热分层效应控制的水库水体氢氧同位素特征

为掌握水库热分层与氢氧同位素空间分布的关系,研究了广西兴安县五里峡水库夏季氢氧同位素空间分布特征及影响因素。研究表明:①五里峡水库夏季出现明显的热分层,库表层至-5 m为表水层,-5 m至-20 m为温跃层,-20 m以下为底温层;②五里峡水库δ18O、δD值沿大气降水线分布,但均落在桂林市大气降水线右下方,其线性方程为δD=4.66δ18O-10.85（R2=0.76）,其斜率与全球大气降雨线（GMWL）和桂林市降雨线（CLMWL）的斜率和截距差异明显,表明五里峡水库主要由降水补给,但在补给五里峡水库前已经过了强烈的蒸发作用和水岩作用;③ δ18O、δD随水深的增加逐渐偏负,具有表水层 > 入库水体 > 温跃层 > 底温层 > 出库水体（>表示偏正）的垂向分布特征。分析认为入库水体氢氧同位素的季节变化和蒸发作用随深度增加而降低是五里峡水库夏季分层期间水体氢氧同位素垂向变化的主要影响因素。     

Physical Controls on Spatial Variability in Decomposition of Organic Matter in Lake Kinneret,Israel

High resolution chemical data collected during summer 2003 indicate that the lower water mass (LWM) of the thermally stratified Lake Kinneret (LK) can be subdivided into three layers: a benthic boundary layer (BBL), overlain by the hypolimnion (HYP), and on top, the lower part of the metalimnion (ME-L). After onset of thermal stratification, the BBL is the first layer that turns anoxic, followed shortly afterward by the ME-L, while the HYP remains oxic and has relatively higher pH until later in summer. Thus, during the early summer, the HYP forms an oxygen-containing layer in-between two DO-deficient layers. Somewhat later, the HYP is characterized by still having significant levels of nitrate NO₃, while in both adjacent layers nitrate is already removed through denitrification. The mechanisms controlling the gradual decline of dissolved oxygen (DO) in the HYP during the summer were studied. The seasonal mean lake-wide vertical eddy diffusion coefficient in this layer, evaluated from heat flux measurements, is approximately 4 × 10⁻⁶ m² s⁻¹. The vertical oxygen flux due to diffusion from within the HYP toward its oxygen-deficient upper and lower boundaries accounts for most of the slow summer decline in DO in this layer. A smaller portion of this decline can be attributed to in-layer respiratory processes. The low turbidity, relatively high pH, and slow accumulation rate of NH₄ in the HYP support the notion that the slower mineralization processes occurring in this layer result from relatively low ambient concentrations of biodegradable organic matter, most probably due to the short residence time of the particles settling through this layer.     

红枫湖夏季分层期间pCO2分布规律的研究

在夏季分层期间对红枫湖南、北湖湖心的水样进行分层采集,同时测定了分层水样的温度、pH、HCO₃-浓度、溶解氧(DO)、叶绿素a(Chl-a)及铵根离子(NH₄+)、硝酸根离子(NO₃-)、磷酸根离子(PO₄3-)的浓度,水体中CO₂的分压(pCO₂)由化学平衡及亨利定律求得。研究结果表明:光合作用、有机质降解及水体热分层是影响红枫湖夏季pCO₂分布的主要因素。其中,温水层CO₂欠饱和是光合作用吸收CO₂引起的,温跃层中pCO₂的急剧增加是光合产物降解产生CO₂引起的。静水层沉积物附近pCO₂最高并且还有持续增加的趋势,说明沉积物中有机质降解是静水层中CO₂增加的主要原因,夏季湖底水温较高加快了沉积物中有机质的降解。分层现象使pCO₂在水体中的分布差别明显,并且使静水层中CO₂得到积累。此外,夏季红枫湖水体中pCO₂的变化与NH₄+、PO₄3-的变化密不可分,表现为温水层中光合作用消耗NH₄+、PO₄3-,有机质降解过程伴随NH₄+、PO₄3-的释放。     

