俯冲隧道内不同深度的壳幔相互作用:地幔楔超镁铁质岩的镁同位素记录

在不同的俯冲深度,俯冲板片会释放出不同来源和组成的熔/流体进入俯冲隧道中,并进而影响上覆地幔楔及衍生岛弧岩浆的地球化学组成.然而,如何识别俯冲隧道中不同深度熔/流体组分的来源一直是俯冲带研究中的难点.对不同深度来源的地幔楔超基性岩进行了Mg同位素研究,发现了Mg同位素具有示踪俯冲板块熔/流体来源的能力.首先,研究了美国加州Franciscan杂岩中一套经历了多期次流体交代作用的浅部来源（< ~60 km）的变质超基性岩.这些部分蛇纹石化的地幔楔超基性岩在蛇纹石脱水形成滑石的过程中会释放轻Mg同位素进入流体,而重Mg同位素更多地残留在滑石相中;随后进一步受俯冲板块来源流体的交代形成具有高CaO和轻Mg同位素组成的透闪石化变橄榄岩,暗示流体中含有源自俯冲板片的、富集轻Mg同位素的碳酸盐,说明在弧前~60 km深度,部分含Mg碳酸盐（方解石）可以在俯冲隧道中发生溶解并迁移交代上覆地幔楔橄榄岩.对深部地幔楔来源（~160 km）的大别造山带毛屋地区超镁铁质岩体岩相学和元素地球化学研究结果证实了其交代成因.结合多相包裹体、元素地球化学以及前人估计的温-压条件,推测交代介质更接近超临界流体.锆石U-Pb年代学研究揭示,交代作用主要发生在古生代洋壳俯冲阶段（454±58 Ma）,超高压变质作用则发生在三叠纪陆壳俯冲阶段（232.8±7.9 Ma）.古生代锆石中大量的碳酸盐矿物包裹体和重O同位素特征说明古生代洋壳俯冲交代过程中有沉积碳酸盐组分加入.全岩和单矿物的Mg同位素组成均显著低于地幔值以及大别新元古代榴辉岩,说明交代的碳酸盐组分来源应为循环的沉积富Mg碳酸盐,暗示了在俯冲带深部富Mg沉积碳酸盐在超临界流体中会发生溶解迁移.由于沉积碳酸盐具有独特的、显著富集轻Mg同位素组成的特征,这种交代作用会造成地幔楔局部具有异常的Mg同位素组成,从而解释目前观察到的岛弧火山岩的Mg同位素特征.因此,Mg同位素是示踪俯冲碳酸盐与上覆地幔楔相互作用的有效工具.      

锂同位素分馏机制讨论

作为一种新兴的稳定同位素示踪工具, 锂同位素地球化学的研究近年来受到了国际地学界日益广泛的关注.其应用领域涵盖了从地表到地幔的流体与矿物之间的相互作用.在地表风化作用过程中, 轻锂同位素(6Li) 优先进入固体相, 而7Li则进入流体相, 因而地表风化作用淋滤出了岩石中的重锂, 致使河水具有重的锂同位素组成, 河水又将重锂同位素组分补给海洋, 洋壳的低温蚀变作用使得海水的锂同位素组成进一步变重.在俯冲带, 由于俯冲板片释放的流体具有重锂同位素组成的特征, 它们上升并交代上覆的地幔楔和相邻的地幔, 使得地幔楔的锂同位素组成变重.同时, 深俯冲的板片由于脱水而具有较轻的锂同位素组成, 它们在地幔中可能形成一个局部轻锂的地幔储源.影响地幔橄榄岩锂同位素分馏的因素主要有3个方面: 温度、扩散机制以及外来熔体的反应.由于高温下地幔矿物之间的锂同位素分馏很小, 而单纯的扩散分馏机制不能够很好的解释我国华北汉诺坝地区地幔橄榄岩中矿物之间的锂同位素分馏.因此, 具有轻锂同位素组成的熔体与橄榄岩之间的反应是上述现象的一个合理解释.需要指出的是, 在橄榄岩-熔体反应的过程中, 锂同位素的扩散作用也对地幔矿物之间的同位素分馏有一定的贡献.      

