吴起薛岔地区长8油层组储层岩石学特征研究

吴起薛岔地区是近年来延长油田的潜力目标开发区,其长8油层组油藏分布面积和储量潜力大。因此,本文通过钻井岩心、铸体薄片、扫描电镜观察和粒度、X衍射全岩分析、黏土矿物定量分析,对研究区长8油层组储层岩石学特征进行了研究。结果显示,研究区长8油层组岩性主要由灰褐色细粒岩屑长石砂岩组成,长石砂岩次之,具有"低石,高长石"特点;碎屑颗粒多为次棱角状,分选性中等,胶结类型以孔隙及加大孔隙型为主;填隙物含量均大于15%,主要以绿泥石膜、水云母、方解石以及铁方解石等自生矿物为主,以及少量高岭石和网状粘土等。     

山东省牛庄洼陷古近系沙河街组沙三中亚段储集层成岩作用研究

山东省牛庄洼陷古近系沙河街组沙三中亚段储集层岩石类型以长石岩屑砂岩和岩屑长石砂岩为主,岩石结构成熟度和成分成熟度均较低。砂岩成岩作用包括压实作用、胶结作用、交代作用、溶解作用等。压实作用主要有刚性颗粒发生脆性破裂、颗粒之间呈线接触和凹凸接触、岩石碎屑颗粒呈明显的定向排列、塑性颗粒挤压变形或刚性颗粒嵌入变形颗粒中、粘土质碎屑被挤压变形发生假杂基化等五种表现形式。胶结物主要有泥质胶结物、碳酸盐胶结物、自生粘土矿物和自生石英、长石。交代作用主要有石英交代长石颗粒、碳酸盐胶结物交代石英、长石及岩屑颗粒、碳酸盐胶结物之间的相互交代。发生溶解作用的主要是石英、长石和岩屑颗粒,胶结物中主要是碳酸盐矿物。目前研究区沙三中亚段储集层成岩演化处于晚成岩A期。影响成岩作用的主要因素为岩石成分、沉积环境、孔隙流体性质等。成岩作用对储集物性的影响主要表现在孔隙度和渗透率的变化,其中压实作用和胶结作用使储层原生孔隙迅速减少、渗透率降低,使得储集物性变差;而溶解作用是次生孔隙发育的主要因素,从而改善砂岩的储集性能。     

惠州凹陷东部珠海组储层碱性成岩作用及孔隙演化

根据铸体薄片、扫描电镜、粒度分析、X衍射等资料,对惠州凹陷东部珠海组储层的岩石学特征、成岩作用和孔隙演化过程进行分析研究。研究认为,惠州凹陷东部珠海组储层的岩石类型以岩屑砂岩、长石质岩屑砂岩、岩屑质石英砂岩和岩屑质长石砂岩为主,结构成熟度与成分成熟度较低。砂岩埋藏过程中经历了明显的碱性成岩作用:石英的溶蚀与交代、碳酸盐矿物胶结、伊利石和绿泥石的沉淀以及钠长石化等。碱性成岩作用对孔隙的影响包括:石英溶蚀形成次生溶孔、碳酸盐胶结物沉淀损失粒间孔隙、黏土矿物沉淀形成晶间微孔。研究区珠海组主要发育粒内溶孔和粒间溶孔,原生孔隙较少。储层现今处于中成岩阶段A期,早期经历了强烈的压实作用,使其孔隙度由原始孔隙度32.1%降低至8.8%。早成岩阶段为碱性成岩环境,石英溶蚀增孔约0.5%;碳酸盐、硫酸盐、伊利石等胶结物沉淀减孔约2.3%。中成岩阶段A期为酸性成岩环境,硅质、高岭石等胶结物沉淀减孔约1.2%;长石、岩屑等溶蚀增孔约4.3%。最终,储层演化至现今孔隙度10.1%。     

鄂尔多斯盆地南梁西区长6油层组砂岩低孔 超低渗储层特征及主控因素

南梁西区位于鄂尔多斯盆地陕北斜坡的西南部.长6油层组作为其主要的勘探目标层位,在研究区东北部发育三角洲前缘亚相、南部发育深湖浊流亚相.砂岩储层主要由长石砂岩及岩屑长石砂岩组成.研究区砂岩中胶结物类型有方解石、伊利石、绿泥石和硅质胶结物,使得砂岩孔隙物性降低.通过对储层孔渗参数的研究,得出长6油层组主要为低孔超低渗储层.根据毛细管压力曲线的形态认为,研究区目的层的孔喉结构为Ⅱ类,孔喉分选中等偏差,并提出成岩作用是影响其储集性能的主要因素.     

鄂尔多斯盆地苏77区块盒8下亚段致密砂岩储层低渗成因与优质储层形成机理

鄂尔多斯盆地苏77区块盒8下亚段属于典型的致密砂岩储层,勘探潜力巨大,但因储层非均质性强、优质储层成因机理和展布规律不清,使得该区的勘探开发部署备受制约。利用岩石普通薄片及铸体薄片、扫描电镜、X射线衍射、常规压汞及物性测试等资料对储层低渗成因及优质储层发育的主控因素进行了详细研究。研究结果表明:储层岩石类型以岩屑砂岩和岩屑石英砂岩为主,结构成熟度较低。孔隙类型以溶孔为主,晶间孔次之。储层低孔低渗且微观孔喉结构相对较差。压实作用是储层低渗的根本原因。硅质胶结物、碳酸盐胶结物、黏土矿物胶结物以及大量塑性岩屑的存在是储层低渗的主要原因。优质储层的发育受多种因素控制:有利沉积微相是优质储层形成的关键;强烈的溶蚀作用是形成优质储层必不可少的条件;适量的绿泥石薄膜和硅质胶结物能增强岩石的抗压实强度,保护原生孔隙;适量的结晶完好的高岭石晶间孔和裂缝的发育有助于改善局部储层的物性。辫状河心滩微相砂体厚度大,杂基含量低,溶蚀强烈,物性较好,是研究区的优质储层。     

