浙江土壤矿物组成特征

对浙江省29种母质和16种土类或亚类构成的69个母质一土类单元共194个土壤样品中的矿物成分进行测定，分析得出矿物种类及矿物百分含量。在此基础上分析了浙江省土壤矿物组成特征。不同土类或亚类土壤中矿物组成存在明显差异，矿物种数和含量变化较大。突出的特征是，相同母质类型土壤含有相似的矿物种类，而且相同母质不同样品中同一矿物含量变化也较小，表现出同母质土壤矿物组成与含量具有相似性。在69个土壤剖面中，由A层到C层矿物种类和含量变化较小，土壤矿物组成明显受基岩影响和控制。宜把地质背景相同、矿物组成相近、土壤环境相似的成土母质作为划分土壤重金属污染评价单元，土壤类型只能作为评价单元的辅助划分依据。     

内蒙古鄂伦春旗土壤钼元素的分布特征及主要影响因素

钼元素是动植物生长必需的微量元素,生命体中的钼元素直接或间接来自土壤.依据内蒙古自治区鄂伦春旗东部主要耕地区1：25万土地质量地球化学调查项目所采集的土壤样品分析数据,对研究区内表层土壤钼含量进行了营养等级评价.鄂伦春旗东部地区土壤钼含量普遍达到丰富级以上.同时分析了地球化学指标、土壤类型、成土母质等对土壤钼含量的影响.认为钼含量在pH值为5～7之间时随pH增大而减小;在有机质含量20×10^-3～140×10^-3时,随有机质含量增加而减少.认为暗棕壤及其对应的成土母质为本区提供了钼的来源;提出了研究区内土壤钼主要来源于基岩风化的结论.     

安徽江淮地区土壤微量元素分布特征及成因分析

多目标区域地球化学调查作为生态地球化学调查的基础工作,以快速查明表层土壤及其背景地球化学元素分布为目的.本文以安徽江淮地区多目标区域地球化学调查结果为基础,对安徽江淮地区耕地土壤及其母质中主要元素分布特征及其成因进行了分析研究,结果得出:(1)大多数地区表层土壤微量元素含量与深层具有一致性和继承性;(2)各地土壤微量元素分布特征主要受成土母质类型控制,说明其成因与成土母质和成土过程等因素有关;(3)耕地土壤微量元素含量的变异受施肥、灌溉和耕作方式等人为因素影响较大,且存在较大的地区差异性.     

中高山区土壤成土母质理化特征及主控因素初探——以西昌市为例

为探讨中高山区土壤及成土母质理化特征及其控制因素,本文以四川省西昌市为例,系统性总结了该地区的地质建造背景,并在基于地质建造背景划分的成土母质类型基础上,讨论了成土母质、土壤的物理化学性质、土壤含水率、pH值、高程等之间的关系,通过对不同成土母质发育的同种土壤的数据分析及营养元素含量评价,我们认为地质建造背景直接制约了成土母质及土壤的物理化学性质,营养元素在成土母质—土壤之间的迁移存在继承性。本文研究成果为中高山区土壤类型和成土母质之间的关系以及成土母质单元划分方案提供理论依据。     

福建龙海土壤垂向剖面元素分布特征

基于福建省龙海市4类典型成土母质的垂向土壤剖面样品分析数据,研究了常量组分和微量元素含量及剖面分布特征。结果表明:研究区在温暖湿润气候条件下,化学风化作用强烈,Ca、Mg、Na、Si、K淋失贫化,含量明显低于全国均值,Al、Fe则相对富集,风化淋溶系数(ba)和硅铝铁率(Saf)值远低于全国土壤,土壤风化程度达到脱硅富铝铁阶段,花岗岩类成土母岩区风化作用尤为强烈;剖面土壤环境质量总体较好,微量元素含量与成土母质密切有关,九龙江口冲海积成因(剖面1)土壤重金属含量明显高于其他3个剖面;多数微量元素垂向分布受常量组分的控制,As、Cd、Cu、Hg、Pb、Zn与土壤中Fe等组分具有显著正相关性。因表层土壤中细粒黏质组分随地表径流淋失或下渗迁移,导致表层土壤低Fe、Al和重金属元素;在生物地球化学循环和人为污染的影响下,Hg、Cd、Pb、Zn等在表层土壤呈富集特征;多数重金属元素的相对富集系数小于1.0,且表层土壤无明显富集特征,认为除Hg、Pb等少数重金属元素外,其他元素受人为污染影响较小。     

