Weathering regime associated with subsurface circulation on volcanic islands

Volcanic islands, being characterized by highly porous basaltic/andesitic lava flows and pyroclastic deposits, are subject to important chemical weathering by subsurface waters. Moreover, such subsurface weathering is impacted by hydrothermal springs in both active and non-active volcanic areas, thus increasing dissolved load concentrations. Here, we focus on the subsurface water chemistry in the volcanic islands of the Lesser Antilles and Réunion and on the origin of these subsurface flows. We are able, through the use of various isotopic tools (C, Sr, U–Th), to identify hydrothermal influences in river water. For example, Li concentrations show a positive correlation with temperature of hot and cold springs and also a relationship with δ¹³C; from this, we can show that several sources of hydrothermal activity influence the rivers of the Lesser Antilles and that some rivers also reveal an important organic influence. As much as 20% of the subsurface hydrothermal springs go to feed the rivers. The increasing temperatures result in more dissolved elements being mobilized and an increase in chemical weathering rates. In addition, using the (²³⁰Th/²³⁸U) isochron for the well and river dissolved loads in Martinique, Guadeloupe and Réunion, we can evaluate residence times in the river water, i.e. the average residence time in the water along the circulation path to the sampling point. Alteration takes longer when the water circulates through thick soil, for example, 400–5,000 years when circulating under an ash profile and 1,200–15,000 years when circulating through a collapse zone. It would appear that waters circulation is globally three times longer for subsurface water than for surficial water. The weathering regime in tropical volcanic environments seems to be controlled mainly by such subsurface circulation with high chemical concentration from hydrothermal inputs. The origin of these compositions is varied and not controlled by a single hydrothermal spring. Consequently, it is subsurface circulation that determines the weathering regime in tropical volcanic islands with the main controlling parameters being temperature and residence time.     

History of scoria-cone eruptions on the eastern shoulder of the Kenya–Tanzania Rift revealed in the 250-ka sediment record of Lake Chala near Mount Kilimanjaro

Reconstructions of the timing and frequency of past eruptions are important to assess the propensity for future volcanic activity, yet in volcanic areas such as the East African Rift only piecemeal eruption histories exist. Understanding the volcanic history of scoria-cone fields, where eruptions are often infrequent and deposits strongly weathered, is particularly challenging. Here we reconstruct a history of volcanism from scoria cones situated along the eastern shoulders of the Kenya–Tanzania Rift, using a sequence of tephra (volcanic ash) layers preserved in the ~250-ka sediment record of Lake Chala near Mount Kilimanjaro. Seven visible and two non-visible (crypto-) tephra layers in the Lake Chala sequence are attributed to activity from the Mt Kilimanjaro (northern Tanzania) and the Chyulu Hills (southern Kenya) volcanic fields, on the basis of their glass chemistry, textural characteristics and known eruption chronology. The Lake Chala record of eruptions from scoria cones in the Chyulu Hills volcanic field confirms geological and historical evidence of its recent activity, and provides first-order age estimates for seven previously unknown eruptions. Long and well-resolved sedimentary records such as that of Lake Chala have significant potential for resolving regional eruption chronologies spanning hundreds of thousands of years.     

中国东部主要入海河流As元素分布、来源及影响因素分析

为查明中国河流中As等重金属元素的分布规律,于2007—2008年分丰水期和枯水期对中国东部30余条入海河流水体、悬浮物统一进行采样分析。结果表明:东部河流中As元素溶解态含量均值为3.1μg/L,同世界河流相比,明显偏高;且频率分布直方图具有多个峰值,反映出明显的人为污染。利用富集系数的研究表明,悬浮物同样受到较明显的人为污染。As在河水中的迁移形式以溶解态为主,pH值和温度对As的迁移形式有明显影响。流域内岩石类型对河流中As含量影响显著,火山岩、火山碎屑岩类广泛分布的流域河水中As含量明显偏高,花岗岩及中、深变质岩广泛分布的流域河流中As含量则偏小。利用生活、工业污水作为As元素人为来源端元,对海河、黄河、长江、珠江等河流人为源进行了估算,分别为46.7%、18.7%、13.5%、8.3%。     

Tall clouds from small eruptions: the sensitivity of eruption height and fine ash content to tropospheric instability

