一维水质模型结合改进的输出系数法在流域非点源污染负荷估算中的应用

非点源污染是导致流域水体水质恶化的关键污染来源之一,为了估算流域非点源污染负荷,本文提出将一维水质模型应用于分离监测断面点源污染负荷和非点源污染负荷的方法,并结合了改进的输出系数法,以COD_Mn和NH₃-N为代表性指标,将该模型应用于潮河下游流域,并与传统的水文分割法结合改进的输出系数法估算非点源污染负荷的结果进行对比。结果表明,一维水质模型结合改进的输出系数法估算流域非点源COD_Mn和NH₃-N污染负荷模拟值的纳什系数均在0.800以上,具有良好的模拟精度,同时避免了水文分割法无法较好地模拟枯水期非点源污染负荷的弊端。该方法在运用SWAT（soil and water assessment tool）模型预测得到水文数据的情况下,能够预测流域非点源污染负荷,作为SWAT模型对COD模拟的补充。     

多模型方法在非点源污染负荷中的应用展望

对非点源污染进行定量化和有效控制的方法是通过非点源污染负荷模型对各类非点源的形成、迁移转化以及负荷量进行模拟。然而,流域非点源污染模型的不确定性是单一模型模拟污染负荷面临的重大挑战。借鉴多模型方法在降低水文模型不确定性方面的优越性,通过分析水文模型与非点源污染模型的相通性,提出多模型方法在非点源污染负荷中应用的基本思路并分析了多模型方法在非点源污染负荷估算中面临的挑战,总结了多模型方法在非点源污染负荷应用中的重点和难点问题。     

自贡市旭水河流域土地利用/覆被对非点源污染负荷的影响

水体污染的首要原因之一是面源污染,地表过多的营养物质通过地表径流进入水体从而产生污染。这里应用RS和GIS技术,结合输出系统模型,对贡井区旭水河流域非点源污染负荷进行多时相空间分布模拟。结果表明:贡井区非点源污染负荷TN、TP由于当地土地开发利用的缘故,从2007年到2009年呈逐渐上升趋势;在空间分布上TN、TP分布呈越来越离散趋势。研究表明:不同土地利用类型对非点源污染负荷的贡献率也存在着显著差异。     

颗粒态氮磷负荷模型研究

为研究妫水河流域的颗粒态氮磷非点源污染来源,以控制非点源污染,在官厅水库周围进行了野外人工降雨试验。试验数据表明,氮磷输移率与产沙率具有很好的相关性,颗粒态氮、磷的平均相关系数分别为0.9594和0.9772。建立了新的颗粒态氮磷负荷模型,其中富集系数等于泥沙中总氮总磷百分含量与土壤中百分含量之比。根据妫水河流域的土壤图、土地利用图及数字高程模型,应用新的模型研究了妫水河流域颗粒态氮磷污染负荷的空间分布。结果表明,颗粒态氮磷主要来自地表植被覆盖差的丘陵和山地。     

我国农村水环境非点源污染研究进展

农业非点源污染是导致水质污染最主要原因之一。我国农村非点源污染研究之初采用的研究方法主要有两种，一种是应用与水文模型紧密相关的模型来模拟和估算非点源污染负荷；另一种是通用土壤流失法。最近又提出了一种简便易用的流域非点源污染负荷估算方法－平均浓度法。将农业非点源污染负荷与3S技术结合、与水质模型对接用于流域水质管理成为农业非点源污染研究的新生长点。近年来，农村非点源污染研究也开始探索非点源污染负荷与河流水质模型接口问题。     

流域非点源磷素输出负荷估算方法研究

目前水质常规监测频率较低,难以客观反映流域非点源污染物浓度随降雨径流过程的变化情况,结果会低估了流域非点源污染物的输出负荷。本文利用流域次降雨过程的连续水质水量同步监测资料,研究分析次降雨过程与流域非点源磷素输出负荷之间的因果关系,并建立次降雨总量与磷素输出负荷的定量相关关系。研究结果表明,流域次降雨总量与非点源磷素输出负荷之间存在较好的相关关系。通过这种定量关系,以流域次降雨总量为输入,可以更为合理地估算出流域非点源磷素输出负荷。     

