青藏高原北羌塘盆地多彩地区蛇绿岩地球化学特征及构造环境

多彩蛇绿岩是通天河蛇绿混杂岩的组成部分,区域上隶属西金乌兰—金沙江缝合带北延部分。多彩蛇绿岩各岩石组分呈构造岩块、岩片产出,出露零星,面积小,但岩石组分较齐全,主要由异剥橄榄岩、单斜辉石岩、辉长岩、玄武岩、辉绿岩及硅质岩等组成,缺乏地幔橄榄岩,蛇绿岩组分均与围岩呈构造接触关系。异剥橄榄岩以富MgO、贫TiO2、贫P2O5为特征,Eu不显异常或显弱负异常,是具有SSZ型蛇绿岩的重要岩石组分;辉长岩具高TiO2、Al2O3;玄武岩与辉绿岩具相似的特性,玄武岩Th/Ta平均为1.78,Ta/Hf0.15,而Ta/Hf=0.15～0.2,与大洋板内玄武岩相似;硅质岩Al2O3/(Al2O3+Fe2O3)比值为0.9,(La/Ce)N值为1.81,可能具有陆源海特性。由上述特征并结合蛇绿岩形成时代及构造环境判别图解,推测多彩蛇绿岩形成于俯冲带构造环境。     

内蒙古西乌珠穆沁旗迪彦庙蛇绿岩的识别

新识别出的内蒙古西乌珠穆沁旗迪彦庙蛇绿岩位于中朝古板块与西伯利亚古板块之间的兴蒙造山带中部。通过对迪彦庙蛇绿岩进行详细的野外地质调查和岩石学、岩石地球化学的研究,发现迪彦庙蛇绿岩由孬来可吐和白音布拉格两个蛇绿岩带组成,各带宽约3km,延伸约30km,蛇绿岩各单元出露齐全。岩性由下到上主要为蛇纹石化方辉橄榄岩、层状-块状辉长岩、斜长岩、细碧岩、枕状玄武岩、角斑岩-石英角斑岩及硅质岩。蛇纹石化方辉橄榄岩稀土配分模式具SSZ型蛇绿岩的地幔橄榄岩特征;枕状玄武岩具岛弧拉斑玄武岩(IAT)特征;硅质岩的Al2O3/(Al2O3+Fe2O3)比值显示大陆边缘沉积环境特征。     

西昆仑于田南部阿羌蛇绿构造混杂岩地质特征及意义

近年的区调工作在西昆仑于田南部阿羌一带新填绘出一套具有蛇绿岩特征的变质橄榄岩、蛇纹岩、变辉长岩、辉绿岩和玄武岩等岩石组合.其中,变质橄榄岩、蛇纹岩具有低SiO2、高MgO、低稀土特征;辉长岩、辉绿岩和玄武岩绝大多数样品岩石化学具有低K2O＜1％,TiO2含量为1.5％等特征;稀土元素及微量元素特征与N-MORB及E-M...     

东天山康古尔塔格蛇绿岩SHRIMP年龄、Nd-Sr同位素特征及构造意义

通过对东天山康古尔塔格蛇绿岩中的辉长岩的SHRIMP锆石U-Pb年龄测定,得出康古尔塔格蛇绿岩形成于晚寒武世-早奥陶世(494±10Ma)。Nd-Sr同位素研究表明,康古尔塔格蛇绿岩中辉长岩、辉绿岩、玄武岩、斜长花岗岩及角斑岩的ε_(Nd)(t)值变化于 5.7～ 10.5之间,与现代大洋岛弧火山岩的ε_(Nd)(t)值一致;(~(87)Sr/~(86)Sr)_i值变化于0.703475～0.704923之间,与现代典型大洋中脊新鲜玄武岩的~(87)Sr/~(86)Sr值变化范围基本一致。上述特征显示出康古尔塔格蛇绿岩与准噶尔蛇绿岩一样,属SSZ型蛇绿岩,其岩浆来自亏损上地幔,且在演化过程中没有受到陆源物质的明显混染。该蛇绿岩形成时代、源区组成结合区域地质构造等暗示康古尔塔格断裂以北地区可能属于准噶尔板块范畴。     

东昆仑山木孜塔格蛇绿混杂岩中火山岩的地球化学特征及构造环境

木孜塔格蛇绿混杂岩沿东西走向的木孜塔格一鲸鱼湖断裂断续出露有变质橄榄岩、堆晶岩、火山岩及其上覆的硅质岩，彼此呈构造接触关系。其中，火山岩由玄武岩、玄武安山岩和安山岩构成。野外观察曾认为火山岩属于蛇绿岩的一部分．但火山岩的微量和稀土元素分析表明，其富集LREE、Cs、Ba、Th、Pb贫Nb，Ba／Nb、Ce／Pb、Cs／Rb、Ba／LaNb／Ta分别为18．59-102．82、1.42～8．13、0．10-0.49、11．76-51．79和6．22-13．58，TiO2含量1．64％-2．09％。这些特征表明该火山岩为形成于较成熟岛弧环境的火山岩而非蛇绿岩成员，也指示木孜塔格地区曾经历了与今西太平洋边缘近似的演化过程，可能形成了较成熟的沟-弧-盆体系。     

