浑河傍河区地下水氮污染来源贡献研究

针对沈阳浑河傍河水源地地表、河流及地下水氮污染情况,利用Hydrus-1D实现以点代面模拟过程,计算包气带底部淋滤出水的水量和氮素浓度,并将其作为初始值输入由Visual Modflow构建的含水层氮素迁移转化数值模型,实现地表、包气带与含水层系统间模拟计算的结合。此外,结合地下水氮素测试结果,通过均衡公式计算不同地下水氮污染来源的贡献率。模拟结果表明,东南部地下水氨氮的主要污染来源为浑河补给,贡献率为61.79%;西北部地下水硝酸盐氮的主要污染来源为地表垂向入渗,贡献率为43.92%。     

贾鲁河中牟段河岸带地下水流及水质特征研究

该文以河南省贾鲁河中牟段为研究区,探究贾鲁河与河岸带浅层地下水的补排关系以及河水对浅层地下水的影响。通 过野外地质调查、水文地质试验、水位监测及水质检测,分析河岸带地表水与地下水的补排关系及污染特征。结果表明,受 中牟县抽取地下水的影响,该河段周围浅层地下水位低于河水位,河流补给地下水,平均单宽补给量为2.04 m2·d-1;河水中 NH3和COD污染较为严重,地下水中“三氮”均超标,其中NO2和NH3污染严重;河水NH3-N浓度远高于地下水,接受河 流补给的地下水NH3污染严重;因硝化作用,远离河流地下水NH3-N浓度逐渐降低,而NO3-N浓度逐渐升高。     

包气带水分运移问题讲座(一)——包气带水分运移基本方程

包气带(非饱和土壤)水分运移是当前一系列学科,如水文地质学、水文学、农田水利学、土壤物理学和渗流力学等研究的一个重要课题。 浅层地下水的开发利用对工农业生产具有重要作用。降雨、灌溉水和地表水的入渗是浅层水的主要补给来源,潜水的蒸发则是地下水的主要消耗途径,而土层的给水度又是决定潜水含水层储存和调蓄能力的重要因素。所有这些参数的确定都与包气带水分运动     

陕北风沙滩地区包气带抗污能力试验研究

为了研究陕北风沙滩地区包气带风积沙的抗污能力,在榆林煤化工厂厂区及其周边地区选择4个试验点,采用双环入渗法,选择渣场炉渣浸出液（Cd、Cr、Cu、Mn、Ni和Pb重金属污染物溶液）进行渣场污水入渗试验,采用人工配置污染物溶液（COD、氨氮、F、石油类和挥发酚）进行了配污试点试验。渣场污水入渗试验过程中,由于水流的冲刷作用,剖面上大部分污染物的含量都小于入渗前的含量;而渗后样的测定结果则表明包气带风积沙对污水中Cr、Cu、Mn、Ni和Pb的净化能力较强。配污试点试验表明包气带对无机污染物的阻滞作用会延缓其对地下水的污染,石油类在包气带中的运移速度缓慢,难以在水流的作用下到达含水层,而COD容易造成地下水污染,挥发酚对含水层的污染能力要小于COD。应考虑采取适当方式降低地下水位,增大包气带厚度,以加强包气带对地下水的保护能力。     

焦作地区浅层地下水铬(Ⅵ)污染机理及迁移预测

通过对焦作地区浅层地下水中铬(Ⅵ)污染物分布特征进行调查,分析了研究区浅层地下水中铬(Ⅵ)的污染机理,并运用Visual MODFLOW建立地下水流模型及溶质运移模型,模拟预测了浅层地下水中铬(Ⅵ)的迁移规律。结果表明:研究区浅层地下水铬(Ⅵ)污染严重,污染源是位于老君庙西南方向的焦作某电厂堆灰场,主要原因是露天堆放的粉煤灰中的铬(Ⅵ)污染物在长期淋滤作用下下渗污染含水层。气候条件、包气带岩性、地下水化学环境以及人为因素等也间接使浅层地下水铬(Ⅵ)浓度升高;模拟结果显示在未来的五年时间内,受地形和地下水动力场的影响,浅层地下水中铬(Ⅵ)的迁移方向与地下径流方向一致,沿大沙河水流方向上扩散速度更快,污染区域面积逐渐增大。      