北极斯瓦尔巴德群岛中部海域表层海水水质研究

掌握北极海水水质特征及地域分布等第一手数据对北极科考意义重大。该项研究工作是全国青少年北极科考子任务,于2017年夏季在北极斯瓦尔巴德群岛中部海域对表层海水水质特征、地域差异及相关控制因素进行了研究。选取了6个区域共40个采样点采集表层海水样本,从温度、酸碱度、电导率、溶解性总固体量、实际盐度和溶解氧饱和度等方面进行了水质特征测量分析,发现该海域6个区域在海水温度、电导率、溶解性总固体量、实际盐度及溶解氧饱和度等方面均有较大差异,而酸碱度差异不大: 北部冰区水温最低,溶解性总固体量最低,溶解氧含量较高; 西北部海湾溶解氧饱和度最高; 中部海峡溶解性总固体量最高,盐度和电导率最低; 南部海域水温最高,实际盐度和电导率最高,溶解氧饱和度最低; 东部沿海水温偏低。采样点地理位置、洋流情况、地形地貌等因素对表层海水水质均有影响。这些研究成果对补充我国在北极地区的第一手科考数据和进行深入的科考研究具有重要意义。     

北极斯瓦尔巴德群岛中部海域表层海水水质研究

掌握北极海水水质特征及地域分布等第一手数据对北极科考意义重大。该项研究工作是全国青少年北极科考子任务,于2017年夏季在北极斯瓦尔巴德群岛中部海域对表层海水水质特征、地域差异及相关控制因素进行了研究。选取了6个区域共40个采样点采集表层海水样本,从温度、酸碱度、电导率、溶解性总固体量、实际盐度和溶解氧饱和度等方面进行了水质特征测量分析,发现该海域6个区域在海水温度、电导率、溶解性总固体量、实际盐度及溶解氧饱和度等方面均有较大差异,而酸碱度差异不大: 北部冰区水温最低,溶解性总固体量最低,溶解氧含量较高; 西北部海湾溶解氧饱和度最高; 中部海峡溶解性总固体量最高,盐度和电导率最低; 南部海域水温最高,实际盐度和电导率最高,溶解氧饱和度最低; 东部沿海水温偏低。采样点地理位置、洋流情况、地形地貌等因素对表层海水水质均有影响。这些研究成果对补充我国在北极地区的第一手科考数据和进行深入的科考研究具有重要意义。     

Measurement of seasonal variability of hydro-environmental characteristics of Kuwait Bay

To fill in the large existing data gap, this study presents results of a comprehensive data set from Kuwait Bay (KB), showing the horizontal and vertical distribution of its prominent hydrodynamic variables (i.e., water temperature, seawater salinity, seawater density) and water quality variables (i.e., chlorophyll-a concentration, turbidity, dissolved oxygen (DO) concentration, DO saturation, apparent oxygen utilization, photosynthetic active radiation). Field measurements were carried out between 11 September 2014 and 17 August 2015 covering number of monitoring stations in the entire bay. The results revealed significant seasonal variations and apparent three-dimensional features of the measured variables exemplifying the necessity of not considering the bay as a well-mixed water body in the future oceanographic studies anytime of the year. However, well-mixed conditions (with the Brunt-Vaisala frequency of about 0.0002 s^?1) were existent only in the winter. Bay’s water column began stratifying in late spring, and these were significantly intensified (with the Brunt-Vaisala frequency of about 0.0008 s^?1) during the summer and early autumn. The stratification, together with the increase oxygen demand for decomposition processes and decrease in DO solubility in summer, led to the formation of a lower DO water mass (daytime DO concentration <4.2 mg l^?1) at the lower layers. Results also suggested that the water of the KB is more transparent (indicated by lower turbidity) compared to the adjacent sea water. Measurement of light intensity along the water column indicated that the light extincts rapidly (i.e., the light reduced to approximately 10 % of the surface values at water depth of 2–6 m) in KB and many times absent at the water near the seabed. This study also suggested that the KB can be classified at a year-round negative, hypersaline, inverse, and hyperpycnal estuary.     