西藏羌塘角木日地区二叠纪蛇绿岩的地质特征及意义

1：25万玛依岗日幅区域地质调查期间，在角木日地区发现了一套保存十分完整的蛇绿岩，岩石由放射虫硅质岩、枕状玄武岩、辉长辉绿岩和变质橄榄岩组成。这套岩石是羌塘中部地区发现的保存最为完整的蛇绿岩组合。     

滇西南耿马地区弄巴剖面早石炭世硅质岩的地球化学特征及古地理意义

滇西南耿马地区弄巴剖面由不同时代、不同岩性的地层断片组成，其中早石炭世2个断片由玄武岩和灰白色、紫红色放射虫硅质岩、硅质泥岩、凝灰岩组成。对硅质岩进行地球化学研究后发现，该地区硅质岩SiO2含量均在80％以上，MnO／TiO2的平均值为0．58，Al/(Al Fe Mn)的平均值约为0．48，Ce／Ce*的平均值为0．91，与已知大地构造背景的硅质岩地球化学特征对比，表明其为近大陆边缘的洋盆边缘型硅质岩。     

青藏高原羌塘早古生代蛇绿岩——堆晶辉长岩的锆石SHRIMP定年及其意义

羌塘中部果干加年山西段发现完整的蛇绿岩组合,由变质橄榄岩、堆晶辉长岩、辉长岩岩墙群、玄武岩、硅质岩等组成。对堆晶辉长岩进行地球化学和定年初步研究,堆晶辉长岩具有洋中脊玄武岩的地球化学特征,获得锆石SHRIMP U-Pb谐和年龄为438±11 Ma,是羌塘地区乃至青藏高原南部首次发现完整早古生代的蛇绿岩。结合角木日地区二叠纪蛇绿岩、双湖以东的晚泥盆世法门期和二叠纪-三叠纪放射虫硅质岩的研究,羌塘中部古特提斯洋盆可能形成于早古生代,持续演化到三叠纪,并且可能是一个连续过程,使我们对青藏高原古特提斯洋的历史及其演化阶段的划分需要重新思考。     

古特提斯多岛洋洋一陆俯冲：木孜塔格蛇绿岩的矿物学证据

前期研究认识到新疆东昆仑木孜塔格蛇绿岩形成在俯冲带环境．为了进一步研究该俯冲带的类型，对新疆东昆仑木孜塔格蛇绿岩变质橄榄岩的岩石学和矿物学特征进行了分析．薄片观察发现变质橄榄岩的橄榄石以变质残余、变质重结晶和斜方辉石熔融结晶3种结构存在，但探针分析发现它们具有稳定且低Fo值（87．8～89．5）；斜方辉石发育变质残余和熔融残余结构，En较低（88～90），Al2O3含量变化大（2．90％～5．13％）；尖晶石为他形一半自形结构，其Cr^#（=Cr／（Cr＋Al））集中分布在0．508～0．723和0．100～0．118两个范围内．根据这些来自岩石学和矿物学的证据，并结合该蛇绿岩的构造背景与时代，认识到该蛇绿岩形成在大洋向具有厚陆壳的大陆弧俯冲的俯冲带环境，为新疆东昆仑地区古特提斯多岛洋洋一陆俯冲的结果．     

金沙江缝合带弯岛湖蛇绿混杂岩带的岩石地球化学特征及其构造背景

弯岛湖蛇绿混杂岩带是金沙江缝合带西段的重要组成部分。蛇绿岩混杂于上三叠统变质碎屑岩夹变质火山岩中,成份主要为镁铁质-超镁铁质杂岩,岩石类型有变质橄榄岩、变质堆晶质辉长岩及其伴生的岛弧型花岗岩系。岩石化学及地球化学特征表明:蛇绿岩主要为低Ti(岛弧-弧后)型、富集型洋中脊(E-MORB)拉斑玄武岩;与之共(伴)生的基性喷出岩、辉绿岩脉属板内洋岛型裂谷型碱性玄武岩及其过渡类型系列。在变质辉长岩获得全岩Sm-Nd等时线年龄值为232±11Ma,代表了镁铁质-超镁铁质杂岩的形成年龄,可能为洋壳初始俯冲变质的时间。在蛇绿岩上覆的硅质岩中发现有中三叠世拉丁晚期至晚三叠世卡宁早期的放射虫化石,表明弯岛湖镁铁质-超镁铁质杂岩可能形成于中三叠世多岛洋盆或弧后盆地构造环境。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。