A critical factor in successfully monitoring and forecasting volcanic ash dispersion for aviation safety is the height reached by eruption clouds, which is affected by environmental factors, such as wind shear and atmospheric instability. Following earlier work using the Active Tracer High Resolution Atmospheric Model for strong Plinian eruptions, this study considered a range of eruption strengths in different atmospheres. The results suggest that relatively weak volcanic eruptions in the moist tropics can trigger deep convection that transports volcanic material to 15–20 km. For the same volcanic strength there can be ~9 km difference between eruption heights in moist tropical and dry subpolar environments (a larger height difference than previously suggested), which appears consistent with observations. These results suggest that eruption intensity should not be estimated from eruption height alone for tropospheric eruptions and also that the average height of volcanic eruptions may increase if the tropical atmospheric belt widens in a changing climate. Ash aggregation is promoted by hydrometeors (particularly liquid water), so the smaller modelled eruptions in moist atmospheres, which have a relatively small ash content for their height and water content, result in a relatively small proportion of fine ash in the dispersing cloud when compared to a dry atmosphere. This in turn makes the ash clouds much more difficult to detect using remote sensing than those in dry atmospheres. Overall, a weak eruption in the tropics is more likely to produce a plume above cruising levels for civil aviation, harder to detect and track, but with a lower concentration of fine ash than a mid-latitude or polar equivalent. There is currently no defined ‘acceptable’ concentration of ash for aircraft, but as these results suggest low-grade encounters in the tropics from undetected clouds are likely, it would be desirable to explore that issue.     

Fluvial response to sudden input of pyroclastic sediments during the 2008–2009 eruption of the Chaitén Volcano (Chile): The role of logjams

The rhyolitic Plinian eruption of the Chilean Chaitén Volcano, initiated on May 2, 2008, suddenly introduced abundant pyroclastic sediments in the Blanco River catchment area, which experienced important modifications. Before May 2, the river was characterised by gravelly and moderate to low-sinuosity channels crossing a vegetated and locally urbanised (Chaitén City) floodplain. This river, limited by steep and densely forested highlands, was connected with the Pacific Ocean via a tidally-influenced delta plain. After heavy rains in May 11–20, the river discharge increased and triggered several responses including logjam formation and breakage, crevassing, avulsion (and channel abandonment), changes in the pattern and dimensions of channels, and construction of a new delta plain area. In this context, the goals of this contribution were: i) to document the sedimentological processes within a detailed geomorphic framework and ii) to understand the influence of logjams on fluvial dynamics. Upstream of the logjam zone, the deposits are mostly composed of ash and lapilli with abundant palaeovolcanic (epiclastic) sediments, which were produced by dilute currents and debris flows. Downstream of the logjam zone, deposits are composed by ash and lapilli, both pumice-rich and lacking important participation of older (epiclastic) sediments. The abandoned and filled palaeochannel, and the proximal part of crevasse splays experienced transient dilute flows with variable sediment concentration and, subordinately, hyperconcentrated flows. The distal sectors of crevasse splays mostly record settling from suspension. At the delta plain, tephra transported by the Blanco River was mixed with older sediments by tide and wave action (dilute flows). We conclude that immediately after eruption, both geomorphic and sedimentary processes of the river were mainly controlled by a combination of high availability of incoherent pyroclastic sediments on steep slopes, abundant rains, large logs that jammed the river and huge areas of devastated forest. Logjams played an important role in the river response to the volcanic eruption; they were responsible of the marked compositional change recorded upstream and downstream of the logjam zone and its breakage resulted in downstream flooding and avulsion. The likelihood of formation of logjams in rivers draining forested volcanic areas should be considered in the evaluation of volcanic hazards related to Plinian eruptions.     

Volcanic ash forecast during the June 2011 Cordón Caulle eruption

We modelled the transport and deposition of ash from the June 2011 eruption from Cordón Caulle volcanic complex, Chile. The modelling strategy, currently under development at the Argentinean Naval Hydrographic Service and National Meteorological Service, couples the weather research and forecasting (WRF/ARW) meteorological model with the FALL3D ash dispersal model. The strategy uses volcanological inputs inferred from satellite imagery, eruption reports and preliminary grain-size data obtained during the first days of the eruption from an Argentinean ash sample collection network. In this sense, the results shown here can be regarded as a quasi-syn-eruptive forecast for the first 16 days of the eruption. Although this article describes the modelling process in the aftermath of the crisis, the strategy was implemented from the beginning of the eruption, and results were made available to the Buenos Aires Volcanic Ash Advisory Centers and other end users. The model predicts ash cloud trajectories, concentration of ash at relevant flight levels, expected deposit thickness and ash accumulation rates at relevant localities. Here, we validate the modelling strategy by comparing results with satellite retrievals and syn-eruptive ground deposit measurements. Results highlight the goodness of the combined WRF/ARW-FALL3D forecasting system and point out the usefulness of coupling both models for short-term forecast of volcanic ash clouds.     