季节性冰封热融浅湖水温原位观测及其分层特征

为探究季节性冰封浅湖热力学特征,于2010年10月至2013年7月对高原腹地一典型热融湖塘冰层生消、水/冰温及气象条件开展原位观测,分析了水温分布时间变化、温跃层以及冰生消对水温结构的影响。结果发现:冰面升华显著,贯穿整个冰期;水温日变化、季节变化和垂直结构受气温、大气辐射、风速、冰生消和湖底沉积层热贡献影响显著;在"无冰期-结冰前-冰生长期-冰融化期-融化后-无冰期"年循环过程中水温垂直结构分别呈现出"分层-翻转-逆温分层-逆温与正温共存-翻转-分层"的循环过程。分层期水温结构仅由上部混合层和温跃层构成,且偶因强风搅动而全湖翻转混合。可见,相比大中型湖泊,季节性冰封浅湖热力学结构差异显著。     

太湖水体水温垂向分层特征及其影响因素

为揭示大型浅水湖泊水温分层特征及其影响因素,采用温度链,高频观测太湖水温分层的周年变化过程.结果表明:太湖水体水温的垂向温差绝大多数处在0～l℃,部分处于l ～4C,偶尔超过4℃;太湖水体水温垂向温差存在季度、月、日差异,相应的分层位置也不同;水温分层影响因素包含太阳辐射、气温、风速、水密度和比热、藻华堆积等.随着太阳...     

渤海层化结构及潮汐锋面季节变化的数值研究

采用三维斜压海流模式(POM)模拟了渤海海温的季节变化,以海表与海底温差ΔT作为判别依据,发现3月份前整个渤海的表、底温差小于0.5℃,说明渤海处于充分混合状态;进入4月份以后,莱州湾、渤海中部以及渤海海峡的局部水域出现超过2℃的表、底温差,意味着垂向层化结构开始形成;层化区域面积随着海表热通量增大的趋势可一直持续到8月,9月后由于日照量逐渐减小,季节性温越层逐渐消失,11月以后渤海又恢复到充分混合的状态.     

天目湖热力学状况的监测与分析

根据2001年6月～2002年5月在天目湖进行的每月一次的全湖水温观测以及2002年5月25～26日在1号点的定点24h连续水温观测资料,分析研究了天目湖水温时空分布、垂直分布、温跃层的形成与变化以及湖泊热力学对溶解氧、营养盐的影响,揭示了各自的基本变化规律。结果表明:天目湖水温的日变化、年变化及垂直分布明显,而其水平差异不大;温跃层随着季节的变化而呈现增强-稳定-减弱-消失的周期变化;水温的变化以及温跃层的存在引起了水中溶解氧以及营养盐的变化。     

岩溶水库热结构变化对水体溶解无机碳及其同位素的影响过程

以中国南方亚热带地区典型的地下水补给型水库——大龙洞水库为对象,于2018年1月、4月、7月、10月、12月分别在上、中、下游三个监测点进行采样,探究水库热结构变化对于水体无机碳及其同位素的影响过程及机理。结果表明:（1）大龙洞水库水体在一个水文年中呈现周期性的混合期—分层期—混合期的热结构变化,4月热分层开始显现,7月逐渐显著呈现完整的热分层,10月以后热分层逐渐消失,水体逐渐实现混合;（2）水体热分层是溶解无机碳（DIC）浓度与碳稳定同位素（δ13C_DIC）值变化的主要驱动力。表水层中DIC主要受水—气界面二氧化碳脱气、水生生物光合作用控制,其DIC浓度与δ13C_DIC值分别为3.22 mmol·L?1和?9.15‰;温跃层中DIC主要受有机质降解过程影响,其DIC浓度与δ13C_DIC值分别为3.43 mmol·L?1和?9.70‰;底水层中DIC主要受碳酸盐沉淀过程影响,其DIC浓度与δ13C_DIC值分别为4.32 mmol·L?1和?11.89‰;（3）三种过程伴随水库热结构的变化而变化,驱动DIC浓度及其同位素的变化梯度 G (DIC)与 G (δ13C_DIC)的变化,表现为底水层＜表水层＜温跃层。热分层结束进入混合期后,DIC浓度与δ13C_DIC值的时空差异均逐渐消失,最终表现出DIC浓度与δ13C_DIC值的均一化。      