雷州半岛土壤地球化学背景值研究

基于雷州半岛多目标区域地球化学调查数据资料,计算了该区的土壤地球化学背景值,并对背景值特征及分布进行了探讨.结果表明:雷州半岛土壤富集B、CaO、Ti、Cd、Se、V、Zr等,贫乏Th、Corg(有机碳)、U、I、Mn、K2O、Co、Tl、Rb、Mo等指标,表层土壤呈酸性背景;不同成土母质土壤背景值差异明显,以玄武岩风化物为成土母质的土壤富集铁族元素,以花岗岩风化物为成土母质的土壤富集钨钼族元素、放射性元素、稀有稀土元素等.雷州半岛不同区域元素分布差异性较大,第四纪以来强烈的火山喷发活动、海侵海退与河流冲洪积交互作用,是控制雷州半岛土壤元素迁移转化的最主要因素.     

宁夏南部山区葫芦河流域土壤地球化学特征及影响因素分析

基于宁夏固原地区土地质量地球化学调查数据资料,采用数理统计方法研究了表层土壤30项元素(指标)的背景值,对比分析了不同成土母质(岩)和土地利用类型元素空间分布特征和富集贫化规律,进一步采用主成分分析法从元素组合特征的角度分析了制约元素分布特征的因素。结果表明：研究区土壤中亲铁元素(Ni)、亲钨元素(Mo)、碱(土)金属元素(Na₂O、MgO、CaO)及卤族元素(I、F)、亲铜元素(As)含量高于全国背景值,Hg、Se、有机质、N、Pb等亲生物元素与全国背景值相比相对贫化。成土母质(母岩)是土壤元素含量特征的主要控制因素,在成土过程中,自然及人为影响造成了部分元素的贫化富集。N、Mo、I、有机质、S等受红土母质和其母岩控制明显,Ca²⁺、Na~+则在水动力影响下造成风化淋失。河谷平原土壤元素含量介于红土和黄土母质之间,在表生环境下易溶于水的Na₂O、K₂O、Cl在水动力的作用下于河口、河谷地带富集,P、Hg、Se、Mo则受人为干扰出现局部富集。因子分析表明,成土母质(岩)、成土过程中的风化、淋滤、生物...     

基于地质建造的西南山区成土母质分类方案——以大凉山区为例

为适应生态地质调查和评价工作对成土母质研究的要求,以四川大凉山区为例,提出基于地质建造的成土母质分类方案,即以地质构造演化和地质建造环境为依据,结合残坡积物的成因类型对成土母质进行分类。大凉山区的成土母质可划分为第四纪冲洪积物、新近纪—第四纪砂泥岩类残坡积物、侏罗纪—白垩纪泥质岩类残坡积物、三叠纪砂泥岩类残坡积物、中生代中酸性岩类残坡积物、二叠纪基性—超基性岩类残坡积物、震旦纪—三叠纪砂泥岩类残坡积物、震旦纪—三叠纪碳酸盐岩类残坡积物、元古宙中酸性岩类残坡积物、元古宙火山碎屑岩类残坡积物、元古宙基性—超基性岩类残坡积物、元古宙变质岩类残坡积物等12类。研究表明,大凉山区成土母质和土壤存在差异性,但同一成土母质上的不同土壤类型具有一定相似的地球化学特征,不同成土母质形成的同一种土壤类型存在较大的地球化学差异。因此,基于地质建造的成土母质分类方案既能有效反映不同构造背景和成岩环境下的成土母质差异,又能有效表征成土母质与其上土壤的内在联系。     