Genetic modelling for banded iron-formation of the Hamersley Group, Pilbara Craton, Western Australia

The banded iron-formation (BIF) of the Hamersley Group, Pilbara Craton, Western Australia, particularly from the well studied Dales Gorge Member, is unique in its lateral stratigraphic and petrological continuity throughout an area exceeding 60,000 km², enabling reasonable estimates for the annual input of components to the depository. In the model of this paper, varying supply of materials for the medley of mesoband types, particularly of iron and silica in the oxide BIF, can be accommodated by the interaction of two major oceanic supply systems: (1) surface currents and (2) convective upwelling from mid-oceanic ridge (MOR) or hot-spot activity, both modified by varied input of pyrochastic material. (1) The surface currents were saturated in silica and carried minimal iron due to photic precipitation, but were periodically recharged by storm mixing. Precipitation from them gave rise to the banded chert-rich horizons, including the varves, whose regular and finely laminated iron/silica distribution resulted from seasonal meteorological influences. (2) Precipitation from convection driven upwelling of high iron solution from MOR or hot-spot activity periodically overwhelmed the delicate seasonal patterns of (1) to produce the iron-dominated mesobands. A wide range of intermediate mesoband types resulted where the deep water supply was modified by varied MOR activity, or by partial blocking of upwelling waters by surface currents (such as by the present El Niño). During these periods of oxide-dominated BIF, silica was deposited from saturated solution mainly by evaporative concentration, and iron by oxidation due to photolysis and photosynthetically produced oxygen.Superimposed on these supply differences was the varying effect of fine aluminous ash from dominantly northern distal volcanic sources, changing the meteorological and depositional conditions. Occasional input of extremely fi ash during BIF precipitation produced mesoband (cm) scale variations involving increased carbonate-silicate precipitation. Sustained volcanic periods resulted in S-macroband deposition (chert-carbonate-silicate BIF, with shale), gradually returning to the dominant hematite-magnetite-chert BIF as the volcanic input waned. During volcanic periods, the normally high capacity of sunlight to precipitate ferric iron directly by photolytic oxidation of ferrous iron, and by photosynthetic production of oxygen, was modified by turbidity in the atmosphere (aerosols and dust) and in the water (colloids from reactive ash). S Surface-precipitated ferric hydroxyoxide redissolved in the presence of decaying organic matter in the subphotic zone, augmenting the iron content of the zone. Precursor ferrous carbonates and silicates were precipitated when the iron concentration of this sub-photic zone exceeded their respective solubilities. During volcanism, the increased availability of nutrients, particularly phosphorus, to surface waters increased the organic contribution despite lower light values, leading to an almost total absence of ferric iron oxides in the S macrobands (i.e. no magnetite or hematite). Cooling of warm, silica-saturated sea-water during these periods of “olcanic winter” increased the ratio of precipitation of silica to iron, which, however, was still controlled by seasonal conditions. Intermediate concentrations of organic matter, insufficient to totally convert the ferric compounds either during precipitation or diagenesis, resulted in overgrowths of magnetite on hematite, and eventually in the substantial conversion of hematite to magnetite, where higher temperatures were achieved during low-grade regional metamorphism.Changes in sea-level to explain facies changes in BIF are not required in this model, but are not excluded. The preferred conditions are for a very low oxygen to anoxic atmosphere, a much higher level of MOR activity than at present, the presence of photosynthetic plankton, the absence of si silica-secreting organisms, and a deep sea-water temperature higher than 20°C. However, none of these conditions is essential to the model.A narrow carbonate bank is postulated for part of the Fortescue River Valley area during Marra Mamba Iron Formation times (basal Hamersley Group), with BIF precipitation on either side. The reef is postulated to have grown northward becoming a major shallow-water carbonate platform on the Pilbara continent during upper Marra Mamba Iron Formation and Wittenoom Dolomite times, but ceased to play an important role in subsequent periods.     