Water Quality Characteristics and Variations of Lake Dian

In order to understand the seasonal change tendencies of the water quality of the Lake Dian (Dianchi), the monitoring data from April to September 2015 at four sites distributed in the central part from North to south were analyzed, these data includes the profiles of the water temperature (Temperature or Temp.), Dissolved Oxygen content (DO), pH values, Chlorophyll-a (Chl-a), Phycocyanin (PC) and Conductivity (CD). At the same time, the Cyanophyte Relative Quantity Index (CRQI) was calculated based on the contents of Phycocyanin and Chlorophyll-a. The results demonstrate that along with the air temperature increase, the water temperature also increased step by step from April and May, and reach the maximum in June, from July to September, the water temperature kept relatively stable and decrease steadily. It also shows that the water temperature is not only various with different water depth, but also show that the temperature increase at different speed, even generally show that the surface temperature increase more rapidly than the deep water. The water temperature and its changes may adjust the air temperature of Kunming strongly and therefore, it is important for the forming of the Four Springs City of Kunming. We found that the amount of eukaryotes represented by Chlorophyll-a increased quickly and reach the highest level in the April, but the blue-green algae, which represented by the Phycocyanin is blooming in the September. This might imply that when the blue-green algae dominated the algae, the algae blooming occur. This is of great importance to understand the algae blooming processes in Lake Dian. We hope the further monitoring will provide us more detailed and useful information. Mean while, the changes of DO, pH and CD all have shown their unique that inspire us to continue the lake water monitoring. This monitoring work also proves that the single site measurements cannot provide any reliable and useful information about the lake water quality. More detailed and sustained monitoring works need to be done before we have a fully understanding on the changes of the lake water quality.     

High-resolution monitoring of water temperature and oxygen concentration in Lake Murten (Switzerland)

Lake Murten is located in the Lake District in western Switzerland and so far, it has been poorly investigated. The Environmental Service of Fribourg (SEn) has monitored this lake once a month for several years by water profiles (water temperature, pH, dissolved oxygen, conductivity) at its deepest part. The SEn identified the stratification of water masses as one of the main causes for oxygen consumption in the hypolimnion. In the present study, a Lander System was deployed in Lake Murten from April to September 2015 at 20 m depth at the northwestern part of the lake to monitor water temperature and dissolved oxygen at higher resolution (30 s interval). These records were compared with time series of atmospheric parameters like atmospheric temperature, wind speed and precipitation. A clear correlation of lake temperatures with wind speed was observed during the Spring and Autumn. The water mass stratification evolved through the season and reached its peak during Summer, preventing surface turbulences to reach the deeper part (20 m) of the water column and to partially oxygenate the metalimnion.     

Advances in Oxygenation Theory and Technology in Deep Lakes

Deep lakes always maintain vertical thermal stratification due to their physical structure. The thermocline prevents the transfer of oxygen from epilimnion to hypolimnion, leading to the formation of anoxic conditions in deeper water, the enhanced release of endogenous pollutants and the deterioration of water quality. Oxygenation is an effective measure to improve the water quality of deep lakes and mitigate the release of endogenous pollutants via the increase of the oxygen level in water. This paper provided an overview of the method and theory of oxygenation in deep lakes. Advantages and limitations of different methods of oxygenation, including artificial destratification, airlift aerators, Speece cone and bubble plume diffusers, were discussed. In addition, challenges and prospects of oxygenation were assessed based on the analyzing of typical examples of oxygenation in deep lakes and the difference in oxygenation system used in deep lakes and shallow lakes.     