河南新郑枣区土壤地球化学研究

对比研究了地球化学景观环境、第四系、成土母质和土壤等的地球化学特征与新郑枣品质和产量的关系。研究表明,覆砂的岗丘是优质新郑枣适生的地球化学环境。典型的地质背景、第四系沉积物组构、成土母质和土壤等综合生态地球化学要素影响了新郑枣的品质和产量。区内中上更新统中发育古土壤层,是枣树生产期有益元素聚集的地球化学障和潜藏的有益元素的地球化学库,在某种程度上决定了枣的品质和产量。本区土壤和土体中多种有益营养元素含量偏低,处于缺乏状态。     

土壤矿物学研究综述

土壤矿物是土壤物质组成的主体 ,是土壤微量元素的主要来源。土壤矿物的研究是土壤学研究的前沿基础领域。通过对土壤矿物尤其是粘土矿物的研究 ,可以揭示土壤的发生学特性、母质特征、成土过程及环境 ,揭示土壤的发育程度和肥力水平 ,为环境保护、优质生产和土壤改良提供基础依据。本文指出了土壤矿物学的研究意义 ,综述了土壤矿物学的研究进展 ,总结了不同类型土壤矿物的组成特征及其与成土作用、风化程度和生物气候条件间的变化规律     

侧向土体耦合作用对土层地震反应的影响

把侧向土体耦合作用简化为一个弹性系数为k的弹簧和一个阻尼系数为η的线性阻尼器并联作用，建立了考虑耦合作用静止边界－一维土层地震反应波动方程，并给出了其完全解析解，为进一步分析侧向土体耦合作用对土层地震反应的影响，土层密度统一取1900kg/m^3，针对不同的土层厚度：10，20，30米，不同的剪切模量：42．75MPa(剪切波速150m/s)，118．75MPa(剪切波速250m/s),232.75MPa(剪切波速350m/s),k,η分别取不同的数值，进行土层地震反应计算，计算结果表明，k,η对地震动位移峰值，速度峰值影响较小，k对地震动加速峰值影响较大，k减少加速度峰值增大，k增大加速度峰值减少，最大影响程度可达15％以上，η对地震动加速度峰值影响较大，η减少加速度峰值增大；η增大加速度峰值减小，最大影响程度可达25％以上。     

Laboratory tests on soil conditioning of clayey soil

Tunnelling in difficult and challenging conditions such as soft soils in urban areas is increasing. In this condition, it is important to minimise the possible negative effect of the tunnel excavation, such as settlement or, in the worst case, collapses. To achieve this result, earth pressure balance machines are commonly used. One of the key parameters that must be considered for an optimal management of the EPB-TBM excavation is soil conditioning since the excavated muck must properly transmit the pressure to the tunnel face. Soil conditioning is also necessary to reduce the effect of the problems, such as clogging in clay layers, that can occur during the excavation and that can affect the performance of the tools and of the entire tunnelling process. For this reason, in the last decade, much research has been carried out to understand how to deal with and reduce the effects of clogging and stickiness, using different conditioning additives. These studies have proposed several different test procedures to evaluate the effect of the conditioning on the adhesion of the soil on the metallic parts of the machines. The present research has been carried out with the aim of proposing a new approach and new devices to study clay conditioning with laboratory tests, and the results of many tests carried out with the proposed device are presented and discussed.     

离子土壤固化剂改性膨胀土的试验研究

利用离子土壤固化剂（ionic soil stabilizer,简称ISS）对河南安阳地区膨胀土进行化学改性试验研究,通过不同配比的自由膨胀率试验结果,结合施工成本,得出ISS溶液改良膨胀土的最优配合比为1:350。对ISS溶液最优配合比改性后土体进行收缩试验、膨胀性试验、固结快剪、高压固结及水浸泡试验。试验结果表明,改性土线缩率减小,膨胀性指标降低,抗剪强度增大,土体由亲水性变成憎水性,且能达到较好的水稳定性,即膨胀土经化学改性为非膨胀土。ISS改性膨胀土的机制可解释为,通过ISS溶液与土粒离子进行强烈的交换作用,打开土粒与水分子之间的“电化键”,降低土颗粒表面吸附水膜厚度,包裹在黏粒颗粒表面的疏水基团覆盖膜使土对水的敏感性减弱,从根本上减少了土体吸水性和膨胀性。     

