Age relationships in supracrustal sequences of the northern part of the Murchison Terrane,Archaean Yilgarn Craton,Western Australia: A combined field and zircon U–Pb study

Mapping carried out in the northern Murchison Terrane of the Archaean Yilgarn Craton, Western Australia, shows that correlation of units between isolated greenstone belts is very difficult and an informal stratigraphic subdivision is proposed where the greenstone sequences have been divided into a number of assemblages. The assemblages may not necessarily be time equivalent throughout the region. The lower units (Assemblages 1–3) consist of ultramafic, mafic and intermediate volcanic rocks deposited without significant breaks in volcanism. Felsic volcanic packages (Assemblage 4) are conformable with underlying units, but are spatially restricted. Discordant units of graphitic sedimentary rocks are developed along major crustal structures (Assemblage 5). SHRIMP and conventional U–Pb study of zircons reveal that felsic volcanic rocks of Assemblage 4 in the Dalgaranga Greenstone Belt were emplaced at 2747 ± 5 Ma, whereas those in the adjacent Meekatharra — Mt Magnet Greenstone Belt range in age from 2762 ± 6 to 2716 ± 4 Ma. The age of emplacement of a differentiated gabbro sill in the Dalgaranga Greenstone Belt at 2719 ± 6 Ma places a maximum age on major folding in the belt. The presence of 2.9–3.0 Ga inherited zircons in some of the felsic volcanic rocks indicates contamination with, or reworking of, underlying 3 Ga sialic crust. This distinguishes the Murchison Terrane from the central parts of the Eastern Goldfields terranes to the south, where there is no evidence for a 3 Ga imprint in zircons from volcanic or granitic rocks, and also from the Narryer Gneiss Terrane to the north and west, which is composed of older gneisses and granitoids. The ca 2.76–2.71 Ga felsic volcanism in the Murchison Terrane is significantly older than 2.71–2.67 Ga felsic volcanism in the Eastern Goldfields lending support to models advocating assemblage of the craton by terrane accretion.     

Early Proterozoic Evolution of the Alto Jauru Greenstone Belt,Southern Amazonian Craton,Brazil

The Alto Jauru Greenstone Belt in west-central Brazil comprises three belts of Early Proterozoic volcano-sedimentary sucessions that were invaded by Early to Middle Proterozoic intrusions, including tonalites, gabbros, and granites. Volcanic rocks represent a bimodal suite with ultrabasic-basic rocks of komatiitic-tholeiitic affinities at the base and intermediate-felsic calc-alkaline lavas and pyroclastic units on the top. Chemical differences exist between basic volcanic rocks from the Jauru Belt and those from the Cabacal Belt, but the volcanic rocks and the Cabacal Tonalite appear to be related to an island-arc environment and possibly were generated from the same mantle source. The volcanic-volcanoclastic sequence in the Jauru Belt hosts important deformed, gold-rich volcanogenic massive sulfide deposits.     

The Nassara gold prospect,Gaoua District,southwestern Burkina Faso

The Nassara-Au prospect is located in the Birimian Boromo Greenstone Belt in southwestern Burkina Faso. It is part of a larger mineralized field that includes the Cu–Au porphyry system of Gaoua, to the north. At Nassara, mineralization occurs within the West Batié Shear Zone that follows the contact between volcanic rocks (basalt and andesite) and volcano-sediments (pyroclastics and black shales) at the southern termination of the Boromo Belt. Gold is associated with pyrite and other Fe-bearing minerals that occur disseminated within the sheared volcanic and volcano-sedimentary rocks. In particular, highest grades are distinguished in alteration halos of small quartz–albite–ankerite veins that form networks along the shear zone. Here, pyrites are marked by As-poor and As-rich growth zones, the latter containing gold inclusions. Gold mineralization formed during D2_NA. Subsequent shear fractures related to D3_NA related are devoid of gold. Nassara is a classical orogenic gold occurrence where gold is associated to disseminated pyrite along quartz veins.     

