大别造山带超高压变质岩稳定同位素地球化学

通过对大别造山带超高压变质岩的氢、氧和碳同位素地球化学研究，发现了显著的稳定同位素异常。结果对扬子板块向华北板块的俯冲提供了如下化学地球动力学制约： (1)北大别榴辉岩和基性麻粒岩与南大别超高压榴辉岩和片麻岩一样，具有较低的δ 18O值，表明它们在板块俯冲前经历了高温地表水热液蚀变，在超高压变质阶段流体以亏损 13C为特征； (2)部分低δ 18O值榴辉岩的共存矿物对之间保存了氧同位素平衡分馏，记录了榴辉岩相变质温度，指示这些榴辉岩在地幔的居留时间较短，折返初期的冷却速率较大； (3)退变质作用过程中存在显著的差异性氢氧同位素交换，早期阶段流体具有内部缓冲性质，而晚期则具有外部来源； (4)东大别大理岩显著富集 13C，反映出其母岩灰岩的沉积环境为封闭的大陆边缘盆地，西大别苏家河大理岩的δ 13C值接近于正常海相碳酸盐，指示其母岩形成环境为宽广开阔的海洋。     

苏鲁变质带北部的岩石构造单元及结晶块体推覆构造

虽然苏鲁变质带北部的超高压变质岩石的类型及其特征与大别山超高压带相似,但是要划出与大别山相对应的岩石构造单元是困难的。详细的区域地质、岩石学、同位素年代学及地球化学的研究已将超高压带的西界大致圈定在牟平断裂至米山断裂的范围内。特别需要提出的是,在荣成超高压变质岩石分布区的南北两侧,出露有3 种不同成因的麻粒岩,即榴辉岩化的麻粒岩;由超高压变质岩经高压升温变质作用生成的麻粒岩;以及未经过榴辉岩相变质的麻粒岩。它们有规律地成带分布。这些麻粒岩带以及在荣成地区出露的未经过麻粒岩相叠加变质的超高压变质带,各自都有着完全不同的变质历史,并且都以深大韧性剪切带为其边界。由此笔者将苏鲁变质带北部由南向北划分为海阳所变质地块(榴辉岩化扬子陆块基底变质单元)、荣成变质地块(超高压变质单元)、威海变质地块(麻粒岩相叠加变质的超高压构造岩片)、昆嵛山边界杂岩带。这些来源于地壳深层的结晶块体是超高压带形成和演化的产物,在后来的进一步碰撞挤压中,这些来源于深层而就位于中上地壳水平的结晶块体,有可能发生了与薄皮构造机制(thin-skin thrust)类似的构造过程。它们有如一系列的推覆体挤压叠置,使华北和华南陆块最后挤压在一起。     

大别超高压变质过程中流体作用的微量元素效应及其地球化学意义

对大别地区角闪岩相－麻粒岩相和榴辉岩相岩石进行较系统的地球化学研究,探讨了超高压俯冲变质及折返过程中元素的再分配行为,并就其对变质过程中的部分熔融作用和流体交代作用的指示进行了分析。研究表明,大别榴辉岩原岩在其俯冲过程中发生了部分熔融作用,并在其早期脱水和后期退变质作用过程中与变质流体相之间产生了交换。脱水作用使榴辉岩Ｎｂ／Ｔａ比值升高,但后期的退变质作用使榴辉岩与其寄主围岩间的Ｎｂ／Ｔａ比值相对     

苏鲁超高压变质带桃行榴辉岩及高压脉体中流体包裹体研究

桃行榴辉岩是苏鲁超高压变质带中段主要榴辉岩体密集分布区之一。流体包裹体研究表明,榴辉岩矿物及高压脉体石英中捕获有五种类型的流体包裹体：在超高压-高压榴辉岩相条件下捕获的N2±CH4包裹体;在榴辉岩发生麻粒岩相叠加变质作用期间被捕获的B型纯CO2液相包裹体;在高压榴辉岩重结晶阶段被捕获的C型CO2-H2O包裹体和D型高盐度水溶液包裹体;超高压岩石折返过程中的最晚阶段（角闪岩相退变质甚至更晚）捕获的E型低盐度水溶液包裹体。利用榴辉岩矿物及高压脉体石英中捕获的流体包裹体类型及期次可以重建超高压变质作用板片折返过程中的流体性状与演化,而石榴石中捕获的纯CO2包裹体为本区榴辉岩相岩石遭受了麻粒岩相叠加提供了佐证。     

大别山麻粒岩包体的氧同位素研究

对北大别变质杂岩中的麻粒岩包体进行详细的氧同位素地球化学研究,发现其全岩δ~(18)O值偏低,为3.3‰～4.4‰。在麻粒岩相变质条件下,大别山麻粒岩包体的共存矿物对之间达到并保存了氧同位素平衡,后期退变质作用未明显破坏这种平衡。由矿物氧同位素地质测温得到的顶峰变质温度800～875C,与一般麻粒岩相变质温度相吻合。在变质作用之前或顶峰变质作用过程中,大别山麻粒岩包体的原岩曾与一δ~(18)O值低于3‰的外来流体发生了高温水—岩交换作用,并且这种交换作用在一定范围内是相对均一的。     