Geochemical mapping of slab-derived fluid and source mantle along Japan arcs

Although slab-derived fluid significantly affects melt generation and dynamics within subduction zones, its amount and distribution are not sufficiently constrained at present. Herein, we use isotopic systematics of arc volcanic rocks, subducting materials, and intrinsic mantle components prior to metasomatism, to quantify the contribution of the slab-derived fluid that metasomatizes the overlying mantle wedge beneath the entire area of Japan arcs. Simultaneous application of several multivariate statistical analyses (clustering analysis and principal/independent component analyses) to the isotopic data set allows Japan arcs to be broadly divided into eastern and western parts at the first order. Moreover, a clear higher-order inter-arc segmentation is observed, together with some intra-arc variations that possibly correspond to the heterogeneity of incoming plates. Inter-arc segmentation is shown to be primarily controlled by the geometrical parameters of the slab and the arc (e.g., subduction of a single plate or double plates beneath either oceanic or continental crust), which results in differences between mantle wedge and slab thermal conditions. Accordingly, the Kuril and Izu arcs, which have thin arc crusts (~20 km), exhibit the lowest extent of slab-derived fluid addition (0.1 wt%) to the mantle wedge, while the NE Japan arc, with a thicker arc crust (up to 36 km), features a higher value of 0.2 wt%, although the slab thermal parameters for these three arcs are essentially the same. The Central Japan arc shows the highest extent of slab-derived fluid addition (>1.0 wt%) because of the overlapping subduction of Pacific and Philippine Sea slabs, while the SW Japan and Ryukyu arcs feature moderate values of ~0.5 wt%. Moreover, a clear exotic plume zone and spots are observed in SW Japan and the Japan Sea. In addition to the variability of slab-derived fluid composition, the intrinsic mantle composition (before slab-derived fluid–induced metasomatism) shows a clear along-arc variation that is possibly caused by a large-scale mantle flow from the continental side. Thus, slab-derived fluid addition and mantle composition variability equally contribute to inter-arc segmentation, which highlights the importance of both local and regional thermal flow structures of slab-mantle systems.     

Li同位素在斜顽辉石、镁铝榴石及镁铝尖晶石晶格内扩散与分馏的理论计算研究

斜顽辉石、镁铝榴石和镁铝尖晶石作为辉石族、石榴石族以及尖晶石族中的重要端元,是地球上地幔主要组成矿物。Li同位素是重要的地幔地球化学示踪剂,其在橄榄石、辉石和石榴石等地幔矿物中的扩散分馏的性质对理解Li同位素作为地幔地球化学示踪剂非常重要。我们通过经典力场经验势方法,从原子尺度上计算研究了不同温压条件下Li同位素在斜顽辉石、镁铝榴石和镁铝尖晶石晶格中分别通过不同的填隙机制和取代空位机制迁移的活化能和其在不同晶格位上的分馏效应。我们发现Li同位素是通过取代空位机制在斜顽辉石、镁铝榴石和镁铝尖晶石中进行迁移扩散。Li同位素在不同晶格位上的分馏作用计算表明,在三种矿物中重同位素7Li会更多地进入晶格填隙位中,而6Li则相对更多进入Mg位。温度是影响这种分馏作用的一个关键因素,相应的结果可用来解释地幔Li同位素组成特征及冷却条件下的同位素分馏等科学问题。     

论铅同位素的地质指示作用

在地球壳、慢物质交换过程中,铅同位素具有从均-趋向不均-或从非均-趋向新的均-的倾向,而使其具备作为指示剂的条件。研究时若将铅同位素的时空演化与成矿作用有机结合,则其指示作用更明显。本文以东秦岭和粤北韶关地区的多种地质体的铅同位素成分资料为基础,探讨了铅同位素在构造环境、物质来源及成矿作用等方面的指示作用。     

