新疆北部镁铁-超镁铁质岩的PGE成矿问题

铂族元素(PGE)矿化主要与镁铁-超镁铁杂岩有关,成矿类型主要为岩浆型矿床,这类PGE矿床的形成主要依赖两个条件:一是岩浆中富含PGE;二是具备PGE从岩浆中分离和富集的机制,主要是在岩浆演化过程中硫达到饱和。新疆北部镁铁-超镁铁质杂岩发育,并产有喀拉通克、黄山、黄山东、图拉尔根4个大型铜镍矿床和香山、土墩、葫芦、白石泉等中、小型铜镍矿,以及香山西、尾亚等中型钒钛磁铁矿矿床,但迄今尚未发现成型的PGE矿床。文中通过对PGE矿床的形成机制与镁铁-超镁铁杂岩源区特征研究,探讨了北疆地区PGE矿床的成矿问题。综合分析认为,新疆北部后碰撞镁铁-超镁铁质岩的岩石类型为经过了分离结晶形成的铁质岩石系列,是PGE矿床的有利容矿岩石;矿床的Sr、Nd、Pb、O、Os和S同位素和含矿岩石地球化学特征表明,铜镍硫化物矿床含矿岩浆在岩浆演化和成矿过程中有地壳物质加入并可导致硫化物熔离作用,说明在成矿机制上也存在形成岩浆型PGE矿化的条件。新疆北部PGE矿化微弱的原因可能在于该区广泛发育的亏损型地幔源(具正的εNd值特征),这一亏损型地幔可能部分源于洋壳熔融,与产于后碰撞造山带环境、发育于"洋壳"或"不成熟"陆壳基底之上有关,由此决定了原始岩浆为贫PGE的源区,因此不利于PGE的富集成矿。     

西藏班-怒带西段荣那铜（金）矿床流体包裹体特征及矿床成因

荣那铜(金)矿床是班公湖-怒江缝合带西段新发现的矿床,是多龙矿集区的重要组成矿床之一,已探明储量达大型规模,具有超大型矿床的成矿潜力。荣那铜(金)矿床矿石矿相学与岩相学研究显示其具有典型高硫化型浅成低温热液型矿床的矿物组合(明矾石、硫砷铜矿等)和矿化蚀变特征。通过资料收集与野外观察,本文将荣那铜(金)矿床的成矿过程划分为石英-黄铁矿阶段、石英-多金属硫化物阶段与碳酸盐阶段,其中石英-多金属硫化物阶段为主成矿阶段。为查明该矿床的成矿流体特征,进一步确定矿床成因类型,对取自深部矿石中的石英脉(均为主成矿阶段含黄铁矿、黄铜矿石英脉)开展了流体包裹体的岩相学观察、显微测温和激光拉曼光谱分析。结果表明,上述矿物中主要发育富液相、富气相和含子矿物三相包裹体;富液相包裹体的均一温度与盐度分别为:80~440℃和4.63%~11.95%NaCl eqv;富气相包裹体的均一温度和盐度分别为:320~440℃和5.55%~10.74%NaCl eqv;含子矿物三相包裹体的均一温度与盐度分别为200~400℃和29.4%~32.56%NaCl eqv;富液相与富气相包裹体的气体成分除少量N2外,气体成分均为H2O。综合分析认为,荣那矿床成矿流体发生了强烈的沸腾作用,流体沸腾作用是该矿床的重要成矿机制。可见,荣那矿床具有高硫型浅成低温热液矿床的矿物组合及蚀变特征,但主成矿阶段石英脉流体包裹体特征与典型斑岩型铜(金)矿床的流体包裹体特征相似。因此,推测荣那高硫型浅成低温热液铜金矿的深部存在斑岩型铜金矿化,该矿床应属浅成低温热液型-斑岩型铜金矿床。     