绿岩套和蛇绿岩套的区分标志

综合绿岩、蛇绿岩的有关概念、地质环境、岩石学、地球化学特征,论述蛇绿岩和绿岩之间的异同。 目前由于太古宙和显生宙地质构造研究的进展,使人们对绿岩套和蛇绿岩套的特征及其相互之间的异同性、联系性和形成环境越来越感兴趣。同时,在不同地区的地质构造研究中,对上述两种岩套在概念上和成因上存在混淆。本文将讨论这一问题。     

Inferred Palaeoproterozoic arc rifting along a consuming plate margin: insights from the stratigraphy,volcanology and geochemistry of the Kangerluluk sequence,southeast Greenland

The 200- to 300-m-thick volcano-sedimentary sequence in the Kangerluluk Fjord, associated with penecontemporaneous and late-tectonic dykes, as well as a synvolcanic plutonic suite, represents an integral component of the Palaeoproterozoic Ketilidian Mobile Belt, south Greenland. The ca. 1808-Ma Kangerluluk supracrustal sequence contains four distinct mappable lithofacies: (a) a conglomerate-sandstone lithofacies; (b) a pyroclastic lithofacies; (c) a volcanic lithofacies; and (d) a peperite lithofacies. The volcanic lithofacies, up to 200 m thick, is characterized by shallow-water subaqueous brecciated and pillowed flows. Flows are either (a) feldspar-phyric, or (b) feldspar-pyroxene-phyric, with 0.2- to 3-cm-size plagioclase and 0.2- to 3-cm-size pyroxene that constitute between 20 and 30% (locally up to 50%) of the flows. Mafic dykes intruded wet unconsolidated pyroclastic lithofacies, resulting in the formation of peperites. Geochemically, the volcanic and pyroclastic units represent a distinct tholeiitic magmatic suite enriched in incompatible trace elements including Th, La, Yb, Zr and Nb, and exhibiting (La/Yb)_n~10. The plutonic suite and associated dykes display a calc-alkaline trend with enriched LREE and unfractionated flat HREE patterns, La_n ranging between 50 and 100, (La/Yb)_n ratios between 8 and 22, and negative Nb and Ti anomalies on the mantle-normalized, incompatible multi-element patterns. The pillowed flows lie in the continental flood basalt field on the Y-Nb-Zr discrimination diagram, and display a Nb anomaly and K₂O-enrichment that collectively suggest a crustal component and/or a subduction-modified mantle source. The geology, stratigraphy of the Kangerluluk area and geochemistry can be used to infer a change in magma genesis from arc to rift volcanism. The 1850- to 1800-Ma calc-alkaline Julianehåb batholith represents a magmatic arc that rifted during crustal extension, allowing for the ascent of mantle-derived mafic magma. The geochemistry of the mafic volcanic flows, synvolcanic dykes and pyroclastic deposits favours a crustal component in magma genesis and offers new insights into the tectonic evolution of the Ketilidian Mobile Belt.     

A modern structural regime in the Paleoarchean (3.64 Ga); Isua Greenstone Belt, southern West Greenland

The footwall gneisses beneath the western part of the Paleoarchean (3.8 Ga) Isua Greenstone Belt, southern West Greenland, are interpreted here in terms of a 3.64 Ga stack of mylonitic crystalline thrust-nappes, the oldest example known on Earth. In present coordinates, the kinematic history of the thrust-nappe stack is couched in terms of initial longitudinal (strike-parallel) thrusting towards the southwest, followed by transverse thrusting to the northwest, and subsequent extensional collapse of the thickened crust toward the southeast.Diorite and tonalite that form the western margin of granitoids, structurally overlying the western part of the Isua Greenstone Belt and its footwall, contain 3.5 Ga mafic dykes, some of which are deformed and/or truncated at fault contacts within the granitoids. Accordingly, a component of the deformation structurally above the Isua Greenstone Belt occurred after 3.5 Ga, significantly later than the formation of the underlying mylonitic nappes, probably during the Neoarchean.The structural regime of mylonitic thrust-nappe stacking is very similar to that in modern mountain belts. It would appear that the deformational behaviour, rheological constitution and overall strength of Paleoarchean and modern continental crust were similar.     

