北羌塘盆地三叠系康南组砂岩地球化学特征及其对物源区和构造背景的制约

沉积盆地中碎屑砂岩的地球化学特征主要受物源区的制约,分析碎屑砂岩的化学成分可以揭示盆地砂岩的物源属性和构造背景。笔者对北羌塘盆地三叠系康南组碎屑砂岩进行全岩分析。样品具有高SiO_2含量,K_2O/Na_2O值变化较大,TFe_2O_3+MgO含量中等。稀土元素配分模式图显示富集轻稀土元素,(La/Yb)N=3.96～9.25,平均为6.32,δEu明显负异常;δCe呈弱负异常。碱土金属元素和化学蚀变指数(CIA)以及成分变异指数(IPV)说明其源区物质较新鲜,成熟度相对较低,化学风化作用较弱—中等。此外,微量元素Th/U、La/Sc、Th/Sc等值以及TiO_2-Ni、La/Th-Hf、Co/Th-La/Sc和Th/Sc-La/Sc源岩判别图解反映砂岩的物源具有长英质特征。砂岩的SiO_2-K_2O/Na_2O、La-Th、La/Y-Sc/Cr双变量图解,La-Th-Sc、Th-Sc-Zr/10、Th-Co-Zr/10三变量图解以及Th/U、Rb/Sr等值表明北羌塘三叠系康南组碎屑砂岩的物源区构造背景以大陆岛弧为主,兼有被动大陆边缘构造背景特征。     

从岩石化学特点看板溪群的沉积大地构造背景

将板溪群和冷家溪群杂砂岩全岩岩石化学分析结果在SiO_2-K_2O/Na_2O图解、SiO_2/Al_2O_3-K_2O/(Na_2O+CaO)图解、Na_2O-K_2O图解以及(K_2O+Na_2O)—Al_2O_3图解上投点,发现多数板溪群杂砂岩样品点落在被动大陆边缘区,而冷家溪群杂砂岩样品点则多落入活动大陆边缘区。因此认为,板溪群沉积于被动大陆边缘,而冷家溪群沉积于活动大陆边缘,它们形成于不同的地质演化阶段。     

四川盆地北部早白垩世剑门关组泥质岩地球化学特征及其地质意义

早白垩世剑门关组是研究四川盆地北部沉积环境演化的良好地层,对该地层开展系统的地球化学研究,对探讨四川盆地北部早白垩世剑门关组物源区性质、构造背景、古风化作用及古环境具有重要意义。系统分析了剑门关组泥质岩主量、微量和稀土元素地球化学特征,发现早白垩世剑门关组泥质岩富CaO、MgO,贫Al_2O_3、Fe_2O_3、K_2O、Na_2O、TiO_2、P_2O_5、MnO,富Cr、Cs、V,贫Sr、Nb、U、Hf,稀土元素总量为(164.96～234.35)×10^-6,轻、重稀土元素比值为11.77～15.87,轻、重稀土元素分馏程度高,轻稀土元素相对富集,具弱的正Eu异常。综合分析认为:剑门关组为同一物源的近物源再旋回沉积岩;源岩为沉积岩,可能富含斜长石、重晶石等富Eu矿物;源岩在沉积前经历了中等程度的化学风化作用,并发生了钾交代作用;剑门关组沉积期为温暖、湿润的气候,物源区具有由活动大陆边缘向大陆岛弧转化的特征。     

北羌塘盆地沃若山地区早侏罗世雀莫错组砂岩地球化学特征与物源判别意义

出露于羌塘盆地沃若山地区的雀莫错组砂岩是北羌塘盆地早侏罗世的沉积物,对研究早侏罗世沉积盆地的演化特征具有重要的意义。通过对其地球化学特征的分析研究,结果表明该组砂岩为被动大陆边缘裂陷期的沉积产物,岩性主要为岩屑砂岩,岩石矿物成分主要在钾长石、斜长石、伊利石、绿泥石以及石英之间变化。化学风化作用指标(CIW)、化学蚀变作用指标(CIA)和A-CN-K图解,反映该组砂岩的碎屑成分受到了强烈的风化环境,并在风化过程中发生钾交代作用,长石发生伊利石化。化学组分指标(ICV)表明岩石碎屑为近源的第一次旋回沉积物,受沉积分选和再循环作用影响不大;A-CN-K图解还反映出砂岩碎屑源岩中斜长石含量高于钾长石含量,主要在花岗岩和花岗闪长岩之间变化;稀土元素特征表明该组砂岩具有同源性,其成分主要受源区岩石成分控制,为酸性火山岩类。     