拉萨地块西段中新世赛利普超钾质火山岩富集地幔源区和岩石成因:Li同位素制约

作为一种“非传统稳定同位素”,锂同位素地球化学研究已经成为近年来国际上研究的热点之一.文章成功应用锂同位素对青藏高原西南部赛利普超钾质火山岩进行了示范研究.研究表明,赛利普超钾质火出岩的w(Li)为11.2×10-6～22.9× 10-6,同位素组成δ7Li为1.2‰～+3.5‰,平均值为0 2‰,与平均上地壳的相当.超钾质火山岩的锂同位素组成与岩浆结晶分异程度参数之间不存在任何相关性,这表明在超钾质火山岩结晶分异过程中没有发生明显的锂同位素分馏,锂同位素组成特征反映了其形成时的源区特征.超钾质火山岩的锂同位素组成变化范围达4.7‰,并且与pb-Sr-Nd同位素和岩浆结晶分异参数之间亦无任何相关性,表明锂同位素异常可能反映了不均匀源区岩石特征.通过计算模拟以及与前人的类似研究成果进行对比,笔者认为俯冲印度地壳而不是特提斯洋壳(包括沉积物)的流体/熔体参与了超钾质火山岩的源区富集,并在此基础上提出了超钾质火山岩成因模式.     

Temperature-dependent isotopic fractionation of lithium between clinopyroxene and high-pressure hydrous fluids

The fractionation of lithium isotopes between synthetic spodumene as representative of Li-bearing clinopyroxene and Cl- and OH-bearing aqueous fluids was experimentally determined between 500 and 900°C at 2.0 GPa. In all the experiments, ⁷Li was preferentially partitioned into the fluid. The fractionation is temperature dependent and approximated by the equation Δ⁷Li_{(clinopyroxene–fluid)}=−4.61×(1,000/T [K]) + 2.48; R ²=0.86. Significant Li isotopic fractionation of about 1.0‰ exists even at high temperatures of 900°C. Using neutral and weakly basic fluids revealed that the amount of fractionation is not different. The Li isotopic fractionation between altered basalt and hot spring water (350°C) in natural samples is in good agreement with our experimentally determined fractionation curve. The data confirm earlier speculations drawn from the Li isotopic record of dehydrated metamorphic rocks that fluids expelled from a dehydrating slab carry heavier Li into the mantle wedge, and that a light Li component is introduced into the deeper mantle. Li and Li isotopes are redistributed among wedge minerals as fluids travel across the wedge into hotter regions of arc magma production. This modifies the Li isotopic characteristics of slab-derived fluids erasing their source memory, and explains the absence of cross-arc variations of Li isotopes in arc basalts.     

Fe-Cu-Zn-Mo同位素示踪氧化还原过程

非传统稳定同位素（Fe-Cu-Zn-Mo）理论与数据相结合提高了科研工作者对地质体系氧化还原过程的理解。本文对这一相对较新的领域进行了综述,包括与氧化还原过程相关的同位素分馏理论和实验约束、时空尺度下的氧逸度以及同位素示踪氧化还原过程。稳定同位素理论预测,Fe-Cu-Zn-Mo同位素应该对氧化还原状态的变化能够做出响应。结果表明,Fe同位素作为岩浆过程、表生过程、俯冲带流体性质"氧逸度计"应用前景广阔;Cu同位素在岩浆、热液、陆地系统可以很好地示踪氧化还原过程;Zn同位素由于络合过程分馏已经被用在许多不同环境中作为含硫/碳流体迁移的敏感示踪剂;Mo同位素作为古氧逸度计可有效重建古海洋-大气氧化还原状态。     

造山带橄榄岩记录的大陆俯冲带多期壳幔相互作用

俯冲带是地壳与地幔之间物质交换的主要场所.前人对大洋俯冲带壳幔相互作用进行了大量研究,但是对俯冲带壳幔相互作用的物理化学过程和机理仍缺乏明确认识.在大陆俯冲带出露有造山带橄榄岩,它们来自俯冲板片之上的地幔楔,是解决这个问题的理想样品.通过对大别-苏鲁和柴北缘造山带橄榄岩进行系统的岩石学和地球化学研究,发现地幔楔橄榄岩由于俯冲地壳的交代作用而含有新生锆石和残留锆石,它们能为地壳交代作用时间、交代介质来源、性质和组成提供制约.地幔楔橄榄岩在大陆碰撞过程的不同阶段受到了俯冲大陆地壳衍生的多期不同性质流体的交代作用.地幔楔橄榄岩还受到了陆壳俯冲之前古俯冲洋壳衍生流体的交代作用.深俯冲陆壳衍生熔体与橄榄岩反应形成的石榴辉石岩具有高的水含量,能提供高水含量的地幔源区.      