中国大陆科学钻探工程主孔734～933m岩芯矿物的氧同位素和羟基含量研究

中国大陆科学钻探工程(CCSD)主孔位于苏鲁超高压变质带南部的东海县毛北村。本文主要研究深度分别为734.21m～737.16m(Ⅰ)和929.67m～932.86m(Ⅱ)两段榴辉岩与片麻岩互层的主孔岩芯，利用激光氟化法和Fourier变换红外光谱技术分别进行矿物的氧同位素组成和结构羟基含量分析。氧同位素分析表明，两段岩芯的榴辉岩中石榴石的δ^18O分别为 1.0‰～ 3.8‰和-4.1‰～-3、3‰，两段岩芯的片麻岩中石榴石的δ^18O均低达-4‰。表明片麻岩和榴辉岩的原岩均在经历超高压变质作用之前一同遭受过古大气降水的高温热液蚀变作用。在第1段岩芯的榴辉岩和片麻岩接触界线附近发现氧同位素交换前锋，指示板块折返过程中靠近片麻岩的榴辉岩与主要来自片麻岩的退变质流体发生流体-岩石交换，且其退变质程度主要受流体的迁移距离控制。红外光谱分析研究表明，所有石榴石都含有以OH形式存在的结构水，其含量的变化范围很大，为50～776ppm；绿辉石中OH含量范围为321～1636ppm；石英中含有以3596cm^-1为特征峰的结构水，但是含量很少。将剖面氧同位素和结构羟基含量的分析结果相结合，我们发现石榴石和绿辉石等矿物的氧同位素组成随着深度的变化与对应矿物的OH含量具有一定的相关性。这证明板块折返过程中的高压退变质作用及其伴生的局部流体活动可能是造成超高压变质矿物之间氧同位素不平衡的主要原因，并且氧同位素不平衡的程度主要受退变质作用发生时的局部水/岩比控制。因此，在深俯冲板块折返过程中，名义上无水矿物中结构水的出溶可以是退变质流体的重要来源。     

北大别洪庙榴辉岩相岩石Sm-Nd年龄:峰期变质时代

前人工作认为北大别榴辉岩在榴辉岩相变质后,经历了麻粒岩相退变质作用,因此获得的Sm-Nd矿物等时线年龄代表了麻粒岩相变质时代.本文对北大别安徽洪庙百丈岩榴辉岩相岩石(辉石石榴石岩)的研究表明,该岩石经历了三叠纪超高压变质作用,经历了角闪岩相退变质.所研究样品在峰期变质之后是否经历了麻粒岩相退变质尚不能明确界定.结合矿物氧同位素体系平衡判据,辉石石榴石岩在峰期变质时达到了Sm-Nd同位素体系的均一化和平衡,并且在后期角闪岩相退变质中该同位素体系未出现明显的扰动,因此其Sm-Nd矿物等时线年龄[(225±14)Ma和(229±13)Ma]代表了榴辉岩相变质时代.同时,样品中矿物的同位素组成表明,在俯冲板块折返和退变质过程中,岩石受到外来和内部流体的不均匀作用,造成退变的单斜辉石在同位素组成上的不均一.     

大别山超高压变质岩形成深度的同位素限制

大别山超高压变质岩形成深度是各国地质学家十分关心的问题。它不仅影响对碰撞造山带形成机制和演化过程的认识,而且影响对地球深部状况及地球动力学的研究。该文对大别山超高压变质岩已有同位素资料进行了分析与讨论。大别山榴辉岩的ε_Nd为-6.2~-17,ε_Sr为18~42,且显示明显的Nd同位素的不平衡现象。大别山榴辉岩的氧同位素组成研究表明,这些榴辉岩的原岩在超高压变质前,不同程度地与贫18O的大气降水(或海水)发生过氧同位素交换,且在超高压变质过程中依然保留了这些痕迹。除一个样品外,大别-苏鲁地区的榴辉岩的3He/4He比值都落在0.79×10-7~9.35×10-7范围内,显示陆壳岩石来源He的重要贡献。所有Sr-Nd、O和He同位素研究均表明:超高压变质岩保存着表壳岩石原岩的同位素特征,而未显示变质时受到地幔物质的明显影响。对于超高压变质岩的上述同位素特征,有人认为是由于大别山造山带俯冲和折返的速度太快造成的。由于造山带俯冲和折返的速度太快,表壳岩石原岩变质时来不及与地幔物质发生交换,故没有留下地幔物质参与的痕迹。该研究认为这种解释有些勉强,因为大别造山带俯冲和折返时间至少需要15Ma.在如此长的时间内,在100多公里地幔深处高于700℃的高温下发生超高压变质作用,表壳岩石原岩不可能不与地幔物质发生同位素交换。相反,如果认为大别山超高压变质岩就在地壳内形成,则大别山超高压变质岩同位素的所有特征就很好解释了。      

大别山双河超高压变质岩的稳定同位素研究

大别山双河地区片麻岩的δ18O值与共生榴辉岩同步变化，为（-4.7—+10.3）‰，这些片麻岩的18O亏损与榴辉岩一样是在遭受超高压变质作用之前原岩与大气降水交换的结果。榴辉岩及其围岩片麻岩在板块俯冲、超高压变质和岩片折返过程中可能为一个构造上的整体，两者为“原地”接触关系。     

北大别超高压榴辉岩的快速折返与缓慢冷却过程

岩石学研究表明,北大别超高压榴辉岩经过了超高压和高压榴辉岩相变质作用以及麻粒岩相叠加和角闪岩相退变质作用.其中,高压麻粒岩相和角闪岩相变质阶段形成的后成合晶以及石榴子石和单斜辉石等矿物中成分分带的存在,证明该区榴辉岩经历了一个快速折返过程;而不同变质阶段的温度、压力和形成时代,却反映该区榴辉岩在峰期超高压变质作用之后又经历了一个缓慢冷却过程.超高压岩石折返期间的缓慢冷却过程也许正是北大别长期难以发现柯石英和有关超高压证据的重要原因.因此,本文为大别山不同超高压岩片的差异折返模型的建立提供了新的证据.     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.