辽河大伙房水库汇水区农业非点源污染入库模拟

利用输出系数法和SWAT模型,对大伙房水库汇水区农业非点源污染(ANSP)进行了入库模拟研究,并用2006—2009年的水文和水质监测数据对模型进行了校准和验证。研究结果表明:汇水区年均输入到水库的泥沙量、总氮和总磷负荷分别为82.65×103 t、1 873.49t和81.97t;月入库泥沙量、总氮和总磷负荷与径流量有着较强的相关性,ANSP的产生和迁移受降水、径流过程影响很大,每年7、8月份的氮、磷和泥沙流失量达到年内最大值,分别占全年流失总量的42.64%、44.42%和67.91%。水库汇水区各流域对水库氮、磷污染的贡献率由大到小依次为:浑河流域(清原段)、苏子河流域、社河流域和水库周边小流域。     

中国非点源污染负荷计算研究现状与存在问题

非点源污染负荷计算对水污染总量控制具有重要意义,为分析中国非点源污染负荷计算研究的现状与问题,在系统调研相关文献的基础上,将中国常用的非点源污染负荷计算方法总结为三大类:输出系数模型、实证模型和机理模型,阐述了各种模型的特点及其在中国的研究和应用情况;从非点源污染的界定、产污量和排污量的区别、国内和国外非点源污染产生环境的差异以及平原河网地区非点源污染负荷的计算4个方面分析了中国非点源污染负荷计算研究存在的主要问题;认为模型和计算方法适应研究区的环境特征是研究工作取得成功的关键,今后要加强实证研究、理论研究与模型开发的结合,逐步建立适应中国环境特点的非点源污染负荷计算方法体系。     

渭河干流典型断面非点源污染监测与负荷估算

渭河水质在较大程度上受非点源污染的影响,因此,有必要对其负荷和比重进行研究。2009年至2010年,对渭河干流关中段咸阳和临潼断面进行了洪水期和非洪水期水质水量同步监测。根据监测结果及水文站实测流量资料,分别采用改进的水文分割法和平均浓度法对两断面的非点源污染负荷进行了计算,分析了非点源污染的特点。结果表明:渭河干流关中段主要污染物为COD、NH₃-N和TN,两断面洪水期间各指标的平均浓度基本都小于平时的平均浓度;各指标非洪水期浓度变化总体上小于洪水期浓度变化幅度,量级较大的洪水水质变化幅度相对较小;改进的水文分割法和已被检验并被广泛采用的平均浓度法计算结果符合良好。2009年(枯水年,P=68%)渭河咸阳和临潼站各指标非点源污染所占比例基本在20%～30%左右;2009年渭河干流咸阳-临潼河段污染以点源污染为主,构成比例在80%以上。对比2006年(枯水年,P=69%),2009年临潼站COD、NH₃-N和TN年点源负荷分别减少11937t、791t和29t,渭河点源治理取得一定成效;此外,临潼站这两年的污染构成比例基本相同。非点源污染在渭河水污染中占较大比重,其对渭河水质的影响不容忽视。     

辽河吉林省段COD环境容量研究

为准确核算辽河吉林省段水环境容量,对该流域水文水质和污染源资料进行了统计分析和合理推断,改进了综合衰减系数(K)的计算方法,得到适合该区域的K值。结合当地经济发展状况与环境特点,采用河流一维稳态模型从分期尺度上核定水环境容量。结果表明,吉林省辽河流域水污染严重:2007—2010年,点源和非点源COD年均入河量分别为35 381.7 t/a和98 488.7 t/a,非点源已成为流域主要污染源;丰、平、枯3个水期的COD管理环境容量分别为71 746.0、37 949.2、3 971.6 t/a,均较小,年内分配极不均衡;在现状COD入河条件下,丰、平、枯水期均无COD剩余环境容量。     

Integration of monthly water balance modeling and nutrient load estimation in an agricultural catchment