Surface history of lunar soil and soil columns

Measurements of cosmic ray track densities are presented for soil samples from Apollo 15, 16 and 17. Median track densities are used to infer total effective exposure times within ~15 cm of the lunar surface. Minimum track densities are used to derive the time of the last impact-produced rearrangement of soil grains. For samples from near various craters ages are derived of 40 m.y. for St. George, 6 (±3) m.y. for S. Ray, 25–90 m.y. for Plum, and 20–35 m.y. for Shorty. The material of 15003. the Apollo 15 deep core at depths of 120–160 cm, is inferred to have been deposited at an average rate of ≥0.35 cm/m.y. The Apollo 16 core at 41–47 cm depths. 60007, appears to be well mixed and was covered up by deposition at 0.3 cm/m.y. for the next few m.y. after its deposition.     

月壤及模拟月壤微观结构的研究

为了对比研究月壤与模拟月壤的微观结构,介绍了月壤的形成作用过程和5种基本颗粒类型;通过真实月壤照片,对月壤微观结构进行了分析;利用火山灰为模拟月壤主体材料,对其成分进行了检测;对模拟月壤的火山灰颗粒进行了显微图像分析试验。结果表明,月壤存在胶结物微观颗粒,胶结物颗粒具有分支的组织形态和封闭的气泡,并且有金属铁珠存在;火山灰所含的主要成分及含量与月壤相似,经过粉碎的火山灰试样棱角较为明显,其纵横比峰值略小,稍显长条状,但与月壤比较相近,而复杂度因子则略有欠缺,说明颗粒还不够粗糙和多棱     

水泥基土壤固化剂固化土的物理化学作用

采用击实试验、液塑限联合测定界限含水率试验、蜡封法测定干密度试验、二氧化碳气量法、交换性钠离子百分比试验等方法,结合黏土矿物组成与结构特点,研究了水泥基土壤固化剂固化土的物理化学作用。试验结果表明：随着固化剂剂量的增加,混合料的最大干密度增大,最优含水率降低;固化土混合料经过养护后,塑性指数降低,干密度增大,碳酸盐含量增加,交换性钠离子百分比升高;黏土矿物在强碱性和钙离子作用下被激活,形成各种水化硅酸盐和铝酸盐。研究认为：在土-固化剂-水-气系统中通过液相和气相向固相的转变以及各类水化产物的填充、挤密、胶结等作用,混合料逐渐形成较致密的整体;离子交换反应对土体的加固作用在后期起负效应;铝硅酸盐黏土矿物在强碱性和钙离子存在条件下被分解,参与水化硅酸盐和铝酸盐的反应。     

Volume-based soil particle fractal relation with soil erodibility in a small watershed of purple soil

The particle size distribution in small watershed changes under different land uses and affects soil erodibility. The aims of this study were (1) to investigate the volume fractal dimension of particle size distribution under different land uses in a typical small watershed of purple soil, (2) to estimate soil erodibilities of various land uses utilizing the Erosion-Productivity Impact Calculator (EPIC) model and the nomogram (NOMO) model, and (3) to relate volume fractal dimension with the soil erodibility used in the Universal Soil Loss Equation (USLE) in purple soil areas. Laser diffractions and double-logarithmic model were used to measure and calculate volume fractal dimension values. The results show that soil volume fractal dimensions were well linearly fitted to the double-logarithmic model with high correlation coefficients of 0.902–0.936 under six land uses in the small watershed. The averaged volume fractal dimension values under different land uses, from high to low were in the order of Zea mays L, Ipomoea batatas, Citrus reticulata Blanco, Setaria viridis, Robinia pseudoacacia L, Pinus massoniana Lamb. The volume fractal dimension was positively correlated to clay particle fraction (R = 0.933). The average soil erodibility values under different land uses from high to low were in the order of Setaria viridis, Citrus reticulata Blanco, Pinus massoniana Lamb, Zea mays L, Ipomoea batatas, Robinia pseudoacacia L while average soil erodibilities from high to low values were in the order of Setaria viridis, Citrus reticulata Blanco, Zea mays L, Ipomoea batatas, Pinus massoniana Lamb, Robinia pseudoacacia L. The soil erodibilities calculated by the two models were similar, and positively correlated (R = 0.630–0.877). The volume fractal dimension values of six land uses were negatively correlated to both soil erodibility estimated by EPIC and by NOMO models. Moreover, the correlations of the volume fractal dimension values of Zea mays L, Ipomoea batatas and Citrus reticulata Blanco estimated by EPIC or NOMO were lower than those of Pinus massoniana Lamb, Robinia pseudoacacia L and Setaria viridis. Further research is needed to determine the influence of volume fractal dimension on the soil erodibility under different land use and managements.     