Li同位素在矿床学中的应用:现状与展望

矿床的形成受制于多种复杂的地质作用,包括全球尺度的板块构造运动、岩浆活动、变质沉积改造等过程,并普遍伴随热液活动、流体迁移、水-岩相互作用、元素分异及同位素分馏等一系列局部区域地质和地球化学过程.在过去的矿床学研究中,地球化学方法主要围绕在主、微量元素和传统的稳定同位素等手段,解决了很多矿床成因问题.但仍存在不少的多解和难解问题,比如许多矿床在矿化类型、蚀变分带与金属矿物组合方面具有诸多相似之处,常规地球化学指标难以区分.随着测试精度的提高和自然储库组成的完善,Li同位素近些年来已成为新兴的稳定同位素体系.Li同位素在自然界过程中高达80‰的同位素分馏使其具有更好的辨识能力,同时兼有直接和间接指示作用,有潜力成为研究各种复杂成矿过程的良好示踪剂.本文总结了近年来有关矿床学中Li同位素的研究和应用进展,以俯冲带成矿为主,阐述了斑岩型-热液矿床、伟晶岩型矿床和沉积矿床等类型矿床的Li同位素地球化学特征,并探究新的Li同位素方法在矿床中的应用前景.基于Li同位素体系在各类矿床的应用实例,我们认为Li同位素体系将为矿床学研究提供更多的指示信息和依据.      

Contribution of slab-fluid in arc magmas beneath the Japan arcs

Identifying the amount and composition of slab-derived fluid and its spatial variation is key to quantifying fluid processes in subduction zones. Based on the isotopic systematics of arc lavas, we found regional variations over the Japan arcs in terms of the amount and composition of slab-derived fluid added to the melting source region. The average amounts of slab-derived fluid differ among the arcs: 2.6 wt.% for Central Japan, 0.69 wt.% for Ryukyu, 0.17 wt.% for NE Japan, and 0.12 wt.% for both Kurile and Izu–Bonin. These differences may be attributed to the arc setting (oceanic or continental) and the geometry of the slabs. Contribution of sediment involved in the slab-derived fluid is dominant in NE Japan compared to the Izu–Bonin and Central Japan arcs. This could be attributed to mechanical features such as fractures near the subducting plate surface, in addition to the arc setting and the slab geometry. Therefore, the amount and composition of slab-derived fluid are thought to be controlled not only by the thermal conditions, but also by the tectonic and mechanical features around the subduction zone. On top of the variability of slab-derived fluid, the mantle wedge shows the regional variation in terms of proportion of the Pacific-type and Indian-type MORB-source mantle components, which also contributes to the compositional variations of arc magmas.     

西藏多不杂铜矿床硫铅同位素地球化学示踪

多不杂铜矿床的发现是西藏地质找矿工作取得的重大突破,前人对其做了大量的研究,但始终未能合理解释该矿床的形成过程,究其原因主要是因为成矿物质和成矿流体来源认识上存在争议。本次研究指出了前人在多不杂铜矿床成因机制认识中存在的问题,并测试了岩矿石及单矿物的硫铅同位素组成。研究表明,矿床中硫主要来源于深源岩浆,幔源岩浆和流体在参与成岩成矿过程中伴随岩浆结晶成岩交代岩石而致自身流体性质演变,进而引发壳幔物质混染;铅同位素具有由岩浆作用形成的地壳与地幔混合的俯冲带铅的特征,伴随着含矿地幔流体的上升侵位,不可避免的混染了地壳铅,导致了多不杂铜矿床铅同位素组成的变化。综合分析认为该矿床的成矿物质和成矿流体主要来源于地幔,成矿动力主要来自深部地质过程,矿床的形成与地幔流体作用有关。     