川东北元坝地区须家河组储层特征与超致密成因探讨

元坝地区须家河组砂岩的致密化程度极高,以超低孔、超低渗储层为主,属于超致密砂岩。本文基于铸体薄片、阴极发光、扫描电镜和物性等资料,在对砂岩的岩石组分、孔隙类型及物性特征分析的基础上,通过与国内外典型致密砂岩对比,揭示研究区砂岩较其他砂岩致密化程度高的原因,分析超致密砂岩的勘探潜能。结果表明,研究区砂岩具有较高的塑性岩屑、碳酸盐岩岩屑和黏土杂基含量;填隙物以黏土杂基和钙质胶结物为主,较强的硅质胶结作用仅发育于石英砂岩中。孔隙多为黏土杂基晶间微孔,喉道呈窄缝状或不发育,孔喉分选差,偏细歪度。砂岩致密化程度高主要有两方面的原因:一是原始组构差,成分成熟度低,含有较高的塑性岩屑、碳酸盐岩岩屑和黏土杂基含量,导致砂岩在早成岩阶段既已经历了很强的压实作用和钙质胶结作用,致密化时间早,溶蚀作用不发育;二是成岩演化阶段高,砂岩经历了中成岩阶段的压溶及进一步的钙质/硅质胶结,使得砂岩超致密化。与国内外典型致密砂岩气藏对比表明,超致密砂岩有效孔隙少,对天然气的富集能力有限。元坝地区须家河组只有孔隙度近于8%(如长石岩屑砂岩)的砂岩才可成为有利的致密气储层。     

鄂尔多斯盆地靖边油田马宁区长2油层组储层特征研究

目前针对靖边油田马宁区长2油层组储层特征研究不足,导致马宁区进一步的勘探开发受到局限.本次研究根据岩心观察、薄片鉴定、孔渗分析、扫描电镜及压汞实验等资料,在研究区长2油层组储层特征研究的基础上,对储层质量进行了有效的分类评价.研究表明,靖边长2油层组储层以中细粒长石砂岩为主;杂基主要由水云母、绿泥石膜组成,胶结物主要为方解石、硅质、白云石;主要储集空间为次生粒间孔.储层砂岩孔喉连通性较好,且分选性较好.总体上马宁地区长2油层组储层由于受岩性、成岩等作用影响,表现中低孔、中低渗储层特征.     

鄂尔多斯盆地小河-青阳地区下马家沟组储层特征研究

通过碎屑岩普通薄片鉴定、铸体薄片鉴定及扫描电镜观察等手段,结合分析实验,对鄂尔多斯盆地小河—青阳地区本溪组盒8储层进行分析。研究结果表明,研究区本溪组盒8砂岩主要有3种岩性类型:石英砂岩、岩屑砂岩、岩屑石英砂岩。碎屑颗粒粒径集中分布在0.2～0.8 mm之间;各层填隙物平均含量为12.8%～16.6%,平均为14.8%,组分有杂基、凝灰质、水云母、硅质、高岭石、铁方解石等;储层孔隙度主要在3%～13%之间,渗透率在0.02～15.0×10~(-3)μm~2之间;渗透率变化主要受孔隙发育程度的控制,渗透率与孔隙度为正相关,属低孔、低渗特低渗致密型储集层。     

白云凹陷珠江组储层岩石学特征及其对储层物性的影响

利用铸体薄片显微镜下观察与统计,结合扫描电镜研究,对白云凹陷珠江组砂岩的岩石学特征进行研究,结合成岩演化分析其对珠江组储层砂岩物性的影响。珠江组砂岩主要为岩屑长石砂岩和长石岩屑砂岩,填隙物以杂基和碳酸盐为主,孔隙类型主要以粒间溶孔为主,其次为粒内溶孔和原生粒间孔。成岩演化分析可知,早期中等压实作用为原始孔隙的保存提供了保证;碳酸盐胶结物是珠江组砂岩储集变差的主要因素;而溶蚀作用是使得砂岩储集物性变好的重要因素,酸性流体的注入为长石、岩屑及石英等碎屑颗粒的溶蚀提供了物质基础。     

松辽盆地南部扶余油层砂岩成岩作用研究——以扶余油田和新立油田为例

对松辽盆地南部扶余油田和新立油田扶余油层砂岩岩石学特征和各成岩作用类型进行了细致分析,研究表明,扶余油田和新立油田的扶余油层主要类型分别为长石砂岩和长石岩屑砂岩,并经历了中等压实作用、自生石英胶结作用、自生粘土矿物胶结作用、碳酸盐胶结作用、交代和溶解作用等,达到晚成岩阶段A2亚期。该油层砂岩中碳酸盐胶结物主要为成岩早期的产物,当碳酸盐胶结物含量大于8%时,直接影响岩石的机械压实作用和油层的孔隙度。扶余油田扶余油层砂岩中长石含量相比新立油田高,可能导致该地区扶余油层砂岩的交代和溶解作用相对发育,从而抑制其内石英颗粒的次生加大,并形成高含量的自生高岭石,及因长石溶解所至的两个自生高岭石峰值特征等。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.