Sources of continental magmatism adjacent to the late Archean Kolar Suture Zone,south India: distinct isotopic and elemental signatures of two late Archean magmatic series

 Conspicuous Nd, Sr and Pb isotopic differences exist between the Archean gneiss terranes adjoining the suture at the Kolar Schist Belt, south India. These gneisses, which are the deformed equivalents of plutonic and volcanic rocks, have known or inferred igneous ages of 2630 to 2530 Ma. Initial isotopic ratios of Nd, Sr and Pb suggest that metaplutonic gneisses west of the Kolar Schist Belt were emplaced into, and variably contaminated by, an evolved continental crust that formed prior to 3200 Ma. Felsic metaigneous gneisses that occur as slivers on the western margin of the schist belt have an isotopic character similar to that of the metaplutonic rocks on the same side of the Kolar Schist Belt. On the east side of the Kolar Schist Belt the isotopic evidence suggests that the 2530 Ma granitic gneisses were not derived from or contaminated by an older continental crust. Their source probably evolved with a Nd isotopic composition similar to that of typical Archean mantle, but became light rare earth element enriched after 2900 to 2700 Ma. The inferred tectonic setting for the west side of the Kolar Schist Belt is an Andean continental magmatic arc. For the east side of the Kolar Schist Belt, a possible Phanerozoic analog is an evolved island arc, such as Japan. Received: 24 June 1994/Accepted: 9 January 1995     

Geological setting and tectonic subdivision of the Neoproterozoic orogenic belt of Tuludimtu, western Ethiopia

The N–S trending Tuludimtu Belt in the extreme west of Ethiopia has been subdivided into five lithotectonic domains, from east to west, the Didesa, Kemashi, Dengi, Sirkole and Daka domains. The Kemashi, Dengi and Sirkole Domains, forming the core of the belt, contain volcano-sedimentary successions, whilst the Didesa and Daka Domains are gneiss terranes, interpreted to represent the eastern and western forelands of the Tuludimtu Belt. The Kemashi Domain, which consists of an ophiolitic sequence of ultramafic and mafic volcanic and plutonic rocks together with sedimentary rocks of oceanic affinity, is interpreted as oceanic crust and is considered to represent an arc-continent suture zone. The Dengi Domain, composed of mafic to felsic volcanic and plutonic rocks, and a sequence of volcanoclastic, volcanogenic, and carbonate sediments, is interpreted as a volcanic arc. The Sirkole Domain consists of alternating gneiss and volcano-sedimentary sequences, interpreted as an imbricated basement-cover thrust-nappe complex. All the domains are intruded by syn- and post-kinematic Neoproterozoic granitoids. Structural analysis within the Didesa and Daka Domains indicate the presence of pre-Pan African structures, upon which Neoproterozoic deformation has been superimposed. The gneissic rocks of these two domains are regarded as pre-Pan African continental fragments amalgamated to West Gondwana during Neoproterozoic collision events. Unconformably overlying all of the above are a series of tilted but internally undeformed conglomerate–sandstone–shale sequences, regarded as post-accretionary molasse-type deposits, formed during gravitational collapse of the Tuludimtu Belt. The Tuludimtu Belt is interpreted as a collision orogenic belt formed during the assembly of West Gondwana prior to final closure of the Mozambique Ocean.     