滇东南猛洞岩群构造环境：变质碎屑岩地球化学约束

猛洞岩群位于滇东南文山-麻栗坡断裂与红河断裂带之间的老君山-Song Chay变质核杂岩核部,由一套经历过多期变质-变形的杂岩体组成。变质碎屑岩地球化学特征显示,主、微量元素平均组成与大陆上地壳相似,且SiO_2/Al_2O_3、K_2O/Na_2O比值显示该套变质沉积岩具有相似的成熟度,但片岩类样品可能遭受过强烈的风化作用;稀土元素特征与变质岩原岩恢复图解显示,片岩类原岩为黏土岩及泥质岩,片麻岩类原岩为砂岩、杂砂岩。化学蚀变指数(CIA)、成分变异指数(ICV)、斜长石蚀变指数(PIA)反映了片岩类原岩形成后经历过较强的风化作用,但副片麻岩类原岩经历的风化作用较弱,反映了副片麻岩类主要来源于不成熟的物源区,显示出活动构造环境沉积物的特征。Rb/Sr和Th/U比值判别结果表明该套碎屑岩经历了较复杂的沉积演化过程;La/Th-Hf图解和砂岩-泥岩套的物源区判别图解表明变质碎屑岩样品以石英岩沉积物源区为主,混合少量中性火成岩物源区;ThSc-Zr/10和La-Th-Sc图解表明猛洞岩群可能沉积于大陆岛弧环境。综上所述,猛洞岩群变质碎屑岩原岩为一套泥质岩-砂岩(杂砂岩),这套碎屑岩经历了较强风化作用及复杂的沉积演化过程,主要沉积于与大陆岛弧环境相关的盆地,推测猛洞岩群的物质来源与昆阳群有关,可能与扬子地块具有较强的亲缘关系。     

福建西部早古生代杂砂岩特征及其源区和构造背景

福建西部早古生代杂砂岩属富石英杂砂岩类。稳定碎屑石英的高含量和不稳定碎屑长石、岩屑的强烈贫化,表现了沉积物具再旋回特点。很高的SiO_2含量及CaO、Na_2O的贫化,并以低的Fe_2O_3+MgO、Al_2O_3/SiO_2、TiO_2和高的变化极大的K_2O/Na_2O、Al_2O_3/(CaO+Na_2O)与被动大陆边缘沉积的杂砂岩相类似。稀土元素模式及其参数特征相似于现代的和古代的被动大陆边缘环境沉积的杂砂岩。分析表明,本套杂砂岩的源岩是以沉积岩、浅变质岩为主和中—酸性火成岩混合组成,所处的大地构造背景为构造上不活动的被动大陆边缘或弧后盆地环境。     

藏南贡嘎晚侏罗世—早白垩世海相地层地球化学特征与古海洋环境演化

西藏南部有出露良好的海相侏罗纪—白垩纪地层。本研究针对采自藏南贡嘎东拉剖面的样品进行了常量、微量和稀土元素分析,探讨晚侏罗世—早白垩世海洋沉积环境的演化。Fe_2O_3+MgO与TiO_2、Al_2O_3/SiO_2关系判别图显示,从晚侏罗世维美组到早白垩世桑秀组,研究区经历了从大陆岛弧到大洋岛弧的构造演化。Mn、Fe、V、Co、Ni、REE等指标元素,和U/Th、V/Cr、Sr/Ba、Lan/Ybn、V/(V+Ni)等比值结合显示:沉积条件也从维美组浅海富氧、低盐、高沉积速率的环境演化为早白垩世桑秀组深海、水体分层、盐度升高、沉积速率降低,具有明显深海沉积特征的环境。地化数据分析结果总体上与岩性成因分析相一致,即维美组砂岩所指示的浅海相沉积,桑秀组从下部的粉砂岩到上部钙质泥岩,经历了水体由浅到深的变化过程。     