Non-point sources pollution has become a serious environmental problem in the aquatic systems throughout the world. The Xitiaoxi catchment is located in the southwest of Taihu Basin, contributing large amounts of runoff and associated nutrients to Taihu Lake. Thus, identifying critical non-point sources pollution in this catchment is urgent and essential to control water pollution, improve the water quality, and reduce the pollutants drained into water bodies. The present study integrated a monthly water balance model with the export coefficient model for total nitrogen and total phosphorus loads estimation in the Xitiaoxi catchment in southeastern China. The simulated monthly runoff are in good agreement with the observed streamflow at both Hengtangcun and Fanjiancun stations with Nash?CSutcliffe coefficients higher than 0.80. The predictions showed reasonable ranges from 1687 to 2046?t/y (2002?C2005) for total nitrogen loads, and from 106 to 157?t/y for total phosphorus loads (1999?C2007), respectively, which are consistent with the observed values at Hengtangcun. Overall, the monthly export coefficient model coupling monthly water balance simulation to export coefficient model presented both the seasonal dynamics and magnitude for streamflow and nutrients loads, which generally match well with the observations. These findings demonstrate that the proposed model can provide encouraging results and can be used as an efficient tool to identify the pollution sources for planning and management of large-scale agricultural catchment.     

太湖流域营养盐产量演变和趋势的数值模拟研究

认识流域湖泊水体富营养化的演变和趋势是湖泊污染控制和治理中的重要研究课题。本文将在分析和论证太湖流域营养盐自然本底、人类活动作用急剧增加的近50年来太湖流域营养盐的变化情况、以及全球气候变化和流域经济发展未来30年太湖流域营养盐变化趋势等三方面的基础上,对太湖流域营养盐产量变化做出评估和预测。研究表明,在未来气候变化概率分析和区域经济发展规划基础上,太湖流域未来30年营养盐流域产量将比现代（2000s）增加25%～33%,这将增大太湖水体污染的压力。     

Inputs,transformations, and transport of nitrogen and phosphorus in Chesapeake Bay and selected tributaries

In this paper we assemble and analyze quantitative annual input-export budgets for total nitrogen (TN) and total phosphorus (TP) for Chesapeake Bay and three of its tributary estuaries (Potomac, Patuxent, and Choptank rivers). The budgets include estimates of TN and TP sources (point, diffuse, and atmospheric), internal losses (burial in sediments, fisheries yields, and denitrification), storages in the water column and sediments, internal cycling rates (zooplankton excretion and net sediment-water flux), and net downstream exchange. Annual terrestrial and atmospheric inputs (average of 1985 and 1986 data) of TN and TP ranged from 4.3 g TN m^?2 yr^?1 to 29.3 g TN m^?2 yr^?1 and 0.32 g TP m^?2 yr^?1 to 2.42 g TP m^?2 yr^?1, respectively. These rates of TN and TP input represent 6-fold to 8-fold and 13-fold to 24-fold increases in loads to these systems since the precolonial period. A recent 11-yr record for the Susquehanna River indicates that annual loads of TN and TP have varied by about 2-fold and 4-fold, respectively. TN inputs increased and TP inputs decreased during the 11-yr period. The relative importance of nutrient sources varied among these estuaries: point sources of nutrients delivered about half the annual TN and TP load to the Patuxent and nearly 60% of TP inputs to the Choptank; diffuse sources contributed 60–70% of the TN and TP inputs to the mainstream Chesapeake and Potomac River. The direct deposition of atmospheric wet-fall to the surface waters of these estuaries represented 12% or less of annual TN and TP loads except in the Choptank River (37% of TN and 20% of TP). We found direct, although damped, relationships between annual rates of nutrient input, water-column and sediment nutrient stocks, and nutrient losses via burial in sediments and denitrification. Our budgets indicate that the annual mass balance of TN and TP is maintained by a net landward exchange of TP and, with one exception (Choptank River), a net seaward transport of TN. The budgets for all systems revealed that inorganic nutrients entering these estuaries from terrestrial and atmospheric sources are rapidly converted to particulate and organic forms. Discrepancies between our budgets and others in the literature were resolved by the inclusion of sediments derived from shoreline erosion. The greatest potential for errors in our budgets can be attributed to the absence of or uncertainties in estimates of atmospheric dry-fall, contributions of nutrients via groundwater, and the sedimentation rates used to calculate nutrient burial rates.     

