阿尔泰小土尔根铜矿区岩体LA-ICP-MS锆石U-Pb定年及地质意义

小土尔根是近年来阿尔泰诺尔特盆地发现的首例斑岩铜矿床,其成岩成矿年代学的研究可以对矿床模型构建、区域成矿规律的总结提供制约。矿区侵入岩发育,矿化受花岗闪长斑岩控制,少部分赋存在地层中。文章利用LA-ICP-MS锆石U-Pb测年法对矿区岩体进行了成岩年代学研究。含矿花岗闪长斑岩、黑云二长花岗岩和花岗斑岩中锆石的206Pb/238U年龄的加权平均值分别为(401.0±2.9)Ma、(398.1±2.2)Ma和(400.5±2.0)Ma,为早泥盆世同一岩浆侵入活动形成的不同侵入岩。侵入岩年龄结合凝灰岩年龄,将矿区地层划归早泥盆世诺尔特组。含矿花岗闪长斑岩锆石U-Pb年龄限定小土尔根斑岩铜矿床成矿时代略晚于401 Ma,即矿床形成于早泥盆世。     

湘南界牌岭锡多金属矿床含矿花岗斑岩SHRIMP锆石U-Pb年代学研究

界牌岭锡多金属矿床是湘南地区一个与花岗斑岩关系十分密切的大型矿床。本文通过对含矿花岗斑岩样品中的锆石进行SHPIMP U-Pb年代学研究,获得206Pb/238U加权平均年龄为92.0±1.6 Ma(MSWD=1.05),显示为晚白垩世侵位。含矿花岗斑岩成岩年龄与矿床锡矿成矿年龄基本一致,它们应属于同一构造-岩浆活动的产物。     

江西北武夷山高家山铜钼矿含矿岩体的特征与锆石U-Pb年代学研究

北武夷山地区高家山矽卡岩型铜钼多金属矿床位于扬子地块与华夏地块碰撞对接带萍乡-广丰深大断裂的甫侧,前人获得与成矿有关正长斑岩、花岗斑岩体的K-Ar法同位素年龄为63.6 Ma、84.7 Ma.本文对与成矿有关的正长斑岩和侵入于正长斑岩、花岗斑岩中的闪长玢岩分别进行了精确的锆石U-Pb定年研究,获得锆石206Pb/238U年龄分别为232.7±0.6 Ma和219.6±1.5 Ma,属印支期.通过分析矿石的氧、硫同位素和成矿岩体的地质地球化学特点,认为高家山铜钼矿床与印支期富碱性岩浆活动存在密切的时空和成因联系.因此,成矿岩体年龄间接地反映了本矿床的形成时代为印支期,提供了北武夷山地区印支期成矿作用的新信息.     

内蒙古莲花山铜矿区花岗闪长斑岩LA-ICP-MS锆石U-Pb年龄

为了精确厘定莲花山铜矿的成矿时代,在前人研究的基础上,开展了与成矿关系密切的花岗闪长斑岩锆石U-Pb定年测定。实验结果共获得4组年龄数据,第1组有1个锆石,206Pb/238U年龄为343Ma±2Ma;第2组1个锆石,206Pb/238U年龄为264Ma±2Ma;第3组有1个锆石,206Pb/238U年龄为256Ma±2Ma;第4组有17个锆石,206Pb/238U年龄在240~249Ma之间,206Pb/238U年龄加权平均值为246.4Ma±1.2Ma(N=17)。结合所测锆石的CL图像特征,确定花岗闪长斑岩就位发生在晚二叠世—早三叠世。     

江西北武夷高家山铜钼矿含矿岩体的特征与锆石U-Pb年代学研究

北武夷地区高家山矽卡岩型铜钼多金属矿床位于扬子地块与华夏地块碰撞对接带萍乡－广丰深大断裂的南侧,前人获得与成矿有关正长斑岩、花岗斑岩体的K-Ar法同位素年龄为63.6Ma、84.7Ma。本文对与成矿有关的正长斑岩和侵入于正长斑岩、花岗斑岩中的闪长玢岩分别进行了精确的锆石U—Pb定年研究,获得锆石 206Pb/238U年龄分别为232.7±0.6Ma和219.6±1.5Ma,属印支期。通过分析矿石的氧、硫同位素和成矿岩体的地质地球化学特点,认为高家山铜钼矿床与印支期富碱性岩浆活动存在密切的时空和成因联系。因此,成矿岩体年龄间接地反映了本矿床的形成时代为印支期,提供了北武夷地区印支期成矿作用的新信息。     