辽宁本溪大台沟铁矿床地球化学特征及成因探讨

为探讨辽宁大台沟铁矿床的成矿物质来源及形成环境,选取典型铁矿石5块进行主量元素、微量元素和稀土元素分析测试。结果显示:大台沟铁矿床保存有明显的化学沉积特征,化学成分主要由Fe_2O_3,FeO和SiO_2组成(Fe_2O_3+FeO+SiO_2=87.33%～96%),其他组分(MnO,MgO,CaO,Na_2O,K_2O,TiO_2,P_2O_5,Al_2O_3)含量较低;页岩标准化后的稀土元素配分曲线显示为稀土总量低(ΣREE平均为19.65×10^-6),轻稀土元素相对亏损,重稀土元素相对富集;且具有一定的Eu(Eu/Eu~*=1.52～2.72),Y(Y/Y~*=1.18～1.52),La(La/La~*=1.17～2.26)的正异常,弱的Ce(Ce/Ce~*=0.79～0.92)异常;Y/Ho值平均34.19接近于海水的分布范围;Sr/Ba值平均1.79,属于火山岩和海相沉积物;Ti/V值平均38.84,属于火山建造。这些特征表明:该矿床的形成可能与海相火山沉积物有关,属于火山沉积变质型铁矿范围;成矿物质来源于热水和海水的混合作用;矿床形成于相对于缺氧的环境。     

内蒙古北山白云山蛇绿混杂岩带南部锡林柯博组碎屑岩地球化学特征、源区属性及构造意义

为揭示北山洋俯冲极性问题,对内蒙古北山造山带白云山地区的锡林柯博组砂岩进行了地球化学分析。结果表明,砂岩主要为长石石英砂岩和长石岩屑砂岩,少量为岩屑石英砂岩,且均表现为弱变质;矿物成分主要为石英、斜长石、钾长石等;主量元素平均含量Si O2为80.70%,Al2O3为8.07%,MgO为1.08%,Ca O为1.48%,TFe2O3为1.86%,K2O为1.12%,N a2O为1.75%;稀土元素配分模式曲线一致,LREE/HREE=11.32～16.54,平均为13.83,(La/Yb)N=7.38～12.39,平均10.43,负Eu异常,轻稀土元素相对重稀土元素明显富集,稀土元素分馏明显。锡林柯博组碎屑沉积岩CIA值反映研究区物源碎屑岩遭受了温暖、湿润条件下中等的化学风化作用,其母岩可能来源于酸性火山岩或花岗岩。结合锡林柯博组岩石组合特征、构造组合特征及地球化学特征,认为其源岩形成于被动陆缘构造环境,揭示了物源可能来自于塔里木地块,从侧面反映了北山洋向北俯冲的极性。     

莺歌海盆地上中新统黄流组海底扇砂岩元素地球化学特征及地质意义

基于砂岩岩心样品元素地球化学资料对莺歌海盆地东方区上中新统黄流组一段海底扇砂体的源岩类型、风化程度及构造背景进行了分析。以平均大陆上地壳(UCC)对主量元素做标准化处理,结果显示SiO2略显示富集,CaO和TiO2仅4个样品相对富集,其他大部分样品主量元素均显示相对亏损特征。稀土元素配分模式呈现轻稀土元素富集、重稀土元素亏损特征,轻稀土元素与重稀土元素比值介于7.58~11.12之间(平均9.28),(La/Yb)N介于7.15~13.55之间(平均11.04),(Gd/Yb)N介于1.34~2.07之间(平均1.81),Eu元素显示负异常,δEu介于0.48~0.70之间(平均0.64),且样品的配分模式与UCC相似,Al_2O_3/TiO_2=11.03~17.02(平均14.48),以及w(K_2O)-w(Rb)和w(TiO_2)-w(Zr)图解均表明源岩为中性-长英质火山岩。化学蚀变指数(CIA)值(56.48~68.97)、长石蚀变指数(PIA)值(58.90~75.78)、A-CN-K图解表明黄流组砂岩经历了中等强度的风化作用。Th-Sc-Zr/10三角图、w(TiO_2)-w(Fe_2O_3+MgO)判别图解以及主量元素判别图解均显示源区具有碰撞环境特征(主动大陆边缘或大陆岛弧),且稀土元素配分模式与越南物源相似。综合可知,西部昆嵩隆起的中性-长英质火山岩为研究区主要物质来源。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Total mercury and monomethylmercury in water, sediments, and hydrophytes from the rivers, estuary, and bay along the Bohai Sea coast, northeastern China