Geology, geochemistry and origin of the banded and granite gneisses in the basement complex of the Ilesha area, southwestern Nigeria

The basement complex in the Ilesha area consists of two distinct units — the gneisses and the schists. The Ilesha Schist Belt is a back-arc basin where there has been a subduction of an ocean slab into the mantle. This was followed by partial melting of mantle and ocean sediments to generate a wet basaltic magma, as revealed by spidergrams and REE fractionation patterns for the rocks in this belt. In this environment, differentiation of the wet basaltic magma led to the emplacement of a set of rocks, which formed a proto-continent. These rocks were then eroded to generate a sedimentary sequence which was metamorphosed into banded gneiss from which the granite gneisses were derived. The banded gneiss, characterised by alternation of felsic and mafic bands, is composed of medium to very coarse plagioclase, hornblende, quartz and biotite. The granite gneiss, composed of biotite, K--feldspars, quartz and minor garnet, occurs in close association with the banded gneiss.Chemical evidence revealed that elements that are depleted in the banded gneiss are concentrated in the granite gneiss and vice-versa; suggesting a petrogenetic link between these rocks.The schists were deposited as sediments composed of quartz, muscovite, biotite and Fe oxides. These sediments were metamorphosed to form quartzite schists which were folded into the gneisses. After the emplacement of these rocks, there was transpressive tectonic activity in this schist belt, causing deformation of these rocks, and emplacement of the northeast-southwest Ifewara-Zungeru Fault System, which separates the Ilesha Schist Belt into two halves.     

Ordovician system

Rocks in the Brungle‐Darbalara area of the Tumut Trough form two distinct domains: basement (mainly Bullawyarra Schist), of Cambrian‐Ordovician age, and an Ordovician ‐ Early Silurian sedimentary and volcanic cover sequence. These two domains are separated by a sharp discontinuity that marks an abrupt change in rock type, structure, metamorphic grade and deformation style. Cover sequences have undergone only one major penetrative deformation during the Late Silurian, involving sub‐greenschist facies metamorphism and upright folding. In contrast, the basement also underwent at least two older deformations at greenschist facies and contains distinct high‐strain zones subconcordant with the basement‐cover contact. The high‐strain zones, characterized by a ubiquitous south‐southeast trending mineral lineation, record a discontinuous history of ductile followed by brittle behaviour, consistent with an extensional origin.

The structural and metamorphic discontinuity separating basement from Silurian cover is characterized by widespread cataclasis and alteration and is interpreted as a major detachment fault associated with lithospheric extension and the development of the Tumut Trough in the Early Silurian. During the main period of movement on the detachment, which took place prior to intrusion of the Blacks Flat Diorite into the Bullawyarra Schist, mafic and serpentinized ultramafic rocks either were tectonically emplaced or intruded into the high strain zones. This preceded and accompanied extensional faulting of the cover and deposition of Silurian trough sediments and volcanics which unconformably overlie and onlap older units.

The development of the Tumut Trough, in the Brungle‐Darbalara area, bears many similarities with that of Cordilleran metamorphic core complexes. Such a model is consistent with environments suggested for the trough by previous workers. The south‐southeast extension direction parallels the trough‐bounding faults and implies an overall strike‐slip tectonic setting.     

Accretionary history of the Archean Barberton Greenstone Belt (3.55-3.22 Ga), southern Africa

The 3.55-3.22 Ga Barberton Greenstone Belt, South Africa and Swaziland, and surrounding coeval plutons can be divided into four tectono-stratigraphic blocks that become younger toward the northwest. Each block formed through early mafic to ultramafic volcanism (Onverwacht Group), probably in oceanic extensional, island, or plateau settings. Volcanism was followed by magmatic quiescence and deposition of fine-grained sediments, possibly in an intraplate setting. Late evolution involved underplating of the mafic crust by tonalitic intrusions along a subduction-related magmatic arc, yielding a thickened, buoyant protocontinental block. The growth of larger continental domains occurred both through magmatic accretion, as new protocontinental blocks developed along the margins of older blocks, and when previously separate blocks were amalgamated through tectonic accretion. Evolution of the Barberton Belt may reflect an Early Archean plate tectonic cycle that characterized a world with few or no large, stabilized blocks of sialic crust.     