Characteristics and Possible Source of a 1479 A.D. Volcanic Ash Layer in a Greenland Ice Core

A microparticle concentration peak in a GISP2 ice core contains volcanic glass shards of rhyolitic composition that correspond in age to the 1479-1480 A.D. Mt. St. Helens Wn eruption. These glass shards are compositionally similar to the Wn tephra and constitute 83% of the total particle population. The shards are very coarse-grained (up to 40 μm diameter), suggesting rapid transport from their source to Greenland. A major sulfate peak in the ice occurs approximately 4 months after deposition of the glass shards. This difference in depositional timing suggests primarily tropospheric transport of the ash and stratospheric transport of the sulfate aerosol. Large-scale climatic perturbations following this eruption were evidently negligible. Glaciochemical seasonal indicators suggest a late-fall to early-winter 1479 A.D. eruption.     

Effect of volatiles erupted from Mesozoic and Cenozoic volcanic activities on paleo-environmental changes in China

Based on the determination of composition of volcanic volatiles and petrologic estimation of the total mass of volatiles erupted, we showed important advances in the study of the impact of Mesozoic and Cenozoic volcanic activities on paleo-environmental changes in China. The volcanic activities include western Liaoning and Zhangjiakou Mesozoic intermediate-acidic explosive eruptions, southern Tibet and Shanwang Cenozoic volcanism, and Mt. Changbai volcanic eruption around one thousand years ago. The paper predominantly discusses the earth’s surface temperature changes, ozone depletion, acidic rain formation and mass mortalities of vertebrate induced by the Mesozoic and Cenozoic volcanism in China. __________ Translated from Bulletin of Mineralogy, Petrology and Geochemistry, 2007, 26(4): 319–322 [译自: 矿物岩石地球化学通报]     

Nutrient biogeochemistry in an upwelling-influenced estuary of the Pacific northwest (Tillamook Bay,Oregon, USA)

Tillamook Bay, Oregon, is a drowned river estuary that receives freshwater input from 5 rivers and exchanges ocean water through a single channel. Similar to other western United States estuaries, the bay exhibits a strong seasonal change in river discharge in which there is a pronounced winter maximum and summer minimum in precipitation and runoff. The behavior of major inorganic nutrients (phosphorus, nitrogen, and silica) within the watershed is examined over seasonal cycles and under a range of river discharge conditions for October 1997–December 1999. Monthly and seasonal sampling stations include transects extending from the mouth of each river to the mouth of the estuary as well as 6–10 sites upstream along each of the 5 major rivers. Few studies have examined nutrient cycling in Pacific Northwest estuaries. This study evaluates the distributions of inorganic nutrients to understand the net processes occurring within this estuary. Based upon this approach, we hypothesize that nutrient behavior in the Tillamook Bay estuary can be explained by two dominant factors: freshwater flushing time and biological uptake and regeneration. Superimposed on these two processes is seasonal variability in nutrient concentrations of coastal waters via upwelling. Freshwater flushing time determines the amount of time for the uptake of nutrients by phytoplankton, for exchange with suspended particles, and for interaction with the sediments. Seasonal coastal upwelling controls the timing and extent of oceanic delivery of nutrients to the estuary. We suggest that benthic regeneration of nutrients is also an important process within the estuary occurring seasonally according to the flushing characteristics of the estuary. Silicic acid, nitrate, and NH₄ ⁺ supply to the bay appears to be dominated by riverine input. PO₄ ⁻³ supply is dominated by river input during periods of high river flow (winter months) with oceanic input via upwelling and tidal exchange important during other times (spring, summer, and fall months). Departures from conservative mixing indicate that internal estuarine sources of dissolved inorganic phosphorus and nitrogen are also significant over an annual cycle.     

贵州紫云晚二叠世-早三叠世初火山作用与生物礁的沉积演化

晚二叠世长兴期是华南地区重要的成礁期,也是火山事件频发的一个时期。生物礁是一种对海洋环境十分敏感的生态系,晚二叠世的火山作用势必影响到当时生物礁的生长和沉积相的演化。然而,前人有关晚二叠世火山事件的研究主要集中在二叠系与三叠系界线附近,而对整个长兴期生物礁的演化与火山事件关系的研究则较少。选择贵州紫云的台地边缘礁为研究对象,通过大量磁化率的测试,分析整个晚二叠世生物礁的沉积演化与火山作用的关系。分析结果显示,长兴早期和末期岩石的磁化率值明显偏高,反映较强的火山活动。在这两个时期,造架生物相对不发育。长兴中期,岩石的磁化率值相较于长兴早期和长兴晚期总体偏低,表明火山活动相对较弱,导致生物礁的快速生长。但长兴中期生物礁灰岩中夹有几层生物碎屑灰岩,其磁化率值有小幅度的升高,说明短时期小规模的火山作用虽然导致了生物礁生长的暂时中断,但礁相动荡的环境使得火山灰中细小的铁磁性物质难以沉积下来。研究发现,尽管早三叠世早期泥岩具有高的磁化率值,但泥质岩中多层火山黏土具有异常高的磁化率值,火山灰物质对磁化率大小的影响远远超过陆源物质的贡献。     