四川大岩子铂-钯矿床(点)热液成矿的地球化学证据

大岩子铂-钯矿区的岩石有白云岩、辉石岩脉、辉绿岩脉,矿体赋存在构造蚀变破碎带中,以外接触带的白云岩一侧为主,次为内接触带的辉石岩,矿石类型有矿化白云岩和矿化辉石岩两种类型。通过对含矿白云岩、含矿辉石岩、断层泥及辉绿岩的地球化学特征研究,认为大岩子矿床先后经历超基性岩浆的侵入,即形成辉石岩脉;基性岩浆的侵入,即形成辉绿岩脉;富含Pt、Pd的岩浆期后热液活动,即形成以Pt、Pd为丰、富含As、Cu、Sb、Ag、Cd的热液矿床,其中Pt、Pd的富集成矿主要与热液活动有关。     

流体在岩浆型铬铁矿和铂族元素成矿过程中的作用及意义

镁铁- 超镁铁岩是揭示地幔物质组成和壳幔相互作用的重要窗口，也是Ni- Cu- PGE- Cr等金属矿产资源的重要载体。不同的镁铁- 超镁铁岩体赋矿特征明显不同：蛇绿岩以产出铬铁矿床为特征，阿拉斯加型岩体主要赋含铂族元素(PGE)矿床，大型层状岩体则可同时产出铬铁矿床、PGE矿床和Cu- Ni硫化物矿床。这种成矿差异显然与赋矿岩体形成的构造背景、母岩浆经历的岩浆演化过程有关，但缺少关键控制因素的研究。前人对上述不同种类矿床的研究工作主要集中于地幔源区的部分熔融、上升过程中或岩浆房内的围岩混染和结晶分异等岩浆过程，而极少关注流体作用。近年来，实验岩石学和岩石地球化学的研究均表明幔源岩浆演化过程中的流体活动可能对成矿元素的富集迁移起到至关重要的作用，同时这些成矿元素的赋存状态和分配系数也在不断更新。厘清Cr和PGE在熔体演化——尤其是流体出溶过程中的地球化学行为，刻画并揭示其迁移富集、分离和再富集的成矿过程及控制因素，已成为当前岩浆矿床研究的热点。本文围绕富水流体与铬铁矿和PGE成矿关系的科学问题，总结了不同镁铁- 超镁铁岩体的成矿差异以及铬铁矿和PGE矿床成矿过程中的流体活动记录，提出流体性质和组分对铬铁矿和PGE迁移富集的控制作用，强调有必要开展蛇绿岩、大型层状镁铁- 超镁铁岩体和阿拉斯加型岩体的对比研究。     

阿尔玛雷克斑岩铜矿地质特征：——矿床地质特征

阿尔玛雷克斑岩铜矿包括了两个超大型矿床、一个大型矿床和一个中型矿床。矿田内４条主断裂切割成５个构造断块，矿床产于西部和东部上升断块中，含矿岩体为海西中晚期中本乡性复式岩体，成矿与晚期富碱高钾浅成花岗闪长斑岩有关，具有成矿元素高含量和低Ｌｉ、Ｒｂ、Ｃｓ含量的特点。矿床具有良好的蚀变－矿化分带特征，矿石中高钾钠比值说明矿化 富集与钾质交代关系密切。     

矿化剂元素硫（S）与成矿

矿化剂元素硫(S)是绝大多数有色金属矿床成矿矿物中必不可少的组成物质,其对矿床形成的直接控制作用不言而喻。在目前收集到的文献资料中,有关S的研究多集中在示踪成矿流体来源方面,而关于地质体中S初始富集及其在成矿过程中的活动特性对成矿的控制却少有涉及。本科研团队历经十余年,在40多个矿床上对矿化剂元素S与成矿进行了系统研究,结果发现,热液成因矿床均产出在富S地质体中,地质体中S的富集与赋矿围岩同期形成,而且伴生有成矿元素的富集,构成初始矿源,奠定成矿物质基础。热液活动期间,初始矿源中矿化剂元素S及成矿元素发生活化、迁移和再富集,是控制成矿的直接因素。青海野马泉铁多金属矿研究结果证实,试验区灰岩中S的富集与灰岩同期形成,同时伴生有Pb、Zn、Ag、Cu等富集,构成矿源层。后期热液作用主导矿源层中S与成矿元素活化、迁移和再富集是成矿的必要条件,矿源层的沉积环境具有其特殊性。此项研究成果对矿床形成机制研究和矿床地球化学勘查均具有借鉴价值。     