河岸带表土层氮素非饱和入渗运移规律模拟

自制土槽装置,室内模拟氮素在河岸带表土层中非饱和入渗的过程.通过观测土槽中不同点位渗流水体出流时间的先后顺序以及各点水体中TN、NH₄+-N浓度随入渗时间的变化,探讨氮素在河岸带表土层中非饱和入渗的运移规律.试验结果表明:在河岸带表土层非饱和入渗过程中,水分水平运移速度小于垂直运移速度,NH₄+-N的运移滞后于水分的运移;在土壤"干"-"湿"-"干"过程中,各点TN、NH₄+-N浓度值随时间先急剧增加再缓慢减少然后趋于稳定.另外,河岸带表土层对非饱和入渗氮素的截留效果较好,试验11 h时,在1.08m的坡长距离上,距土表面12 cm深度TN、NH₄+-N浓度比进水分别下降74.23%和68.02%.     

垃圾渗漏液在包气带及含水层中的联合运移模拟

近年来,全国各地新建了大量的垃圾填埋场,其中多有不符合垃圾处理处置场地建设规范的,垃圾填埋场渗滤液对地下水的污染风险也逐年凸显,这就要求对后续垃圾填埋场建设时,在环评阶段做好垃圾填埋场渗滤液对地下水的污染风险预测,为垃圾填埋场地下水污染预防设施的设计与建设提供指导。本文探索了垃圾渗滤液在包气带和含水层中的联合运移模拟,首先利用Hydrus建立包气带模型,模拟垃圾渗滤液中氨氮在包气带中的迁移转化,在此基础上用Visual Modflow软件建立地下含水层模型,对比渗滤液经过包气带过滤和没经过包气带过滤两种情景下的污染范围和程度。模拟结果显示,包气带和含水层联合运移模拟渗滤液泄漏后的运移途径和路线,更接近渗滤液进入含水层的实际情况。     

干旱区包气带土壤水分运移及其对地下水补给研究进展

包气带是指地表到地下水之间垂直剖面中土壤孔隙没有被水充满、水分处于非饱和状态的区域,是地表水进入地下水的通道。包气带土壤水分运移过程不仅影响到地下水补给,而且与相邻景观之间存在水力联系。评述了干旱区包气带土壤水分运移模拟、地球化学示踪技术、地球物理技术在包气带土壤水分运移研究中的应用、影响包气带土壤水分运移及对地下水补给的因素、包气带水分运移对景观间水分交换的影响等方面的研究进展,提出在未来的研究中,应加强包气带土壤水分运移参数的试验观测及数据库建立、加强包气带土壤水分运移及其对地下水补给的研究,应借鉴地球关键带研究的思路,开展包气带土壤水分运移、溶质运移、地下水补给耦合研究。     

基于GMS软件对某污染厂区地下水污染规律研究

以某污染厂区为研究对象,通过野外调查并结合已有资料,利用GMS软件建立研究区域地下水流场模型和溶质运移模型,并且详细分析了地下水污染规律。研究结果表明:降雨入渗扩散方式下,污染物在地下水中的迁移速率与污染物的浓度及地下水介质密切相关。在潜水含水层中,污染物主要以垂向运移为主,并且受污染源强影响较大,污染物浓度越高,其垂向运移速率越快,污染物在水平面上的扩散速率受污染源强的影响较小;在承压含水层中,污染物沿水流方向迁移,并且呈现匀速扩散趋势。     

基于Visual Modflow的某生活垃圾填埋场地下水污染物运移模拟

针对生活垃圾填埋场运行中面临的渗滤液泄漏污染地下含水层的潜在威胁,论文通过概化某生活垃圾填埋场地的水文地质物理概念模型,利用Visual Modflow软件对该场地进行建模和拟合调参,预测了渗滤液发生泄漏后20年特征污染物NH3-N在含水层中的运移规律。模拟发现:在水平方向上,污染物随水流方向不断扩散,污染面积不断加大,污染速率呈先增长较快后逐渐变缓慢的趋势,污染浓度由渗漏中心向周围递减,污染物在20年内向下游地区运移时所到达的最远污染距离为841.3m,受污染区域面积最大为0.243km~2;在垂向上,由于存在第3、5、7层为弱透水层的阻隔作用,虽随着时间推移,污染物不断向下扩散,但研究周期内在污染物到达模型底板时,特征污染物的浓度均小于1.5mg/L,由此可见特征污染物不会渗入深部含水层。     