洪湖流域传统农业条件下营养盐输移模拟研究*

文章选择位于长江中游的洪湖流域作为研究对象,应用流域分布式水文模型SWAT,探讨传统农业条件下流域营养盐输移的规律。模拟时段选择为建国初期的1951~1960年,模拟的边界条件设置为自然地形、土壤、传统农业生产和土地利用方式,其中土壤资料包括营养盐(N和P)、有机质含量、粒径等理化参数等。根据流域汇水范围的变化,模拟分汛期与非汛期两个时间段进行。通过对模型参数率定和调试,水文模拟结果与实测值有较好的吻合程度,由此进行营养盐输出模拟。模拟结果显示,传统农业条件下流域营养盐输出,TN和TP浓度变化有明显的季节特征,体现了耕作制度对营养盐浓度的影响; 同时,该时段营养盐浓度相比较自然条件下有了很大的改变,体现了人类活动对流域营养盐输移的影响,主要是土地利用类型变化和湖泊水域面积的缩小。     

太湖流域营养盐沉积200年的历史模拟研究

介绍边界条件设置为工业时代以前太湖流域处于自然农耕状况下,对太湖的总氮和总磷沉积反演200年的数值模拟研究。模拟反映了自然状况占1990s湖泊富营养化观测资料的湖区总氮约7%,占总磷约12%。模拟总氮和总磷浓度与太湖沉积钻孔沉积样推算的水体含量的数量级和变化范围相当,太湖流域的营养盐空间来源模拟也能够与流域自然地理变化吻合,表明模拟能够捕捉到流域营养盐历史变化特征,对湖泊营养物质来源、沉积和空间分布的流域环境历史变化响应具有良好模拟能力。      

A comparative study of nutrient transfer via surface runoff from two small agricultural catchments in north China

A field study was conducted to determine the effect of landscape spatial pattern and micro-topography on nutrient transfer via runoff from two catchments into Yuqiao Reservoir in north China. The surface runoff discharge was measured during rainfall events and water samples were analyzed in 2004 and 2005. The mean annual total nitrogen (TN) and total phosphorus (TP) exports per unit area from Caogezhuang catchment (C catchment) were 1.048 and 0.561 kg ha⁻¹ year⁻¹, respectively, while the TN and TP exports from Taohuasi catchment (T catchment) were 0.158 and 0.027 kg ha⁻¹ year⁻¹. In both catchments, village and vineyard shared the highest nutrient export ability due to the accumulated animal waste and heavy application of fertilizer and manure. In T catchment, the distance of village and vineyard was about 1,500 m away from the receiving water and in between were woodland and cropland. In the hydrological pathway, there were sink landscape structures of small stone dams, roadside swale, vegetated filter strip and dry ponds, which could detain water and nutrients. In C catchment, the distance between the village and the receiving water was about 200 m, and the hydrological pathway was compacted roads and ditches with no sink structures. It is suggested that the distance between the pollution source area and the receiving water and the micro-topographical features were the main factors to control the great difference in nutrient export rates.     

Characteristics of Non—Point Source Pollution in the Watershed of Miyun Reservoir,Beijing,China

Nitrogen and phosphorus are the major nutrients to cause eutrophication to degrade water quality of the Miyun Reservoir,a very important drinking water source of Bijing,China,and they are mainly from non-point sources.The watershed in Miyun County was selected as the study region with a totoal area of 1400km^2.Four typical monitoring catchments and two experimental units were used to monitor the precipitation,runoff,sediment yield and pollutant loading related to various land uses in the meantime.The results show that the total nutrient loss amounts of TN and TP are 898.07t/a,and 40.70t/a,respectively,in which nutrients N and P carried by runoff are 91.3% and 77.3%,respectively.There is relatively heavier soil eroson in the northern mountain area whereas the main nutrient loss occurs near the northeast edge of the reservoir.Different land uses would influence the loss amounts of non-point source pollutants.The amount of nutrient loss from the agricultural land per unit is highest,that from forestry comes next that from grassland is lowest.However,due to the variability of land use areas,agricultural land contributes a lot to TP and forestry lands to TN.     