Two-dimensional modelling of hydrodynamics and water quality of a stratified dam reservoir in the southern side of the Mediterranean Sea

A vertical two-dimensional, laterally averaged hydrodynamic and water quality model CE-QUAL-W2 was used to simulate water temperature, dissolved oxygen, electrical conductivity, chlorophyll a, total suspended solids, alkalinity, ammonium, phosphate, and total iron in the Sejnane Dam (North Tunisia) in response to external forcings that characterize main features of climate in the southern side of the Mediterranean Sea. The hydrodynamic modelling results show that the model is able to reproduce accurately the measured water surface elevation, spatio-temporal patterns of temperature, dissolved oxygen and other state of variables and to capture most of the seasonal changes in the reservoir. Three scenarios involving the impacts of severe drought season, summer rainfall and total suspended solids load on hydrodynamics and water quality are analyzed. Severe drought reduces the thickness of hypoxic waters from 10 to 2–4 m and shifts the temperature of the entire water column up to 5 °C during summer and about 1.2 °C in winter. The thermocline takes place 1 month before that of the reference and sinks to the bottom faster by 1–2 m per month. Summer rainfall dilutes the first waves of the autumn rains and disrupts the thermal gradient in the water column, which may show complex thermal structures. TSS load has the most negative effects on water quality in that it shifts the phosphorus concentration by 1–3 mg/l and promotes an early warming of surface water in spring and an early cooling since late summer by up to 1 °C. During summer stratification, it contributes to the cooling of the metalimnion by 2 °C on average, which may alter its structure and dynamics as an aquatic biotope.     

Hydrological and biogeochemical dynamics of the minor and trace elements in the St. Lawrence River

Surface water samples from the St. Lawrence River were collected in order to study the processes controlling minor and trace elements concentrations (Al, Fe, Mn, Cd, Co, Cu, Ni and Zn), and to construct mass balances allowing estimates of the relative importance of their natural and anthropogenic sources. The two major water inputs, the upper St. Lawrence River, which drains waters originating from the Lake Ontario, and the Ottawa River were collected fortnightly over 18 months. In addition, other tributaries were sampled during the spring floods. The output was monitored near Quebec City at the river mouth weekly between 1995 and 1999. Dissolved metal concentrations in the upper St. Lawrence River carbonated waters were lower than in the acidic waters of the tributaries draining the crystalline rocks of the Canadian shield and the forest cover. Biogeochemical and hydrodynamic processes occurring in Lake Ontario drive the seasonal variations observed in the upper St. Lawrence River. Biogeochemical processes relate to biological uptake, regeneration of organic matter (for Cd and Zn) and oxyhydroxide formation (for Mn and Fe), while hydrodynamic processes mainly concern the seasonal change in vertical stratification (for Cd, Mn, and Zn). In the Ottawa River, the main tributary, oxyhydroxide formation in summer governs seasonal patterns of Al, Fe, Mn, Cd, Co and Zn. The downstream section of the St. Lawrence River is a transit zone in which seasonal variations are mainly driven by the mixing of the different water masses and the large input of suspended particulate matter from erosion. The budget of all dissolved elements, except Fe and Zn, was balanced, as the budget of particulate elements (except Cd and Zn). The main sources of metals to the St. Lawrence River are erosion and inputs from tributaries and Lake Ontario. Direct anthropogenic discharges into the river accounted for less than 5% of the load, except for Cd (10%) and Zn (21%). The fluxes in transfer of dissolved Cd, Co, Cu and Zn species from the river to the lower St. Lawrence estuary were equal to corresponding fluxes calculated for Quebec City since the distributions of dissolved concentrations of these metals versus salinity were conservative. For Fe, the curvature of the dilution line obtained suggests that dissolved species were removed during early mixing.     

Arsenic speciation in Mono Lake, California: Response to seasonal stratification and anoxia