内蒙古达茂旗花岗岩类LA—ICP—MS锆石U—Pb年龄及其地质意义

对内蒙古达茂旗北部构造单元的巴特敖包岛弧带2个花岗闪长岩岩体样品和南部构造单元一个花岗岩岩体的2件样品进行了LA—ICP-MS锆石u—Pb定年。北部构造单元采自2个花岗闪长岩岩体的样品锆石^206Pb／^238U年龄分别为468Ma±2Ma和452Ma±2Ma,代表了这2个岩体的侵位时间,表明古亚洲洋向华北克拉通之下俯冲不晚于468Ma±2Ma;南部构造单元采自同一花岗岩岩体的2件样品获得的锆石~pb／z38U年龄分别为268Ma±2Ma和264Ma±2Ma,和该单元西部岩体已有的锆石年龄相符。这为华北克拉通北缘岩浆作用研究提供了新的年代学证据。     

江西大湖塘超大型钨矿床平苗矿段花岗斑岩的年代学和地球化学及成矿意义

<正>江西大湖塘钨矿床是近年发现的多类型矿化紧密共生的超大型岩浆热液型钨矿床。本团队在大湖塘平苗矿段地表考察花岗斑岩脉时,首次发现多条岩脉中发育黑钨矿-石英细脉,见大量细粒针状黑钨矿。矿脉仅局限在岩体中,未进入围岩中。LA-ICP-MS对该花岗斑岩锆石U-Pb定年,一组206Pb/238U加权平均年龄为149.1±1.1 Ma,为花岗斑岩年龄;另一组为890 Ma左右,为同化混染晋宁期围岩导致。     

粤北大宝山矿区花岗闪长斑岩LA-ICP-MS锆石U-Pb年龄及其地质意义

对粤北大宝山钼钨多金属矿区的花岗闪长斑岩进行了锆石阴极发光显微结构观察和LA-ICP-MS锆石微区U-Pb定年.在锆石阴极发光图像中, 两个花岗闪长斑岩样品中的锆石颗粒具有明显的振荡环带, 为典型的岩浆锆石.LA-ICP-MS U-Pb定年结果显示: 大宝山花岗闪长斑岩样品中具岩浆环带锆石区域12个分析点的206Pb/238U加权平均年龄为175.8±1.5 Ma(MSWD=0.037), 船肚花岗闪长斑岩样品中具岩浆环带锆石区域16个分析点的206Pb/238U加权平均年龄为175.0±1.7 Ma(MSWD=0.41).它们的形成时代约175 Ma, 为燕山早期第Ⅰ阶段(180~170 Ma)产物.本次对大宝山矿区花岗闪长斑岩形成时代的准确厘定, 为大宝山和船肚花岗闪长斑岩原本连为一体被后期构造错断的认识提供了新证据, 岩体错断部位是矿区Mo-W矿进一步勘探的重要方向.结合相关研究表明, 其成岩成矿动力学背景与邻区岩体相似, 为南岭地区同一期岩石圈伸展-减薄事件的产物.同时启示我们, 在南岭地区还存在燕山早期第一阶段(180~170 Ma)利于形成Mo-W矿的花岗岩类小岩体未被揭露.      

广西苍梧宝山铜多金属矿床花岗岩锆石U-Pb年龄及其地质意义

广西苍梧县宝山矿床位于大瑶山隆起区的东南部,是一个与石英斑岩有关的铜多金属矿床。本文对该矿区内花岗闪长岩、细粒花岗岩和石英斑岩进行了单颗粒锆石LA-ICP-MS U-Pb测年,获得了3件花岗闪长岩的~(206)Pb/~(238)U加权平均年龄分别为433.7±1.2 Ma、435.0±1.2 Ma和449.7±2.3 Ma;1件细粒花岗岩的~(206)Pb/~(238)U加权平均年龄为100.4±0.5 Ma,2件石英斑岩样品的~(206)Pb/~(238)U加权平均年龄分别为95.4±0.7 Ma和92.5±0.5 Ma。本文认为,宝山矿区存在晚奥陶世、早志留世、早白垩世晚期和晚白垩世早期等多期岩浆活动,与成矿有关的石英斑岩锆石U-Pb年龄揭示宝山铜铅锌多金属矿床形成于晚白垩世早期。这些高精度花岗岩锆石U-Pb测年数据为进一步深入研究大瑶山地区的岩浆活动及其成矿作用提供了重要的年代学依据。     