Trophic states and nutrient storage of reservoirs in Chongqing

The trophic states of 35 reservoirs were investigated in the region of Chongqing, Southwest China. The results showed that the concentrations of nutrients and chlorophyll a were high and organic pollution and transparence （SD） were low in the water body. The concentrations of total nitrogen （TN） range from 0.52 mg/L to 5.94 mg/L and those of total phosphorus （TP） range from 0.002 mg/L to 0.598 mg/L. Chemical oxygen demand （COD） ranges from 0.75 mg/L to 9.3 mg/L and SD ranges from 0.48 m to 3.2 m. There was a significant positive correlation between COD and chlorophyll a, but a significant negative correlation between SD and chlorophyll a. In terms of the integrated nutrition state index, the eutrophication states of the reservoirs were assessed. Of the investigated reservoirs, about 22 reached the grade of eutrophication. Only one reservoir was in the state of oligotropher, the rest were in the state of mestropher. Integrated nutrition state indices range from 25.4 to 74.5. The storage capacity of nutrients in the reservoirs was calculated. The stored TN, TP and COD were about 4731, 206 and 10259 t, respectively. The main pollution sources are industrial and domestic wastes. With the development of aquaculture, the contamination level increases gradually.     

河南南阳盆地东南耕区表层土壤养分地球化学综合评价及影响因素

为了全面加强河南南阳西南耕区土地资源的利用、开发和管理工作,充分了解当地土壤的养分状况,通过实地调研、样品采集、实验分析等手段对研究区内各乡镇耕地土壤的pH值及养分(TN、TP和K)的空间分布特征进行研究,讨论不同土地利用方式下pH值及养分数据之间的差异及其各自的影响因素。半方差分析结果表明,TP最佳拟合模型为指数模型,TN、pH值、K含量以及有机质为球状模型。研究区pH、养分均表现出较弱的空间相关性,反映其受到人类活动的影响较为强烈。研究区土壤pH平均值为5.44,偏酸性,总体上呈现南高北低的空间分布特征。养分等级评价显示:TN、TP、K含量较为丰富,而有机质较为缺乏,分别为分级标准中的Ⅲ级、Ⅲ级、Ⅱ级和Ⅳ级。土壤养分地球化学综合等级评价显示,全区养分等级总体上以中等为主,占总点位的69.1%,全区广泛分布。Pearson相关性分析发现研究区内土壤pH与有机质、TN弱负相关,与K显著正相关;有机质与TN表现为显著正相关,与K为负相关。不同土地利用方式下土壤各因子差异显著,旱地土壤pH值、TN、有机质以及K含量的平均值均小于灌木林地,而TP则相反。此外,区内作物调查显示玉米种植区平均pH值低于花生种植区。施肥方式、用量及种类、作物类型、土地管理、种植结构和土壤背景是造成全区养分及pH值分布差异的主要原因。     

Characteristics of Danish estuaries

We review various aspects of the structure and functioning of Danish estuaries from data collected by the National Monitoring Program and from information in published sources. We present data on the physical, chemical, and biological characteristics of estuaries in Denmark, we evaluate the functioning of these systems as filters and transformers of nutrients and we evaluate the outlook for Danish estuaries in the future. Danish estuarine systems are for the most part shallow (<3 m deep), have short residence times, and tend to be heavily loaded with nutrients primarily from agricultural sources. Total average loads from land per unit watershed area are 112 kg P km^?2 yr^?1 and 2,400 kg N km^?2 yr^?1 during the period 1989–1995. The total phosphorus (TP) load in estuaries has been significantly reduced over the last decade, following implementation of the 1987 Action Plan for the Aquatic Environment (Vandmiljøplan in Danish) that prescribed that nitrogen loads to the total aquatic environment should be reduced by 50% and phosphorus loads by 80%. Reductions in the total nitrogen (TN) load have been more modest. Nutrient loading is one of the primary determinants of estuarine nutrient concentration with 70% of the annual variation in TN concentration and 55% of the annual variation in TP concentration explained by variation in the load. Many Danish estuaries have rich communities of macrophytes and benthic filter feeders, such asMytlis edulis andCiona intestinalis, that can control water column chlorophyll concentrations by their filter feeding activities. Many of the estuaries experience hypoxia and anoxia, especially during warm and calm summer months. Further reductions in nutrient loading are expected following implementation of the Action Plan for the Aquatic Environment II, with predicted improvements in oxygen concentrations and in the functioning of these shallow, dynamic estuarine systems.