The Vulnerability of Canada to Volcanic Hazards

Western Canada lies in a zone of active tectonics and volcanism, but thedispersed population has witnessed few eruptions due to the remoteness of the volcanoes and their low level ofactivity. This has created a false perception that Canada's volcanoes are extinct.There are more than 200 potentially-active volcanoes in Canada, 49of which have erupted in the past 10,000 years. They occur in five belts, with origins related totectonic environment. The minimum annual probability of a Canadian volcanic eruption is approximately 1/200;for an effusive (lava) eruption the probability is about 1/220, and for a significant explosive eruptionit is about 1/3333. In-progress studies show that there have been earthquakes associated with at least 9 ofthe youngest Canadian volcanoes since 1975. A scenario of an eruption of Mt. Cayley (50.1°N,123.3°W) shows how western Canada is vulnerable to an eruption. The scenario is basedon past activity in the Garibaldi volcanic belt and involves both explosive and effusive activity.The scenario impact is largely a result of the concentration of vulnerable infrastructure in valleys.Canadian volcanoes are monitored only by a regional seismic network,that is capable of detecting a M > 2 event in all potentially-active areas.This level of monitoring is probably sufficient to alert scientistsat or near eruption onset, but probably insufficient to allow a timelyforecast of activity. Similarly the level of geological knowledge about the volcanoes is insufficient to createhazard maps. This will improve slightly in 2002 when additional monitoring is implemented in theGaribaldi volcanic belt. The eruption probabilities, possible impacts, monitoring limitations and knowledgegaps suggest that there is a need to increment the volcanic risk mitigation efforts.     

Using cryptotephras to extend regional tephrochronologies: An example from southeast Alaska and implications for hazard assessment

Cryptotephrochronology, the use of hidden, diminutive volcanic ash layers to date sediments, has rarely been applied outside western Europe but has the potential to improve the tephrochronology of other regions of the world. Here we present the first comprehensive cryptotephra study in Alaska. Cores were extracted from five peatland sites, with cryptotephras located by ashing and microscopy and their glass geochemistry examined using electron probe microanalysis. Glass geochemical data from nine tephras were compared between sites and with data from previous Alaskan tephra studies. One tephra present in all the cores is believed to represent a previously unidentified eruption of Mt. Churchill and is named here as the ‘Lena tephra’. A mid-Holocene tephra in one site is very similar to Aniakchak tephra and most likely represents a previously unidentified Aniakchak eruption, ca. 5300-5030 cal yr BP. Other tephras are from the late Holocene White River eruption, a mid-Holocene Mt. Churchill eruption, and possibly eruptions of Redoubt and Augustine volcanoes. These results show the potential of cryptotephras to expand the geographic limits of tephrochronology and demonstrate that Mt. Churchill has been more active in the Holocene than previously appreciated. This finding may necessitate reassessment of volcanic hazards in the region.     

大兴安岭诺敏河第四纪火山岩分期:岩石学、年代学与火山地质特征

大兴安岭北段诺敏河第四纪火山24座,分布于诺敏河及其支流毕拉河和甘河支流奎勒河,火山岩分布面积约600km2。诺敏河火山岩均属于钾质系列火山岩(K2O含量2%～4%,且K2O>Na2O-2%),类似于邻区五大连池-科洛钾质火山岩,具有来自类似的富钾地幔源区。但诺敏河火山岩的K2O含量明显低于五大连池-科洛火山岩的K2O含量(一般4%～6%)。东北地区和内蒙东部处于中亚造山带东段,从古生代到新生代,多重构造-岩浆活动导致火山岩源区地球化学非均一性和火山岩的多样性。根据本文提出的火山岩K-Ar年龄(2.3～0.128Ma)及火山地质特征,可将诺敏河第四纪火山岩分为四期。早期(早更新世)火山活动主要沿诺敏河和奎勒河流域分布,火山产物多被晚期沉积物或火山产物所覆盖。中更新世保留的火山锥体及熔岩流是诺敏河第四纪火山产物的主体,表明是第四纪火山活动的高潮期。晚更新世-全新世火山活动限于毕拉河流域,典型的四方山火山和马鞍山火山是该时期火山活动的代表作,保留了较完好的火山地质地貌特征。从火山产物的时空展布,推测诺敏河第四纪火山活动有从东向西发展的趋势。     