塔城盆地地下水“三氮”污染特征及成因

地下水氮元素污染是一个全球性的环境问题,其来源和迁移转化特征是国内外研究的热点。文章以新疆塔城盆地80组地下水样品水化学组分测试结果为依据,研究塔城盆地地下水“三氮”污染特征。结果表明:塔城盆地地下水质量总体较好;对比2017年发布的地下水质量标准,深层承压水“三氮”均未超标;浅层地下水“三氮”污染较轻,“三氮”超标点零星分布于地下水的中下游冲洪积平原区,其中,NO3-N超标率最高,超标率为8.8 %;NO2-N和NH4-N次之,超标率均为1.3 %。沿着地下水流向,从山区到盆地中央的平原区,地下水污染逐渐变重。“三氮”重污染点主要分布在塔城市、额敏县及其周边地区。区内地下水污染点的分布与工矿企业污染源、污水处理厂、垃圾填埋场等大型污染源的分布具有一定的相关性。城市化进程中,生活污水的不合理排放是塔城盆地“三氮”污染的主要来源,而通过排污河流下渗是研究区地下水“三氮”污染的重要途径;氧化还原条件、pH值、包气带岩性结构、补径排条件等是“三氮”迁移转化及其空间分布的主要影响因素。     

通过永定河渗漏补给地下水的适宜性评估研究

受气候变化和人类活动等因素的综合影响,地下水超采和含水层水量亏空已成为备受关注的全球性问题。为了弥补含水层水量亏空和促进地下水资源涵养,已探索出多种人为干预地下水补给的措施,其中通过河道开展地下水人工补给由于具有明显优势而受到重视。已有实践表明,受渗漏补给潜力和包气带调蓄能力等的限制,并不是所有河流或河段都适宜开展地下水人工补给工作。目前缺乏为大家广泛接受的适宜性评估方法。本研究以永定河生态补水为契机,以北京平原段河道和下伏含水层为研究区开展了案例研究,并用实测数据对研究结果进行了检验。应用指标体系法建立的适宜性评估模型（LMBGITSC模型）包括河床土地利用类型、河床介质类型、河床宽度、河床地形坡度、包气带介质类型、包气带厚度、包气带给水度、包气带水平渗透性等8个指标。案例研究结果表明,沿河流流向,通过河道渗漏补给地下水的适宜性由好变差（防渗河段除外）。该规律主要受渗漏补给潜力和包气带调蓄能力控制,因此适宜性也呈现出“阶梯式”演变规律。检验结果表明所建的评估方法适用性较好。该方法具有可移植性,因此也可为其他同类地区提供参考。     

黑河中游不同灌溉方式下地下水入渗补给特征研究

降水和人工灌溉是黑河中游浅层地下水重要的补给来源。长期以来入渗补给量评价采用经验参数法,但没有成熟的监测方法和实证数据。采用人工溴示踪法研究黑河中游不同灌溉条件和不同深度条件下的地下水入渗补给规律。结果表明:研究区大气降水条件下包气带溴离子含量峰值年均运移距离为21.25 cm,年平均入渗补给量为11.93 mm,入渗补给系数为0.1;大水漫灌条件下包气带溴离子含量峰值年均运移距离为86.51 cm,年平均入渗补给量为148.7 mm,入渗补给系数为0.16;小水漫灌条件下包气带溴离子含量峰值年均运移距离为46.35 cm,年平均入渗补给量为 53.81 mm,入渗补给系数为0.07;滴灌条件下年包气带溴离子含量峰值年均运移距离为41.72 cm,年平均入渗补给量为52.6 mm,入渗补给系数为0.11。人工溴示踪剂应投放在包气带水分单向入渗下行区,一般西北内陆盆地在地表3 m以下为宜。此研究成果可为黑河流域地下水资源评价提供实证参数,对西北内流盆地地下水水资源量与合理开发利用的科学认识具有重要意义。     

Characteristics of the main inorganic nitrogen accumulation in surface water and groundwater of wetland succession zones