Petrology and deformation of metamorphosed volcanic-exhalative sediments in the Gairloch Schist Belt,N.W. Scotland

The Gairloch Schist Belt in the Archaean to Early Proterozoic Lewisian Complex of north-west Scotland is largely composed of amphibolite facies metabasites and metagreywackes. These are associated with a distinctive suite of metamorphosed volcanic-exhalative sediments including quartz-magnetite rocks, garnet-grunerite rocks and compositionally variable, siliceous calcite- and dolomite-bearing lithologies. The carbonate horizons are locally rich in sulphide and carry Cu-Zn-Au mineralization. Meta-exhalites occur within parts of metavolcanic units characterized by metamorphosed tuffs and tuffs mixed with exhalative material. Quartz-magnetite and carbonate horizons were dismembered and underwent mylonitic recrystallization during regional compression. The associated metabasic rocks in the shear zones have suffered extensive phyllonitization. This style and degree of deformation are not developed elsewhere in the immediate area which suggests that ductile shear zones in the Gairloch Schist Belt were preferentially initiated near and localized around the meta-exhalative horizons.     

Upper crustal structure of the Tamworth Belt,New South Wales: constraints from new gravity data

New gravity data along five profiles across the western side of the southern New England Fold Belt and the adjoining Gunnedah Basin show the Namoi Gravity High over the Tamworth Belt and the Meandarra Gravity Ridge over the Gunnedah Basin. Forward modelling of gravity anomalies, combined with previous geological mapping and a seismic-reflection transect acquired by Geoscience Australia, has led to iterative testing of models of the crustal structure of the southern New England Fold Belt, which indicates that the gravity anomalies can generally be explained using the densities of the presently exposed rock units. The Namoi Gravity High over the Tamworth Belt results from the high density of the rocks of this belt that reflects the mafic volcanic source of the older sedimentary rocks in the Tamworth Belt, the burial metamorphism of the pre-Permian units and the presence of some mafic volcanic units. Modelling shows that the Woolomin Association, present immediately east of the Peel Fault and constituting the most western part of the Tablelands Complex, also has a relatively high density of 2.72 – 2.75 t/m³, and this unit also contributes to the Namoi Gravity High. The Tamworth Belt can be modelled with a configuration where the Tablelands Complex has been thrust over the Tamworth Belt along the Peel Fault that dips steeply to the east. The Tamworth Belt is thrust westward over the Sydney – Gunnedah Basin for 15 – 30 km on the Mooki Fault, which has a shallow dip (～25°) to the east. The Meandarra Gravity Ridge in the Gunnedah Basin was modelled as a high-density volcanic rock unit with a density contrast of 0.25 t/m³ relative to the underlying rocks of the Lachlan Fold Belt. The modelled volcanic rock unit has a steep western margin, a gently tapering eastern margin and a thickness range of 4.5 – 6 km. These volcanic rocks are assumed to be Lower Permian and to be the western extension of the Permian Werrie Basalts that outcrop on the western edge of the Tamworth Belt and which have been argued to have formed in an extensional basin. Blind granitic plutons are inferred to occur near the Peel Fault along the central and the southern profiles.     

Neoproterozoic Deformation at a Boundary Zone Between the Nellore-Khammam Schist Belt and Pakhal Basin, SE India: Strain Analysis of Deformed Pebbles

In the Kinnerasani area in southeastern India, the terrain boundary between the Archean Nellore-Khammam Schist Belt and the Proterozoic Pakhal Supergroup overlying the Dharwar-Bastar cratons can be observed. We analyzed the mesoscopic and microscopic structural features of the highly deformed pebbles in the basal conglomerate bed of the Pakhal Supergroup that occurs at the terrain boundary. The results of the analysis of the pebbles suggest that: 1) deformation of pebbles resulted from ductile deformation during peak metamorphism 2) the mode of strain is plane strain to constrictive and maximum elongation located to be vertical and 3) the apparent stretch of the pebbles is up to 300%.In the Nellore-Khammam Schist Belt, quartz grains constituting the quartz layer of the feldspathized gneiss folded by the last-phase deformation also show vertical maximum stretching in constrictive strain. This observation suggests that the deformational features, at least the mode of strain, during the last-phase deformation is comparable to the deformation forming elongated pebbles of the Pakhal conglomerate. The last-phase deformation structures of the Nellore-Khammam Schist Belt are well observed near the terrain boundary. This indicates that the Pakhal deformation overprinted the rocks of the Nellore-Khammam Schist Belt near the boundary, and that their tectonic juxtaposition occurred during or before this deformation period. Because the Pakhal deformation took place during or soon after the peak metamorphism of the Pakhal Supergroup, which is known to be 1000 Ma, and the last metamorphism of the Nellore-Khammam Schist Belt in the Khammam area were reported to be 1100 Ma. The tectonic juxtaposition between the Pakhal Supergroup and Nellore-Khammam Schist Belt was around 10001100 Ma.     