Relationships between Campi Flegrei and Mt. Somma volcanism: evidence from melt inclusions in clinopyroxene phenocrysts from volcanic breccia xenoliths

Summary We present compositions of reheated melt inclusions in clinopyroxene phenocrysts from three mafic xenoliths in Breccia Museo, Campi Flegrei, Italy. Melt inclusion compositions are remarkably different from the compositions of known contemporary Campi Flegrei lavas, being significantly enriched in K₂O and depleted in Na₂O. Some differences are also evident in FeO^* (total Fe as FeO) and TiO₂ contents. The clinopyroxene phenocrysts could not have crystallised from Campi Flegrei magmas. We suggest that they originated from a volcanic system genetically very similar to, and possibly linked with, the >14 ka volcanic system of Mt. Somma, another Campanian volcano ∼ 30 km east from Campi Flegrei, from which Vesuvius subsequently developed. This result indicates a close relationship (or link) between the two volcanic systems which have until now been considered separate. We speculate that the link was established prior to eruption of the Neapolitan Yellow Tuff (NYT) (∼ 12 ka). The xenoliths were derived from a volcanic system older than the host breccias themselves. We suggest that this older volcanism had close similarities with the volcanism of the older products of Mt. Somma (∼25 ka). Received March 20, 2000; accepted November 2, 2000     

Blooms of Dinoflagellate Mixotrophs in a Lower Chesapeake Bay Tributary: Carbon and Nitrogen Uptake over Diurnal,Seasonal, and Interannual Timescales

A multi-year study was conducted in the eutrophic Lafayette River, a sub-tributary of the lower Chesapeake Bay during which uptake of inorganic and organic nitrogen (N) and C compounds was measured during multiple seasons and years when different dinoflagellate species were dominant. Seasonal dinoflagellate blooms included a variety of mixotrophic dinoflagellates including Heterocapsa triquetra in the late winter, Prorocentrum minimum in the spring, Akashiwo sanguinea in the early summer, and Scrippsiella trochoidea and Cochlodinium polykrikoides in late summer and fall. Results showed that no single N source fueled algal growth, rather rates of N and C uptake varied on seasonal and diurnal timescales, and within blooms as they initiated and developed. Rates of photosynthetic C uptake were low yielding low assimilation numbers during much of the study period and the ability to assimilate dissolved organic carbon augmented photosynthetic C uptake during bloom and non-bloom periods. The ability to use dissolved organic C during the day and night may allow mixotrophic bloom organisms a competitive advantage over co-occurring phytoplankton that are restricted to photoautotrophic growth, obtaining N and C during the day and in well-lit surface waters.     

Evidence of Microbial Activity in the Formation of Manganese Wads at the Asahidake Hot Spring in Hokkaido, Japan

Abstract. Mt. Asahidake is an active volcano, with more than 90 active wells, in the Daisetsu volcanic group located in central Hokkaido, Japan. Wells along the Yukomanbetsu-sawa River showed high manganese concentrations and associated manganese deposits. These deposits consist of manganese oxides, and the concentration of iron is very low except for one sample collected from the upper reach of the river. Most of the wet samples showed basal diffraction characteristic of todorokite (9.6 Å). Cultivation tests showed that microorganisms were responsible for the oxidation of dissolved Mn²⁺ in the Asahidake hot spring. The dissolved Mn²⁺ concentration in the sterilized hot spring water was unchanged after four days, whereas the Mn²⁺ concentration in the sterilized hot spring water with a small amount of fresh manganese wad was decreased to zero after three days, and manganese oxide formed. This result implies that the activity of microorganism oxidizes dissolved Mn²⁺ and forms manganese oxide at the Asahidake manganese deposits. In addition to Komanoyu hot spring and Yunotaki Falls, this is the third report of microbial activity forming considerable deposits of manganese oxides in hot spring waters.     