青海省纳日贡玛斑岩钼铜矿床成矿花岗斑岩锆石LA-ICP-MSU-Pb定年及地质意义

对青海省纳日贡玛斑岩钼铜矿床开展了锆石LA-ICP-MS U-Pb同位素定年研究,结果表明,纳日贡玛矿区2个黑云母花岗斑岩样品的锆石206Pb/238U同位素加权平均年龄分别为(43.4±0.4)Ma和(42.9±0.3)Ma,锆石形态、结晶振荡环带结构及元素含量均显示出岩浆成因特点;因此,锆石U-Pb年龄可代表斑岩的岩浆结晶年龄,纳日贡玛含矿斑岩岩浆的侵位年代可精确地限定于新生代喜马拉雅期,相当于中始新世。1件辉钼矿样品Re-Os同位素模式年龄为(40.8±0.4)Ma,结合前人的辉钼矿测试结果,认为在纳日贡玛岩浆活动约2.6 Ma后,岩浆热液成矿流体开始产生成矿作用。三江走滑断裂构造系统控制斑岩矿床的分布,青海三江北段斑岩钼铜矿具有很大的找矿潜力。     

SHRIMP Zircon U-Pb and Molybdenite Re-Os Datings of the Superlarge Donggou Porphyry Molybdenum Deposit in the East Qinling, China,and Its Geological Implications

Located in the eastern part of the East Qinling molybdenum belt, the Donggou deposit is a superlarge porphyry molybdenum deposit discovered in recent years. The authors performed highly precise dating of the mineralized porphyry and ores in the Donggou molybdenum deposit. A SHRIMP U-Pb zircon dating of the Donggou aluminous A-type granite-porphyry gave a rock-forming age of 112±1 Ma, and the ICP-MS Re-Os analyses of molybdenite from the molybdenum deposit yielded ReOs model ages ranging from 116.5±1.7 to 115.5±1.7 Ma for the deposit. The ages obtained by the two methods are quite close, suggesting that the rocks and ores formed approximately at the same time. The Donggou molybdenum deposit formed at least 20 Ma later than the Jinduicheng, Nannihu, Shangfanggou and Leimengou porphyry molybdenum deposits in the same molybdenum belt, implying that these deposits were formed in different tectonic settings.     

东昆仑小灶火软玉中热液锆石U-Pb年龄及Hf同位素特征:对成矿时代的制约

小灶火软玉矿床位于东昆仑造山带西段,同新疆和田玉处于昆仑山脉同一条成矿带上。该矿床软玉种类主要为青玉,其中透闪石含量达99%以上,为特殊的镁矽卡岩矿床。对该矿区青玉及其相关的黑云二长花岗岩进行了系统的LA-MC-ICP-MS锆石微量元素、U-Pb及Lu-Hf同位素研究。结果显示,黑云二长花岗岩中均为具典型韵律振荡环带的岩浆成因锆石,锆石U-Pb定年得到其成岩年龄为415.8±1.7 Ma;锆石ε_(Hf)(t)值为1.5~6.6,亏损地幔Hf模式年龄(tDM)为779~965 Ma,指示黑云二长花岗岩为东昆仑原特提斯造山带后碰撞阶段新生的新元古代地壳物质熔融的产物。青玉中的锆石可分为两类,其中主要锆石群——I类锆石呈补丁状环带、面状环带或无环带,且具有与黑云二长花岗岩中的岩浆锆石明显不同的稀土元素及Hf同位素特征,显示典型的热液锆石特点,其U-Pb年龄416.4±1.5 Ma代表了青玉的形成时间;II类锆石(416 Ma、471 Ma、818 Ma)呈韵律振荡环带,为热液流体从围岩中捕获的继承锆石。小灶火地区成岩-成矿作用的同时性(~416 Ma)表明岩浆岩侵入是软玉矿床形成的岩浆岩条件,软玉成矿作用方式为热液交代和充填作用。值得注意的是,用热液锆石的Hf同位素来示踪软玉成矿流体性质时应十分谨慎,因为成矿热液中的Hf元素在同时结晶的两种不同矿物(热液锆石和透闪石)间发生了重新分配。     