Mercury contamination in aquatic environments is of worldwide concern because of its high biomagnification factor in food chains and long-range transport. The rivers, estuary and the bay along the northwestern Bohai Sea coast, northeastern China have been heavily contaminated by Hg due to long-term Zn smelting and chlor-alkali production. This work investigated the distributions of total Hg (THg) and monomethylmercury (MMHg) in the water, sediment and hydrophytes from this area. Concentrations of THg in sediment (0.5–64 mg kg⁻¹) and water (39–2700 ng L⁻¹) were elevated by 1–3 orders of magnitude compared to background concentrations, which induced high concentrations of MMHg in these media. The highest concentration of MMHg in sediment reached 35 μg kg⁻¹, which was comparable to that in the Hg mining area, Wanshan, China, and the highest MMHg concentration of 3.0 ng L⁻¹ in the water sample exceeded the MMHg Chinese drinking water guideline of 1.0 ng L⁻¹. Concentrations of THg in a sediment profile from Jinzhou Bay were found to be consistent with annual Hg emission flux from a local Zn smelter (r = 0.74, p < 0.01), indicating that Hg contamination was mainly caused by Zn smelting locally. For some freshwater hydrophytes, concentrations of THg and MMHg ranged from 5.2 to 100 μg kg⁻¹ and 0.15 to 12 μg kg⁻¹, respectively. Compared to sediment, concentrations of THg in hydrophytes were 2–3 orders of magnitude lower but MMHg was comparable or higher, indicating that the bioaccumulation in plants was distinct for the two Hg species studied. The data suggest that a significant load of Hg has been released into the northwestern coastal region of the Bohai Sea.     

Metals,arsenic, and sulfur in the Aue and Eibenstock granites,Erzgebirge

Average concentrations of Pb, Zn, Cu, and other metals, as well as S and As, were calculated for the Aue granitic cupola, the contact aureole of which hosts the large vein-type uranium deposit of Schlema-Alberoda and the Schneeberg uranium-base metal deposit (Erzgebirge, Germany). The cupola was exposed by mine workings and boreholes, which provided an opportunity to evaluate variations in the abundances of metals in the granites over a vertical interval of more than 2.5 km and estimate their losses in the upper oxidized part of the investigated volume of the cupola (coefficient of iron oxidation, KO _Fe, increases in the granites from bottom to top from 7 to 70%) compared with the lower unaltered and unoxidized part (with a KO _Fe plateau at about 5%). The average concentrations of metals in the upper part of the cupola are lower than those in the lower part by a factor of 2.5 for Pb, 1.56 for Zn, 1.45 for Cu, 1.3 for Co, etc. A similar decrease in the abundances of ore elements along the vertical section associating with the relative epigenetic alteration and oxidation of the granite was previously described by us for U and Th and for the components of high-temperature ores, W, Sn, and Mo. The removal of ore elements from the granite was accompanied by a decrease in the bulk contents of sulfur and arsenic by a factor of 1.35 and 1.65, respectively. The leaching of trace metals from the granites of the upper part of the Aue cupola was followed by their partial redeposition above the cupola in the ore veins of the Schlema and Schneeberg deposits. Original Russian Text ? Vikt. L. Barsukov, N.T. Sokolova, O.M. Ivanitskii, 2006, published in Geokhimiya, 2006, No. 9, pp. 967–982.     