Remains of trilobites and other species discovered in a volcanic ash bed of the end-Permian,Yangtze craton,South China

The remains of trilobites and other species were unexpectedly discovered in a volcanic ash layer beneath the Permian–Triassic Boundary (PTB). Based on a biostratigraphic investigation of the Zhongliangshan section in Chongqing, South China, the quantity of the species gradually decreased with subsequent volcanism. This finding provides an opportunity to further understand the disappearance of trilobites and the evolution of the mass extinction event. The temporal coincidence between the volcanic eruption event and the loss of trilobites and other species supports the idea of a cause-and-effect relationship. The species remains in the ash bed appeared before the disappearance of Clarkina yini and the climax of the negative carbon isotope excursion, which implies that the onset of the mass extinction occurred at the end-Permian. The explosive volcanic events caused massive releases of CO₂, toxic gases and volcanic ash and resulted in loss of habitat for certain species in the Tethys domain. This phenomenon may have led to the abrupt death of trilobites and the catastrophic collapse of biodiversity.     

基于FY-3A遥感数据的冰岛火山灰云识别

2010年4月至5月期间冰岛艾雅法拉火山喷发造成了欧洲航空业史无前例的瘫痪以及巨大的经济损失,其严重影响再次显示,对火山灰云进行有效监测的重要性。火山灰云是由火山碎屑物及气体组成的混合物,火山碎屑物主要由直径小于2mm的岩石、矿物、火山玻璃碎片组成,火山灰云中的气体主要包括水汽、CO2、SO2、H2S、CH4、CO、HCL、HF、HBr、和NOx等。使用具有我国自主知识产权的FY-3A/VIRR数据,对此次艾雅法拉火山喷发的不同阶段选取具有典型风向变化的日期,采用分裂窗亮温差算法(SWTD)、RGB真彩色方法、中红外波段数据等进行火山灰云的识别,并将结果与冰岛地区的火山灰监测报告以及前人的研究结果进行对比研究,结果表明:火山喷发初期火山灰云中较高含量的水汽会补偿反面吸收的影响,妨碍分裂窗亮温差算法(SWTD)对火山灰云的识别,而中红外波段数据因对高温物体的敏感性,不受水汽的影响,对喷发初期较高温度的火山灰云识别效果较好;在喷发中期,火山灰云浓度较大时三种方法均表现良好,卫星图像中火山灰云的位置信息及漂移方向均非常清晰,且同气象条件相吻合,验证了识别方法的正确性。该项结果表明,具有我国自主知识产权的FY-3A数据能够达到监测火山灰云的目的,而如何更加清晰地界定火山灰云的边界位置以及更加准确的计算出火山灰云的浓度需要进一步的深入研究。     

Rare earth elements (REE) of dissolved and suspended loads in the Xijiang River, South China

The Xijiang River is the main channel of the Zhujiang (Pearl River), the second largest river in China in terms of water discharge, and flows through one of the largest carbonate provinces in the world. The rare earth element (REE) concentrations of the dissolved load and the suspended particulate matter (SPM) load were measured in the Xijiang River system during the high-flow season. The low dissolved REE concentration in the Xijiang River is attributed to the interaction of high pH and low DOC concentration. The PAAS-normalized REE patterns for the dissolved load show some common features: negative Ce anomaly, progressively heavy REE (HREE) enrichment relative to light REE (LREE). Similar to the world’s major rivers the absolute concentration of the dissolved REE in the Xijiang River are mainly pH controlled. The degree of REE partitioning between the dissolved load and SPM load is also strongly pH dependent. The negative Ce anomaly is progressively developed with increasing pH, being consistent with the oxidation of Ce (III) to Ce (IV) in the alkaline river waters, and the lack of Ce anomalies in several DOC-rich waters is presumably due to both Ce (III) and Ce (IV) being strongly bound by organic matter. The PAAS-normalized REE patterns for the dissolved load and the SPM load in rivers draining the carbonate rock area exhibit middle REE (MREE) enrichment and a distinct maximum at Eu, indicating the preferential dissolution of phosphatic minerals during weathering of host lithologies. Compared to the Xijiang River waters, the MREE enrichment with a maximum at Eu disappeared and light REE were more depleted in the South China Sea (SCS) waters, suggesting that the REE sourced from the Xijiang River must be further fractionated and modified on entering the SCS. The river fluxes of individual dissolved REE introduced by the Xijiang River into the SCS vary from 0.04 to 4.36 × 10⁴ mol a⁻¹.