Mono Lake is a closed-basin, alkaline, hypersaline lake located at the western edge of the Great Basin in eastern California. We studied the distribution of arsenic (As) species in the water column of Mono Lake between February and November, 2002. This period captured the seasonal progression from winter mixing, through summer thermal stratification, to autumn overturn. Arsenic speciation was determined by ion chromatography-inductively coupled-plasma-mass spectrometry of samples preserved in the field by flash-freezing in liquid nitrogen. We found that arsenic speciation was dominated (>90%) by arsenate when oxygen was detectable. Once levels fell below 6 μmol/L O₂, arsenic speciation shifted to dominance by reduced species. Arsenate and arsenite co-occurred in a transition zone immediately below the base of the oxycline and low but significant concentrations of arsenate were occasionally detected in sulfidic hypolimnion samples. Thio-arsenic species were the dominant form of As found in sulfidic waters. Maxima of thio-arsenic species with stoichiometries consistent with mono-, di- and trithio-arsenic occurred in succession as sulfide concentration increased. A compound with a stoichiometry consistent with trithio-arsenic was the dominant As species (∼50% of total As) in high sulfide (2 mmol/L) bottom water. Lower concentrations of total As in bottom water relative to surface water suggest precipitation of As/S mineral phases in response to sulfide accumulation during prolonged anoxia.     

太湖水体光学衰减系数的分布及其变化特征

利用2001-2002年周年太湖全湖不同湖区湖泊光学的实测资料,分析了太湖水体光学衰减系数的区域分布,季节变化,垂直分布及日变化特征,并阐述了其变化原因,将太湖与国外一些湖泊进行对比,进一步阐述了太湖的光学特征.结果表明:光学衰减系数的湖区分布大致为:河口区>五里湖>湖心区>梅梁湾>贡湖>东太湖;由于不同湖区对光学衰减系数影响的主导因素不一样,其季节变化存在差异,东太湖季节变化不大,湖心区衰减系数秋冬季较大,而梅梁湖区则夏秋较大;衰减系数日变化则表现为中午大,上午和下午小;衰减系数的垂直分布主要有逐渐递减和先递减后均匀2种类型;衰减系数的光谱特性表现为在短波部分较大,长波部分较小,670nm处有一相对高值.     

Hydrogeochemistry and groundwater quality in the coastal sandy clay aquifers of Alappuzha district, Kerala

Groundwater qualities of coastal aquifers in the Chennam-Pallippuram Panchayath of Alappuzha district, Kerala have been extensively monitored in summer from January to May, 2007 to assess its suitability in relation to domestic and agricultural uses. The water samples (n=36) were analyzed for various physico-chemical attributes like temperature, pH, electrical conductivity (EC), dissolved oxygen (DO), Na, K, Ca, Mg, alkalinity, hardness, silica, chloride, salinity, total dissolved solids (TDS) and sulphate (SO₄ ^2?). Values of most of these parameters fall within permissible limits. Major ionic relationships indicate that weathering reactions have insignificant role in the hydrochemical processes of the shallow groundwater system. Hydrogeochemical processes controlling the water chemistry are precipitation rather than rock-water interaction. Various determinants such as Sodium Absorption Ratio (SAR), Percent Sodium (Na %), Residual Sodium Carbonate (RSC), and Kelley’s Ratio revealed that most of the samples are suitable for irrigation.     

Seasonal variations in sulfur isotopic composition of dissolved SO<Subscript>4</Subscript><Superscript>2−</Superscript> in the Aha Lake,Guiyang and their implications

The Aha Lake is a seasonal anoxic water system in the southwest of Guiyang City, Guizhou Province, China. Seasonal variations in SO42- concentrations and their isotopic compositions in lake water as well as in the tributaries were investigated in this study. The results showed that sulfate concentrations in river water range from 0.94 to 6.52 mmol/L and their δ34S values range from -14.9‰ and 0.9‰, while lake water has sulfate concentrations ranging from 1.91 to 2.79 mmol/L, and δ34S values from -9.8‰ to -5.9‰. It is suggested that coal mining drainage is the major source of SO42- in the Aha Lake. Rainfall, sewage discharge, sulfide oxidation and gypsum dissolution have made only limited contributions. Different depth-dependent distributions of dissolved SO42- and δ34S were de-veloped for both DB and LJK in summer and winter. Due to water overturn, δ34S values display homogenous vertical distributions in winter and spring. While in summer and autumn, significant positive shifts of δ34S were clearly ob-served in epilimnion and bottom strata as a result of water stratification. High δ34S values in epilimnion may result from the retention of rainwater during water stratification. Dissimilatory sulfate reduction by bacteria was thought to be responsible for the increase of δ34S value in hypolimnion.