俯冲带碳酸盐化对深部碳循环的启示:以中国西南天山碳酸盐化云母片岩为例

俯冲带可将地球表层碳输送至深部地幔,同时也记录着俯冲板片来源碳质流体的迁移沉淀机制,对地球深部碳循环具有重大影响。近年来,俯冲带脱碳机制的研究表明流体溶解脱碳作用是冷的大洋俯冲板片释放COH流体的重要方式,而上覆板块(尤其地幔楔)则被认为是缓冲这些COH流体的重要场所,甚至是俯冲带CO_2的唯一"归宿"。事实上,俯冲带岩石本身的固碳能力却受到了忽视,而对俯冲带岩石捕获和固存CO_2(carbon capture and storage,CCS)能力的评估对全球碳通量的估算尤为重要。本文以中国西南天山高压-超高压变质带中碳酸盐化云母片岩为例,探讨俯冲带岩石的碳酸盐化对深部碳循环的影响。西南天山长阿吾子一带的碳酸盐化云母片岩记录了俯冲板片起源的碳质流体对俯冲带云母片岩的交代作用,地球化学特征表明蛇纹岩释放的富水流体溶解俯冲洋壳中的碳酸盐可能是产生COH流体的重要机制。基于碳质流体对多硅白云母(Si(a.p.f.u.)=3.58～3.73)的交代及相对高压的碳酸盐矿物(主要为白云石和菱镁矿)与金红石的共生,结合区域上碳酸盐化云母片岩与高压碳酸盐化蛇纹岩(HP-ophidolomite)的伴生,我们认为云母片岩的碳酸盐化作用可能发生在俯冲板片峰期稍后的高压折返阶段。俯冲带云母片岩的固碳作用表明除了上覆板块,俯冲带岩石本身对于碳质流体也具有很好的吸收能力。初步估算表明俯冲带云母片岩的碳酸盐化每年可固存至少2.46～6.68Mt/yr,约占俯冲板片每年进碳量的4%～17%。     

板块俯冲起始与大陆地壳演化

组成大陆地壳的物质主要来自两个地质过程:地幔柱活动和板块俯冲。目前大多数研究认为板块俯冲起始于30多亿年前。在板块俯冲起始之前,基性的初始地壳物质受热重熔是大陆地壳生长的主要方式,其中,地幔柱活动是关键。地幔柱不仅向地壳输送玄武质岩浆,同时导致已有玄武质岩石和沉积岩通过部分熔融向中酸性岩石转化。当原始岩石圈强度足够大时,地幔柱会导致岩石圈倾斜、破裂,产生下滑力,诱发板块俯冲。板块俯冲引发岩浆活动,产生大量的岩浆岩,如岛弧安山岩、弧后盆玄武岩等。这些岩浆岩通过喷发、侵位,再经由块体拼贴、增生等过程加入到大陆地壳,是大陆地壳生长的主要途径。同时,板内岩浆活动乃至地幔柱活动等也与板块俯冲有直接或者间接的联系。俯冲再循环物质促进地幔柱发育,也为大陆地壳的生长提供物源和热能。与此同时,大陆地壳不断风化剥蚀,其中一部分沉积物随俯冲板块再循环到地幔,而板块俯冲过程也通过俯冲剥蚀等过程,将仰冲盘岩石圈物质刮削带入地幔。这些是大陆地壳消减的主要途径。目前大陆地壳增生和消减基本处于动态平衡。     

板块俯冲过程中的Mg-Li-Fe-Cr同位素分馏

金属稳定同位素体系是示踪板块俯冲对壳幔物质再循环影响的全新工具,因此其在俯冲带的地球化学行为备受关注.Mg同位素在俯冲过程中不发生显著分馏,但大陆玄武岩具有低于洋中脊玄武岩的Mg同位素,这可能是碳酸岩的俯冲再循环导致的.与角闪岩继承原岩的Li同位素组成不同,榴辉岩具有轻于原岩的Li同位素组成,可归因于俯冲折返过程中的动力学扩散、脱水反应或低Li同位素的流体交代.作为变价元素,Fe和Cr的同位素在榴辉岩的形成过程中均不发生显著分馏,但是蛇纹岩的Fe同位素和Cr同位素与氧逸度指标具有相关性,指示氧化还原条件变化时脱水过程或流体交代会导致同位素分馏.      