Based on the observation of a complete hydrological year from June 2014 to May 2015, the temporal and spatial variations of the main inorganic nitrogen(MIN, referring to NO_3~--N, NO_2~--N, NH_4~+-N) in surface water and groundwater of the Li River and the Yuan River wetland succession zones are analyzed. The Li River and the Yuan River are located in agricultural and non-agricultural areas, and this study focus on the influence of surface water level and groundwater depth and precipitation on nitrogen pollution. The results show that NO_3~-N in surface water accounts for 70%-90% of MIN, but it does not exceed the limit of national drinking water surface water standard. Groundwater is seriously polluted by H_4~+-N. Based on the groundwater quality standard of H_4~+-N, the groundwater quality in the Li River exceeds Class III water standard throughout the year, and the exceeding months' proportion of Yuan River reaches 58.3%. Compared with the Yuan River, MIN in groundwater of the Li River shows significant temporal and spatial variations owing to the influence of agricultural fertilization. The correlation between the concentrations of MIN and surface water level is poor, while the fitting effect of quadratic correlation between H_4~+-N concentration and groundwater depth is the best(R~2=0.9384), NO_3~-N is the next(R~2=0.5128), NO_2~--N is the worst(R~2=0.2798). The equation of meteoric water line is δD =7.83δ~(18) O+12.21, indicating that both surface water and groundwater come from atmospheric precipitation. Surface infiltration is the main cause of groundwater H_4~+-N pollution. Rainfall infiltration in non-fertilization seasons reduces groundwater nitrogen pollution, while rainfall leaching farming and fertilization aggravate groundwater nitrogen pollution.     

北京怀柔地区入渗河水空间分布研究

河水入渗路径和范围对确定地下水补给条件,以及水资源调控和合理利用有着重要意义。针对2015年以来怀柔地区地下水水位回升现象,开展了地下水动态影响因素研究,采集了河水和地下水样品,测试了水化学和氢氧稳定同位素组成。δD-δ18 O数据表明该区有河水入渗补给地下水,河流附近地下水为地下水与入渗河水的混合物。利用地下水δ18O值以及二元混合模型计算了地下水中入渗河水的比例,揭示出地下水中河水占比减小方向与地下水水力梯度下降方向一致;局部河段附近地下水Cl-含量增加,表明河水入渗会引起地下水水质变化。入渗河水影响范围的圈定为评价入渗河水对地下水的影响提供了重要数据。该项工作对理解研究区地下水水文过程、控制因素以及水资源管理具有指导意义。     

昌源河国家湿地公园含水层水文地质特征研究

通过系统分析山西祁县昌源河中下游丘陵—平原地区沿河分布的19口钻井资料,查明了昌源河湿地中下游地区含水层的主要岩性,根据含/隔水层的埋深和发育特征将研究区第四系含水层划分了浅、中、深三个含水层组;并通过连井剖面和栅状图对比、总结了区内含水层的空间分布特征;同时,基于Arc GIS平台,采用Kriging插值法对地下水埋深进行了插值分析。结果表明昌源河流域含水层的主要岩石类型为第四系砂、砾石沉积物,在顺昌源河流向上浅部含水层为一楔状体,在横切河流方向上各含水层组厚度变化较大,这与研究区含水层组形成于冲/洪积扇沉积背景相符合。地下水埋深插值分析表明,昌源河流域中、下游平原区存在大面积的浅层地下水降落漏斗,这将会影响昌源河湿地公园及流域的生态水文过程。最后,在以上研究的基础上对昌源河流域地下水的补排关系进行了探讨,并建立了相应的补排模式。     

Application of electrical resistivity to map the stratigraphy and salinity of fluvio-deltaic aquifers: case studies from Bangladesh that reveal benefits and pitfalls