Magmatic changes during the stabilisation of a cordilleran fold belt: the Late Carboniferous–Triassic igneous history of eastern New South Wales, Australia

In a 60 Ma interval between the Late Carboniferous and the Late Permian, the magmatic arc associated with the cordilleran-type New England Fold Belt in northeast New South Wales shifted eastward and changed in trend from north–northwest to north. The eastern margin of the earlier (Devonian–Late Carboniferous) arc is marked by a sequence of calcalkaline lava flows, tuffs and coarse volcaniclastic sedimentary rocks preserved in the west of the Fold Belt. The younger arc (Late Permian–Triassic) is marked by I-type calcalkaline granitoids and comagmatic volcanic rocks emplaced mostly in the earlier forearc, but extending into the southern Sydney Basin, in the former backarc region. The growth of the younger arc was accompanied by widespread compressional deformation that stabilised the New England Fold Belt. During the transitional interval, two suites of S-type granitoids were emplaced, the Hillgrove Suite at about 305 Ma during an episode of compressive deformation and regional metamorphism, and the Bundarra Suite at about 280 Ma, during the later stages of an extensional episode. Isotopic and REE data indicate that both suites resulted from the partial melting of young silicic sedimentary rocks, probably part of the Carboniferous accretionary subduction complex, with heat supplied by the rise of asthenospheric material. Both mafic and silicic volcanic activity were widespread within and behind the Fold Belt from the onset of rifting (ca. 295 Ma) until the reestablishment of the arc. These volcanic rocks range in composition from MORB-like to calcalkaline and alkaline. The termination of the earlier arc, and the subsequent widespread and diverse igneous activity are considered to have resulted from the shallow breakoff of the downgoing plate, which allowed the rise of asthenosphere through a widening lithospheric gap. In this setting, division of the igneous rocks into pre-, syn-, and post-collisional groups is of limited value.     

Geochemical stratigraphy of the Huronian continental volcanics at Thessalon,Ontario: contributions of two-stage crustal fusion

The 1500 m thick sequence of Huronian continental volcanics at Thessalon, Ontario is subdivided into 4 volcanic cycles, each of which includes abundant early mafic end-members, central intermediate flows, and late rhyolite units. Major and trace element concentrations are dominated by extensive gabbroic fractionation trends that ultimately produced two types of felsic flows: (1) rhyolites with high light rare earth element (LREE) and relatively low large-ion lithophile element (LILE) concentrations (high-LREE, low-LILE rhyolites), and (2) following late separation of REE-rich accessory phases, rhyolites depleted in LREE (low-LREE, high-LILE rhyolites). Mafic end-members of individual volcanic cycle are progressively less siliceous and less enriched in LILE and LREE with height in the stratigraphic section. Ti/Zr ratios gradually rise from 35 in early mafic flows to stabilize at about 85 in late units, while average SiO₂ contents decrease from 56 to about 50% and Mg# rises from about 48 to 52. -Nd values are consistently negative, indicating variable degrees of pre-fractionation crustal contamination of the end-member magmas during their uprise through the crust. Mixing models are consistent with up to 50% contamination by crustal material of tonalitic hornblende-gneiss composition. A progressive increase in -Nd, from about-5.0 to-0.5 upward in the volcanic succession, reflects a decreasing degree of crustal contamination due to development of insulating layers along margins of the feeder system. Detailed stratigraphic variations suggest that successive magmas batches were intercepted by a progressively fractionating, periodically replenished magma source, giving rise to open-system magmatism. Despite the prevalence of crustal assimilation in the Huronian lavas, (La/Sr)N ratios are too low in least contaminated end-members to be explained by contamination of tholeiitic magmas. The late basalts resemble instead modern island are basalts, and it is suggested that the subcontinental mantle source was enriched by subduction-related processes during crustal formation. Within individual volcanic cycles gabbroic fractionation trends systematically deviate from calculated factors toward compositions characteristic of hornblende-gneiss. Such relations suggest that further crustal contamination of the magmas occurred simultaneous with crystal fractionation. probably within undulating sills at upper crustal levels. Quantitative analysis suggests assimilation/fractional crystallization (A/FC) ratios of about 0.45. As a result of extensive two-stage contamination, rhyolites from the initial volcanic cycle incorporate a total of over 60% of crust.     