Distribution of REE,LILE, and HFSE between biotite,feldspar, and the melt in the granulite facies migmatite,nimnyr block,Aldan shield

The behavior of trace elements under conditions of partial melting of granitoid rocks has been studied. The element’s partition coefficients between minerals and the melt D_i^min/melt depends, in the first place, on the composition of the primary melt. In biotite the HREE D_i are a little below 1, while those of LREE, especially D_i for Ce, are 1–3 orders of magnitude less. This leads to an efficient differentiation of REEs in anatexic melts especially when biotite is the main mineral phase of restite. On the contrary, there are feldspars, the D_i of which cannot provide such a magnitude of differentiation. Unlike garnets and pyroxenes, whose stability in restite permits enrichment of anatexic melts produced in migmatization zones with Nb, Ti, and Cr, the presence of biotite in restite causes depletion of melts with those elements as well as with Rb. Feldspars, under conditions of their fractional crystallization or during differentiation of an anatexic melt, deplete the latter with Sr, Ba, and Rb, but enrich it with Nb, Ti, Cr, Y, Zr, and V.     

Text, talk, things, and the subpolitics of performing place

This article tells the story of how a group of Dutch and Belgian citizens organized themselves to promote an area that they valued, to put it on the map, to raise awareness about its qualities, and to protect it from urban and industrial development. Our theoretical perspective focuses on the performative and political aspects of this place-making process and the discursive and material practices involved. We connect this to Beck’s concept of subpolitics.Our findings show how the group performed this place not only through text and talk - giving the area a name, using their knowledge and expertise to raise awareness about its values, lobbying and cooperating with decision-makers -, but also through things - installing art objects and information signs that articulate certain characteristics and values of the area. Our findings demonstrate the struggles involved in these performances. The group involved multiple perspectives on what the important values and characteristics of the area are and on what strategies would work best in trying to influence decision-making and protect the area. However, the use of expertise as the main strategy to gain influence excluded the more critical and activist strategies and privileging archaeological and historical values and characteristics came at the expense of attention on agricultural and natural values.Our findings make clear that performing place cannot be taken to be homogeneous and that it inevitably involves multiple perspectives and demands. The struggles, power relations and dynamics of inclusion and exclusion that this multiplicity implicates reveal a form of sub-politics that involves both politicization and depoliticization. Also, it is a form of subpolitics that is more diverse and ambiguous than Beck’s conceptualization presupposes by its emphasis on the role of outsiders as a homogeneous group.     

Dielectric constants of apatite,epidote, vesuvianite,and zoisite,and the oxide additivity rule

The dielectric constants and dielectric loss values of 4 Ca-containing minerals were determined at 1 MHz using a two-terminal method and empirically determined edge corrections. The results are: vesuvianitel κ′ _a=9.93 tan δ=0.006 κ′ _c=9.79 tan δ=0.005 vesuvianitel κ′ _a=10.02 tan δ=0.002 κ′ _c=9.85 tan δ=0.003 zoisite1 κ′ _a =10.49 tan δ=0.0006 κ′ _b =15.31 tan δ=0.0008 κ′ _c=9.51 tan δ=0.0008 zoisite2 κ′ _a =10.55 tan δ=0.0011 κ′ _b =15.45 tan δ=0.0013 κ′ _c=9.39 tan δ=0.0008 epidote κ′ ₁₁= 9.52 tan δ=0.0008 κ′ ₂₂=17.1 tan δ=0.0009 κ′ ₃₃= 9.37 tan δ=0.0006 fluorapatite1 κ′ _a =10.48 tan δ=0.0008 κ′ _c = 8.72 tan δ=0.0114 fluorapatite2 κ′ _a =10.40 tan δ=0.0010 κ′ _c=8.26 tan δ=0.0178 The deviation (δ) between measured dielectric polarizabilities as determined from the Clausius-Mosotti equation and those calculated from the sum of oxide polarizabilities according to α _D (mineral)=∑ α _D (oxides) for vesuvianite is ～ 0.5%. The large deviations of epidote and zoisite from the additivity rule with Δ=+ 10.1 and + 11.7%, respectively, are attributed to “rattling” Ca ions. The combined effects of both a large F thermal parameter and possible F-ion conductivity in fluorapatite are believed to be responsible for Δ=+2–3%. Although variation of oxygen polarizability with oxygen molar volume (V_o) is believed to affect the total polarizabilities, the variation of V_o in these Ca minerals is too small to observe the effect.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.