Late Jurassic-Early Cretaceous Plutonism in the Northern Part of the Precambrian North China Craton： SHRIMP Zircon U-Pb Dating of Diorites and Granites from the Yunmengshan Geopark, Beijing

The Yunmengshan Geopark in northern Beijing is located within the Yanshan range.It contains the Yunmengshan batholith,which is dominated by two plutons:the Yunmengshan gneissic granite and the Shicheng gneissic diorite.Four samples of the Yunmengshan gneissic granite give SHRIMP zircon U-Pb ages from 145 to 141 Ma,whereas four samples of the Shicheng gneissic diorite have ages from 159 Ma to 151 Ma.Dikes that cut the Yunmengshan diorite record SHRIMP zircon UPb age of 162±2 and 156±4 Ma.The cumulative pl...     

甘肃礼县中川地区金矿成岩和成矿年龄的SHRIMP厘定

甘肃省礼县中川地区属于礼（县）岷（县）金矿带的东段,成矿作用与中川花岗杂岩体有密切的关系。运用高分辨率和高灵敏度离子探针（SHRIMP）测试技术,获得了中川花岗杂岩体形成的精确年龄,主侵入时代为210～160 Ma（可信度95%,MSWD=1.4）,该花岗岩体属于燕山早期-印支期造山运动的产物;3颗锆石（4个测点）的SHRIMP测试结果表明,中川地区金成矿的年龄为197～162 Ma,证实礼县中川地区金成矿于中川花岗岩体形成及稍后的时间段。年龄测试和地质剖面测量资料都证实,中川花岗岩体南部地层应该划在中石炭统地层中。与中川花岗杂岩体地质情况类似的碌础坝、 柏家庄、 闾井、 教场坝、 温泉等岩体外接触带仍然有很大的找矿前景。     

松潘-甘孜地块南缘燕山早期矽卡岩型钨钼矿床 ——来自大牛场成岩成矿年代学及锆石Hf同位素证据

矽卡岩型矿床是钨、钼、锡等矿产的重要来源之一,中国的矽卡岩型矿床绝大多数分布于中国东部,成矿时代主要为燕山期.川西九龙大牛场是在松潘-甘孜地块新发现的矽卡岩型钨钼矿床,其成岩成矿时代尚未得到精确限定.大牛场地区铁厂河花岗岩体以二长花岗岩为主,少量正长花岗岩,而钨钼矿体主要产于矽卡岩中.文章对该矿床开展锆石U-Pb定年、...     

黑龙江佳木斯地块兴东群大盘道组碎屑锆石U-Pb定年及其地质意义

兴东群是佳木斯地块的结晶基底和多个铁、金、钨矿床(点)的含矿地层。为厘定其形成时代,揭示其地质和成矿意义,选取黑龙江省林口地区的兴东群大盘道组,在剖面实测、岩相学研究基础上,开展了代表性岩石的碎屑锆石U-Pb年代学研究。结果表明,所测大盘道组的主要岩石类型为大理岩与石英片岩,其原岩为灰岩及泥岩,变质程度可达角闪岩相,沉积于浅海陆棚相环境;石英片岩中碎屑锆石的LA-ICP-MS U-Pb年龄为(2338±20)Ma^751±18Ma,存在952 Ma、898 Ma、820 Ma及761 Ma 4个年龄峰值。结合羊鼻山地区大盘道组地层内有~520 Ma的花岗岩侵入以及该区域经历了~500 Ma的泛非期变质作用,确定大盘道组原岩沉积于新元古代—早古生代。本文测年结果显示有4个年龄峰值,其中898 Ma和761 Ma与前人报道的峰期年龄为898~891 Ma和757~751 Ma的两期岩浆事件相对应,另两组所测锆石也均为岩浆成因锆石,反映该区兴东群的物源复杂,且以岩浆岩为主。多期次岩浆作用使大盘道组富集Au、Cu、Pb、Zn、Fe等金属成矿元素,为羊鼻山铁钨矿床、孟家岗铁矿床和七星河金矿床等金属矿床形成提供了丰富的成矿物质基础。     

