known fossil constraints on the age of basin formation, and indicates that basin inversion and deformation rapidly followed sedimentation. In contrast, replacive Ag‐Pb‐Zn mineralization occurred at 384.0 ± 1.4 Ma (⁴⁰Ar/³⁹Ar on muscovite) during an extended period of relaxation characterized by normal faulting (D₄) which followed the shortening deformation. This mineralization was associated with desilicification and chlorite‐muscovite replacement assemblages which cross‐cut the cleavages, and which may have been broadly contemporaneous with the deposition of part of the Mulga Downs Group which unconformably overlies the Cobar Supergroup. Rhyolite exposed in the core of the Peak Au mine largely contains inherited zircons that range in age from ～430–1500 Ma. A few euhedral zircons have an age of ～430 Ma and this is interpreted as a maximum date for the rock. Zircons from a syn‐D₃ chlorite‐muscovite replacement zone within the deposit have ²⁰⁶Pb/²³⁸U ages of ～410–650 Ma and are apparently inherited.     

Stratigraphy and tectonic evolution of the Kazdağı Massif (NW Anatolia) based on field studies and radiometric ages

The Kazda?? Massif was previously considered as the metamorphic basement of the Sakarya Zone, a microcontinental fragment in NW Anatolia. Our new field mapping, geochemical investigations, and radiometric dating lead to a re-evaluation of previous suggested models of the massif. The Kazda?? metamorphic succession is subdivided into two major units separated by a pronounced unconformity. The lower unit (the Tozlu metaophiolite) is a typical oceanic crust assemblage consisting of ultramafic rocks and cumulate gabbros. It is unconformably overlain by a thick platform sequence of the upper group (the Sar?k?z unit). The basement ophiolites and overlying platform strata were subjected to a single stage of high-temperature metamorphism under progressive compression during the Alpine orogeny, accompanied by migmatitic metagranite emplacement. Radiometric age data obtained from the Kazda?? metamorphic succession reveal a wide range of ages. Metagranites of the Kazda?? metamorphic succession define a U–Pb discordia upper intercept age of ca. 230 Ma and a lower intercept age of 24.8 ± 4.6 Ma. This younger age agrees with ²⁰⁷Pb/²⁰⁶Pb single-zircon evaporation ages of 28.2 ± 4.1 to 26 ± 5.6 Ma. Moreover, a lower intercept age of 28 ± 10 Ma from a leucocratic metagranite supports the Alpine ages of the massif within error limits. Reconnaissance detrital zircon ages constrain a wide range of possible transport and deposition ages of the metasediments in the Sar?k?z unit from ca. 120 to 420 Ma. Following high-temperature metamorphism and metagranite emplacement, the Kazda?? sequence was internally imbricated by Alpine compression, and the lowermost Tozlu ophiolite thrust southward onto the Sar?k?z unit. Field mapping, internal stratigraphy, and new radiometric age data show that the Sar?k?z unit is the metamorphic equivalent of the Mesozoic platform succession of the Sakarya Zone. The underlying metaophiolites are remnants of the Palaeo tethys Ocean, which closed during the early Alpine orogeny. After strong deformation attending nappe emplacement, the unmetamorphosed Miocene Evciler and Kavlaklar granites intruded the tectonic packages of the Kazda?? Massif. During Pleistocene time, the Kazda?? Massif was elevated by EW trending high-angle normal faults dipping to Edremit Gulf, and attained its present structural and topographic position. Tectonic imbrication, erosion and younger E–W-trending faulting were the main cause of the exhumation of the massif.     

诸广中部鹿井铀矿田辉绿岩磷灰石U- Pb年龄、地球化学特征及其与铀成矿关系

辉绿岩脉与热液型铀矿化关系十分密切。本文以鹿井矿田辉绿岩为研究对象,通过野外地质调查、磷灰石U-Pb年代学和地球化学研究,旨在探究其成岩时代、岩石成因、成岩构造背景及其与铀成矿关系,为探讨区域铀成矿机制提供依据。辉绿岩中磷灰石的U-Pb定年指示,辉绿岩的成岩年龄为~200 Ma,是诸广—贵东地区200~190 Ma基性岩浆活动的重要组成。辉绿岩地球化学组成类似于洋岛玄武岩（OIB）特征,形成于早侏罗世—晚三叠世之交的岩石圈伸展构造背景下,岩浆起源于亏损地幔源区被流体交代的石榴石橄榄岩经过约5%~10%部分熔融,成岩过程经历了一定程度的分离结晶和地壳混染作用。鹿井矿田主要铀矿床的成矿年龄为128~51 Ma,明显早于区内辉绿岩的成岩时代（~200 Ma）,因此,由~200 Ma的基性岩浆活动直接提供成矿所需的矿化剂∑CO2的可能性较小。辉绿岩在鹿井矿田“交点”型矿化的形成过程中,不仅提供了有利的氧化—还原界面,而且基性岩浆侵位时所形成的次级构造裂隙还为成矿提供了有利的空间。     

LA-ICP-MS工作参数优化及在锆石U-Pb定年分析中的应用

将激光器(LA)和电感耦合等离子体质谱仪(ICP-MS)联用避免了溶液分析繁琐、耗时的前处理操作,减少了样品制备过程中可能带来的污染,同时又具备分析成本低、测试速度快、分析数据精度高等优势。本文将LA与ICP-MS联接使用,通过激光能量密度和剥蚀频率组合来讨论较低的元素分馏效应,同时匹配RF功率、采样深度、载气及He气流速等主要工作参数以获得较高的元素信号灵敏度和稳定性,从而得到仪器最优工作参数组合,建立了可靠的锆石U-Pb定年方法。通过对锆石标样91500、GJ-1及Ple2ovic互测结果表明,其206Pb/238U加权平均年龄分别为1063.9±6.0 Ma(2σ,n=20)、600.3±2.6 Ma(2σ,n=27)及337.6±1.7 Ma(2σ,n=20),测试结果准确度和精度均在1%范围内,与前人报道的误差范围一致。使用优化后的仪器参数对来自鄂东南铜绿山矿区石英正长闪长玢岩岩体中的实际锆石样品进行测试,获得其206Pb/238U年龄与前人研究结果基本一致,表明本法能准确地对锆石进行定年分析。     

Highly retentive core domains in K-feldspar and their implications for 40Ar/39Ar thermochronology illustrated by determining the cooling curve for the Capoas Granite,Palawan, The Philippines

K-feldspar from the late Miocene Capoas Granite on Palawan in The Philippines appears to contain highly retentive diffusion domains that are closed to argon diffusion at near-solidus temperatures during cooling of this ～7 km-diameter pluton. This is an important result, for K-feldspar is commonly considered not retentive in terms of its ability to retain argon. Closure temperatures for argon diffusion in K-feldspars are routinely claimed to be in the range ～150–400°C but the release of ³⁹Ar from irradiated K-feldspar during furnace step-heating experiments in vacuo yields Arrhenius data that imply the existence of highly retentive core domains, with inferred closure temperatures that can exceed ～500–700°C. These high closure temperatures from the Capoas Granite K-feldspar are consistent with the coincidence of ⁴⁰Ar/³⁹Ar ages with U–Pb zircon ages at ca 13.5 ± 0.2 Ma. The cooling rate then accelerated, but the rate of change had considerably slowed by ca 12 Ma. Low-temperature (U–Th)/He thermochronology shows that the cooling rate once again accelerated at ca 11 Ma, perhaps owing to renewed tectonic activity.