Qualitative thermobarometry of inverted metamorphism in the Pelona and Rand Schists, southern California, using calciferous amphibole in mafic schist

Abstract The Rand and Pelona Schists consist of eugeoclinal rock types overlain by continental basement along the Vincent-Chocolate Mountains (VCM) faults. Both schists display inverted metamorphic zonation, defined in part by a systematic variation in composition of calcic to sodic-calcic amphibole in mafic schist structurally upward. The compositional progressions include increase of total A1, A1^IV and Ti, but decrease in the ratios of Na/(Na + Ca) to A1/(A1 + Si), and Na^M4 to (A1^VI+ Fe³⁺+ Ti). These variations imply that structurally high rocks belong to a lower-pressure metamorphic fades series than those at depth. This result is consistent with previous views that the inverted metamorphic zonations represent intact structural sequences.
Amphibole composition is dependent not only on structural position (i.e. P-T ), but also upon bulk-rock composition. The important controls are whole-rock Mg/(Mg + Fe²⁺+ Mn) and Fe³⁺/Fe²⁺. The greatest impact of these factors, however, is on the absolute values of Na and Al, rather than their ratio. Thus, interpretation of facies series is not seriously hindered by compositional variability.
Sodic amphibole in epidote blueschists from the Rand Schist is extensively replaced by sodic-calcic amphibole. Sodic-calcic amphibole in the Rand Schist and Pelona Schist is, itself, rimmed by actinolitic amphibole. Similar blueschist to greenschist transitions in other metamorphic terranes are typically attributed to exhumation. In the Rand and Pelona Schists, the sequence probably formed during burial.     

Petrogenesis of ultramafic and mafic rocks of the Thompson Nickel Belt,Manitoba

Abundant sill-like bodies of serpentinized ultramafic rocks, with associated nickel sulfide deposits, are found on the western side of the Thompson Nickel Belt near the Moak Lake-Setting Lake cataclastic fault zone. The ultramafic rocks range in composition from dunite to orthopyroxenite and feature variable alteration. Chemical variation across the bodies is suggestive of in-situ differentiation controlled mainly by olivine and orthopyroxene. Relative abundances of some elements, incompatible for olivine and orthopyroxene, suggest a parental liquid of komatiitic affinity. Ultramafic and mafic rocks are petrogenetically linked. A high degree of partial melting of mantle material and subsequent low-pressure crystal fractionation are responsible for the spectrum of composition from ultramafic to mafic.Publication 19-84, Ottawa-Carleton Centre for Geoscience Studies     

PGE, Re-Os, and Mo isotope systematics in Archean and early Proterozoic sedimentary systems as proxies for redox conditions of the early Earth