Fluid/rock interaction and mass transfer in continental subduction zones: constraints from trace elements and isotopes (Li,B, O,Sr, Nd,Pb) in UHP rocks from the Chinese Continental Scientific Drilling Program,Sulu, East China

In order to better understand the role of fluids during subduction and subsequent exhumation, we have investigated whole-rock and mineral chemistry (major and trace elements) and Li, B as well as O, Sr, Nd, Pb isotopes on selected continuous drill-core profiles through contrasting lithological boundaries from the Chinese Continental Scientific Drilling Program (CCSD) in Sulu, China. Four carefully selected sample sets have been chosen to investigate geochemical changes as a result of fluid mobilization during dehydration, peak metamorphism, and exhumation of deeply subducted continental crust. Our data reveal that while O and Sr-Nd-Pb isotopic compositions remain more or less unchanged, significant Li and/or B isotope fractionations occur between different lithologies that are in close contact during various metamorphic stages. Samples that are supposed to represent prograde dehydration as indicated by veins formed at high pressures (HP) are characterized by element patterns of highly fluid-mobile elements in the veins that are complementary to those of the host eclogite. A second sample set represents a UHP metamorphic crustal eclogite that is separated from a garnet peridotite by a thin transitional interface. Garnet peridotite and eclogite are characterized by a >10% difference in MgO, which, together with the presence of abundant hydroxyl-bearing minerals and compositionally different clinopyroxene grains demonstrate that both rocks have been derived from different sources that have been tectonically juxtaposed during subduction, and that hydrous silicate-rich fluids have been added from the subducting slab to the mantle. Two additional sample sets, comprising retrograde amphibolite and relatively fresh eclogite, demonstrate that besides external fluids, internal fluids can be responsible for the formation of amphibolite. Li and B concentrations and isotopic compositions point to losses and isotopic fractionation during progressive dehydration. On the other hand, fluids with isotopically heavier Li and B are added during retrogression. On a small scale, mantle-derived rocks may be significantly metasomatized by fluids derived from the subducted slab. Our study indicates that during high-grade metamorphism, Li and B may show different patterns of enrichment and of isotopic fractionation.     

Lithium isotopic composition of Central American Volcanic Arc lavas: implications for modification of subarc mantle by slab-derived fluids

Li contents and isotopic compositions were determined for a suite of well-characterized basaltic lavas from the Central American Volcanic Arc (CAVA). Variable Li/Y (0.2–0.5), Li/Sc (0.1–0.4), and δ⁶Li values (+2.6 to −7.7‰) attest to significant compositional heterogeneity in the subarc mantle. Within specific arc segments, these parameters correlate strongly with each other and with a number of other constituents (e.g., K, Rb, Ba, B/La, ¹⁰Be/⁹Be, ⁸⁷Sr/⁸⁶Sr, U/Ce, and ²³⁰Th/²³²Th, among others); these correlations are particularly strong for Nicaragua samples. Coupling of this particular set of constituents is best explained in terms of addition of ‘subduction components' to the subarc mantle. Moreover, their selective enrichment with respect to relatively fluid-immobile incompatible elements signifies the dominance of fluid vs. silicate melt transport of slab components to the subarc mantle. Several interesting nuances are revealed by the Li data. First, although Li and B are strongly correlated in both Costa Rica and Nicaragua, there are systematic along-strike variations in Li/B that are consistent with these elements having different ‘fluid release patterns' from subducted slab segments. For example, Li/B is highest in Costa Rica where auxiliary evidence indicates higher subduction zone temperatures; apparently B is preferentially depleted and Li retained in the slab under warmer conditions. The same relations are reflected in Li/¹⁰Be and other subduction tracer systematics, all of which point to larger subduction contributions below Nicaragua. Yet, even Nicaragua lavas vary widely in levels of subduction enrichment. High-Ti basalts from Nejapa are the least enriched and have the highest δ⁶Li (1.4 to 2.6‰); these values are greater than in fresh MORB (ca. −4‰) and are not easily explained by additions of subducted Li because most oceanic crustal rocks and marine sediments have lower δ⁶Li than MORB (with typical values between −8 and −20‰). Thus, it appears the Nejapa data may be representative of isotopically light mantle domains. Relatively light δ⁶Li values in an undepleted spinel lherzolite (+11.3‰) from Zabargad Is. (Red Sea) and in primitive backarc basalts (−1.6 to −0.5‰) from Lau Basin support this conclusion. Considering representative fluid and mantle endmember compositions, the CAVA data are consistent with limited (up to a few percent) additions of slab-derived fluids to a heterogeneous mantle containing variably depleted and enriched domains to form the respective magma sources. In our view, the subarc mantle is heterogeneous on a small scale, but some arc sectors clearly received greater slab inputs than others.     