Tropical residual soil as compacted soil liners

A series of laboratory tests was conducted on a tropical residual soil, which is widespread and readily available over a considerable part of Peninsular Malaysia, to assess whether it could be compacted as hydraulic barriers in waste disposal landfills. Index properties, swelling potential, cation exchange capacity (CEC), compaction characteristics, and hydraulic conductivity of the soil indicate that it is inorganic, very plastic, inactive (activity <0.75), moderately expansive (modified free swell index is about 3.06), and of fair attenuation capacity (for inorganic contaminants). For hydraulic conductivity measurement, the soil was compacted in rigid-wall permeameter moulds at a variety of water contents and compactive efforts and then permeated with de-aired tap water. The results of hydraulic conductivity tests illustrate that hydraulic conductivity lower than 1×10^–7 cm/s can be achieved using a broad range of water contents and compactive efforts, including water contents dry of optimum. Its shrinkage and strength properties show that it has minimal potential to shrinkage and has adequate strength to support the overburden pressure imposes by the waste body. These findings suggest that the residual soil can be potentially utilized as compacted soil liner material.     

土壤酶对碘离子在土壤中吸附行为的影响

以批式试验法研究了微生物、葡萄糖氧化酶、脲酶、纤维素酶及其催化底物葡萄糖、尿素和纤维素对Ⅰ-在土壤中吸附的影响,结果表明微生物能显著提高Ⅰ-吸附量,但葡萄糖氧化酶、脲酶、纤维素酶及葡萄糖、尿素和纤维素对Ⅰ-吸附并无促进作用.葡萄糖氧化酶及葡萄糖含量在小于100 mg/L时对Ⅰ-吸附无影响,1000 mg/L时与Ⅰ-呈竞争吸附;脲酶及尿素随浓度增大,对Ⅰ-吸附的抑制作用变得明显;1～1000 mg/L范围内,纤维素酶和纤维素对Ⅰ-吸附没有影响;但葡萄糖氧化酶和葡萄糖生成的中间产物可促进土壤对Ⅰ-的吸附.平衡液中溶解性有机碳(DOC)含量随时间增加而逐渐降低,有机质浓度越大,降低趋势越明显.     

Simulation of liquefaction of unsaturated soil using critical state soil model

Several researchers have reported that the mean effective stress of unsaturated soils having a relatively high degree of saturation gradually decreases under fully undrained cyclic loading conditions, and such soils can be finally liquefied like saturated soils. This paper describes a series of simulations of fully undrained cyclic loading on unsaturated soils, conducted using an elastoplastic model for unsaturated soils. This model is a critical state soil model formulated using effective stress tensor for unsaturated soils, which incorporates the following concepts: (a) the volumetric movement of the state boundary surface containing the critical state line owing to the variation in the degree of saturation; (b) the soil water characteristic curve considering the effects of specific volume and hydraulic hysteresis; and (c) the subloading surface concept for considering the effect of density. Void air is assumed to be an ideal gas obeying Boyle's law. The proposed model is validated through comparisons with past results. The simulation results show that the proposed model properly describes the fully undrained cyclic behavior of unsaturated soils, such as liquefaction, compression, and an increase in the degree of saturation. Finally, the effects of the degree of saturation, void ratio, and confining pressure on the cyclic strength of unsaturated soils are described by the simulation results. The liquefaction resistance of unsaturated soils increases as the degree of saturation and the void ratio decrease, and as the confining pressure increases. Furthermore, the degree of saturation has a greater effect on the liquefaction resistance than the confining pressure and void ratio. Copyright © 2017 John Wiley & Sons, Ltd.