Fluvio-deltaic aquifers are the primary source of drinking water for the people of Bangladesh. Such aquifers, which comprise the Ganges-Brahmaputra-Meghna Delta, are hydrogeologically heterogeneous. Because of widespread groundwater quality issues in Bangladesh, it is crucial to know the hydrostratigraphic architecture and hydrochemistry, as some aquifer units are contaminated, whereas others are safe. Geophysical methods provide a potentially effective and noninvasive method for extensive characterization of these aquifers. This study applies and investigates the limitations of using electrical resistivity imaging (ERI) for mapping the hydrostratigraphy and salinity of an aquifer-aquitard system adjacent to the Meghna River. Some electrical resistivity (ER) sections showed excellent correlation between resistivity and grain size. These suggest that ERI is a powerful tool for mapping internal aquifer architecture and their boundaries with finer-grained aquitards which clearly appear as low-ER zones. However, in parts of some ER sections, variations in electrical properties were determined by porewater resistivity. In these cases, low ER was indicative of brine and did not indicate the presence of finer-grained materials such as silt or clay. Accordingly, the following hydrostratigraphic zones with different resistivities were detected: (1) aquifers saturated with fresh groundwater, (2) a regional silt/clay aquitard, and (3) a deeper brine-saturated formation. In addition, shallow silt/clay pockets were detected close to the river and below the vadose zone. ERI is thus a promising technique for mapping aquifers versus aquitards; however, the observations are easily confounded by porewater salinity. In such cases, borehole information and groundwater salinity measurements are necessary for ground-truthing.

     

Characteristics of the main inorganic nitrogen accumulation in surface water and groundwater of wetland succession zones

Based on the observation of a complete hydrological year from June 2014 to May 2015, the temporal and spatial variations of the main inorganic nitrogen (MIN, referring to NO3--N, NO2--N, NH4+-N) in surface water and groundwater of the Li River and the Yuan River wetland succession zones are analyzed. The Li River and the Yuan River are located in agricultural and non-agricultural areas, and this study focus on the influence of surface water level and groundwater depth and precipitation on nitrogen pollution. The results show that NO3--N in surface water accounts for 70%-90% of MIN, but it does not exceed the limit of national drinking water surface water standard. Groundwater is seriously polluted by NH4+-N. Based on the groundwater quality standard of NH4+-N, the groundwater quality in the Li River exceeds Class III water standard throughout the year, and the exceeding months’ proportion of Yuan River reaches 58.3%. Compared with the Yuan River, MIN in groundwater of the Li River shows significant temporal and spatial variations owing to the influence of agricultural fertilization. The correlation between the concentrations of MIN and surface water level is poor, while the fitting effect of quadratic correlation between NH4+-N concentration and groundwater depth is the best (R2=0.9384), NO3--N is the next (R2=0.5128), NO2--N is the worst (R2=0.2798). The equation of meteoric water line is δD =7.83δ18O+12.21, indicating that both surface water and groundwater come from atmospheric precipitation. Surface infiltration is the main cause of groundwater NH4+-N pollution. Rainfall infiltration in non-fertilization seasons reduces groundwater nitrogen pollution, while rainfall leaching farming and fertilization aggravate groundwater nitrogen pollution.     

River–groundwater connectivity in a karst system,Wellington, New South Wales,Australia

The characterization of river–aquifer connectivity in karst environments is difficult due to the presence of conduits and caves. This work demonstrates how geophysical imaging combined with hydrogeological data can improve the conceptualization of surface-water and groundwater interactions in karst terrains. The objective of this study is to understand the association between the Bell River and karst-alluvial aquifer at Wellington, Australia. River and groundwater levels were continuously monitored, and electrical resistivity imaging and water quality surveys conducted. Two-dimensional resistivity imaging mapped the transition between the alluvium and karst. This is important for highlighting the proximity of the saturated alluvial sediments to the water-filled caves and conduits. In the unsaturated zone the resistivity imaging differentiated between air- and sediment-filled karst features, and in the saturated zone it mapped the location of possible water- and sediment-filled caves. Groundwater levels are dynamic and respond quickly to changes in the river stage, implying that there is a strong hydraulic connection, and that the river is losing and recharging the adjacent aquifer. Groundwater extractions (1,370 ML, megalitres, annually) from the alluvial aquifer can cause the groundwater level to fall by as much as 1.5 m in a year. However, when the Bell River flows after significant rainfall in the upper catchment, river-leakage rapidly recharges the alluvial and karst aquifers. This work demonstrates that in complex hydrogeological settings, the combined use of geophysical imaging, hydrograph analysis and geochemical measurements provide insights on the local karst hydrology and groundwater processes, which will enable better water-resource and karst management.