锦州-迁安太古宙赞岐岩类片麻岩成因及其动力学意义

详细的野外地质调查和综合研究表明冀东-辽西南部地区太古宙变质基底主要由富钾花岗质岩石组成,由锦州至迁安构成一条NEE向延伸200余千米的富钾花岗质岩石带。这些富钾花岗质岩石主要由似斑状/中粒石英二长闪长质-花岗闪长质-二长花岗质片麻岩和中粒二长花岗岩-正长花岗岩构成。全岩地球化学分析表明这些石英二长闪长质-花岗闪长质-二长花岗质片麻岩具有高FeO~T、MgO、K_2O和Mg~#值的地球化学特征,与全球范围内中-新太古宙赞歧岩类相似。LA-ICP-MS锆石U-Pb同位素定年结果表明这些岩石形成于2546~2543Ma。岩石成因研究表明这些赞歧岩类片麻岩形成于俯冲板片及其拖曳的洋壳沉积物、增生楔物质的熔体和受俯冲流体、熔体交代的地幔楔之间相互作用引发的一系列的岩浆作用。这一多样化的赞岐岩类岩浆作用形成了一条新太古代赞岐岩类带,该赞岐岩类带反映了冀东-辽西南部地区新太古代从NNW向SSE向板片热俯冲的动力学体制。     

造山带橄榄岩起源和大陆俯冲带壳幔相互作用

俯冲地壳衍生流体交代地幔楔,是产生俯冲带岩浆作用的重要机制.但是,目前人们对俯冲大陆物质改造地幔楔的岩石学过程和机理仍缺乏深入认识,造山带橄榄岩是解析这一问题的直接样品.通过对大别-苏鲁造山带橄榄岩进行系统的矿物学、岩石学和地球化学研究,发现橄榄石Ni/Co比值可有效区分幔源和壳源造山带橄榄岩,揭示幔源造山带橄榄岩起源于华北岩石圈地幔.苏鲁李家屯纯橄岩在进入俯冲带之前就已在地幔内部经历了碳酸盐熔体交代.大别毛屋和苏鲁蒋庄橄榄岩及其交代脉体记录了约170~200 km深度的俯冲带壳幔相互作用过程.深俯冲陆壳释放的富Si-Al质熔体可不同程度地改造地幔楔底部,形成富石榴石和富辉石的交代岩,并引发强烈的Os同位素分馏效应.该过程不仅改变地幔楔岩性和化学组成,还能够改变交代介质成分,为俯冲带各类深部地幔岩浆提供源区物质.因此,大陆深俯冲是导致上地幔不均一的重要途径.      

The Chemical Composition of Global Subducting Sediments and Its Geological Significance

Subducted sediments play an important role in crust-mantle interaction and deep mantle processes, especially for subduction zone magmatism and mantle geochemistry. The current rate of Global Subducting Sediments (GLOSS) is 0.5~0.7 km³/a. The GLOSS are composed of terrigenous material(76 wt.%), calcium carbonate(7 wt.%), opal(10 wt.%) and mineral-bound H₂O⁺(7 wt.%). The chemical compositions of GLOSS are similar to those of upper continental crust which is mainly controlled by the terrigenous materials, and yet the materials formed by marine processes will dilute the terrigenous materials. The components of subducted sediments are different among trenches. In the accretionary margin, the components of subducted sediments are similar to those of the upper crust, while in the non-accretionary margin the components are terrigenous materials plus those produced by marine processes. During subduction, subducted sediments will released fluids, melt or supercritical fluid to affect island arc/back-arc basin magmatism by means of aqueous fluid or sediment melt. In addition, a part of subducted sediments, together with underlying altered oceanic crust/lithosphere, recycle into the mantle and contribute to the mantle heterogeneity. Geochemical tracers indicate that subducted sediments play variable contributions to the magmatic processes in different tectonic setting. Thus, subducted sediments play an important role in two relatively independent dynamics systems (plate tectonics and mantle plume), as well as related mantle evolution models. As a result, by accurately calculating the compositions of subduction sediments and using various geochemical indicators, we can further limit the input and output fluxes of various elements or isotopes, and then obtain more accurately residual subducted components, which can provide us some important clues for geodynamic process.