Re-Os data and PGE concentrations as well as Mo concentrations and isotope data are reported for suites of fine clastic sediments and black shales from the Barberton Greenstone Belt, South Africa (Fig Tree and Moodies Groups, 3.25-3.15 Ga), the Belingwe Greenstone Belt, Zimbabwe (Manjeri Formation, ca. 2.7 Ga) and shales from the Witwatersrand, Ventersdorp and Transvaal Supergroups, South Africa ranging from 2.95 to 2.2 Ga. Moderately oxidizing conditions are required to mobilize Re and Mo in the environment, Mo fractionation only occurs in solution, and these parameters thus have potential use as paleoredox proxies for the early Earth.PGE + Re abundance patterns of Barberton Greenstone Belt sediments are uniform and very similar in shape to those of komatiites. This indicates (1) that the PGE came from a source of predominantly ultramafic composition and, (2) that PGE were transported and deposited essentially in particulate form. Sediments from the younger Belingwe Greenstone Belt show more fractionated PGE + Re patterns and have Re/Os ratios 10 to 100× higher than those of Barberton sediments. Their PGE abundance patterns and Re/Os ratios are intermediate between those of the mid-Archean shales and Neoproterozoic to Recent black shales. They reflect scavenging of Re from solution in the sedimentary environment.δ^98/95Mo values of black shales of all ages correlate with their concentrations. The Barberton Greenstone Belt samples have ∼1-3 ppm Mo, similar to a granitoid-basaltic source. This Mo has δ^98/95Mo between −1.9 and −2.4‰ relative to present day mean ocean water molybdenum, MOMO and is thus not isotopically fractionated relative to such a source. Similar to the PGE this indicates transport in solid form. Sediments from the Belingwe Greenstone Belt show in part enhanced Mo concentrations (up to 6 ppm) and Mo isotope fractionation (δ^98/95Mo up to −1.4‰ relative to MOMO). The combined PGE + Re and Mo data show mainly reducing conditions in the mid-Archean and suggest that by 2.7 Ga, the atmosphere and oceans had become more oxidizing.Substantially younger samples from the Transvaal Supergroup (to ca. 2.2 Ga) surprisingly have mainly low Mo concentrations (around 1 ppm) and show no significant Mo isotope fractionation relative to the continental source. Among possible explanations for this are a return to reducing atmospheric conditions after 2.7 Ga, reservoir effects, or Mo removal by sulfide precipitation following sulfate reduction in early Proterozoic oceans.     

Mantle peridotite in newly discovered far-inland subduction complex,southwest Arizona: initial report

The latest Cretaceous to early Palaeogene Orocopia Schist and related units are generally considered a low-angle subduction complex that underlies much of southern California and Arizona. A recently discovered exposure of Orocopia Schist at Cemetery Ridge west of Phoenix, Arizona, lies exceptionally far inland from the continental margin. Unexpectedly, this body of Orocopia Schist contains numerous blocks, as large as ~300 m, of variably serpentinized mantle peridotite. These are unique; elsewhere in the Orocopia and related schists, peridotite is rare and completely serpentinized. Peridotite and metaperidotite at Cemetery Ridge are of three principal types: (1) serpentinite and tremolite serpentinite, derived from dunite; (2) partially serpentinized harzburgite and olivine orthopyroxenite (collectively, harzburgite); and (3) granoblastic or schistose metasomatic rocks, derived from serpentinite, made largely of actinolite, calcic plagioclase, hercynite, and chlorite. In the serpentinite, paucity of relict olivine, relatively abundant magnetite (5%), and elevated Fe³⁺/Fe indicate advanced serpentinization. Harzburgite contains abundant orthopyroxene, only slightly serpentinized, and minor to moderate (1–15%) relict olivine. Mantle tectonite fabric is locally preserved. Several petrographic and geochemical characteristics of the peridotite at Cemetery Ridge are ambiguously similar to either abyssal or mantle-wedge (suprasubduction) peridotites and serpentinites. Least ambiguous are orthopyroxene compositions. Orthopyroxene is distinctively depleted in Al₂O₃, Cr₂O₃, and CaO, indicating mantle-wedge affinities. Initial interpretation of field and petrologic data suggests that the peridotite blocks in the Orocopia Schist subduction complex at Cemetery Ridge may be derived from the leading corner or edge of a mantle wedge, presumably in (pre-San Andreas fault) southwest California. However, derivation from a subducting plate is not precluded.