安徽桂花冲铜矿床成矿流体演化特征研究

桂花冲铜矿床是铜陵矿集区沙滩脚矿田内新发现的一个以斑岩型矿化为主的矽卡岩-斑岩复合型铜矿床。文章对该矿床的矿床地质和斑岩型矿化成矿流体进行了初步研究,旨在查明该矿床成矿流体的演化过程。根据脉体的穿切关系及矿物共生组合,桂花冲铜矿斑岩型矿化成矿过程可划分为钾化、硅化、石英黄铁矿、石英多金属硫化物和碳酸盐5个阶段。硅化阶段主要发育纯气体、含子矿物及富气相包裹体,石英黄铁矿阶段主要发育纯气体、富液相、富气相及含子矿物包裹体,石英多金属硫化物阶段及碳酸盐阶段主要发育富液相包裹体。从硅化阶段至碳酸盐阶段,成矿流体由高温(472.9℃)、高盐度(47.7%~74.0%)的岩浆热液逐渐向中低温(140.2~280.3℃)、低盐度(1.6%~7.7%)的岩浆热液和大气降水的混合流体演化,成矿过程中流体经历了沸腾及混合作用,混合作用是导致铜沉淀的主要机制。     

贵州天桥铅锌矿床闪锌矿微量元素组成初探

天桥铅锌矿床位于川-滇-黔铅锌成矿带中东部,为黔西北地区铅锌矿床的典型代表之一。长期以来,对该矿床的成因认识存在较多争议,前人的研究主要集中在分散元素的富集规律、稀土元素及同位素对成矿流体来源的指示意义等方面,对天桥矿床中闪锌矿的微量元素特征缺乏系统的研究。本文应用ICP-MS对天桥矿床中闪锌矿的微量元素进行测试分析,研究结果表明,该矿床中闪锌矿的微量元素具有富Ge、Ga贫Mn、In、Sn、Cd的特征,其微量元素富集规律明显与夕卡岩型、喷流沉积型及岩浆热液型铅锌矿床不同,而与典型MVT型矿床(如勐兴、牛角塘等矿床)非常类似,仅其中Cd含量较低(均值为1282×10-6),该特征与川滇黔地区MVT型铅锌矿床(会泽和杉树林)中闪锌矿微量元素组成一致。总体上,本矿床闪锌矿富集Ge和Ga等低温成矿元素,其In/Ga比值中等,Zn/Cd比值较高,暗示其形成于中温环境。综合前人研究成果及矿床产出地质特征,我们认为天桥铅锌矿床属于MVT型铅锌矿床。     

滇黔桂地区铊富集的矿化剂和沉淀富集剂及成矿模式

T1虽然是一种分散元素，但在一定条件下也是可以富集的，甚至形成独立矿体。笔者在分析滇黔桂地区富铊矿床的地球化学特征后，认为T1在低温阶段富信，并提出T1的富集与沉积盆地局部高地球化学背景有关；促使T1富集万丈和的主要条件是矿化剂和沉淀富集剂，卤素和有机质是主要的成矿化剂，富硫流体和热液改造的有机质是主要的沉淀富集剂，在此基础上进一步探讨铊的二期三阶段成矿模式。     

新疆且末县刀峰山一带锑金多金属矿地质特征及成矿远景

新疆且末县刀峰山一带锑金多金属矿为木孜塔格RM-Fe-Mn-Pb-Zn-Sb-Hg-Au-Cu-Mo-Zn-水晶成矿带之黄羊岭(前陆盆地)Sb-Hg-Au-Cu矿带内新发现的矿化效果好、具较大成矿远景的矿点。通过对矿区成矿地质背景、矿床特征、控矿要素等综合分析,确定该矿床成矿类型为低温热液型矿床。经与邻区典型矿床成矿要素对比研究,分析了成矿远景,总结了成矿理想模式。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.