黑龙江金厂金矿区J0 号矿体闪长岩角砾的锆石U——Pb 测年及其地质意义

通过对黑龙江省金厂金矿区J0 号矿体中闪长岩角砾的单颗粒锆石LA--ICP--MS U--Pb 形成年龄测定,获得205 ～ 207 Ma、116 ～ 130 Ma 和104 ～ 114 Ma ( 加权平均年龄为110. 6 ± 1. 1 Ma) 三组年龄。结合锆石的晶形和Cl 图像特征,进一步确定205 ～ 207 Ma 是捕获印支晚期岩浆热事件形成的锆石; 116 ～ 130 Ma 远离谐和线,有明显的放射成因Pb 丢失; 而104 ～ 114 Ma ( 加权平均年龄为110. 6 ± 1. 1 Ma) 具有代表闪长岩岩浆作用过程形成的锆石年龄。此项成果揭示在早白垩世孙家湾期( 113 ～ 108 Ma) 曾发生过一期重要的中性岩浆热事件,而金厂金矿成矿作用应在110 Ma 之后。     

The Longmala and Mengya’a skarn Pb–Zn deposits,Gangdese region,Tibet: evidence from U–Pb and Re–Os geochronology for formation during early India–Asia collision

The Longmala and Mengya’a deposits are two representative skarn Pb–Zn deposits of the Nyainqêntanglha Pb–Zn–(Cu–Mo–Ag) polymetallic belt in the Gangdese region, Tibet, China. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U–Pb dating of the mineralization-related biotite monzogranite from the Longmala deposit yielded a weighted mean age of 55.7 Ma, which can be interpreted as the emplacement age of the pluton. Re–Os dating of three molybdenite samples from the Longmala deposit yielded model ages of 51.8–54.3 Ma, with a weighted mean age of 53.3 Ma, which is interpreted as the mineralization age of the deposit and overlaps the age of the causative intrusion. The Re–Os dating of four molybdenite samples from the Mengya’a deposit yielded model ages of 60.4–65.8 Ma, with a weighted mean age of 63.6 Ma, which represents the mineralization age of this deposit. Our new precise age data for these two deposits are consistent with the existing ages of ca. 65–51 Ma for other skarn polymetallic deposits in the Nyainqêntanglha metallogenic belt. In addition, these new age data, combined with existing information on the geological evolution history of the Lhasa terrane, indicate that the belt of skarn deposits is closely related to initial collision between India and the Asian continents.     

Early Cretaceous magmatism and associated polymetallic mineralization in South China: the Tiantang example

ABSTRACT

The Tiantang Cu–Pb–Zn polymetallic deposit in western Guangdong, South China, is hosted in the contact zone between the monzogranite porphyry and limestone of the Devonian Tianziling Formation. Orebodies occur in the skarn and skarnized marble as bedded, lenses, and irregular shapes. In this study, we performed LA-ICP-MS zircon U–Pb dating, zircon trace elements, and Hf isotopic analyses on the Tiantang monzogranite porphyry closely related to Cu–Pb–Zn mineralization. Twenty-two zircons from the sample yield excellent concordia results with a weighted mean ²⁰⁶Pb/²³⁸U age of 104.5 ± 0.7 Ma, which shows that the emplacement of the monzogranite porphyry in the Tiantang deposit occurred in the Early Cretaceous. The zircon U–Pb age is largely consistent with the sulphide Rb–Sr isochron ages, indicating that both the intrusion and Cu–Pb–Zn mineralization were formed during the Early Cretaceous in South China. The ε_Hf(t) values of three inherited zircons from the monzogranite porphyry are 13.1, 11.9, and 12.9, respectively, and the two-stage Hf model ages are 1096 Ma, 1087 Ma, and 1055 Ma, respectively. Except for the three inherited zircons, all ε_Hf(t) values of zircons are negative and have a range of ?7.6 to ?3.4, with the two-stage model ages (T_DM2) of 1380–1643 Ma, which indicates the rock-forming materials were mainly derived from the partial melting of Mesoproterozoic to Neoproterozoic crust rocks, and probably included some Neoproterozoic arc-related volcanic-sedimentary materials. In this study, the monzogranite porphyry from the Tiantang deposit has calculated Ce⁴⁺/Ce³⁺ ratios of zircon ranging from 91 to 359, indicative of a more oxidized signature and significant prospecting potential for ore-related magmatism. Based on ore deposit geology, isotope geochemistry, and geochronology of the Tiantang Cu–Pb–Zn deposit and regional geodynamic evolution, the formation of Early Cretaceous magmatism and associated polymetallic mineralization in South China is believed to be related to large-scale continental extension and subsequent upwelling of the asthenosphere.